SE2350068A1 - A process for upgradation of paper pulp quality - Google Patents
A process for upgradation of paper pulp qualityInfo
- Publication number
- SE2350068A1 SE2350068A1 SE2350068A SE2350068A SE2350068A1 SE 2350068 A1 SE2350068 A1 SE 2350068A1 SE 2350068 A SE2350068 A SE 2350068A SE 2350068 A SE2350068 A SE 2350068A SE 2350068 A1 SE2350068 A1 SE 2350068A1
- Authority
- SE
- Sweden
- Prior art keywords
- pulp
- feedstock
- process according
- paper
- barg
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 78
- 230000008569 process Effects 0.000 title claims abstract description 74
- 229920001131 Pulp (paper) Polymers 0.000 title claims abstract description 41
- 238000010521 absorption reaction Methods 0.000 claims abstract description 27
- 238000004806 packaging method and process Methods 0.000 claims abstract description 11
- 239000002023 wood Substances 0.000 claims abstract description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 20
- 238000004519 manufacturing process Methods 0.000 claims description 14
- 238000000926 separation method Methods 0.000 claims description 8
- 101100536354 Drosophila melanogaster tant gene Proteins 0.000 claims description 7
- 241000272470 Circus Species 0.000 claims description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 4
- 239000001301 oxygen Substances 0.000 claims description 4
- 229910052760 oxygen Inorganic materials 0.000 claims description 4
- 238000007599 discharging Methods 0.000 claims description 2
- 239000007788 liquid Substances 0.000 abstract description 6
- 239000006096 absorbing agent Substances 0.000 abstract description 3
- 239000000123 paper Substances 0.000 description 33
- 239000000047 product Substances 0.000 description 26
- 238000001035 drying Methods 0.000 description 17
- 102100031260 Acyl-coenzyme A thioesterase THEM4 Human genes 0.000 description 6
- 101000638510 Homo sapiens Acyl-coenzyme A thioesterase THEM4 Proteins 0.000 description 6
- 239000013074 reference sample Substances 0.000 description 6
- 239000002655 kraft paper Substances 0.000 description 5
- 239000007789 gas Substances 0.000 description 4
- 230000001976 improved effect Effects 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 239000000523 sample Substances 0.000 description 4
- -1 board Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000011122 softwood Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 229920000875 Dissolving pulp Polymers 0.000 description 2
- 230000004888 barrier function Effects 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 238000004880 explosion Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 238000004537 pulping Methods 0.000 description 2
- 238000012827 research and development Methods 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- 229920001046 Nanocellulose Polymers 0.000 description 1
- 238000002835 absorbance Methods 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 235000019568 aromas Nutrition 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000007385 chemical modification Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000002803 fossil fuel Substances 0.000 description 1
- 238000004108 freeze drying Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000011121 hardwood Substances 0.000 description 1
- 238000011031 large-scale manufacturing process Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000013618 particulate matter Substances 0.000 description 1
- 238000010248 power generation Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000002459 sustained effect Effects 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
Classifications
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
- D21C9/18—De-watering; Elimination of cooking or pulp-treating liquors from the pulp
- D21C9/185—De-watering; Elimination of cooking or pulp-treating liquors from the pulp comprising at least one step where the pulp is suspended in a gaseous medium, e.g. flash drying
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
- D21C9/001—Modification of pulp properties
- D21C9/007—Modification of pulp properties by mechanical or physical means
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H11/00—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
- D21H11/16—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only modified by a particular after-treatment
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F26—DRYING
- F26B—DRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
- F26B21/00—Arrangements or duct systems, e.g. in combination with pallet boxes, for supplying and controlling air or gases for drying solid materials or objects
- F26B21/06—Controlling, e.g. regulating, parameters of gas supply
- F26B21/10—Temperature; Pressure
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F26—DRYING
- F26B—DRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
- F26B3/00—Drying solid materials or objects by processes involving the application of heat
- F26B3/02—Drying solid materials or objects by processes involving the application of heat by convection, i.e. heat being conveyed from a heat source to the materials or objects to be dried by a gas or vapour, e.g. air
- F26B3/04—Drying solid materials or objects by processes involving the application of heat by convection, i.e. heat being conveyed from a heat source to the materials or objects to be dried by a gas or vapour, e.g. air the gas or vapour circulating over or surrounding the materials or objects to be dried
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F26—DRYING
- F26B—DRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
- F26B2200/00—Drying processes and machines for solid materials characterised by the specific requirements of the drying good
- F26B2200/24—Wood particles, e.g. shavings, cuttings, saw dust
Landscapes
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Mechanical Engineering (AREA)
- Wood Science & Technology (AREA)
- General Engineering & Computer Science (AREA)
- Microbiology (AREA)
- Paper (AREA)
Abstract
The present invention discloses a process for upgradation of pulp quality. The present invention discloses the process for the upgradation of characteristics bulk and absorption capacity of bleached and non-bleached paper pulp wood and nonwood feedstocks for various applications. The resultant pulp can be utilized in sanitary applications, tissue making, packaging paper, specialty papers, dry and wet molded products, healthcare, food and liquid absorbers and print/publication paper.
Description
A process for upgradation of paper pulp quality Technical field of the invention The present invention relates to a process for upgradation of paper pulp quality, such as characteristic bulk and absorption capacity of bleached and non-bleached paper pulp. Background of the lnvention Quality of market pulp is determined by different parameters depending upon the final application. For sanitary products like diapers, kitchen, towel, napkin the absorption capacity for a given amount of pulp is important. Bulk is an important parameter for all applications as it is closely related to absorption capacity and softness of the final product. Bulk is also of importance for other paper and board products as it improves the bending stiffness.
Different processes have been suggested in the past to improve the bulk and absorption properties of market pulps. Chemical modification of cellulosic fibers, blending with high absorbent cellulosic material as nanocellulose, and synthetic polymers are examples that have been tested.
The most common drying technique of pulp is air-drying, alternative processes have been evaluated in the past to improve and preserve the bulk and absorption e.g., freeze, and vacuum drying. These processes have their challenges in being implemented on a larger scale, as the drying takes place with significantly less drying content, which is also an expensive process to carry out.
Drying with superheated steam is another drying process that have the possibility to improve the bulk and the absorption capacity, but the research has been very limited especially when it comes to study the final properties of market pulps. Earlier work has reported improved effect on paper and pulp properties with superheated steam drying (McCall J. and Douglas W.J.M. Enhancement of properties of diverse grades of paper by superheated steam drying. ln: proceedings at the 14th International Drying Symposium (IDS 2004) Sao Paulo. Brazil, 22-25 of August, BB pp. 1255- 1262) wherein the strength properties increased up to 32 % for paper and 10 % for bulk.
The conventional drying technologies are not necessarily optimal in terms of energy consumption, quality of dried product, safety in operation, ability to control the dryer in the event of process upsets, ability to perform optimally even with large changes in throughput, ease of control, and minimal environmental impact due to emissions or combustion of fossil fuels used to provide energy for drying.
Most drying technologies were developed empirically over sustained periods of time, often by small vendors of drying equipment with little access to research and development (R&D) resources human or financial. They were also designed at a time when energy and environmental considerations as well as quality demands were not very stringent.
Perhaps most processes are already designed and operated at their asymptotic limit of performance. However, if for any reason one aims to exceed the performance of drying pulp in a cost-effective way, there is a need for alternative technologies with a higher asymptotic limit to performance, which is necessarily below the maximum defined by thermodynamic constraints. ln view of the above, there is a need to develop a process for improving paper pulp qualities that can be implemented in small- or large-scale production of market pulp, with no emission and in a cost-effective manner. Summary of the invention lt is a first objective of the present disclosure to provide a process for upgradation of paper pulp quality.
Another objective of the present disclosure is to provide a pulp demonstrating improved properties such as increased bulk properties and absorption properties.
Another objective of the present disclosure is to provide a process for the upgradation of characteristics bulk and absorption capacity of bleached and non- bleached paper pulp such as mechanical pulp, chemical pulp, thermo-mechanical pulp, chemical thermo-mechanical pulp and dissolving pulp from wood and non- wood feedstocks.
Accordingly, the present disclosure provides a process for upgradation of quality of pulp feedstock wherein the process steps comprising: i. feeding said pulp wet feedstock into vaporized oxygen free upgradation apparatus at elevated pressure conditions in the range between 0.1 barg to 10 barg, ii. subjecting said feedstock to super-heated circulating vapor at a temperature in the range 120 °C to 300 °C, thereby modifying the properties of said feedstock, iii. discharging the modified pulp feedstock from said upgradation apparatus when the moisture content of the pulp feedstock is controlled between 5 % to 30 %, wherein, said process is characterized by the operating parameters of high temperature and pressure at a short residence time between 2 seconds to 3 minutes. ln another aspect of the present disclosure, the moisture content of the resu|tant pulp feedstock is controlled between 5 % to 30 %, preferably 10 % to 20 %. ln another aspect of the present disclosure, the bulk properties of the resu|tant pulp feedstock obtained by claimed process is enhanced by 5 % to 40 %. ln another aspect of the present disclosure, the absorption of the resu|tant pulp feedstock obtained by the process of the present disclosure is enhanced by 50 to 100 %. ln another aspect of the present disclosure, wet feedstock in step (i) is selected from the group consisting wood and non-wood feedstocks. ln another aspect of the present disclosure, the elevated pressure in step (i) is in the range of 0.5 barg to 6 barg, preferably between 2 barg to 4 barg. ln another aspect of the present disclosure, the elevated temperature in step (ii) is in the range of 120 °C to 300 °C, preferably in 130 °C to 180 °C. ln another aspect of the present invention, the residence time for the feedstock inside the apparatus is between 1 second to 3 minutes, preferably in 10 seconds to seconds. ln another aspect of the present disclosure, the process further comprises extracting moisture from resultant feedstock in the form of vapor from the apparatus. ln another aspect of the present disclosure, the process further comprises circulating vapors inside the upgradation apparatus constantly. ln another aspect of the present disclosure, the process further comprises the constant circu|ation of vapor by arrangement of one or more circulating fans. ln another aspect of the present disclosure, the process further comprises elevated operating temperatures between 120 °C to 300 °C. ln another aspect of the present disclosure, the process further comprises elevated operating temperature between 120 °C to 300 °C by heat exchangers. ln another aspect of the present disclosure, the process further comprises circulating vapor through a combination of conduits. ln another aspect of the present disclosure, the process further comprises: iv. separating vapors and processed pulp in separator, v. re-circulating the separated vapor to heat exchangers. ln another aspect of the present disclosure, the upgraded property of the feedstock is achieved by the process defined in claim 1 by the combination of pressure, temperature and short residence time. ln another aspect of the present disclosure, the process is carried out in the upgradation apparatus which consists of a closed, pressurized conveying loop, in which superheated vapor is circulated by means of one or more fans , the conveying loop is fitted with feeding and discharge apparatus, heat exchangers for adding heat and controlling of temperature and water content, a separation apparatus such as cyclone for separation of paper pulp and vapors. ln another aspect of the present disclosure, the upgraded properties of the resultant feedstock increase in bulk, increase in absorption capacity and changes in tensile strength. ln another aspect of the present disclosure, the upgraded and dried feedstock is used in the production of various products including tissue papers, hygiene articles, packaging paper, board, other paper products etc. ln another aspect of the present disclosure, there is provided a tissue paper, hygiene article, packaging paper, board, and other paper products produced by the upgraded and dried feedstock. ln another aspect of the present disclosure, there is provided a process wherein, the upgraded resultant feedstock, finally dried in a PSSD dryer, for example at 2.5 bar, exhibits increased bulk capacity of at least 5 %, and increased absorption capacity of at least 50 %, compared to a referenced sample which is finally commercially flash dried. ln another aspect of the present disclosure, there is provided a process wherein the upgraded and dried feedstock, is used in the production of various products including tissue papers, hygiene articles, packaging paper, board, other paper products, wherein said products exhibit a bulk capacity of at least 3 cm3/g. ln another aspect of the present disclosure, there is provided a pulp having a moisture content of 5 % to 30 %, and an absorption capacity of at least 15 g/g. Corresponding to at least a 50 % increase compared to traditionally dried pulp. ln another aspect of the present disclosure there is provided a paper product such as tissue paper, hygiene articles, packaging paper, and boards produced by the upgraded and dried feedstock or pulp, wherein said products exhibit a bulk capacity of at least 3 cm3/g. Corresponding to an increase in at least 5 % compared to traditionally dried pulp.
Brief description of drawings: FIG. 1 lllustrates an example of an apparatus suitable for manufacturing a pulp of the present disclosure. FIG. 2 lllustrates a configuration of the apparatus shown in Fig. 1.
Detailed description of disclosure The present invention may be understood more readily by reference to the following detailed description of the invention taken in connection with the accompanying drawing figures, which forms a part of this disclosure. lt is to be understood that this invention is not limited to the specific apparatus, process, conditions, or parameters described and/or shown herein and that the terminology used herein is for the example only and is not intended to be limiting of the claimed invention. Also, as used in the specification including the appended claims, the singular forms 'a', 'an', and 'the' include the plural, and references to a particular numerical value includes at least that value unless the content clearly directs otherwise. Ranges may be expressed herein as from 'about' or approximately' another value when such a range is expressed another embodiment. Also, it will be understood that unless otherwise indicated, dimensions and material Characteristics stated herein are by way of example rather than limitation and are for better understanding of sample embodiment of suitable utility, and variations outside of the stated values may also be within the scope of the invention depending upon the application.
Embodiments will now be described in detail with reference to the accompanying drawings. To avoid unnecessarily redundancy in the present disclosure, well-known features may not be described or substantially the same elements may not be redundantly described, for example. This is for ease of understanding.
The following description are provided to enable those skilled in the art to fully understand the present disclosure and are in no way intended to limit the scope of the present disclosure as set forth. ln one embodiment of the present invention, a process for upgradation of paper pulp quality is disclosed herein. The term pulp is also mentioned as feedstock pulp or feedstock.
According to one embodiment of the present invention, the sustainable increase in bulk and absorption capacity of the paper pulp is achieved by the process by the combination of pressure, temperature and time in a single step. it ie pertinent te nete thet the buik ef paper ie defined ae tideheity ie defined es producing high buik paper has ett eeeriemieei advantage for pepermekers since less puip fibres can be used te produce paper at a given thickness. in addition, controlling buik of a sheet or producing a high bulk sheet is an important technoiogyf for speciaity paper like fiiter paper.
Further, market pulp is defined as paper pulp produced by pulp and paper mills for sale to external clients is often termed as market pulp. Paper mills that are integrated mills for production of paper pulp and final products like paper, packaging etc. normally does not produce market pulp as their production is for own consumption. However, integrated mills with excess pulp production capacity can produce market pulp. ln another embodiment of the present invention, an apparatus suitable for performing the process of the present disclosure is shown in Fig 1. The apparatus consists of a closed, pressurized conveying loop, in which superheated water vapor is circulated by means of a blower. The conveying loop is fitted with gas tight feeding and discharge apparatus, heat exchangers for adding heat and controlling of temperature and water content, a separation apparatus such as cyclone for separation of paper pulp and vapors. During the process, paper pulp particles are subject to uniform treatment to each particle for homogenous product quality. ln another embodiment of the present invention, the apparatus consists of an arrangement of heat-to-heat exchangers, that are added indirectly from external sources such as high-pressure steam, thermal oil, hot gases, electricity etc. wherein, the amount of heat is carefully controlled to achieve drying of the paper pulp and quality improvements.
According to another embodiment of the present invention, the apparatus as shown in Fig. 1, consists of heat exchangers 2 which are vertical and/or horizontal, circulating fan 4 before heat exchangers 2 and/or circulating fan 3 after heat exchangers 2, feeding cell wheel 6, feeding conveyor 5; drying & transport conduits 7, top connector conduits 8, loop heat exchangers 9, bottom connecting conduits 10, cyclone connecting conduits 11, cyclone separators 12, vortex breaker hoppers 13, discharge cell wheel 14, flash vessel/cooler vessel 15, air lock 16, discharge product conveyor 17.
Further, the heat energy supply apparatus consists of a heat generator 1 and for cleaning of recovered vapors from main apparatus, there may be a vapor scrubber 18 and/or a vapor scrubber 18 and a re-boiler 19 with a circulation pump 20.
As an alternative to heat generator 1, a mechanical vapor re-compressor 2) may be used as illustrated in Fig. 2.
According to another embodiment of the present invention, the apparatus is 100 % closed loop system with no openings to the atmosphere. This means that there is no emission to the atmosphere from the apparatus during operation. The apparatus works at elevated pressures from 0.1 barg to 10 barg. During pressurization of the apparatus, all oxygen is driven out, thereby creating an oxygen free atmosphere inside the apparatus. This eliminates any risk of fire and explosion inside the apparatus, which is very important. Further, feedstock that passes through the apparatus will not get oxidized. The temperature inside the apparatus is in the range of from 120 °C to 300 °C.
According to another embodiment of the present invention, vapors inside the apparatus are kept in constant circulation by circulating fan 3 or circulation fan 4 or both circulating fans 3 and 4. Heat energy required by apparatus for modification of feed-stock properties and removal of moisture is added in heat exchanger 2 and heat exchangers 9. ln the apparatus there is only one heat exchanger of type 2 or one heat exchanger of type 2 and one or several heat exchangers of type 9. Also, any combination of heat exchangers 2 and heat exchangers 9 can be used. Heat generator 1 can be a steam boiler providing steam heat and/or thermal oil heater and/or hot gas generator using liquid or gaseous fuel providing heat energy to the exchangers 2 and 9. Heat transfer in heat exchangers 2 and 9 is always indirect and heating media is not allowed to mix with vapors being heated inside the apparatus.
According to another embodiment of the present invention, wet feedstock A is fed inside the apparatus by conveyor 5 and cell wheel 6. Cell wheel 6 allows the wet feedstock to enter inside the apparatus working at elevated pressure between 0.1 barg to 10 barg. Rotating wings of the cell wheel maintain pressure barrier with minimum leakage of vapors from inside the apparatus. Feed stock once inside the apparatus, meets hot super-heated vapors circulating inside the apparatus at a temperature in the range of from 120 °C to 300 °C. Feedstock along with circulating vapors B passes through drying conduits 7, connecting top conduits 8, heat exchangers 9, bottom connecting conduits 10 and conduit connecting to cyclone 11. Feed stock properties are modified and moisture in the feed stock is extracted and converted into vapors inside the apparatus. Feedstock and vapors are separated inside cyclone separators 12 and discharged through vortex breaker hopper 13 and discharge cell wheel 14. Cell Wheel 14 maintains pressure barrier between apparatus and outside atmosphere. Feed stock is now allowed to cool inside the flash vessel/cooler 15 and finally discharged to conveyor 17 via air lock 16. Residence time for feedstock inside the apparatus is between 1 second to 30 seconds. Feedstock stays inside the apparatus for 1 to 30 seconds. Combination of pressure, temperate and short residence time instantly modifies feedstock properties. Most significant modifications achieved are increase in bulk, increase in absorption capacity and changes in the tensile strength.
Modified and dried feedstock D is ready for use in production of various products like tissue paper, hygiene articles, packaging paper and board, other paper products etc.
According to another embodiment of the present invention, vapors C separated in cyclone separators 12 is re-circulated back to heat exchanger 2 though circulating fan 4 and/or circulating fan 3. This process continues as continuous process. As more wet feed stock is processed, more vapors are generated inside the apparatus and pressure increases as whole apparatus has fixed volume. ln order to maintain constant pressure between 0.1 barg to 10 barg inside the apparatus, part of the vapors is released as recovered vapors E. Recovered vapors mainly consist of moisture from feedstock and some particulate matter along with volatiles from feedstock. These vapors can be used in other industrial processes for heating, power generation in condensing turbine or ORC systems, district heat production, C02 capture or any other purposes. Vapors can be cleaned from dust particles in a wet scrubber 18 and used as clean vapors F. Generated vapors can also be used to generated clean steam G using clean condensate H and used in steam turbines or other processes. Condensed vapors I are used in scrubber 18 to clean generated vapors and is available as liquid phase. When removing water vapors in the apparatus, this liquid phase is available as liquid water. The apparatus helps in reducing water footprint by recovery of feedstock moisture as liquid water. Vapors may also consist of other valuable aromas or chemicals and can be recovered and used/reused.
According to another embodiment of the present invention, clean steam G can be compressed in a mechanical vapor re-compressor 21 to increase pressure of clean steam from 7 barg to 50 barg and condensed in heat exchanger 2 and/or heat exchangers 9 to transfer required heat energy for operating the apparatus. Only electrical energy is needed to operate mechanical vapor re-compressor 21. Mechanical vapor re-compressor 21 eliminates need of thermal energy from heat generator 1. The apparatus with mechanical vapor re-compressor 21 becomes 100 % electrified process with no need for thermal energy.
According to another embodiment of the present invention, paper pulp temperature is increased momentarily to 130 °C to 180 °C and pressure 0.5 barg to 6 barg, preferably 2 barg to 4 barg. The temperature is maintained for a period of 2 seconds to 3 minutes, preferably 10 to 15 seconds. Increase in temperature and pressure is obtained by allowing paper pulp to be contacted with water vapors at pressure 0.5 to 6 barg.
According to another embodiment of the present invention, the paper pulp moisture is controlled between 10 % to 20 % at the end of the process by evaporating water from paper pulp which has moisture 80 % to 60 % at the inlet of the apparatus.
The apparatus shown in Fig. 1 consists of a closed, pressurized conveying loop, in which superheated water vapor is circulated by means of a blower. The conveying loop is fitted with gas tight feeding and discharge apparatus, heat exchangers for adding heat and controlling of temperature and water content, a separation apparatus such as cyclone for separation of paper pulp and water vapors.
During the process, paper pulp particles are subject to uniform treatment for homogenous product quality.
The paper pulp temperature is increased momentarily to 130 °C to 180 °C. The pressure is increased momentarily to 0.5 barg to 6 barg, preferably 2 barg to 4 barg. The temperature and pressure are maintained for a period of 2 seconds to 3 minutes, preferably 10 to 15 seconds. Increase in temperature and pressure is obtained by allowing paper pulp to be contacted with water vapors at pressure of 0.5 to 6 barg.
The paper pulp moisture is controlled between 10 % to 20 % at the end of the process by evaporating water from paper pulp which has moisture 80 % to 60 % at the in|et of the apparatus.
The experimental data used in the present process is shown in Table 1.
Table 1. Process and experimental data Bleached Bleached Softwood Hardwood Paper pulp Unit CTMP CTMP Kraft Pulp Kraft Pulp lnlet T °C 30.8 30.8 29.8 29 lnlet water % 87 87 49 50 content Pressure Barg 0.5 2.5 2.5 2.5 lnlet T of water °C 227 236 235 230 vapors Residence time S 8-10 8-10 10-15 9-12 Outlet t of vapors °C 190 216 220 210 Outlet moisture % 8 6 3.7 5 content Table 1. T is temperature and CTMP means chemi-thermo mechanical pulping.
Analysis of the results of the paper pulp and sheets of the present disclosure is shown in Table 2A and B.
Table 2A. Pulp properties Paper pulp BSKP, CTMP, BHKP Absorption + 50 - 150 % Table 2B. Pulp properties after making sheet from pulp Paper pulp Bulk 11 BSKP, CTMP, BHKP +5 - 40 % Here, bëaached softwood kraft pulp is abbreviated as BSKP, bieached i-Eardwood Kraft Pulp is abbreviated as BHKP, and chemi-thermo mechanical pulping is abbreviated as CTMP. Pressurized äuperheated åteazfi Üryer is abbreviated PSSD.
Tables 2A and B demonstrate the improved properties of the present pulp (A) and the sheets made from the pulp (B). The absorption properties of the resultant pulp are improved by 50 % to 150 %, depending on the source of the pulp and process parameters. ln addition, the tensile strength of the resultant pulp found to increased or decreased depending upon the process parameters. Further, the resultant sheets made from the pulp demonstrate increased bulk properties between 5 % to 40 %.
Other paper pulp characteristics are maintained and there is no degradation of the paper pulp manufactured by the process disclosed here, which is an advantage because of the optimum process parameters.
As shown in Table 3, the pulp of the present disclosure exhibits 2 to 4 times higher absorbance when Northern Bleached Softwood Kraft (NBSK) is used, and at least 1.5 times higher absorption when finally dried in a PSSD dryer (inventive sample) compared to the reference samples finally dried in a commercial cylinder dryer. The absorption capacity of the pulp is at least 15 g/g, and between 5-12 g/g for the reference sample.
The data is demonstrated for pulp (Table 3) and for sheets (Table 4), such as a cardboard product, below. 12 Table 3. Pulp absorption Pulp Description Gravimetric lncreased determination absorption in of absorption relation to for pure pulp reference (times). (9/9)- NBSK (1) Reference finally dried in 5-6 a commercial cylinder dryer.
Pulp taken before 20-25 4 commercial dryer and finally dried in a PSSD dryer at 2.5 bar.
NBSK (2) Reference finally dried in 8-10 a commercial flash dryer.
Pulp taken before 15-17 2 commercial flash dryer and finally dried in PSSD drier at 2.5 bar.
CTMP Reference finally dried in 10-12 a commercial flash dryer. Pulp taken before 15-20 1.5-2 commercial flash dryer and finally dried in PSSD dryer at 2.5 bar.
Table 4 below shows the bulk capacity of sheets (60 g/m2) manufactured from the pulp of the present disclosure (Table 3). The sheets exhibit an increase bulk capacity compared to the reference sample. 13 Table 4. Bulk of manufactured sheets Pulp Description Determination of Increase of bulk bulk for 60 g/m2 in relation to laboratory sheet reference (wt%) (Cms/g) NBSK Reference finally dried in a 2.2 (1) commercial cylinder dryer. Re- slushing and manufacturing of 60 g/m2 sheets. Pulp removed before 3.2 45 commercial drying and finally dried in PSSD dryer at SEAB at 2.5 bar. Re-slushing and manufacturing of 60 g/m2 sheets. NBSK Reference finally dried in 2.6 (2) commercial flash dryer. Re- slushing and manufacturing of 60 g/m2 sheets.
Pulp removed before 3.1 20 commercial flash dryer and finally dried in PSSD dryer at SEAB at 2.5 bar. Re-slushing and manufacturing of 60 g/m2 sheets.
The pulp was partly dried directly in the factory for each case with the dryer that was available (reference sample), thereafter the pulp was taken out to be completely dried in the PSSD dryer (inventive sample) as described under material and methods. All masses were re-slushed in water and shaped, pressed and dried in the lab to 60 g/m2 sheets. As shown in table 4, the sheet of the present disclosure finally dried in PSSD dryer exhibits 20 to 45 % higher bulk. The bulk capacity of a product produced by the pulp presented here is at least 3 cmß/g and 2.2 to 2.6 for the reference sample, when using NBSK compared to the reference finally dried in a commercial cylinder dryer.
A pulp finally dried by using a PSSD dryer can advantageously be used directly in any product wherein a high absorption capacity is important. The pulp exhibits 1.5 to 4 times higher absorption compared to the reference sample, and the product manufactured by using the pulp, exhibits 20-45 % increased bulk capacity compared to the reference sample. 14 The apparatus has no emissions to atmosphere, no risk for fire and explosion and is most environmentally friendly and energy efficient solution.
The process disclosed here can be used for number of commercially important applications such as mechanical pulp, chemical pulp, thermo-mechanical pulp, chemical thermo-mechanical pulp and dissolving pulp from wood and non-wood feedstocks for applications for sanitary applications, tissue making, packaging paper, specialty papers, dry and wet molded products, healthcare, cardboard products, food and liquid absorbers and print/publication paper.
The resultant pulp from the above-mentioned process can be applied in a range of paper products such as sanitary applications, tissue making, packaging paper, specialty papers, dry and wet molded products, healthcare, cardboard products, food and liquid absorbers and print/publication paper.
Claims (19)
1. A process for upgradation of quality of pulp feedstock wherein the process steps comprising: i. feeding said pulp wet feedstock into a vaporized oxygen free apparatus at elevated pressure conditions in the range between 0.1 barg to 10 barg, ii. subjecting said feedstock to super-heated circulating vapor at a temperature in the range from 120 °C to 300 °C, thereby modifying the properties of said feedstock, iii. discharging the modified pulp feedstock from said upgradation apparatus when the moisture content of the pulp feedstock is controlled between 5 % to 30 %, wherein, said process is characterized by the operating parameters of high temperature and pressure at a short residence time between 2 seconds tominutes.
2. The process according to c|aim 1, wherein the moisture content of the resu|tant pulp feedstock is controlled between 5% to 30 %, preferably 10 % to 20 %.
3. The process according to any one of claims 1 or 2, wherein the bulk properties of the resu|tant pulp feedstock obtained by the process is enhanced by 5 % to 40 %.
4. The process according to any one of the preceding claims, wherein the resu|tant pulp feedstock has an enhanced absorption by 50 % to 150 %.
5. The process according to any one of the preceding claims, wherein said pulp wet feedstock in step (i) is selected form the group consisting wood and non-wood feedstocks.
6. The process according to any one of the preceding claims, wherein the elevated pressure in step (i) is in the range of 0.5 barg to 6 barg, preferably between 2 barg - 4 barg.
7. The process according to any one of the preceding claims, wherein the elevated temperature in step (ii) is in the range of from 120 °C to 300 °C, preferably from 130 °C to 180 °C.
8. The process according to any one of the preceding claims, wherein, the residence time for the feedstock inside the apparatus is between 1 second tominutes, preferably between 10 seconds to 15 seconds.
9. The process according to any one of the preceding claims, wherein the process further comprises extracting moisture from resu|tant feedstock in the form of vapor from the apparatus.
10. The process according to any one of the preceding claims, wherein the process further comprises circu|ating vapors in the internal area of the apparatus constantly.
11. The process according to any one of the preceding claims, wherein the process further comprises the constant circu|ation of vapor by arrangement of one or more circu|ating fans.
12. The process according to any one of the preceding claims, wherein the process further comprises elevated operating temperature such as temperature in the range of from 120 °C to 300 °C, preferably between 130 °C to 180 °C by heat exchangers.
13. The process according to any one of the preceding claims, wherein the process further comprises circu|ating vapor through a combination of conduits.
14. The process according to any one of the preceding claims, wherein the process further comprises the steps of iv. separating vapor in a separator, v. re-circu|ating the separated vapor to heat exchangers.
15. The process according to any one of the preceding claims, wherein the process is carried out in an apparatus comprising a closed, pressurized conveying loop, in which superheated water vapor is circulated by means of a blower, the conveying loop is fitted with feeding and discharge apparatus, heat exchangers foradding heat and controlling of temperature and water content, a separation apparatus such as cyclone for separation of paper pulp and water vapors.
16. The process according to any one of the preceding claims, wherein, the upgraded resultant pulp feedstock, finally dried in a PSSD dryer exhibits increased absorption capacity of at least 50 %, compared to a referenced sample finally commercially flash dried.
17. The process according to any one of the preceding claims, wherein, the upgraded and dried pulp feedstock is used in the production of various products including tissue papers, hygiene articles, packaging paper, board, other paper products, wherein said products exhibit a bulk capacity of at least 3 cm3/g.
18. A pulp feedstock having a moisture content of 5 % to 30 %, and an absorption capacity of at least 15 g/g.
19. A paper product such as tissue paper, hygiene articles, packaging paper, and boards produced by the upgraded and dried pulp feedstock produced according to any one of claims 1-17 or the pulp feedstock according to claim 18, wherein said products exhibit a bulk capacity of at least 3 cm3/g.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/SE2023/050189 WO2023167626A1 (en) | 2022-03-04 | 2023-03-02 | A process for upgradation of paper pulp quality |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SE2250298 | 2022-03-04 |
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| SE2350068A1 true SE2350068A1 (en) | 2023-09-05 |
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| Application Number | Title | Priority Date | Filing Date |
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| SE2350068A SE2350068A1 (en) | 2022-03-04 | 2023-01-26 | A process for upgradation of paper pulp quality |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4537655A (en) * | 1982-05-07 | 1985-08-27 | Modo-Chemetics Ab | Process for producing and flash drying high yield mechanical cellulose pulp with steam and condensate recycle |
| WO1994023121A1 (en) * | 1993-03-26 | 1994-10-13 | James River Corporation Of Virginia | Process for crosslinking of cellulosic fibers |
| US6322667B1 (en) * | 1994-07-04 | 2001-11-27 | Mcgill University | Paper and paperboard of improved mechanical properties |
| US20150376347A1 (en) * | 2014-06-30 | 2015-12-31 | Weyerhaeuser Nr Company | Modified fiber, methods, and systems |
| WO2016029904A2 (en) * | 2014-08-25 | 2016-03-03 | McAirlaid's Vliesstoffe GmbH | Absorbent fibrous web |
-
2023
- 2023-01-26 SE SE2350068A patent/SE2350068A1/en unknown
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4537655A (en) * | 1982-05-07 | 1985-08-27 | Modo-Chemetics Ab | Process for producing and flash drying high yield mechanical cellulose pulp with steam and condensate recycle |
| WO1994023121A1 (en) * | 1993-03-26 | 1994-10-13 | James River Corporation Of Virginia | Process for crosslinking of cellulosic fibers |
| US6322667B1 (en) * | 1994-07-04 | 2001-11-27 | Mcgill University | Paper and paperboard of improved mechanical properties |
| US20150376347A1 (en) * | 2014-06-30 | 2015-12-31 | Weyerhaeuser Nr Company | Modified fiber, methods, and systems |
| WO2016029904A2 (en) * | 2014-08-25 | 2016-03-03 | McAirlaid's Vliesstoffe GmbH | Absorbent fibrous web |
Non-Patent Citations (3)
| Title |
|---|
| McCall JM et al., "Use of superheated steam drying to increase strength and bulk of papers produced from diverse commercial furnishes", Drying Technology, 2006, vol. 24, pp. 233-238. See 235, left column, first paragraph, lines 1-4 * |
| Romdhana H et al., "Superheated steam drying: An overview of pilot and industrial dryers with a focus on energy efficiency", Drying Technology, 2015, vol. 33, pp. 1255-1274 * |
| Svensson C, "Steam drying of pulp", In: International Drying Symposium (IDS'80), McGill University, Montreal, August; Hemisphere: New York, 1980, pp. 301-307 * |
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