SE451470B - APPLICATION OF AN ACID ADDITION SALT OF AN ALKYLAMINE FOR REGULATING THE VISCOSITY OF PAPER COATING METHODS - Google Patents
APPLICATION OF AN ACID ADDITION SALT OF AN ALKYLAMINE FOR REGULATING THE VISCOSITY OF PAPER COATING METHODSInfo
- Publication number
- SE451470B SE451470B SE8505811A SE8505811A SE451470B SE 451470 B SE451470 B SE 451470B SE 8505811 A SE8505811 A SE 8505811A SE 8505811 A SE8505811 A SE 8505811A SE 451470 B SE451470 B SE 451470B
- Authority
- SE
- Sweden
- Prior art keywords
- batter
- use according
- acid addition
- viscosity
- alkylamine
- Prior art date
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Classifications
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/46—Non-macromolecular organic compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/38—Coatings with pigments characterised by the pigments
- D21H19/385—Oxides, hydroxides or carbonates
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/38—Coatings with pigments characterised by the pigments
- D21H19/40—Coatings with pigments characterised by the pigments siliceous, e.g. clays
Abstract
Description
15 20 25 30 35 451 470 En del av alkylaminen föreligger i form av syraadditionssalt. Syraaddítionssaltet är bildat genom omsättning med svavelsyra, fosforsyra, halogenvätesyror, salpe- tersyra, perklorsyra, alifatiska, alícykliska, aromatiska och heterocykliska kol- och sulfonsyror. Sådana salter är därvid hydroklorider, sulfat, vätesiilfat, fosfat, vätefosfat, nitrat, formiat, acetat, propionat, succinat, glykolat, glukonat, hep- tonat, laktat, tartrat, citrat, oxalat, askorbat, maleat, hydroxymaleat, bensoat, p-aminobensoat, p-hydroxibensoat, salicylat, p-amínosalicylat, pikrat, dietyl- entriamínpentaacetat (DTPA), etylendiamíntetraacetat (EDTA), nitrilotriacetat (NTA), hydroxyetyliminodiacetat, bís(hydroxyetyl)glukonat. A portion of the alkylamine is in the form of an acid addition salt. The acid addition salt is formed by reaction with sulfuric acid, phosphoric acid, hydrohalic acids, nitric acid, perchloric acid, aliphatic, alicyclic, aromatic and heterocyclic carbonic and sulfonic acids. Such salts are hydrochlorides, sulphate, hydrogen sulphate, phosphate, hydrogen phosphate, nitrate, formate, acetate, propionate, succinate, glycolate, gluconate, heptonate, lactate, tartrate, citrate, oxalate, ascorbate, maleate, hydroxymaleate, hydroxymaleate aminobenzoate, p-hydroxybenzoate, salicylate, p-aminososalicylate, picrate, diethylenetriamine pentaacetate (DTPA), ethylenediaminetetraacetate (EDTA), nitrilotriacetate (NTA), hydroxyethyliminodiacetate, bis (hydroxyethyl).
Ytterligare karatäristika framgår av hithörande patentkrav.Additional characteristics appear from the appended claims.
I gruppen utnyttjade alkylaminer ingår företrädesvis primära alkylamíner, såsom metylamin, etylamin, propylamin, 1-metyletylamin, butylamin, l-metylpropyl- amin, Z-metylpropylamin, pentylamin, ß-metylbutylamin, Z-metylbutylamin, l-etylpropylamín, l-metylbutylamin, 1,1-dimetyletylamin, Ll-dímetylpropyl- amin, men även sekundära och tertiära alkylaminer, såsom dimetylamin, dietyl- amin och trimetylamin kan förekomma.The group of alkylamines used preferably includes primary alkylamines, such as methylamine, ethylamine, propylamine, 1-methylethylamine, butylamine, 1-methylpropylamine, Z-methylpropylamine, pentylamine, β-methylbutylamine, Z-methylbutylamine, 1-ethylpropylamine, 1-methylbutylamine, 1,1-dimethylethylamine, L1-dimethylpropylamine, but also secondary and tertiary alkylamines such as dimethylamine, diethylamine and trimethylamine may be present.
Produkten framställes genom att blanda en lösning av en alkylamin med en lös- ning av en lämplig syra för reaktion till bildning av avsett syraadditionssalt.The product is prepared by mixing a solution of an alkylamine with a solution of a suitable acid for reaction to form the intended acid addition salt.
Härvid är det oväsentligt om den ena lösningen sättes till den andra, eller vice versa.In this case, it is immaterial whether one solution is added to the other, or vice versa.
Respektive lösning kan utgöras av koncentrat eller resp. förening löst i ett lös- níngsmedel.The respective solution can consist of concentrate or resp. compound dissolved in a solvent.
Beroende på graden av önskad substitution tages 1-4 moler amin per mol syra.Depending on the degree of substitution desired, 1-4 moles of amine are taken per mole of acid.
Under tillsats av en lösning till en annan skall temperaturen kontrolleras och styras så att kokning av alkylaminen undvikas.During the addition of one solution to another, the temperature should be controlled and controlled so that boiling of the alkylamine is avoided.
Reaktionen mellan alkylamin och syra är momentan, varefter produkten kan avfiltras (om reaktionen sker i icke-lösande lösningsmedel) eller användas direkt som lösning 10 15 20 25 30 85 451 470' Exem 1 33,6 kg citronsyramonohydrat löstes i 301 vatten. Därefter tillsattes försiktigt 361 (25,9 kg) n-propylamin under omrörning och kylning. Temperaturen hölls under 45°C. Den erhållna slutprodukten, (n-propylaminß-citrat förblev i lösning i vattenfasen. I l Pa samma sätt framställdes: Smp °C 2. (sekbutylamimz-sulfat >250 3. (selobutylamin)g-vätefosfat 130-195 4. (sekmutylaminh-acetat 5. IR (selobutylamixdg-citrat 6. (n-butylaminh-sulfat 225 7. (n-propylamimz-sulfat 8. (isobutylaminh-sulfat >265 9. 0 (metylamimz-sulfat 10. (ternbutylamimg-sulfat 11. (sekbutylaminlg-fosfat 12. (n-butylamin)3-fosfat 13. v (iso-butylaminkg-fosfat 14. (ternbutylamimg-fosfat 88-125 15. (n-propylaminlyfosfat 135-145 16. (n-propylamimg-vätefosfat 17. IR (n-propylamimz-citrat 18. IR (n-propylamimg-citrat 19. r (sekbutylamitüg-oxalat 175-225 20. (sek.buty1amin)4-EDTA:t A1. (n-oktylamimg-sulfat >250 dekomp. 220°C 21. (diety1amin)3-citrat 114-118 En serie 'försök genomfördes med anvädning av substanserna ovan, varvid bered- des en första kaolinsmet bestående av 100 delar torr kaolin, 50 delar vatten, 11,35 dem move-ag Dsspexfl sam: Neon :in pH 8,5. Därener dispergeredes under 1 h med tillsats av 9 delar latex Dow 685, 1,2 delar CMC(karboximety1cel1u1osa) sem: veuen :in viekesimen en 1ooo-1soo. :mer pH-juszering :in pn inser-hans viskositeten ca 1500 eps, torrsubstanshalt 55-5896. Detaljer kring olika utgångs- kaolinsmetar ges i nedanstående tabell 1, vänstra spalten. 10 15 20 25 30 35 451 470 En andra, gipsbaserad smet framställdes med 100 delar torr gips, 1,5 delar CMC, 9 delar latex Dow 685, Na0H till pH 8,5 och vatten, varvid erhölls en smet med TS 64,496, viskositet 950 cps. Till 400 g kaolinsmet sattes olika aminer i enligt ovan, i angiven mängd enligt tabell 1, varefter 30,1 g av gipssmeten tillsattes och viskositeten mättes. Även viskositeten efter tillsats av amínen mättes. Erhàllna resultat efter tillsats av den gipsbaserade smeten framgår av tabell 1 högra spalten nedan. 1202011 I Amin viskositet Amin 'rs pa I viskositet 'rs pH nr före tillsatt 96 före | efter efter mängd 96 'I 96 - 1460 - 50,0 0,6' 1 7000 50,6 7,6 2 1440 0,1 50,0 0,4 , 2440 7,6 2 1600 0,2 50,0 0,1 : 2200 7,0 2 1640 0,5 50,0 7,0 I 1040 7,5 2 1640 1,0 50,0 7,0 I 1760 7,5 0 1440 0,04 50,5 0,4 I 2200 50,6 7,6 0 1460 0,2 0,1 1 1760 7,5 0 1600 0,5 7,0 f 2040 7,5 0 1000 1,0 7,0 { 2020 7,4 10 1000 0,2 7,0 i 1040 0,0 19 1040 0,5 0,2 : 2000 5,0 10 2040 1,0 5,2 1 0000 4,0 19 1400 0,05 0,1 I 0600 7,0 I - 1040 - 57,0 0,0 ; 0200 57,6 7,5 0 1060 0,2 7,0 ; 1700 7,4 0 1400 0,5 7,6 ; 1020 7,0 6 1600 1,0 7,4 i 1700 7,0 0 1000 0,2 7,0 { 1740 7,4 0 1460 0,5 7,7 § 1500 7,0 0 1500 1,0 7,5 { 1600 7,0 10 1440 0,2 5 0,0 } 1020 7,4 { 1520 7,0 10 1380 0,5 '7,7 10 15 20 25 30 35 451 470 10 1440 1,0 57,3 7,4 ; 1540 57,5 7,2 5 1240 0,2 5,4 I 1540 5,9 5 1200 0,5 5,5 § 1400 " 5,1 5 1450 1,0 5,4 ; 1500 4,9 7 ~ 1340 0,2 7,9 1 1540 7,4 7 1320 0,5 7,7 § 1540 7,4 7 1540 1,0 7,5 1 1550 7,4 A1 2340 0,2 7,7 1 >10.000 7,1 A1 >10.000 0,5 ' 7,4 : >10.000 7,0 A1 går ej 1,0 - ' - - - 1200 - 5,4 1 5100 55,0 7,5 12 1240 0,05 3,3 1 2000 ' 7,5 12 1440 0,10 5,2 I 1500 7,5 12 1520 0,2 3,1 I 1530 7,5 12. 1500 0,5 3,1 1 2000 7,5 13 1340 0,1 5,2 1 1040 55,5 7,5 13 1400 0,2 5,2 I 1320 7,4 13 1440 0,5 5,1 I 1540 7,5 14 1350 0,1 5,2 1 1750 7,4 - 14 1420 0,2 5,1 | 1700 7,4 14 1520 0,5 7,9 { 1350 7,4 11 1420 0,1 5,2 å 2050 7,5 11 1500 0,2 5,0 ; 1550 7,5 11 1540 0,5 7,0 1 1740 7,5 3 1250 0,1 ' 5,2 § 1550 7,5 1350 0,2 5,1 ; 1500 7,5 3 1320 0,5 5,0 1 1550 7,5 15 1350 0,1 3,3 I 1700 7,5 15 1420 0,2 5,2 1 1550 7,5 15 1350 0,5 3,1 : 1730 7,5 Föreliggande användning har också testats i halvstor skala i en anläggning med en volym av 251. Anläggningen omfattar ett maskinkar med en fyllnads- volym av 151, ett filter, och en bufferttank med utlopp dels till maskinkaret, dels till "bestrykning", dvs simulering av bestrykning av pappersbana genom 10 15 20 25 30 35 451 470 uttag av 1 liter/min. Den cirkulerande volymen var 7 l och flödet var 10 1/min.The reaction between alkylamine and acid is instantaneous, after which the product can be filtered off (if the reaction takes place in non-dissolving solvent) or used directly as a solution. Then 361 (25.9 kg) of n-propylamine was carefully added with stirring and cooling. The temperature was kept below 45 ° C. The resulting final product, (n-propylamine citrate remained in solution in the aqueous phase. In 1 Pa the same way was prepared: mp ° C 2. (secbutylamine sulfate> 250 3. (selobutylamine) g-hydrogen phosphate 130-195 4. (secmutylamine) acetate 5. IR (selobutylamine sulfate citrate 6. (n-butylamine sulfate 225 7. (n-propylamine sulfate) (isobutylamine sulfate> 265 9. 0) methylamine sulfate 10. (ternbutylamine sulfate 11. (secbutylamine sulfate). -phosphate 12. (n-butylamine) 3-phosphate 13. v (iso-butylamine g-phosphate 14. (tern-butylamine-phosphate 88-125 15. (n-propylamine-phosphate 135-145 16. (n-propylamine-hydrogen-phosphate 17. IR) (n-propylamimz citrate 18. IR (n-propylamimg citrate 19. r (secbutylamitug oxalate 175-225 20. (sec.butylamine) 4-EDTA: t A1.) ° C 21. (diethylamine) 3-citrate 114-118 A series of experiments were carried out using the above substances, preparing a first kaolin batter consisting of 100 parts of dry kaolin, 50 parts of water, 11.35 d of move-ag Dsspex fl sam: Neon: in pH 8.5 Darener dispersed for 1 h me d addition of 9 parts latex Dow 685, 1.2 parts CMC (carboxymethylcellulose) sem: veuen: in viekesimen and 1ooo-1soo. : more pH adjustment: in pn inser-hans viscosity about 1500 eps, dry matter content 55-5896. Details about different starting kaolin angles are given in Table 1, left column below. A second, gypsum-based batter was prepared with 100 parts of dry gypsum, 1.5 parts of CMC, 9 parts of latex Dow 685, NaOH to pH 8.5 and water to give a batter of TS 64.449, viscosity 950 cps. To 400 g of the kaolin batter were added various amines as above, in the amount indicated in Table 1, after which 30.1 g of the gypsum batter were added and the viscosity was measured. The viscosity after addition of the amine was also measured. Results obtained after the addition of the gypsum-based batter are shown in Table 1 on the right-hand column below. 1202011 I Amine viscosity Amine's pa I viscosity's pH no before added 96 before | after after quantity 96 'I 96 - 1460 - 50.0 0.6' 1 7000 50.6 7.6 2 1440 0.1 50.0 0.4, 2440 7.6 2 1600 0.2 50.0 0 , 1: 2200 7.0 2 1640 0.5 50.0 7.0 I 1040 7.5 2 1640 1.0 50.0 7.0 I 1760 7.5 0 1440 0.04 50.5 0.4 I 2200 50.6 7.6 0 1460 0.2 0.1 1 1760 7.5 0 1600 0.5 7.0 f 2040 7.5 0 1000 1.0 7.0 {2020 7.4 10 1000 0 , 2 7.0 i 1040 0.0 19 1040 0.5 0.2: 2000 5.0 10 2040 1.0 5.2 1 0000 4.0 19 1400 0.05 0.1 I 0600 7.0 I - 1040 - 57.0 0.0; 0200 57.6 7.5 0 1060 0.2 7.0; 1700 7.4 0 1400 0.5 7.6; 1020 7.0 6 1600 1.0 7.4 i 1700 7.0 0 1000 0.2 7.0 {1740 7.4 0 1460 0.5 7.7 § 1500 7.0 0 1500 1.0 7, 5 {1600 7.0 10 1440 0.2 5 0.0} 1020 7.4 {1520 7.0 10 1380 0.5 '7.7 10 15 20 25 30 35 451 470 10 1440 1.0 57.3 7.4; 1540 57.5 7.2 5 1240 0.2 5.4 I 1540 5.9 5 1200 0.5 5.5 § 1400 "5.1 5 1450 1.0 5.4; 1500 4.9 7 ~ 1340 0.2 7.9 1 1540 7.4 7 1320 0.5 7.7 § 1540 7.4 7 1540 1.0 7.5 1 1550 7.4 A1 2340 0.2 7.7 1> 10,000 7, 1 A1> 10,000 0.5 '7.4:> 10,000 7.0 A1 does not go 1.0 -' - - - 1200 - 5.4 1 5100 55.0 7.5 12 1240 0.05 3.3 1 2000 '7.5 12 1440 0.10 5.2 I 1500 7.5 12 1520 0.2 3.1 I 1530 7.5 12. 1500 0.5 3.1 1 2000 7.5 13 1340 0.1 5.2 1 1040 55.5 7.5 13 1400 0.2 5.2 I 1320 7.4 13 1440 0.5 5.1 I 1540 7.5 14 1350 0.1 5.2 1 1750 7.4 - 14 1420 0.2 5.1 | 1700 7.4 14 1520 0.5 7.9 {1350 7.4 11 1420 0.1 5.2 å 2050 7.5 11 1500 0.2 5.0; 1550 7.5 11 1540 0.5 7.0 1 1740 7.5 3 1250 0.1 '5.2 § 1550 7.5 1350 0.2 5.1; 1500 7.5 3 1320 0.5 5.0 1 1550 7.5 15 1350 0.1 3.3 I 1700 7.5 15 1420 0.2 5.2 1 1550 7.5 15 1350 0.5 3.1: 1730 7.5 The present use has also been tested in half-scale in a plant with a volume of 251. The plant comprises a machine with a filling volume of 151, a filter, and a buffer tank with outlet partly for the machine tank, partly for "coating", ie simulation of coating of paper web by 10 15 20 25 30 35 451 470 withdrawal of 1 liter / min. The circulating volume was 7 l and the flow was 10 1 / min.
Systemet fylles med en smet 1, varefter rundpumpning och "bestrykning" startas.The system is filled with a batter 1, after which round pumping and "coating" are started.
När maskinkaret tömts genom "bestrykningen" och ca 101 smet 1 finns kvar i systemet, fylls det helt med den smet 2 man skall byta till under fortsatt rundpumpning och "bestrykning". Prov på smeten 1+2 uttages var 30:e sekund för bestämning av viskositet, pH samt i vissa fall även TS och blandningsförhâll- ande mellan smet 1 och 2.When the machine vessel has been emptied through the "coating" and about 101 batter 1 remains in the system, it is completely filled with the batter 2 to be changed during continued round pumping and "coating". Samples of batter 1 + 2 are taken every 30 seconds to determine viscosity, pH and in some cases also TS and mixing ratio between batter 1 and 2.
Vid testning av en konventionell kaoljnsmet (smet 2), 100 delar kaolin, 0,35 delar Dispex R N40, 1,2 delar CMC FF5, och 9 delar latex Dow 685, TS 56-5996, pH 8,5-9, och en gipsbaserad bestrykningssmet (smet 1), 100 delar torr gips, díhydrat, 1,5 delar CMC och 9 delar Dow 685, TS 60-6596, pI-I 8,5-9 erhölls nedanstående resultat enligt tabell 2, då blandning skedde utan annan extra tillsats av en förening enligt föreliggande uppfinning. 'rasen z man :mms Tidpunkt Tillsats Viskosítet Halt min smet 2 mPas smet 1, 96 0 x 1000 100 1 2600 60 1,5 3200 2,0 2300 2,5 3000 45 3,0 3300 3,5 2500 4,0 3000 4,5 2600 6,0 x 2100 40 7,0 3200 i 30 7,5 3900 8,0 3200 8,5 4100 25 9,0 3200 10,0 3200 10,5 4000 10 15 20 25 30 35 12 x 12,5 13,0 14,0 15,0 15,5 16,0 16,5 1900 3500 5200 4200 4500 5500 4200 3700 451 470 10 I tabell 3 anges de erhållna resultaten efter tillsats av 0,4 delar propylaminfos- fat, räknat som amín, till smet 1, glpssmeten.When testing a conventional kaolin batter (batter 2), 100 parts kaolin, 0.35 parts Dispex R N40, 1.2 parts CMC FF5, and 9 parts latex Dow 685, TS 56-5996, pH 8.5-9, and a gypsum-based coating batter (batter 1), 100 parts dry gypsum, dihydrate, 1.5 parts CMC and 9 parts Dow 685, TS 60-6596, pI-I 8.5-9, the following results were obtained according to Table 2, when mixing took place without another additional addition of a compound of the present invention. 'breeds z man: mms Time Additive Viscosity Content min smet 2 mPas smet 1, 96 0 x 1000 100 1 2600 60 1.5 3200 2.0 2300 2.5 3000 45 3.0 3300 3.5 2500 4.0 3000 4.5 2600 6.0 x 2100 40 7.0 3200 i 30 7.5 3900 8.0 3200 8.5 4100 25 9.0 3200 10.0 3200 10.5 4000 10 15 20 25 30 35 12 x 12 .5 13.0 14.0 15.0 15.5 16.0 16.5 1900 3500 5200 4200 4500 5500 4200 3700 451 470 10 Table 3 shows the results obtained after the addition of 0.4 parts of propylamine phosphate, calculated as amine, to batter 1, glpssmeten.
Tabell 3 Med tillsats av 0,4 delar (propylaminßfosfat Tidpunkt Tillsats viskositet Halt min smet 2 mPas smet 1, 96 0 X 900 100 1 1500 75 1 ,5 2000 2 1900 3 1900 4 1900 4,5 1900 25 6 X 1800 7 1800 8 1800 10 9 1800 10 1800 1 2 1850 13 1850 5 14 1850 15 1850 1 6 1850 5 10 15 20 25 30 35 451 470 lett laboratorietest, vilket genomfördes genom att blanda en smet 1 och en smet 2 i olika förhållanden under försiktig omrörning under 1 minut fastställdes erhâllen viskositet enligt Brookfield (30 s 100 rpm). I ett sådant test studerades blandningen mellan en gipsbaserad smet enligt ovan, smet 1, och en kaolinsmet, smet 2, med syntetiskt förtjockningsmedel, TS 55% och viskositet 400 mPas.Table 3 With addition of 0.4 parts (propylamine phosphate Time Additive viscosity Content min batter 2 mPas batter 1, 96 0 X 900 100 1 1500 75 1, 5 2000 2 1900 3 1900 4 1900 4.5 1900 25 6 X 1800 7 1800 8 1800 10 9 1800 10 1800 1 2 1850 13 1850 5 14 1850 15 1850 1 6 1850 5 10 15 20 25 30 35 451 470 led laboratory test, which was carried out by mixing a batter 1 and a batter 2 in different conditions with gentle stirring for 1 minute, the viscosity obtained was determined according to Brookfield (30 s 100 rpm) In such a test, the mixture between a gypsum-based batter as above, batter 1, and a kaolin batter, batter 2, with synthetic thickener, TS 55% and viscosity 400 mPas was studied.
Resultaten framgår av tabell 4 och 5, resp.The results are shown in Tables 4 and 5, resp.
Tabell 4 Utan tillsats Sill ingå 'viskositet mPas 0 100 450 5 95 2300 10 90 2500 20 80 2000 40 60 1600 70 30 1200 100 0 500 Tabell 5 Med tillsats av 0,4 delar (sekhutylamirfiz citrat §rEt__1_ flgtl viskositet mPas 0 100 450 5 95 750 20 80 -z 800 40 60 f 800 70 30 850 100 0 500 Som framgår av ovanstående sker en utomordentlig viskositetsstabilisering vid användning av ett alkylaminsyraadditionssalt enligt ovan.Table 4 Without additive Herring included 'viscosity mPas 0 100 450 5 95 2300 10 90 2500 20 80 2000 40 60 1600 70 30 1200 100 0 500 Table 5 With addition of 0.4 parts (sekhutylamir fi z citrate §rEt__1_ fl gtl viscosity mPas 0 100 450 5 95 750 20 80 -z 800 40 60 f 800 70 30 850 100 0 500 As can be seen from the above, an excellent viscosity stabilization takes place when using an alkylamic acid addition salt as above.
Vid användning av alkylaminsyraadditionssaltet har det visat sig möjligt att få en godtagbar effekt även då endast en del av alkylaminen föreligger i form av sådant syraadditionssalt.When using the alkylamic acid addition salt, it has been found possible to obtain an acceptable effect even when only a part of the alkylamine is present in the form of such an acid addition salt.
Det är vidare möjligt att tillsätta saltkomponenterna, dvs alkylamin och syra, var för sig direkt till bestrykningssmeten för uppnående av ett bra resultat. 10 451 470 Med kaolinbaserad smet avses häri en smet som innehåller mer än 50% kaolin av pigmentdelen. Det är sålunda känt kaolínsmetar med 60% kaolín och 4096 gips.It is further possible to add the salt components, i.e. alkylamine and acid, separately directly to the coating batter to achieve a good result. By kaolin-based batter is meant herein a batter which contains more than 50% kaolin of the pigment moiety. It is thus known kaolin anglers with 60% kaolin and 4096 gypsum.
Med kritabaserad smet avses en smet som innehåller mer än 5096 krita, och_ med gipsbaserad smet en smet som innehåller mer än 5Ö96 gips. Pígmentdelen behöver sålunda ej vara 100%-igt baserad på ett pigment.Chalk-based batter refers to a batter that contains more than 5096 chalk, and gypsum-based batter a batter that contains more than 5Ö96 gypsum. Thus, the pigment portion need not be 100% based on a pigment.
Claims (8)
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
SE8505811A SE451470B (en) | 1985-12-09 | 1985-12-09 | APPLICATION OF AN ACID ADDITION SALT OF AN ALKYLAMINE FOR REGULATING THE VISCOSITY OF PAPER COATING METHODS |
FI864771A FI864771A (en) | 1985-12-09 | 1986-11-24 | VISKOSITETSREGLERANDE MEDEL. |
ES86850427T ES2016568B3 (en) | 1985-12-09 | 1986-12-08 | VISCOSITY REGULATORY SUBSTANCE. |
EP86850427A EP0227623B1 (en) | 1985-12-09 | 1986-12-08 | Use of alkylamine salts as viscosity regulating substance |
DE8686850427T DE3673144D1 (en) | 1985-12-09 | 1986-12-08 | USE OF ALKYLAMINE SALTS AS A VISCOSITY REGULATING SUBSTANCE. |
AT86850427T ATE55107T1 (en) | 1985-12-09 | 1986-12-08 | USE OF ALKYLAMINE SALTS AS VISCOSITY REGULATOR. |
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SE8505811A SE451470B (en) | 1985-12-09 | 1985-12-09 | APPLICATION OF AN ACID ADDITION SALT OF AN ALKYLAMINE FOR REGULATING THE VISCOSITY OF PAPER COATING METHODS |
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SE8505811D0 SE8505811D0 (en) | 1985-12-09 |
SE8505811L SE8505811L (en) | 1987-06-10 |
SE451470B true SE451470B (en) | 1987-10-12 |
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EP (1) | EP0227623B1 (en) |
AT (1) | ATE55107T1 (en) |
DE (1) | DE3673144D1 (en) |
ES (1) | ES2016568B3 (en) |
FI (1) | FI864771A (en) |
SE (1) | SE451470B (en) |
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US8252143B2 (en) | 2004-06-22 | 2012-08-28 | Akzo Nobel N.V. | Filler for paper making process |
CN1965128A (en) * | 2004-06-22 | 2007-05-16 | 阿克佐诺贝尔公司 | Filler for paper making process |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1150561A (en) * | 1965-07-14 | 1969-04-30 | Kurashiki Rayon Kk | Coating Compositions for High Grade Paper |
DE1696193B2 (en) * | 1966-04-07 | 1974-07-04 | Farbwerke Hoechst Ag, Vormals Meister Lucius & Bruening, 6000 Frankfurt | Satin white coating slips with good viscosity stability |
DE2810348A1 (en) * | 1978-03-10 | 1979-09-20 | Hoechst Ag | AQUEOUS PLASTIC DISPERSION BASED ON VINYL POLYMERS |
-
1985
- 1985-12-09 SE SE8505811A patent/SE451470B/en not_active IP Right Cessation
-
1986
- 1986-11-24 FI FI864771A patent/FI864771A/en not_active Application Discontinuation
- 1986-12-08 EP EP86850427A patent/EP0227623B1/en not_active Expired - Lifetime
- 1986-12-08 AT AT86850427T patent/ATE55107T1/en not_active IP Right Cessation
- 1986-12-08 ES ES86850427T patent/ES2016568B3/en not_active Expired - Lifetime
- 1986-12-08 DE DE8686850427T patent/DE3673144D1/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
SE8505811D0 (en) | 1985-12-09 |
DE3673144D1 (en) | 1990-09-06 |
ES2016568B3 (en) | 1990-11-16 |
FI864771A (en) | 1987-06-10 |
EP0227623A1 (en) | 1987-07-01 |
FI864771A0 (en) | 1986-11-24 |
SE8505811L (en) | 1987-06-10 |
EP0227623B1 (en) | 1990-08-01 |
ATE55107T1 (en) | 1990-08-15 |
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