SG11201506147XA - Online monitoring of polymerization inhibitors for control of undesirable polymerization - Google Patents

Online monitoring of polymerization inhibitors for control of undesirable polymerization

Info

Publication number
SG11201506147XA
SG11201506147XA SG11201506147XA SG11201506147XA SG11201506147XA SG 11201506147X A SG11201506147X A SG 11201506147XA SG 11201506147X A SG11201506147X A SG 11201506147XA SG 11201506147X A SG11201506147X A SG 11201506147XA SG 11201506147X A SG11201506147X A SG 11201506147XA
Authority
SG
Singapore
Prior art keywords
polymerization
control
online monitoring
undesirable
inhibitors
Prior art date
Application number
SG11201506147XA
Inventor
Jr Ramon Colorado
Vincent Lewis
Robert A Geiger
Jessica Hancock
Andrew R Neilson
Original Assignee
Ecolab Usa Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ecolab Usa Inc filed Critical Ecolab Usa Inc
Publication of SG11201506147XA publication Critical patent/SG11201506147XA/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00Purification; Separation; Use of additives
    • C07C7/20Use of additives, e.g. for stabilisation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/38Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0006Controlling or regulating processes
    • B01J19/002Avoiding undesirable reactions or side-effects, e.g. avoiding explosions, or improving the yield by suppressing side-reactions
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049Controlling or regulating processes
    • B01J2219/00164Controlling or regulating processes controlling the flow
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049Controlling or regulating processes
    • B01J2219/00245Avoiding undesirable reactions or side-effects
    • B01J2219/00254Formation of unwanted polymer, such as "pop-corn"
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2438/00Living radical polymerisation
    • C08F2438/02Stable Free Radical Polymerisation [SFRP]; Nitroxide Mediated Polymerisation [NMP] for, e.g. using 2,2,6,6-tetramethylpiperidine-1-oxyl [TEMPO]

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Water Supply & Treatment (AREA)
  • Polymerisation Methods In General (AREA)
  • Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
  • Hydrogenated Pyridines (AREA)
SG11201506147XA 2013-02-12 2014-01-13 Online monitoring of polymerization inhibitors for control of undesirable polymerization SG11201506147XA (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US13/765,508 US9266797B2 (en) 2013-02-12 2013-02-12 Online monitoring of polymerization inhibitors for control of undesirable polymerization
PCT/US2014/011276 WO2014126663A1 (en) 2013-02-12 2014-01-13 Online monitoring of polymerization inhibitors for control of undesirable polymerization

Publications (1)

Publication Number Publication Date
SG11201506147XA true SG11201506147XA (en) 2015-09-29

Family

ID=51297895

Family Applications (1)

Application Number Title Priority Date Filing Date
SG11201506147XA SG11201506147XA (en) 2013-02-12 2014-01-13 Online monitoring of polymerization inhibitors for control of undesirable polymerization

Country Status (11)

Country Link
US (2) US9266797B2 (en)
JP (1) JP6338600B2 (en)
KR (1) KR102160164B1 (en)
CN (1) CN104981485B (en)
AU (1) AU2014216712B2 (en)
BR (1) BR112015017301A2 (en)
CA (1) CA2896696C (en)
MX (1) MX2015009713A (en)
MY (1) MY171891A (en)
SG (1) SG11201506147XA (en)
WO (1) WO2014126663A1 (en)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107073435B (en) * 2014-10-24 2019-12-13 沙特基础工业全球技术有限公司 System and method for cumene hydroperoxide cleavage with improved on-line instrumentation configuration
JP6730203B2 (en) 2017-02-07 2020-07-29 株式会社日立製作所 Optical analysis device, optical analysis system, and optical analysis method
JP6772103B2 (en) * 2017-04-12 2020-10-21 横河電機株式会社 Polymerization suppression system and polymerization suppression method
KR102153474B1 (en) 2017-06-20 2020-09-08 주식회사 엘지화학 Control system and method for ethylene vinyl acetate copolymerization process
CN109218126B (en) * 2017-06-30 2023-10-17 中兴通讯股份有限公司 Method, device and system for monitoring node survival state
TW202005938A (en) 2018-07-13 2020-02-01 美商藝康美國公司 Polymerization inhibitor and retarder compositions with amine stabilizer
CN112513005A (en) 2018-07-13 2021-03-16 埃科莱布美国股份有限公司 Amine oxide and methylated quinone combination as an antifoulant for ethylene monomers
CN112739725B (en) 2018-09-28 2023-09-26 埃科莱布美国股份有限公司 Amino quinone anti-polymerization agent and method of use thereof
JP2022514026A (en) 2018-12-20 2022-02-09 エコラボ ユーエスエー インコーポレイティド Hydroxylated quinone polymerization inhibitor and usage
JP7247630B2 (en) * 2019-02-13 2023-03-29 栗田工業株式会社 Method for inhibiting polymerization of unsaturated aromatic monomer
EP3962889A1 (en) 2019-04-29 2022-03-09 Ecolab USA Inc. Oxygenated aminophenol compounds and methods for preventing monomer polymerization
CN110075774A (en) * 2019-06-14 2019-08-02 长岭炼化岳阳工程设计有限公司 Change products the MTBE device and its automatic control method of heat bodied oil with safety auto-controlled system
TW202114976A (en) 2019-10-11 2021-04-16 美商藝康美國公司 Quinone methide and ammonium salt antipolymerant composition and method
CN111455455A (en) * 2020-02-29 2020-07-28 武汉大学 Crystal growth device with online monitoring function
EP4232490A1 (en) 2020-10-21 2023-08-30 Ecolab USA Inc. Alkoxylated (hydroxyalkyl)aminophenol polymers and methods of use

Family Cites Families (58)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4360776A (en) 1980-09-11 1982-11-23 Bauman Albert J ESR Based portable microanalytic apparatus and method
US4415671A (en) 1980-10-30 1983-11-15 Chevron Research Company Method for modifying electron spin resonance signals from hydrocarbon crude
US4536711A (en) 1983-05-05 1985-08-20 Southwest Research Institute Method and apparatus for measuring flow in a pipe or conduit
US4531093A (en) 1983-05-05 1985-07-23 Southwest Research Institute Method and apparatus for coal analysis and flow measurement
US4593248A (en) 1984-03-27 1986-06-03 The Medical College Of Wisconsin, Inc. Oxymeter
US4783314A (en) 1987-02-26 1988-11-08 Nalco Chemical Company Fluorescent tracers - chemical treatment monitors
US5120661A (en) 1987-12-11 1992-06-09 Diversey Corporation Method for detection and quantitative analysis for water treatment chemicals
US4992380A (en) 1988-10-14 1991-02-12 Nalco Chemical Company Continuous on-stream monitoring of cooling tower water
US5041386A (en) 1988-12-19 1991-08-20 Nalco Chemical Company Concentration cycles, percent life holding time and continuous treatment concentration monitoring in boiler systems by inert tracers
US4966711A (en) 1989-02-27 1990-10-30 Nalco Chemical Company Transition metals as treatment chemical tracers
US5200106A (en) 1989-02-27 1993-04-06 Nalco Chemical Company Compositions comprising transition metals for treating and monitoring liquid systems
GB2238383B (en) 1989-11-15 1993-12-01 Ciba Geigy Ag UV sensitive marker compounds for use in aqueous systems
US5006311A (en) 1990-03-23 1991-04-09 Nalco Chemical Company Monitoring performance of a treating agent added to a body of water
US5132096A (en) 1990-03-23 1992-07-21 Nalco Chemical Company Monitoring performance of a water treating agent by measuring and resolving optical voltage analogs
US5171450A (en) 1991-03-20 1992-12-15 Nalco Chemical Company Monitoring and dosage control of tagged polymers in cooling water systems
US5233303A (en) 1991-05-23 1993-08-03 Barney Bales Portable dedicated electron spin resonance spectrometer
US5242602A (en) 1992-03-04 1993-09-07 W. R. Grace & Co.-Conn. Spectrophotometric monitoring of multiple water treatment performance indicators using chemometrics
US5282379A (en) 1992-04-03 1994-02-01 Nalco Chemical Company Volatile tracers for diagnostic use in steam generating systems
US5278074A (en) 1992-04-22 1994-01-11 Nalco Chemical Company Method of monitoring and controlling corrosion inhibitor dosage in aqueous systems
JPH0659008A (en) 1992-08-06 1994-03-04 Sumitomo Electric Ind Ltd Physical property measuring device and method therefor
US5236845A (en) 1992-10-22 1993-08-17 Nalco Chemical Company On-line iron (II) concentration monitoring to continuously determine corrosion in boiler systems
US5277135A (en) 1992-11-23 1994-01-11 Nalco Chemical Company Controlling concentration of chemical treatment for flue gas reduction of the oxides of nitrogen
US5266493A (en) 1993-01-22 1993-11-30 Nalco Chemical Company Monitoring boric acid in fluid systems
US5494030A (en) 1993-08-12 1996-02-27 Trustees Of Dartmouth College Apparatus and methodology for determining oxygen in biological systems
US5706805A (en) 1993-08-12 1998-01-13 Trustees Of Dartmouth College Apparatus and methodology for determining oxygen tension in biological systems
JP3496219B2 (en) 1993-09-20 2004-02-09 ダイキン工業株式会社 Method for measuring concentration of polymerization inhibitor contained in fluorinated olefin monomer and method for polymerizing fluorinated olefin monomer comprising the method
US5389548A (en) 1994-03-29 1995-02-14 Nalco Chemical Company Monitoring and in-system concentration control of polyelectrolytes using fluorochromatic dyes
US5830645A (en) * 1994-12-09 1998-11-03 The Regents Of The University Of California Comparative fluorescence hybridization to nucleic acid arrays
US6046587A (en) 1997-06-24 2000-04-04 Southwest Research Institute Measurement of flow fractions, flow velocities, and flow rates of a multiphase fluid using NMR sensing
US6068012A (en) 1998-12-29 2000-05-30 Ashland, Inc. Performance-based control system
US6153110A (en) 1999-05-17 2000-11-28 Chemtreat, Inc. Method for controlling treatment chemicals in aqueous systems
DE19926758A1 (en) * 1999-06-11 2000-12-14 Basf Ag Method for preventing undesired polymerization in a substance mixture containing ethylenically unsaturated compounds
US6462546B1 (en) 1999-11-13 2002-10-08 Bruker Analytik Gmbh Method and apparatus for investigating the imperishability of liquid foodstuffs by means of electron spin resonance
AR029410A1 (en) * 1999-12-02 2003-06-25 Crompton Corp METHOD FOR INHIBITING PREMATURE POLYMERIZATION OF ETHENICALLY INSATURED MONOMERS AND COMPOSITIONS OF THE SAME
DE10006900A1 (en) * 2000-02-16 2001-08-23 Basell Polyolefine Gmbh Process for radical ethylene high-pressure polymerization while avoiding undesirable polymer deposits
US6587753B2 (en) 2000-05-01 2003-07-01 Ondeo Nalco Company Use of control matrix for boiler control
JP2002053871A (en) * 2000-08-07 2002-02-19 Nippon Zeon Co Ltd Method for separating and purifying conjugated dienes and apparatus for separating and purification
JP3614352B2 (en) 2000-09-04 2005-01-26 伯東株式会社 Method for measuring the concentration of stable free radical compounds
JP4451581B2 (en) 2001-09-28 2010-04-14 株式会社日本触媒 Polymerization inhibitor preparation and supply device and preparation supply method
US20050004413A1 (en) * 2001-10-19 2005-01-06 Masanobu Kanauchi Process and apparatus for separation and purification of conjugated diene
US6790664B2 (en) 2001-12-28 2004-09-14 Nalco Company Fluorometric monitoring and control of soluble hardness of water used in industrial water systems
DE10207725B4 (en) 2002-02-20 2006-02-16 Bruker Biospin Gmbh Resonator assembly for electron spin resonance (ESR) measurements and methods for measuring electron spin resonance (ESR) signals
AU2003244750A1 (en) * 2002-06-13 2003-12-31 A H Marks And Company Limited Polymerisation inhibitor
US7084628B2 (en) 2002-12-09 2006-08-01 Resonance Research Inc. Methods and apparatus for post-exposure determination of ionizing radiation dose
JP4024669B2 (en) * 2002-12-24 2007-12-19 株式会社カネカ Stabilization method of vinyl polymer having terminal group with polymerizable carbon-carbon double bond
CN100522902C (en) * 2003-03-17 2009-08-05 伯东株式会社 Polymerization inhibitor for aromatic vinyl compounds and method for inhibiting the polymerization of the compounds
US7220382B2 (en) 2003-07-31 2007-05-22 Nalco Company Use of disulfonated anthracenes as inert fluorescent tracers
ITMI20032551A1 (en) * 2003-12-22 2005-06-23 Polimeri Europa Spa IMPROVED PROCEDURE FOR THE PRODUCTION AND PURIFICATION OF VINYLAROMATIC MONOMERS
EP1720917B1 (en) * 2004-03-01 2018-08-29 Bridgestone Corporation Continuous polymerization process
WO2006015379A2 (en) 2004-08-02 2006-02-09 Cornell Research Foundation, Inc. Electron spin resonance microscope for imaging with micron resolution
GB0521319D0 (en) 2005-10-20 2005-11-30 A H Marks And Company Ltd Method
US7868616B2 (en) 2006-10-31 2011-01-11 Active Spectrum, Inc. Method of and apparatus for in-situ measurement of changes in fluid composition by electron spin resonance (ESR) spectrometry
US7589529B1 (en) 2005-11-14 2009-09-15 Active Spectrum, Inc. Method of and apparatus for in-situ measurement of degradation of automotive fluids and the like by micro-electron spin resonance (ESR) spectrometry
US8648596B2 (en) 2006-10-31 2014-02-11 Active Spectrum, Inc. Method of and apparatus for analysis of the composition of a sample by electron spin resonance (ESR) spectrometry employing carrier suppression
US8212563B2 (en) 2006-10-31 2012-07-03 Active Spectrum, Inc. Method and apparatus for in-situ measurement of soot by electron spin resonance (ESR) spectrometry
EP1944604A1 (en) 2007-01-09 2008-07-16 Total Petrochemicals Research Feluy Process to monitor formation of a polymer having internal strain by acoustic emission analysis
JP5945739B2 (en) 2010-10-04 2016-07-05 旭化成株式会社 Polymerization inhibitor addition method, purification method and purification apparatus
US8822717B2 (en) 2010-11-24 2014-09-02 LyondellBassell Acetyls, LLC Vinyl acetate production process

Also Published As

Publication number Publication date
US20160176788A1 (en) 2016-06-23
KR102160164B1 (en) 2020-09-28
US9266797B2 (en) 2016-02-23
CN104981485A (en) 2015-10-14
AU2014216712B2 (en) 2017-03-09
JP6338600B2 (en) 2018-06-06
WO2014126663A1 (en) 2014-08-21
AU2014216712A1 (en) 2015-07-02
MX2015009713A (en) 2015-11-06
MY171891A (en) 2019-11-06
CA2896696A1 (en) 2014-08-21
US20140228604A1 (en) 2014-08-14
BR112015017301A2 (en) 2017-07-11
CA2896696C (en) 2021-01-12
KR20150119115A (en) 2015-10-23
JP2016506989A (en) 2016-03-07
CN104981485B (en) 2017-07-28
US9656930B2 (en) 2017-05-23

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