SE501158C2 - Ways to clean flue gases with a deficit of oxygen and formed soot - Google Patents

Ways to clean flue gases with a deficit of oxygen and formed soot

Info

Publication number
SE501158C2
SE501158C2 SE9201232A SE9201232A SE501158C2 SE 501158 C2 SE501158 C2 SE 501158C2 SE 9201232 A SE9201232 A SE 9201232A SE 9201232 A SE9201232 A SE 9201232A SE 501158 C2 SE501158 C2 SE 501158C2
Authority
SE
Sweden
Prior art keywords
soot
flue gases
oxygen
deficit
flue gas
Prior art date
Application number
SE9201232A
Other languages
Swedish (sv)
Other versions
SE9201232D0 (en
SE9201232L (en
Inventor
Peter Odenmo
Original Assignee
Flaekt Ab
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Flaekt Ab filed Critical Flaekt Ab
Priority to SE9201232A priority Critical patent/SE501158C2/en
Publication of SE9201232D0 publication Critical patent/SE9201232D0/en
Priority to PCT/SE1993/000163 priority patent/WO1993020926A1/en
Priority to AU39104/93A priority patent/AU3910493A/en
Publication of SE9201232L publication Critical patent/SE9201232L/en
Publication of SE501158C2 publication Critical patent/SE501158C2/en

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/64Heavy metals or compounds thereof, e.g. mercury
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/68Halogens or halogen compounds
    • B01D53/70Organic halogen compounds
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J15/00Arrangements of devices for treating smoke or fumes
    • F23J15/006Layout of treatment plant

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Treating Waste Gases (AREA)
  • Filtering Of Dispersed Particles In Gases (AREA)

Abstract

In a method for cleaning flue gases generated upon incineration in an incinerator (1), especially upon incineration of refuse, the flue gases are conducted through a flue gas duct (2) to an installation (4) for separating particulate impurities. Soot-generating incineration of a fuel is performed with a deficiency of oxygen, and the generated soot is mixed with the flue gases in the flue gas duct (2).

Description

501 10 15 20 25 30 35 158 2 innehåller dioxiner och kvicksilver. Föreliggande uppfin- ning är särskilt inriktad på avskiljningen av just dioxi- ner och kvicksilver. 501 10 15 20 25 30 35 158 2 contains dioxins and mercury. The present invention is particularly focused on the separation of just dioxins and mercury.

Rökgaserna ledes från förbränningsugnen 1 via en rök- gasledning 2 till en anläggning 3 för avskiljning av gas- formiga föroreningar, såsom svaveldioxid och klorväte, och därefter till en anläggning 4 för avskiljning av partikel- formiga föroreningar (stoft). Anläggningen 3 är här en våtskrubber men kan också vara en kontaktreaktor av annat slag. Anläggningen 4 är här en spärrfilterenhet i form av ett slangfilter med textila filterslangar men kan exempel- vis också vara en elektrostatisk stoftavskiljare. Arbets- temperaturen i spärrfilterenheten är lämpligen 60-150°C.The flue gases are led from the incinerator 1 via a flue gas line 2 to a plant 3 for the separation of gaseous pollutants, such as sulfur dioxide and hydrogen chloride, and then to a plant 4 for the separation of particulate pollutants (dust). The plant 3 here is a wet scrubber but can also be a contact reactor of another kind. The system 4 here is a blocking filter unit in the form of a hose filter with textile filter hoses, but can also be an electrostatic dust collector, for example. The operating temperature in the barrier filter unit is suitably 60-150 ° C.

Från anläggningen 4 ledes rökgaserna eventuellt vidare till ytterligare behandlingsanläggningar innan de slutli- gen utsläppes i atmosfären via en skorsten (icke visad).From plant 4, the flue gases may be passed on to additional treatment plants before they are finally released into the atmosphere via a chimney (not shown).

I en förbränningsenhet 5 utföres en sotbildande för- bränning av ett bränsle med ett underskott av syre. De härvid bildade, sotbemängda rökgaserna inledes i rökgas- ledningen 2 mellan gasavskiljaren 3 och stoftavskiljaren 4. Sotpartiklarna adsorberar dioxiner och kvicksilver innan de avskiljes i stoftavskiljaren 4.In a combustion unit 5, a soot-forming combustion of a fuel with a deficit of oxygen is performed. The soot-laden flue gases thus formed are introduced into the flue gas line 2 between the gas separator 3 and the dust collector 4. The soot particles adsorb dioxins and mercury before they are separated in the dust trap 4.

Att i enlighet med uppfinningen på detta vis utföra en sotbildande förbränning och utnyttja det bildade sotet för att adsorbera dioxiner och kvicksilver är enklare och avsevärt billigare än att för detta ändamål utnyttja aktivt kol eller aktivt koks i enlighet med den ovan be- skrivna kända tekniken.According to the invention, in this way carrying out a soot-forming combustion and using the soot formed to adsorb dioxins and mercury is simpler and considerably cheaper than using activated carbon or activated coke for this purpose in accordance with the known technique described above.

Det ovan beskrivna förfarandet kan modifieras på olika sätt inom ramen för uppfinningen. Sålunda kan exem- pelvis de sotbemängda rökgaserna från enheten 5 inledas i rökgasledningen 2 mellan förbränningsugnen l och gasav- skiljaren 3. Enheten 5 kan vid speciella tillämpningar er- sättas med en i rökgasledningen 2 mellan gasavskiljaren 3 och stoftavskiljaren 4 placerad brännare, som förbränner ett därtill matat bränsle på sotbildande vis. Brännaren höjer då temperaturen i rökgasledningen 2, vilket ger den 10 15 20 25 30 35 501 158 3 fördelen att en avskiljningsgraden ökande sänkning av temperaturen i gasavskiljaren 3 kan utföras.The method described above can be modified in various ways within the scope of the invention. Thus, for example, the soot-laden flue gases from the unit 5 can be introduced into the flue gas line 2 between the incinerator 1 and the gas separator 3. The unit 5 can in special applications be replaced by a burner placed in the flue gas line 2 between the gas separator 3 and the dust separator 4, which burns a in addition, fuel is fed in a soot-forming manner. The burner then raises the temperature in the flue gas line 2, which gives it the advantage that a degree of lowering increasing the temperature in the gas separator 3 can be performed.

Claims (3)

1. 501 158 10 15 20 25 30 35 PÅTENTKRAV l. Sätt att rena rökgaser, Qom bildas vid förbränning i en förbränningsugn (1), särskilt vid förbränning av av- fall, vid vilket sätt rökgaserna ledes genom en rökgasled- ning (2) till en anläggning (4) för avskiljning av parti- kelformiga föroreningar, k ä n n e t e c k n a t därav, att en sotbildande förbränning av ett bränsle utföres med ett underskott av syre och att det bildade sotet blandas med rökgaserna i rökgasledningen (2) för att adsorbera dioxiner och kvicksilver.1. 501 158 10 15 20 25 30 35 PATENT REQUIREMENTS 1. Methods for purifying flue gases to a plant (4) for the separation of particulate pollutants, characterized in that a soot-forming combustion of a fuel is carried out with a deficit of oxygen and that the soot formed is mixed with the flue gases in the flue gas line (2) to adsorb dioxins and Quicksilver. 2. Sätt enligt patentkravet l, att den sotbildande förbränningen utföres i k ä n n e t e c k - n a t därav, en förbränningsenhet (5), som är belägen utanför rökgas- ledningen (2).2. A method according to claim 1, that the soot-forming combustion is carried out in the sense of a combustion unit (5), which is located outside the flue gas line (2). 3. Sätt enligt patentkravet l, att den sotbildande förbränningen utföres kånneteCk- n a t därav, med hjälp av en i rökgasledningen (2) placerad brännare.3. A method according to claim 1, that the soot-forming combustion is carried out by means of a burner placed in the flue gas line (2).
SE9201232A 1992-04-16 1992-04-16 Ways to clean flue gases with a deficit of oxygen and formed soot SE501158C2 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
SE9201232A SE501158C2 (en) 1992-04-16 1992-04-16 Ways to clean flue gases with a deficit of oxygen and formed soot
PCT/SE1993/000163 WO1993020926A1 (en) 1992-04-16 1993-02-26 Method for cleaning flue gases
AU39104/93A AU3910493A (en) 1992-04-16 1993-02-26 Method for cleaning flue gases

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
SE9201232A SE501158C2 (en) 1992-04-16 1992-04-16 Ways to clean flue gases with a deficit of oxygen and formed soot

Publications (3)

Publication Number Publication Date
SE9201232D0 SE9201232D0 (en) 1992-04-16
SE9201232L SE9201232L (en) 1993-10-17
SE501158C2 true SE501158C2 (en) 1994-11-28

Family

ID=20385997

Family Applications (1)

Application Number Title Priority Date Filing Date
SE9201232A SE501158C2 (en) 1992-04-16 1992-04-16 Ways to clean flue gases with a deficit of oxygen and formed soot

Country Status (3)

Country Link
AU (1) AU3910493A (en)
SE (1) SE501158C2 (en)
WO (1) WO1993020926A1 (en)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5843205A (en) * 1996-12-06 1998-12-01 Kabushiki Kaisha Kawasaki Giken Method of removing dioxins in a waste incineration plant
US9321002B2 (en) 2003-06-03 2016-04-26 Alstom Technology Ltd Removal of mercury emissions
US6848374B2 (en) 2003-06-03 2005-02-01 Alstom Technology Ltd Control of mercury emissions from solid fuel combustion
US8069797B2 (en) 2003-06-03 2011-12-06 Alstom Technology Ltd. Control of mercury emissions from solid fuel combustion
US7766997B2 (en) 2007-12-21 2010-08-03 Alstom Technology Ltd Method of reducing an amount of mercury in a flue gas
US8828341B1 (en) 2013-07-18 2014-09-09 Alstom Technology Ltd Sulfite control to reduce mercury re-emission
US9120055B2 (en) 2014-01-27 2015-09-01 Alstom Technology Ltd Mercury re-emission control

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AT390206B (en) * 1988-04-22 1990-04-10 Howorka Franz DEVICE FOR THE THERMAL DISASSEMBLY OF FLUID POLLUTANTS
SE466814B (en) * 1989-06-01 1992-04-06 Kvaerner Generator Ab DEVICE FOR DEGRADATION OF GASES GENERATED FOR PRESENT BURNING AT UNGEFER 850 DEGREES C OF THE SOLID BROWN IN A LIQUID BED

Also Published As

Publication number Publication date
SE9201232D0 (en) 1992-04-16
WO1993020926A1 (en) 1993-10-28
AU3910493A (en) 1993-11-18
SE9201232L (en) 1993-10-17

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