SG11201500337YA - Catalytic reduction of nox with high activity catalysts with nh3 reductant - Google Patents

Catalytic reduction of nox with high activity catalysts with nh3 reductant

Info

Publication number
SG11201500337YA
SG11201500337YA SG11201500337YA SG11201500337YA SG11201500337YA SG 11201500337Y A SG11201500337Y A SG 11201500337YA SG 11201500337Y A SG11201500337Y A SG 11201500337YA SG 11201500337Y A SG11201500337Y A SG 11201500337YA SG 11201500337Y A SG11201500337Y A SG 11201500337YA
Authority
SG
Singapore
Prior art keywords
reductant
nox
catalytic reduction
high activity
activity catalysts
Prior art date
Application number
SG11201500337YA
Inventor
Ajit B Dandekar
Richard L Eckes
Richard F Socha
S Beau Waldrup
Jason M Mcmullan
Original Assignee
Exxonmobil Res & Eng Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxonmobil Res & Eng Co filed Critical Exxonmobil Res & Eng Co
Publication of SG11201500337YA publication Critical patent/SG11201500337YA/en

Links

Classifications

    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86—Catalytic processes
    • B01D53/8621—Removing nitrogen compounds
    • B01D53/8625—Nitrogen oxides
    • B01D53/8628—Processes characterised by a specific catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9404—Removing only nitrogen compounds
    • B01D53/9409—Nitrogen oxides
    • B01D53/9413—Processes characterised by a specific catalyst
    • B01D53/9418—Processes characterised by a specific catalyst for removing nitrogen oxides by selective catalytic reduction [SCR] using a reducing agent in a lean exhaust gas
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/16—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J29/166—Y-type faujasite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/48—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing arsenic, antimony, bismuth, vanadium, niobium tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/78—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/78—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J29/7815—Zeolite Beta
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/78—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J29/7853—MFS-type, e.g. ZSM-57
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/20—Reductants
    • B01D2251/206—Ammonium compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20723—Vanadium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20746—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20776—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/50—Zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2258/00—Sources of waste gases
    • B01D2258/01—Engine exhaust gases
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2258/00—Sources of waste gases
    • B01D2258/02—Other waste gases
    • B01D2258/0283—Flue gases

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Environmental & Geological Engineering (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Biomedical Technology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
  • Catalysts (AREA)
SG11201500337YA 2012-08-09 2013-07-23 Catalytic reduction of nox with high activity catalysts with nh3 reductant SG11201500337YA (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201261681268P 2012-08-09 2012-08-09
PCT/US2013/051642 WO2014025529A1 (en) 2012-08-09 2013-07-23 Catalytic reduction of nox with high activity catalysts with nh3 reductant

Publications (1)

Publication Number Publication Date
SG11201500337YA true SG11201500337YA (en) 2015-02-27

Family

ID=50065136

Family Applications (1)

Application Number Title Priority Date Filing Date
SG11201500337YA SG11201500337YA (en) 2012-08-09 2013-07-23 Catalytic reduction of nox with high activity catalysts with nh3 reductant

Country Status (7)

Country Link
US (1) US8858907B2 (en)
EP (1) EP2882520B1 (en)
CN (1) CN104602792B (en)
CA (1) CA2878273C (en)
IN (1) IN2014DN11247A (en)
SG (1) SG11201500337YA (en)
WO (1) WO2014025529A1 (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103933859B (en) * 2014-03-31 2015-09-16 上海德凯工业技术有限公司 A kind of SCR denitration system for acrylonitrile installation vent gas treatment
CN104841476A (en) * 2015-04-23 2015-08-19 碗海鹰 SCR catalyst for ship diesel engine post-treatment, and preparation method thereof
US10920636B2 (en) 2017-11-09 2021-02-16 Exxonmobil Research And Engineering Company Treatment of combustion exhaust
CN109590020B (en) * 2018-12-27 2021-08-24 桂林理工大学 Preparation method of microporous-mesoporous composite molecular sieve denitration catalyst
WO2024052387A1 (en) * 2022-09-06 2024-03-14 Umicore Ag & Co. Kg Catalytic system and method for the removal of hcn from off-gases of a fluid cracking unit using same, and fcc unit assembly including the catalytic system

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US4210628A (en) 1973-07-12 1980-07-01 Takeda Chemical Industries, Ltd. Removal of nitrogen oxides
JPS5850777B2 (en) * 1975-03-28 1983-11-12 トウアネンリヨウコウギヨウ カブシキガイシヤ Chitsusosankabutsunokangenyoushiyokubai
EP0077424A1 (en) 1981-10-21 1983-04-27 The Standard Oil Company Process for removing nitrogen oxides from a gas stream
US4663300A (en) * 1985-12-23 1987-05-05 Uop Inc. Pollution control catalyst
JPH0817939B2 (en) * 1986-11-19 1996-02-28 三菱化学株式会社 Flue gas denitration catalyst
JP2547762B2 (en) * 1987-03-27 1996-10-23 バブコツク日立株式会社 Nitrogen oxide removal catalyst
JPH06198188A (en) * 1992-12-28 1994-07-19 Tosoh Corp Exhaust gas purification catalyst
US5589147A (en) 1994-07-07 1996-12-31 Mobil Oil Corporation Catalytic system for the reducton of nitrogen oxides
US5741468A (en) 1994-12-28 1998-04-21 Kabushiki Kaisha Riken Exhaust gas cleaner and method for cleaning exhaust gas
KR100204257B1 (en) 1995-10-02 1999-06-15 마스다 노부유키 Heat treated activated carbon for denitration process for preparing the same method of denitration using the same and system of denitration using the same
US6346498B1 (en) 1997-12-19 2002-02-12 Exxonmobil Oil Corporation Zeolite catalysts having stabilized hydrogenation-dehydrogenation function
AU2001252241A1 (en) 2000-04-03 2001-10-15 Basf Aktiengesellschaft Catalyst system for the decomposition of n2o
NL1017245C2 (en) 2001-01-31 2002-08-01 Stichting Energie Method for simultaneously removing nitrogen oxides and nitrous oxide from a gas stream containing nitrogen oxides and nitrous oxide.
US7135153B2 (en) 2002-03-07 2006-11-14 Southwest Research Institute NOx reduction system for diesel engines, using hydrogen selective catalytic reduction
GB0318776D0 (en) 2003-08-09 2003-09-10 Johnson Matthey Plc Lean NOx catalyst
US20050163691A1 (en) 2004-01-23 2005-07-28 C.P. Kelkar NOx reduction composition for use in FCC processes
MX2007013254A (en) 2005-04-29 2008-01-21 Grace W R & Co Nox reduction compositions for use in partial burn fcc processes.
US7803338B2 (en) 2005-06-21 2010-09-28 Exonmobil Research And Engineering Company Method and apparatus for combination catalyst for reduction of NOx in combustion products
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Also Published As

Publication number Publication date
CN104602792A (en) 2015-05-06
EP2882520A1 (en) 2015-06-17
CA2878273C (en) 2019-03-12
US8858907B2 (en) 2014-10-14
EP2882520B1 (en) 2020-03-11
CN104602792B (en) 2016-08-24
US20140041364A1 (en) 2014-02-13
IN2014DN11247A (en) 2015-10-09
WO2014025529A1 (en) 2014-02-13
CA2878273A1 (en) 2014-02-13

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