SG11201703849QA - Methods of changing polyolefin production rate with the composition of the induced condensing agents - Google Patents

Methods of changing polyolefin production rate with the composition of the induced condensing agents

Info

Publication number
SG11201703849QA
SG11201703849QA SG11201703849QA SG11201703849QA SG11201703849QA SG 11201703849Q A SG11201703849Q A SG 11201703849QA SG 11201703849Q A SG11201703849Q A SG 11201703849QA SG 11201703849Q A SG11201703849Q A SG 11201703849QA SG 11201703849Q A SG11201703849Q A SG 11201703849QA
Authority
SG
Singapore
Prior art keywords
composition
methods
production rate
condensing agents
polyolefin production
Prior art date
Application number
SG11201703849QA
Inventor
Bruce J Savatsky
Brandon C Locklear
R Eric Pequeno
Abarajith S Hari
David M Glowczwski
Original Assignee
Univation Tech Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Univation Tech Llc filed Critical Univation Tech Llc
Publication of SG11201703849QA publication Critical patent/SG11201703849QA/en

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/0015Feeding of the particles in the reactor; Evacuation of the particles out of the reactor
    • B01J8/003Feeding of the particles in the reactor; Evacuation of the particles out of the reactor in a downward flow
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/005Separating solid material from the gas/liquid stream
    • B01J8/0055Separating solid material from the gas/liquid stream using cyclones
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/005Separating solid material from the gas/liquid stream
    • B01J8/006Separating solid material from the gas/liquid stream by filtration
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/1809Controlling processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/1818Feeding of the fluidising gas
    • B01J8/1827Feeding of the fluidising gas the fluidising gas being a reactant
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/1836Heating and cooling the reactor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/24Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/34Polymerisation in gaseous state
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008Controlling the process
    • B01J2208/00017Controlling the temperature
    • B01J2208/00026Controlling or regulating the heat exchange system
    • B01J2208/00035Controlling or regulating the heat exchange system involving measured parameters
    • B01J2208/00044Temperature measurement
    • B01J2208/00053Temperature measurement of the heat exchange medium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008Controlling the process
    • B01J2208/00017Controlling the temperature
    • B01J2208/00026Controlling or regulating the heat exchange system
    • B01J2208/00035Controlling or regulating the heat exchange system involving measured parameters
    • B01J2208/00044Temperature measurement
    • B01J2208/00061Temperature measurement of the reactants
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008Controlling the process
    • B01J2208/00017Controlling the temperature
    • B01J2208/00106Controlling the temperature by indirect heat exchange
    • B01J2208/00265Part of all of the reactants being heated or cooled outside the reactor while recycling
    • B01J2208/00274Part of all of the reactants being heated or cooled outside the reactor while recycling involving reactant vapours
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008Controlling the process
    • B01J2208/00548Flow
    • B01J2208/00557Flow controlling the residence time inside the reactor vessel
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008Controlling the process
    • B01J2208/00628Controlling the composition of the reactive mixture
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008Controlling the process
    • B01J2208/00628Controlling the composition of the reactive mixture
    • B01J2208/00637Means for stopping or slowing down the reaction
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00796Details of the reactor or of the particulate material
    • B01J2208/00946Features relating to the reactants or products
    • B01J2208/00955Sampling of the particulate material, the reactants or the products
    • B01J2208/00982Particulate material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00796Details of the reactor or of the particulate material
    • B01J2208/00991Disengagement zone in fluidised-bed reactors
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049Controlling or regulating processes
    • B01J2219/00191Control algorithm
    • B01J2219/00193Sensing a parameter
    • B01J2219/00195Sensing a parameter of the reaction system
    • B01J2219/002Sensing a parameter of the reaction system inside the reactor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049Controlling or regulating processes
    • B01J2219/00191Control algorithm
    • B01J2219/00211Control algorithm comparing a sensed parameter with a pre-set value
    • B01J2219/00213Fixed parameter value
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049Controlling or regulating processes
    • B01J2219/00191Control algorithm
    • B01J2219/00222Control algorithm taking actions
    • B01J2219/00227Control algorithm taking actions modifying the operating conditions
    • B01J2219/00238Control algorithm taking actions modifying the operating conditions of the heat exchange system
SG11201703849QA 2014-11-25 2015-11-24 Methods of changing polyolefin production rate with the composition of the induced condensing agents SG11201703849QA (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201462084271P 2014-11-25 2014-11-25
PCT/US2015/062465 WO2016086006A1 (en) 2014-11-25 2015-11-24 Methods of changing polyolefin production rate with the composition of the induced condensing agents

Publications (1)

Publication Number Publication Date
SG11201703849QA true SG11201703849QA (en) 2017-06-29

Family

ID=54848903

Family Applications (1)

Application Number Title Priority Date Filing Date
SG11201703849QA SG11201703849QA (en) 2014-11-25 2015-11-24 Methods of changing polyolefin production rate with the composition of the induced condensing agents

Country Status (8)

Country Link
US (1) US10174142B2 (en)
EP (1) EP3224284A1 (en)
CN (1) CN107018663A (en)
BR (1) BR112017010363B1 (en)
CA (1) CA2967417C (en)
RU (1) RU2696875C2 (en)
SG (1) SG11201703849QA (en)
WO (1) WO2016086006A1 (en)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2016085896A1 (en) * 2014-11-25 2016-06-02 Univation Technologies, Llc Methods of controlling polyolefin melt index while increasing catalyst productivity
WO2018063764A1 (en) * 2016-09-27 2018-04-05 Exxonmobil Chemical Patents Inc. Polymerization process
EP3519446B1 (en) 2016-09-27 2021-05-19 ExxonMobil Chemical Patents Inc. Polymerization process
BR112019005989B1 (en) 2016-09-27 2023-05-02 Exxonmobil Chemical Patents Inc POLYMERIZATION PROCESS
BR112019005991B1 (en) 2016-09-27 2023-05-09 Exxonmobil Chemical Patents Inc POLYMERIZATION PROCESS
EP3559051B1 (en) 2016-12-20 2021-03-24 ExxonMobil Chemical Patents Inc. Polymerization process
US20220119563A1 (en) * 2019-03-21 2022-04-21 Exxonmobil Chemical Patents Inc. Methods For Improving Production In Gas Phase Polymerization
WO2020190510A1 (en) * 2019-03-21 2020-09-24 Exxonmobil Chemical Patents Inc. Methods for improving gas phase polymerization
US11958906B2 (en) 2022-04-13 2024-04-16 Genentech, Inc. Pharmaceutical compositions of mosunetuzumab and methods of use

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NZ235032A (en) 1989-08-31 1993-04-28 Dow Chemical Co Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component
US5026798A (en) 1989-09-13 1991-06-25 Exxon Chemical Patents Inc. Process for producing crystalline poly-α-olefins with a monocyclopentadienyl transition metal catalyst system
US5747406A (en) 1997-01-10 1998-05-05 Union Carbide Chemicals & Plastics Technology Corporation Catalyst composition for the production of olefin polymers
US6242545B1 (en) 1997-12-08 2001-06-05 Univation Technologies Polymerization catalyst systems comprising substituted hafinocenes
FR2772383B1 (en) * 1997-12-16 2000-02-04 Bp Chemicals Snc PROCESS FOR STARTING A GASEOUS OLEFIN POLYMERIZATION
US6069213A (en) 1997-12-16 2000-05-30 Union Carbide Chemicals & Plastics Technology Corporation Mixed catalyst system
US6894131B2 (en) 1998-08-21 2005-05-17 Univation Technologies, Llc Polymerization process using a metallocene catalyst system
US6391986B1 (en) 2000-12-05 2002-05-21 Union Carbide Chemicals & Plastics Technology Corporation Control of solution catalyst droplets
US7244795B2 (en) 2003-12-08 2007-07-17 Univation Technologies, Llc Polymerization process using metallocene catalyst systems
US20050182207A1 (en) * 2003-12-23 2005-08-18 Diwaker Singh Gas-phase process
US7410926B2 (en) 2003-12-30 2008-08-12 Univation Technologies, Llc Polymerization process using a supported, treated catalyst system
US7157531B2 (en) 2004-06-21 2007-01-02 Univation Technologies, Llc Methods for producing polymers with control over composition distribution
US20070060724A1 (en) 2005-09-13 2007-03-15 Nova Chemicals Corporation And Innovene Europe Ltd. Enhanced catalyst productivity
US7696289B2 (en) * 2006-05-12 2010-04-13 Exxonmobil Chemical Patents Inc. Low molecular weight induced condensing agents
AU2007293486A1 (en) * 2006-09-07 2008-03-13 Univation Technologies, Llc Methods for on-line determination of degree of resin stickiness using a model for depression of melt initiation temperature
CN102947351B (en) * 2010-05-27 2014-09-17 沙特基础工业公司 Olefin gas phase polymerisation
CN108106968B (en) 2012-09-07 2020-09-25 尤尼威蒂恩技术有限责任公司 System for controlling a polymerization reactor
US9718896B2 (en) 2012-09-07 2017-08-01 Univation Technologies, Llc Controlling a polyolefin reaction

Also Published As

Publication number Publication date
BR112017010363B1 (en) 2022-05-10
RU2696875C2 (en) 2019-08-07
CA2967417A1 (en) 2016-06-02
CA2967417C (en) 2023-09-12
WO2016086006A1 (en) 2016-06-02
CN107018663A (en) 2017-08-04
RU2017120186A3 (en) 2019-06-11
EP3224284A1 (en) 2017-10-04
US10174142B2 (en) 2019-01-08
BR112017010363A2 (en) 2017-12-26
RU2017120186A (en) 2018-12-10
US20170355791A1 (en) 2017-12-14

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