SG11201507100UA - Carbonylation process - Google Patents

Carbonylation process

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Publication number
SG11201507100UA
SG11201507100UA SG11201507100UA SG11201507100UA SG11201507100UA SG 11201507100U A SG11201507100U A SG 11201507100UA SG 11201507100U A SG11201507100U A SG 11201507100UA SG 11201507100U A SG11201507100U A SG 11201507100UA SG 11201507100U A SG11201507100U A SG 11201507100UA
Authority
SG
Singapore
Prior art keywords
carbonylation process
carbonylation
Prior art date
Application number
SG11201507100UA
Inventor
Evert Jan Ditzel
Bogdan Costin Gagea
David John Law
John Glenn Sunley
Original Assignee
Bp Chem Int Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bp Chem Int Ltd filed Critical Bp Chem Int Ltd
Publication of SG11201507100UA publication Critical patent/SG11201507100UA/en

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    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00Preparation of carboxylic acid esters
    • C07C67/36Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
    • C07C67/37Preparation of carboxylic acid esters by reaction with carbon monoxide or formates by reaction of ethers with carbon monoxide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/18Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/18Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
    • B01J29/185Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/18Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
    • B01J29/20Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type containing iron group metals, noble metals or copper
    • B01J29/24Iron group metals or copper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/65Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38, as exemplified by patent documents US4046859, US4016245 and US4046859, respectively
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7015CHA-type, e.g. Chabazite, LZ-218
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7026MFS-type, e.g. ZSM-57
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/87Gallosilicates; Aluminogallosilicates; Galloborosilicates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08Heat treatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/30Ion-exchange
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/26Mordenite type
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/50Zeolites wherein inorganic bases or salts occlude channels in the lattice framework, e.g. sodalite, cancrinite, nosean, hauynite
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/09Preparation of carboxylic acids or their salts, halides or anhydrides from carboxylic acid esters or lactones
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/02Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen
    • C07C69/12Acetic acid esters
    • C07C69/14Acetic acid esters of monohydroxylic compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10After treatment, characterised by the effect to be obtained
    • B01J2229/14After treatment, characterised by the effect to be obtained to alter the inside of the molecular sieve channels
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10After treatment, characterised by the effect to be obtained
    • B01J2229/18After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30After treatment, characterised by the means used
    • B01J2229/42Addition of matrix or binder particles
SG11201507100UA 2013-03-08 2014-03-06 Carbonylation process SG11201507100UA (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP13158469 2013-03-08
PCT/EP2014/054395 WO2014135662A1 (en) 2013-03-08 2014-03-06 Carbonylation process

Publications (1)

Publication Number Publication Date
SG11201507100UA true SG11201507100UA (en) 2015-10-29

Family

ID=47827087

Family Applications (1)

Application Number Title Priority Date Filing Date
SG11201507100UA SG11201507100UA (en) 2013-03-08 2014-03-06 Carbonylation process

Country Status (12)

Country Link
US (1) US9598347B2 (en)
EP (1) EP2964379A1 (en)
JP (1) JP2016514105A (en)
KR (1) KR20150125720A (en)
CN (1) CN105339084B (en)
BR (1) BR112015021851A2 (en)
CA (1) CA2903134A1 (en)
RU (1) RU2658820C2 (en)
SG (1) SG11201507100UA (en)
TW (1) TW201441188A (en)
UA (1) UA120086C2 (en)
WO (1) WO2014135662A1 (en)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20150126850A (en) * 2013-03-08 2015-11-13 비피 케미칼즈 리미티드 Carbonylation catalyst and process
US10053403B2 (en) 2015-02-04 2018-08-21 Exxonmobil Chemical Patents Inc. Catalyst compositions and their use in transalkylation of heavy aromatics to xylenes
CA2983038C (en) * 2015-02-04 2023-01-31 Exxonmobil Chemical Patents Inc. Process for preparing a molecular sieve
US10118165B2 (en) 2015-02-04 2018-11-06 Exxonmobil Chemical Patents Inc. Catalyst compositions and use in heavy aromatics conversion processes
CN106365995B (en) * 2015-07-20 2018-06-05 中国科学院大连化学物理研究所 A kind of production method of methyl acetate
RU2739320C2 (en) * 2016-04-19 2020-12-22 Бп Кемикэлз Лимитед Carbonylation method for producing methyl acetate
CN107376987B (en) * 2016-05-16 2020-06-26 天津大学 Double-template method for synthesizing mordenite molecular sieve catalyst and application thereof in methanol/dimethyl ether carbonylation reaction
US9938217B2 (en) 2016-07-01 2018-04-10 Res Usa, Llc Fluidized bed membrane reactor
WO2018004992A1 (en) 2016-07-01 2018-01-04 Res Usa, Llc Conversion of methane to dimethyl ether
WO2018004993A1 (en) 2016-07-01 2018-01-04 Res Usa, Llc Reduction of greenhouse gas emission
JP2019536774A (en) 2016-11-30 2019-12-19 ビーエーエスエフ ソシエタス・ヨーロピアBasf Se Method for converting monoethanolamine to ethylenediamine using copper-modified zeolite having a MOR skeleton structure
EP3573949B1 (en) 2016-11-30 2021-10-13 Basf Se Process for the conversion of monoethanolamine to ethylenediamine employing a nanocrystalline zeolite of the mor framework structure
JP2020503261A (en) 2016-11-30 2020-01-30 ビーエーエスエフ ソシエタス・ヨーロピアBasf Se Method for converting ethylene glycol to ethylenediamine using zeolite catalyst
GB201705882D0 (en) 2017-04-12 2017-05-24 Bp Chem Int Ltd Process
CN109092348B (en) * 2017-06-20 2020-12-25 天津大学 Mordenite molecular sieve catalyst, preparation method thereof and application thereof in carbonylation synthesis of methyl acetate
EP3909675A1 (en) 2020-05-11 2021-11-17 Bp P.L.C. Process and catalyst for the preparation of ethylene
CN114516640B (en) * 2020-11-18 2024-04-16 中国科学院大连化学物理研究所 Mordenite, preparation method and application thereof
CN115108565B (en) * 2022-08-29 2022-11-25 中国科学院山西煤炭化学研究所 Hydrogen-type FER molecular sieve and preparation method and application thereof

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US4229424A (en) 1979-04-09 1980-10-21 Mobil Oil Corporation Crystalline zeolite product constituting ZSM-5/ZSM-11 intermediates
US4612387A (en) 1982-01-04 1986-09-16 Air Products And Chemicals, Inc. Production of carboxylic acids and esters
US5164170A (en) * 1991-06-14 1992-11-17 Mobil Oil Corporation Synthesis of zeolite Beta
GB0409490D0 (en) * 2004-04-28 2004-06-02 Bp Chem Int Ltd Process
US7465822B2 (en) * 2005-05-05 2008-12-16 Bp Chemicals Ltd. Process for carbonylation of alkyl ethers
US20060252959A1 (en) 2005-05-05 2006-11-09 The Regents Of The University Of California Process for carbonylation of alkyl ethers
CN101500707B (en) * 2006-08-03 2014-03-12 埃克森美孚化学专利公司 Production of light olefins
EP2054154A1 (en) * 2006-08-03 2009-05-06 ExxonMobil Chemical Patents Inc. Production of light olefins
EP1985606A1 (en) * 2007-04-26 2008-10-29 BP Chemicals Limited Process for the carbonylation of dimethyl ether
EP1985608A1 (en) 2007-04-26 2008-10-29 BP Chemicals Limited Process for the carbonylation of dimethyl ether
EP2189215A1 (en) * 2008-11-19 2010-05-26 BP Chemicals Limited Carbonylation process catalysed by mordenite supported on inorganic oxides
EP2199272A1 (en) * 2008-11-27 2010-06-23 BP Chemicals Limited Carbonylation process
EP2198963A1 (en) * 2008-12-10 2010-06-23 BP Chemicals Limited Bound mordenite zeolite carbonylation catalyst

Also Published As

Publication number Publication date
CN105339084A (en) 2016-02-17
CA2903134A1 (en) 2014-09-12
EP2964379A1 (en) 2016-01-13
US20160009629A1 (en) 2016-01-14
UA120086C2 (en) 2019-10-10
US9598347B2 (en) 2017-03-21
JP2016514105A (en) 2016-05-19
BR112015021851A2 (en) 2017-07-18
RU2658820C2 (en) 2018-06-25
KR20150125720A (en) 2015-11-09
TW201441188A (en) 2014-11-01
CN105339084B (en) 2018-12-21
WO2014135662A1 (en) 2014-09-12
RU2015142615A (en) 2017-04-13

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