SE2250977A1 - A direct reduction facility for reduction of a metal oxide material - Google Patents

A direct reduction facility for reduction of a metal oxide material

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Publication number
SE2250977A1
SE2250977A1 SE2250977A SE2250977A SE2250977A1 SE 2250977 A1 SE2250977 A1 SE 2250977A1 SE 2250977 A SE2250977 A SE 2250977A SE 2250977 A SE2250977 A SE 2250977A SE 2250977 A1 SE2250977 A1 SE 2250977A1
Authority
SE
Sweden
Prior art keywords
hydrogen gas
reducing agent
temperature
direct reduction
metal oxide
Prior art date
Application number
SE2250977A
Inventor
Björn Åström
Daniel Marjavaara
Göran Tuomas
Ola Eriksson
Original Assignee
Luossavaara Kiirunavaara Ab
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Luossavaara Kiirunavaara Ab filed Critical Luossavaara Kiirunavaara Ab
Priority to SE2250977A priority Critical patent/SE2250977A1/en
Priority to PCT/SE2023/050837 priority patent/WO2024039280A1/en
Publication of SE2250977A1 publication Critical patent/SE2250977A1/en

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Classifications

    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21BMANUFACTURE OF IRON OR STEEL
    • C21B13/00Making spongy iron or liquid steel, by direct processes
    • C21B13/0073Selection or treatment of the reducing gases
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21BMANUFACTURE OF IRON OR STEEL
    • C21B13/00Making spongy iron or liquid steel, by direct processes
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21BMANUFACTURE OF IRON OR STEEL
    • C21B13/00Making spongy iron or liquid steel, by direct processes
    • C21B13/004Making spongy iron or liquid steel, by direct processes in a continuous way by reduction from ores
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21BMANUFACTURE OF IRON OR STEEL
    • C21B13/00Making spongy iron or liquid steel, by direct processes
    • C21B13/0046Making spongy iron or liquid steel, by direct processes making metallised agglomerates or iron oxide
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B5/00General methods of reducing to metals
    • C22B5/02Dry methods smelting of sulfides or formation of mattes
    • C22B5/12Dry methods smelting of sulfides or formation of mattes by gases
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21BMANUFACTURE OF IRON OR STEEL
    • C21B2100/00Handling of exhaust gases produced during the manufacture of iron or steel
    • C21B2100/20Increasing the gas reduction potential of recycled exhaust gases
    • C21B2100/22Increasing the gas reduction potential of recycled exhaust gases by reforming
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21BMANUFACTURE OF IRON OR STEEL
    • C21B2100/00Handling of exhaust gases produced during the manufacture of iron or steel
    • C21B2100/40Gas purification of exhaust gases to be recirculated or used in other metallurgical processes
    • C21B2100/44Removing particles, e.g. by scrubbing, dedusting
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21BMANUFACTURE OF IRON OR STEEL
    • C21B2100/00Handling of exhaust gases produced during the manufacture of iron or steel
    • C21B2100/60Process control or energy utilisation in the manufacture of iron or steel
    • C21B2100/66Heat exchange
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21BMANUFACTURE OF IRON OR STEEL
    • C21B2300/00Process aspects
    • C21B2300/04Modeling of the process, e.g. for control purposes; CII
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00Electrolytic production of inorganic compounds or non-metals
    • C25B1/01Products
    • C25B1/02Hydrogen or oxygen
    • C25B1/04Hydrogen or oxygen by electrolysis of water
    • C25B1/042Hydrogen or oxygen by electrolysis of water by electrolysis of steam
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B15/00Operating or servicing cells
    • C25B15/08Supplying or removing reactants or electrolytes; Regeneration of electrolytes
    • C25B15/081Supplying products to non-electrochemical reactors that are combined with the electrochemical cell, e.g. Sabatier reactor
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/10Reduction of greenhouse gas [GHG] emissions
    • Y02P10/134Reduction of greenhouse gas [GHG] emissions by avoiding CO2, e.g. using hydrogen
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/25Process efficiency

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)

Abstract

The present invention concerns a metal material production configuration (1) and a method of direct reduction of a metal oxide material (5) holding a first thermal energy into a direct reduced metal material (16) by means of a metal material production configuration (1). The method comprises charging the metal oxide material (5), holding the first thermal energy, into a direct reduction facility (7); introducing a hydrogen gas, holding a second thermal energy, into the direct reduction facility (7).The invention involves reducing the metal oxide material (5) by using the first thermal energy of the metal oxide material (5) to heat or further heat the introduced hydrogen gas containing reducing agent (8) toward a required reaction temperature for providing a chemical reaction. A high-temperature exit gas (12) is removed from the direct reduction facility and fed to a high-temperature electrolysis unit (21) configured to produce the hydrogen gas.

Description

TECHNICAL FIELD The present invention relates to a method of direct reduction of a metal oxide material into a reduced metal material according to claim 1.
The present invention further relates to a metal material production configuration according to claim 9.
The present invention further relates to a direct reduction facility configured to reduce the metal oxide material and producing a reduced metal material.
The present invention further relates to a data program adapted to control the operation of the metal material production configuration.
The present invention primarily concerns the mining industry and industries making reduced metal material, and concerns manufacturers and suppliers of metal material production configurations and metal oxide material production units, direct reduction facilities, metal making industries, high-temperature electrolysis units, data program providers etc.
The present invention may concern the metallurgical industry producing industrial metals, such as sponge iron or other types of reduced metal material.
The present invention may concern various types of metallurgical industries processing non- ferrous metals, such as aluminium, copper, lead, zinc, etc.
BACKGROUND OF THE INVENTION Current technologies designed for direct reduction of metal oxide material into reduced metal material may use different solutions to save energy.
Current technologies aim to provide energy efficient production of reduced metal material, such as sponge iron.
Current technologies aim to provide energy efficient direct reduction of metal oxide material making use of hydrogen as a reducing gas, which hydrogen entirely or partly is produced by electrolysis units utilizing fossil free and/or renewable energy.
The direct reduction ofthe metal oxide material by means ofthe introduced hydrogen gas containing reducing agent requires a high reaction temperature for providing the chemical reaction in the direct reduction facility.
SUMMARY OF THE INVENTION There is an object to provide energy efficient production of reduced metal material.
There is an object to provide efficient direct reduction ofthe metal oxide material at the same time as efficient control of the production of reduced metal material is established.
There is an object to provide efficient use of hydrogen gas in the production of a reduced metal material, which production makes use of fossil free and/or renewable energy.
There is an object to provide a method of direct reduction of a metal oxide material into a reduced metal material by using hydrogen gas produced by fossil free and/or renewable energy.
There is an object to provide a metal material production configuration configured to produce a reduced metal material on an industrial scale, in a CO2-neutral and/or C02-low emission and/or C02 free fashion.
There is an object to achieve a substantially fully metallized reduced metal material, wherein the reduced metal material is reduced greater than about 90 %, preferably about 95-100 %, thereby decreasing hydrogen accumulation and simplifying treatment and efficient re- cycling of the top gas.
There is an object to provide a metal material production configuration that operates in an energy efficient way and which is controllable toward a required reaction temperature for reaching an efficient direct reduction and/or chemical reaction in the direct reduction facility.
These or at least one of said objects has been achieved by a method of direct reduction of a metal oxide material holding a first thermal energy into a direct reduced metal material by means of a metal material production configuration; the method comprises; providing the metal oxide material, holding the first thermal energy, by means of a metal oxide material provider unit; charging the metal oxide material, holding the first thermal energy, into a direct reduction facility; introducing a hydrogen gas containing reducing agent, holding a second thermal energy, into the direct reduction facility. The method comprises the steps of; reducing the metal oxide material by using the first thermal energy of the metal oxide material to heat or further heat the introduced hydrogen gas containing reducing agent toward a required reaction temperature for providing a chemical reaction between the hydrogen gas containing reducing agent and the metal oxide material; removing a high- temperature exit gas from the reduction facility; feeding a high-temperature water steam of the high-temperature exit gas to a high-temperature electrolysis unit configured to produce a hydrogen gas; and introducing the hydrogen gas into the direct reduction facility.
Alternatively, the method comprises the step of adding the hydrogen gas to the hydrogen gas containing reducing agent to be introduced into the direct reduction facility and/or introducing the hydrogen gas directly into the direct reduction facility. Alternatively, the first thermal energy is higher than the second thermal energy.
Alternatively, the hydrogen gas to the hydrogen gas containing reducing agent comprises the hydrogen gas.
Alternatively, the hydrogen gas is fed to a reducing agent supply configured to transfer the hydrogen gas containing reducing agent to the direct reduction facility.
Alternatively, the method comprises charging the metal oxide material, holding the first thermal energy, via a metal oxide material charging inlet device of the direct reduction facility into an upper interior portion ofthe direct reduction facility.
Alternatively, the introduction of the hydrogen gas containing reducing agent, holding the second thermal energy, is provided into the direct reduction facility via a reducing agent inlet device.
Alternatively, the introduction ofthe hydrogen gas is made directly into the direct reduction facility. Alternatively, the first thermal energy is higher than the second thermal energy.
Alternatively, the high-temperature exit gas is removed from the upper interior portion of the reduction facility via a gas out|et device.
Alternatively, the upper interior portion ofthe direct reduction facility comprises the gas out|et device configured to remove the high-temperature exit gas from the direct reduction facility.
Alternatively, a high-temperature exit gas is removed from the direct reduction facility by means of a pump arrangement controlled by means of a control circuitry. ln such way is achieved a substantially fully metallized reduced metal material achieving that the reduced metal material is reduced greater than about 90 %, preferably about 95-100 %, or greater than about 80 %, preferably about 85-95 %, thereby decreasing hydrogen accumulation in the top gas. ln such way is achieved efficient treatment and energy saving re-cycling of the high- temperature water steam of the top gas, generated by the chemical reaction, fed to the high-temperature electrolysis unit, and thus providing that the high-temperature electrolysis unit is able to operate energy efficient due to an efficient heat recovery of the high- temperature water steam and due to the high content of high-temperature water steam of the top gas discharged from the direct reduction facility. ln such way is achieved an high content of high-temperature water steam of the high- temperature exit gas , which promotes efficient utilization ofthe high-temperature water steam injected into the high-temperature electrolysis unit.
Alternatively, the reduced metal material is discharged from the direct reduction facility via a metal material discharge device of a lower interior portion ofthe direct reduction facility.
Alternatively, the control circuitry is adapted to adjust the second thermal energy for reaching the required reaction temperature causing effective direct reduction.
Alternatively, the method further comprises pre-heating the hydrogen gas and/or the hydrogen gas containing reducing agent to be introduced into the direct reduction facility for reaching the required reaction temperature. ln such way is achieved that the metal oxide material holding the first thermal energy not will be cooled down to rapidly during its motion downward in the direct reduction facility, whereas it is feasibly to maintain the required reaction temperature of the introduced hydrogen gas containing reducing agent.
Alternatively, the pre-heating ofthe hydrogen gas and/or the hydrogen gas containing reducing agent is provided by a reducing agent pre-heating device electrically coupled to the control circuitry for controlling the second thermal energy of the hydrogen gas and/or the hydrogen gas containing reducing agent for reaching the required reaction temperature.
Alternatively, the reducing agent pre-heating device comprises an electric pre-heater unit and/or a heat exchange device.
Alternatively, the hydrogen gas is fed from the high-temperature electrolysis unit to the reducing agent pre-heating device and/or directly into the direct reduction facility.
Alternatively, the direct reduction facility is provided as a solid-gas counter-current moving bed reactor, wherein the metal oxide material holding the first thermal energy is charged into the upper interior portion and descends by gravity toward the lower interior portion of the direct reduction facility, and wherein the hydrogen gas containing reducing agent, holding the second thermal energy, is heated or further heated by the first thermal energy providing the required reaction temperature ofthe hydrogen gas containing reducing agent for causing the chemical reaction between the metal oxide material and the hydrogen gas containing reducing agent.
Alternatively, the introduction ofthe hydrogen gas containing agent into the direct reduction facility is provided via the reducing agent inlet device positioned at a position that is lower than that of the metal oxide material charging inlet device.
Alternatively, the required reaction temperature is maintained by pre-heating the hydrogen gas containing reducing agent to be introduced into the direct reduction facility and by utilizing the high temperature ofthe metal oxide material, holding the first thermal energy.
Alternatively, the required reaction temperature for maintaining the direct reduction in the direct reduction facility may be at temperatures of from about 800 °C to about 1200 °C, preferably about 900 °C to about 1100 °C.
Alternatively, the required reaction temperature for maintaining the direct reduction in the direct reduction facility may be at temperatures of from about 600 °C to about 1400 °C, preferably about 850 °C to about 1250 °C.
Alternatively, the upper interior portion is configured for enabling a required reaction temperature that is higher than the required reaction temperature provided by the lower interior portion.
Alternatively, the hydrogen gas containing reducing agent being introduced into the direct reduction facility exhibits a temperature of about 600 °C to about 1200 °C, preferably about 850 °C to about 950 °C.
Alternatively, the hydrogen gas containing reducing agent being introduced into the direct reduction facility exhibits a temperature of about 400 °C to about 950 °C, preferably about 550 °C to about 800 °C.
Alternatively, the hydrogen gas containing reducing agent that is fed into the direct reduction facility may exhibit a temperature of about 350 °C to about 900 °C, preferably about 450 °C to about 750 °C.
Alternatively, the hydrogen gas containing reducing agent being introduced into the direct reduction facility exhibits a temperature of about 200 °C to about 700 °C, preferably about 300 °C to about 600 °C.
Alternatively, a first hydrogen gas containing reducing agent being introduced into the direct reduction facility exhibit a temperature of about 600 °C to about 1200 °C, preferably about 850 °C to about 950 °C.
Alternatively, a second hydrogen gas containing reducing agent being introduced into the direct reduction facility exhibit a temperature of about 200 °C to about 700 °C, preferably about 300 °C to about 600 °C.
Alternatively, the second hydrogen gas containing reducing agent is introduced into the direct reduction facility at a level below the introduction of the first hydrogen gas containing reducing agent being introduced into the direct reduction facility.
Alternatively, a cooling gas comprising hydrogen may be introduced into the lower interior portion of the direct reduction facility for cost-effective management of cooled down reduced metal material discharged from the direct reduction facility.
Alternatively, the metal oxide material holding thermal energy being charged into the direct reduction facility exhibits a temperature of 1000 °C to about 1450 °C, preferably about 1100 °C to about 1300 °C.
Alternatively, the metal oxide material holding thermal energy being charged into the direct reduction facility exhibits a temperature of 900 °C to about 1300 °C, preferably about 1000 °C to about 1200 °C.
Alternatively, the metal oxide material holding thermal energy being charged into the direct reduction facility exhibits a temperature of 800 °C to about 1200 °C, preferably about 900 °C to about 1100 °C.
Alternatively, the method further comprises providing the hydrogen gas containing reducing agent, to be introduced into the direct reduction facility, by adding the hydrogen gas to a primary reducing agent.
Alternatively, the primary reducing agent may be a hydrogen gas containing reducing agent and/or any suitable reducing agent, such as syngas or other reducing agents.
Alternatively, the hydrogen gas is fed to a reducing agent supply configured to add the hydrogen gas to the primary reducing agent. ln such way is provided that the hydrogen gas containing reducing agent exhibits proper chemical properties ready to be used for the chemical reaction.
Alternatively, the hydrogen gas is fed to a hydrogen gas buffer reservoir of the reducing agent supply.
Alternatively, the hydrogen gas buffer reservoir is configured to store the hydrogen gas and/or any hydrogen gas produced by an external hydrogen producing source.
Alternatively, the primary reducing agent is formed of the hydrogen gas fed from the hydrogen gas buffer reservoir and/or the hydrogen produced by the external hydrogen producing source and/or a suitable process gas configured for direct reduction of the metal oxide material.
Alternatively, the method comprises the step of providing the high-temperature exit gas in the upper interior portion by means of charging the metal oxide material holding the first thermal energy into the upper interior portion for causing the chemical reaction between the metal oxide material and the hydrogen gas containing reducing agent. ln such a way, an endothermal chemical reaction is able to take place in the upper interior portion between the metal oxide material and the hydrogen gas containing reducing agent, despite the fact that the hydrogen gas containing reducing agent comprises a high content of water steam generated by the chemical reaction.
Alternatively, the method further comprises removing the high-temperature water steam of the high-temperature exit gas , which high-temperature water steam is generated by the chemical reaction between the metal oxide material and the hydrogen gas containing reducing agent.
By means of the high-temperature of the charged metal oxide material holding the first thermal energy, it is achieved that the high-temperature exit gas produced in the upper interior portion of the direct reduction facility will comprise the high-temperature exit gas , comprising the high-temperature water steam, due to high-temperature transfer from the charged metal oxide material heating or further heating the introduced hydrogen gas containing reducing agent providing said (endothermal) chemical reaction.
Alternatively, the high-temperature water steam exhibits a temperature of about 700 °C to about 1450 °C, preferably at about 800 °C to about 1350 °C.
Alternatively, the high-temperature water steam exhibits a temperature of about 600 °C to about 1200 °C, preferably at about 700 °C to about 1100 °C.
Alternatively, the high-temperature exit gas contains up to about 100 vol. % high- tempefatufe Water Steam.
Alternatively, the high-temperature exit gas contains up to about 80-100 vol. %, preferably about 85-95 vol. %, high-temperature water steam.
Alternatively, the high-temperature exit gas contains up to about 60-90 vol. %, preferably about 70-80 vol. %, high-temperature water steam.
Alternatively, the high-temperature exit gas contains up to about 40-80 vol. %, preferably about 50-70 vol. %, high-temperature water steam.
Alternatively, the high-temperature exit gas contains up to about 20-60 vol. %, preferably about 30-40 vol. %, high-temperature water steam.
Alternatively, the high-temperature exit gas contains up to about 15-35 vol. %, preferably about 20-30 vol. %, high-temperature water steam.
Alternatively, the high-temperature exit gas comprises the high-temperature water steam and an excess hydrogen gas.
Alternatively, the excess hydrogen gas being separated from the high-temperature exit gas and is re-circulated to the direct reduction facility and introduced into the direct reduction facility. ln such way a cost-effective use of hydrogen gas is achieved. ln such way is achieved an efficient heat recovery that is utilized by the high-temperature electrolysis unit. ln such way is achieved that none or at least minimal external thermal source is needed to supply the overall thermal energy for reaching said required reaction temperature.
Alternatively, the metal material production configuration comprises a top gas recycling arrangement adapted to recycle a hydrogen gas portion ofthe high-temperature exit gas and adding it to the hydrogen gas produced by the high temperature electrolysis unit.
Alternatively, the hydrogen gas containing reducing agent introduced into the direct reduction facility comprises about 80-100 vol. % hydrogen gas, preferably about 100 vol. % hydrogen gas.
Alternatively, the hydrogen gas containing reducing agent introduced into the direct reduction facility comprises greater than about 70 vol. % hydrogen gas.
Alternatively, the hydrogen gas containing reducing agent introduced into the direct reduction facility comprises about 40 vol. % to about 80 vol. % hydrogen gas, preferably about 50 vol. % to about 70 vol. % hydrogen gas.
Alternatively, the hydrogen gas containing reducing agent introduced into the direct reduction facility comprises about 60 vol. % to about 100 vol. % hydrogen gas, preferably about 70 vol. % to about 90 vol. % hydrogen gas.
The method according to any of the preceding claims, wherein the method further comprises adjusting the second thermal energy ofthe hydrogen gas containing reducing agent, to be introduced into the direct reduction facility, for reaching the required reaction temperature.
Alternatively, the direct reduction facility and/or the metal oxide material provider unit and/or the control circuitry and/or the high temperature electrolysis unit being part/s of the metal material production configuration or at least being integral parts of the metal material production configuration.
Alternatively, the introduction the hydrogen containing reducing agent, holding the second thermal energy content, is made into an intermediate interior portion and/or the lower interior portion of the direct reduction facility.
Alternatively, the control circuitry is adapted to control the second thermal energy of the hydrogen gas containing reducing agent by means of the reducing agent pre-heating device and/or by means of a thermal energy adjusting device of the reducing agent pre-heating device.
Alternatively, the pre-heating ofthe hydrogen gas H and/or the hydrogen gas containing reducing agent is provided by the reducing agent pre-heating device electrically coupled to the control circuitry for controlling the second thermal energy of the hydrogen gas and/or the hydrogen gas containing reducing agent. 11 ln such way is achieved that the second thermal energy is adjustable to conform to the required reaction temperature taking into account the actual first thermal energy of the cha rged metal oxide material.
Alternatively, the method further comprises feeding the high-temperature exit gas to the high-temperature electrolysis unit via a filter device configured for removing impurities from the high-temperature water steam. ln such a way, there is provided a filtered high temperature water steam ready to be fed to the high-temperature electrolysis unit.
Alternatively, the method further comprises the step of separating excess hydrogen gas from the high-temperature exit gas for providing the high temperature water steam to be fed to the high-temperature electrolysis unit.
Alternatively, the method further comprises the step of separating eventual exhaust gas from the high-temperature exit gas.
Alternatively, the method further comprises the step of; recovering a third thermal energy from the high-temperature water steam by means of the heat exchange device.
Alternatively, the hydrogen gas produced by the high-temperature electrolysis unit is fed from the high-temperature electrolysis unit via the reducing agent pre-heating device and/or directly into the direct reduction facility via the heat exchange device configured to transfer heat energy from the high-temperature water steam to the hydrogen gas produced by the high-temperature electrolysis unit.
Alternatively, the high-temperature electrolysis unit is coupled to and/or associated with the gas outlet device via a first fluid line arrangement, configured for fluid communication and adapted to feed the high-temperature water steam from the gas outlet device to the high- temperature electrolysis unit.
Alternatively, the first fluid line arrangement comprises the heat exchange device configured to cool down the high-temperature water steam to hold a thermal heat suitable for operation of the high-temperature electrolysis unit.
Alternatively, the first fluid line arrangement comprises the filter device. 12 Alternatively, the filter device is arranged between the gas outlet device and the heat exchange device.
Alternatively, the first fluid line arrangement is coupled between the gas outlet device and the high-temperature electrolysis unit.
Alternatively, the first fluid line arrangement comprises the filter device and/or the separation unit and/or the heat exchange device.
Alternatively, the separation unit is configured to separate a high-temperature water steam from the high-temperature exit gas.
Alternatively, the separation unit is configured to separate the excess hydrogen gas from the high-temperatu re exit gas.
Alternatively, the high-temperature electrolysis unit is coupled to the direct reduction facility via a second fluid line arrangement configured for fluid communication and configured to feed the hydrogen gas, produced by the high-temperature electrolysis unit, from the high- temperature electrolysis unit to the direct reduction facility.
Alternatively, the reducing agent supply is coupled to the direct reduction facility via a third fluid line arrangement configured for fluid communication and adapted to feed the hydrogen gas containing reducing agent to the direct reduction facility from the reducing agent supply.
Alternatively, the third fluid line arrangement comprises a reducing agent supply and/or a primary reducing agent provider.
Alternatively, the second fluid line arrangement comprises the third fluid line arrangement and/or the reducing agent supply and/or the reducing agent pre-heating device.
Alternatively, the heat exchange device is coupled to the direct reduction facility via a fourth fluid line arrangement configured for fluid communication and adapted to feed the pre- heated hydrogen gas produced by the high-temperature electrolysis unit from the heat exchange device to the direct reduction facility.
Alternatively, the fourth fluid line arrangement comprises the reducing agent pre-heating device. 13 Alternatively, the heat exchange device is configured to recover a third thermal energy from the high-temperature water steam fed to the heat exchange device via the first fluid line arrangement, which heat exchange device is coupled to the direct reduction facility via a fourth fluid line arrangement adapted for feeding the hydrogen gas pre-heated by means of the heat exchange device.
Alternatively, the first, second, third and/or fourth fluid line arrangement may comprise gas lines and/or fluid pipes etc. and may comprise fans and/or pumps or other fluid driving means and may comprise valve devices for controlling the flow of fluids.
Alternatively, the valve devices, fans and pumps may be coupled to the control circuitry configured for controlling the flow of fluids.
Alternatively, the method step of adjusting the second thermal energy is provided by controlling the reducing agent pre-heating device and/or by controlling the heat exchange device to adapt the heat energy of the hydrogen gas produced by the high-temperature electrolysis unit toward the second thermal energy.
Alternatively, the third thermal energy is transferred from the heat exchange device to the metal oxide material provider unit and/or to the reducing agent pre-heater device configured to pre-heat the hydrogen gas containing reducing agent and/or to any apparatus of the metal material production configuration, that requires heat energy for the production of reduced metal material.
Alternatively, the hydrogen gas containing reducing agent is pre-heated by an electrical pre- heater.
Alternatively, the method further comprises the step of; operating the high-temperature electrolysis unit by means of electrical energy produced by a re-generative energy source; and producing the hydrogen gas by means ofthe high-temperature electrolysis unit making use of the high-temperature water steam.
Alternatively, the method comprises the step of feeding the produced hydrogen gas directly and/or via the heat exchange device to the reducing agent pre-heater device.
Alternatively, the reducing agent pre-heater device is configured to pre-heat the hydrogen gas containing reducing agent, e.g. by means of an electrical pre-heater. 14 ln such way is achieved that chemical reactivity and/or high impetus of the hydrogen containing reducing agent is maintained as the hydrogen gas containing reducing agent is not needed to be fired or burned by an oxygen fuel source for reaching the required reaction temperature.
The chemical reactivity and/or high impetus being essential for providing an efficient direct reduction of the metal oxide material. ln such way is achieved that the reduction potential ofthe hydrogen gas containing reducing agent is maintained for achieving an efficient direct reduction ofthe metal oxide material for producing the reduced metal material.
There is thus no need to "burn" the hydrogen gas containing reducing agent for reaching the desired reaction temperature. ln such way is eliminated the need of heating the hydrogen gas containing reducing agent by means of e.g. an exothermic partial oxidation ofthe hydrogen gas containing reducing agent with oxygen or air, for reaching the required reaction temperature.
The required reaction temperature is to great extent reached by using the first thermal energy of the metal oxide material produced by the metal oxide material provider unit.
Alternatively, the step of reducing the metal oxide material holding the first thermal energy in the upper interior portion is achieved by utilizing the first thermal energy of the metal oxide material and/or by utilizing the thermal energy of partly reduced metal material in the upper interior portion to heat or further heat the introduced pre-heated hydrogen gas containing reducing agent.
By charging the metal oxide material from the metal oxide material provider unit directly into the direct reduction facility, which metal oxide material holds the first thermal energy that originates from a heating process operated by the metal oxide material provider unit, the reduction and/or the chemical reaction between the metal oxide material and the hydrogen containing reducing agent can be provided energy efficient, at the same time as the hydrogen gas of the hydrogen gas containing reducing agent will maintain its reduction potential. ln such way is eliminated the need of further heating of the hydrogen gas containing reducing agent by means of exothermic partial oxidation of the hydrogen gas containing reducing agent with oxygen or air, which would destroy the reduction potential. ln such way is achieved an energy saving direct reduction of metal oxide material by efficient heat recovery by making use of the high-temperature exit gas and thus recovering the heat energy ofthe high-temperature water steam for producing the hydrogen gas by means of the high-temperature electrolysis unit. ln such way is achieved an efficient electrolysis reaction provided by the high-temperature electrolysis unit.
Alternatively, the high-temperature electrolysis unit operates at temperature at about 100 °C to about 850 °C, preferably at about 300 °C to about 650 °C.
Alternatively, the high-temperature exit gas removed from the direct reduction facility exhibits a temperature at about 150 °C to about 900 °C, preferably at about 350 °C to about 700 °C.
Alternatively, the high-temperature electrolysis unit operates at temperature at about 300 °C to about 1050 °C, preferably at about 500 °C to about 850 °C.
Alternatively, the high-temperature exit gas removed from the direct reduction facility exhibits a temperature at about 350 °C to about 1100 °C, preferably at about 550 °C to about 900 °C.
Alternatively, the high-temperature exit gas removed from the direct reduction facility exhibits a temperature at about 800 °C to about 1300 °C, preferably at about 900 °C to about 1100 °C.
Alternatively, the high-temperature electrolysis unit operates at temperature at about 200 °C to about 500 °C, preferably at about 250 °C to about 450 °C.
Alternatively, the high-temperature electrolysis unit is configured to dissociate the high- temperature water steam into hydrogen gas and oxygen at temperatures between about 500 °C and 1100 °C, preferably at about 600 °C to about 1000 °C.
Alternatively, the high-temperature electrolysis unit is configured to dissociate the high- temperature water steam into hydrogen gas and oxygen at temperatures higher than 1000 16 °C making use of the fact that the electrolysis efficiency increases with increasing operating tempeFatUFeS.
By making use of the high-temperature water steam produced by the direct reduction facility there is achieved a more energy efficient electrolysis than that of the conventional electrolysis achieved at room temperature.
Alternatively, the thermal energy needed for the high-temperature electrolysis is supplied directly to the high-temperature electrolysis unit by direct injection ofthe high-temperature water steam produced by the direct reduction, or is supplied via a heat exchange device to the high-temperature electrolysis unit, toward efficient operating temperatures for the operation of the high-temperature electrolysis unit.
Alternatively, eventual external thermal energy for operation of the high-temperature electrolysis is produced by re-generative energy source.
Alternatively, exhaust thermal heat is recovered from the high-temperature electrolysis unit and is distributed to external heat energy demanding facilities and/or devices of the metal material production configuration. ln such a way, it is possibly to recover heat energy ofthe high-temperature water steam by means of the heat exchange device, which high-temperature water steam subsequently is fed to the high-temperature electrolysis unit.
Alternatively, the control circuitry is adapted to control cell voltage operation, electrolysis current, temperature, pressure, reactant concentration, water steam flow rate, etc., which features may be essential for operation ofthe high-temperature electrolysis unit.
Alternatively, the temperature ofthe pre-heated hydrogen containing reducing agent to be introduced into the direct reduction facility is controlled to reach the second thermal energy for providing the required reaction temperature. ln such a way, the heat energy ofthe first thermal energy generated by the metal oxide material provider unit in combination with the heat energy of the hydrogen gas containing reducing agent 8 and/or the hydrogen gas H being utilized to reach the required reaction temperature.
Alternatively, the heat exchange device is electrically coupled to the control circuitry. 17 Alternatively, the control circuitry is adapted to control the heat energy of the high- temperature water steam to reach a suitable temperature for effective electrolysis. ln such a way, it is achieved that the temperature of the high-temperature water steam is adjustable toward an efficient operating temperature for the operation of the high- temperature electrolysis unit Alternatively, the temperature of the high-temperature water steam is adjustable toward an efficient operating temperature for the operation of the high-temperature electrolysis unit by adding liquid water to the high-temperature water steam.
Alternatively, the control circuitry is adapted to control the reducing agent pre-heating device for providing the second thermal energy of the hydrogen gas containing reducing agent to be introduced into the direct reduction facility, and is adapted to control a reducing agent flow regulating apparatus for providing the flow of the hydrogen gas containing reducing agent into the direct reduction facility, which hydrogen gas containing reducing agent is to be heated or further heated by the metal oxide material holding the first thermal energy for causing the direct reduction at the required reaction temperature.
Alternatively, the introduced hydrogen gas containing reducing agent holding the second thermal energy is adapted to heat or further heat the metal oxide material subject to reduction for preventing cooling of the metal oxide material (e.g. further down in the direct reduction facility), whereby the required reaction temperature for enabling that the chemical reaction between the hydrogen gas containing reducing agent and the metal oxide material is maintained.
Alternatively, the required reaction temperature is reached by using the first thermal energy of the metal oxide material produced by the metal oxide material provider unit.
Alternatively, the required reaction temperature is partially achieved by using the first thermal energy of the metal oxide material produced by the metal oxide material provider unit and is partially achieved by using the second thermal energy ofthe introduced hydrogen gas containing reducing agent.
Consequently, the required reaction temperature, in the lower and/or in an interior portion ofthe direct reduction facility, is thus partially achieved by using the second thermal energy 18 of the introduced hydrogen gas containing reducing agent to further heat the metal oxide material. ln such way is achieved, by making use of the first therma| energy for the chemical reaction, that chemical reactivity and/or high impetus of the hydrogen gas containing reducing agent is maintained as the hydrogen gas containing reducing agent is not needed to be "burned" for reaching the required reaction temperature.
Alternatively, the heat energy of the metal oxide material holding the first therma| energy is achieved by means of the metal oxide material provider unit, such as a metal oxide pelletizing apparatus, configured to produce the metal oxide material holding the first therma| energy.
Alternatively, a metal ore material is dried and then pre-heated in a pre-heating zone of the metal oxide pelletizing apparatus, which pre-heating zone is configured to pre-heat the metal ore material into pre-heated metal ore material.
Alternatively, the metal ore material may be in the form of metal ore pellets (e.g. green pellets).
Subsequently, the pre-heated metal ore material is transferred into an induration zone of the metal oxide pelletizing apparatus, which induration zone is configured to indurate the pre-heated metal ore material.
Alternatively, the induration zone comprises an oxidation zone configured for oxidation of the pre-heated metal ore material and/or a sintering zone for sintering the oxidized pre- heated metal ore material.
Alternatively, the oxygen produced by the high temperature electrolysis unit is transferred into the oxidation zone for oxidation of the pre-heated metal ore material.
Alternatively, the induration zone is configured to indurate the pre-heated metal ore material toward a temperature of about 1000 °C to about 1450 °C, preferably about 1100 °C to about 1300 °C, for producing the metal oxide material holding the first therma| energy.
Alternatively, the oxidation zone is configured to increase the temperature of the pre- heated metal ore material toward temperature of about 1000 °C to about 1450 °C, 19 preferably about 1100 °C to about 1300 °C by means of the oxygen introduced into the oxidation zone providing an exothermal chemical reaction between a magnetite material of the pre-heated metal ore material and the oxygen.
Alternatively, the metal oxide material holding said first thermal energy is discharged from the metal oxide pelletizing apparatus and charged directly into the direct reduction facility.
Alternatively, the heat energy of the metal oxide material holding the first thermal energy is achieved by means of the metal oxide material provider unit, such as a metal oxide material pre-heating device, configured to pre-heat previously cooled down metal oxide material, for producing the metal oxide material holding thermal energy.
Alternatively, the temperature of the metal oxide material holding the first thermal energy is achieved by means ofthe metal oxide material pre-heating device configured to pre-heat metal oxide material to a temperature of 1000 °C to about 1450 °C, preferably about 1100 °C to about 1300 °C, for the production of the metal oxide material holding the first thermal energy.
Alternatively, the metal oxide material holding the first thermal energy is discharged from the metal oxide material pre-heating device and charged directly into the direct reduction facility.
Alternatively, the metal oxide material holding the first thermal energy discharged from the metal oxide material provider unit exhibits a temperature of 900 °C to about 1300 °C, preferably about 1000 °C to about 1200 °C.
Alternatively, the metal oxide material holding the first thermal energy discharged from the metal oxide material provider unit exhibits a temperature of 1000 °C to about 1450 °C, preferably about 1100 °C to about 1300 °C, for the production of the metal oxide material holding the first thermal energy.
Alternatively, the metal oxide material holding the first thermal energy is discharged from the metal oxide material provider unit and charged via a charging hopper arrangement into the direct reduction facility.
Alternatively, a metal oxide material transfer device is coupled to the metal oxide material provider unit and to a metal oxide material cooler unit and/or the charging hopper arrangement associated with the upper interior portion of the direct reduction facility.
Alternatively, the charging hopper arrangement is configured to introduce a first seal gas, such as an inert gas or carbon dioxide gas, into the direct reduction facility in conjunction with charging the metal oxide material holding the first thermal energy into the direct reduction facility. ln such way is achieved that formation of explosive air/process gas mixtures are avoided when charging the metal oxide material holding the first thermal energy into the direct reduction facility.
Alternatively, the chemical reaction comprises direct reduction ofthe metal oxide material into the reduced metal material.
Alternatively, the control circuitry is adapted to control the chemical reaction between the hydrogen gas containing reducing agent and the metal oxide material, and/or by adjusting the flow of hydrogen gas containing reducing agent into the direct reduction facility by means of the reducing agent flow regulating apparatus.
Alternatively, the high-temperature exit gas comprises hydrogen gas not being consumed by the chemical reaction between the metal oxide material and hydrogen gas of the hydrogen containing reducing agent.
Alternatively, the continuously introduction ofthe hydrogen gas containing reducing agent is of such amount that the top gas removed from the direct reduction facility always comprises hydrogen gas. ln such way is guaranteed that hydrogen gas is available in the direct reduction facility for providing the chemical reaction.
Alternatively, the introduction ofthe hydrogen gas containing reducing agent into the direct reduction facility is provided to such extent that excess of hydrogen gas resides in the direct reduction facility enabling the complete and/or substantially complete reduction of the metal oxide material holding the first thermal energy. 21 Alternatively, the metal oxide material to be charged into the direct reduction facility is in the form of metal oxide pellets, each of which is structurally formed by metal oxide particles.
Alternatively, the metal oxide material subject to direct reduction is in the form of metal oxide pellets, each of which is structurally formed by metal oxide particles subject to direct reduction.
Alternatively, the direct reduced metal material is in the form of direct reduced metal pellets, each ofwhich is structurally formed by reduced metal particles.
Alternatively, the direct reduction is performed in the direct reduction facility at a pressure below 1 Bar.
Alternatively, the direct reduction is performed in the direct reduction facility at a pressure of from about 1 Bar to about 10 Bar, preferably from 3 Bar to about 8 Bar.
Alternatively, the direct reduction is performed in the direct reduction facility at a pressure of from about 4 Bar to about 14 Bar, preferably from 6 Bar to about 12 Bar. Alternatively, the metal ore material comprises iron ore material.
Alternatively, the iron ore material comprises hematite material and magnetite material. Alternatively, the pre-heated metal ore material comprises pre-heated iron ore material. Alternatively, the metal oxide material comprises iron ore oxide material.
Alternatively, the reduced metal material comprises reduced iron ore material.
Alternatively, the metal oxide material provider unit comprises an iron ore oxide material provider unit.
Alternatively, the first thermal energy is generated by means of an induration process provided by an iron ore oxide pelletizing plant of the iron ore oxide material provider unit, which iron ore oxide pelletizing plant is configured to provide the metal oxide material to be charged into the direct reduction facility.
Alternatively, a fireproof iron ore oxide material transportation device is arranged between the iron ore oxide pelletizing plant and the charging hopper arrangement of the direct reduction facility. 22 Alternatively, a fireproof iron ore oxide material transportation device comprises a fireproof conveyer belt.
Alternatively, the iron ore material being in the form of iron ore pellets (e.g. so called green pellets) and being indurated by the induration process provided by means ofthe metal oxide pelletizing plant.
Alternatively, the iron ore oxide material provider unit comprises an iron ore oxide pelletizing plant configured to provide the iron ore oxide material to be charged into the direct reduction facility via the charging hopper arrangement. Alternatively, the metal oxide material is formed as metal oxide agglomerates.
Alternatively, the direct reduction facility is provided as a solid-gas counter-current moving bed reactor.
Alternatively, each dimension of the metal oxide agglomerates being charged into the direct reduction facility is of such value, that the hydrogen gas of the hydrogen gas containing reducing agent is able to pass through and in between the metal oxide agglomerates for providing an effective and time saving direct reduction of the metal oxide material. Alternatively, the reduced metal material is formed as reduced metal agglomerates.
Alternatively, the metal oxide material holding the first thermal energy is continuously charged into the direct reduction facility.
Alternatively, the metal oxide material holding the first thermal energy is batch-wise charged into the direct reduction facility.
Alternatively, the upper interior portion of the direct reduction facility is configured for introduction ofthe pre-heated gas hydrogen containing reducing agent, which pre-heated hydrogen gas containing reducing agent is adapted to react with (reduce) the metal oxide material holding the first thermal energy.
Alternatively, the partially reduced metal material holding a non-consumed part of the first thermal energy, continuously descends in the direct reduction facility and/or in the upper interior portion and/or in the intermediate interior portion and/or in the lower interior 23 portion of the direct reduction facility and is in contact with the pre-heated gas hydrogen containing reducing agent.
Alternatively, the hydrogen gas containing reducing agent and/or the hydrogen gas to be introduced into the direct reduction facility is pre-heated and/or coo|ed down by means of the control circuitry, electrically coupled to and contro||ing the reducing agent pre-heater device, for reaching the required reaction temperature for providing an efficient chemical reaction between the hydrogen gas containing reducing agent and the metal oxide material.
Alternatively, the control circuitry is electrically coupled to and is adapted to control the reducing agent flow regulating apparatus for contro||ing the flow rate of the hydrogen gas containing reducing agent and/or the hydrogen gas being introduced into the direct reduction facility. ln such way is guaranteed that the chemical reaction (substantially an endothermal reaction) is made energy efficient by using the first thermal energy for reaching the required reaction temperature, and wherein the reduction potential of the pre-heated hydrogen gas containing reducing agent and/or hydrogen gas is maintained further saving energy at the same time as the heat energy ofthe pre-heated hydrogen gas containing reducing agent holding the second thermal energy and/or pre-heated hydrogen gas holding the second thermal energy securing that the required reaction temperature also is maintained further down in the direct reduction facility.. ln such way, the first thermal energy of the "hot" charged metal oxide material can be used to a great extent by its high content of heat energy for the direct reduction in the upper interior portion, where the metal oxide material holding the first thermal energy initially meets the hydrogen containing reducing agent. lt is thus possible to provide efficient reduction of the metal oxide material (holding said first thermal energy). This is achieved by the complementary heat energy of the hydrogen gas containing reducing agent holding the second thermal energy being added to the first thermal energy further down in the direct reduction facility, thus achieving that the required reaction temperature is maintained. 24 Alternatively, the temperature and/or flow of the pre-heated hydrogen gas containing reducing agent and/or hydrogen gas is adjustable by the control circuitry toward the second thermal energy for reaching and maintaining the required reaction temperature.
Alternatively, the control circuitry is electrically coupled to the reducing agent flow regulating apparatus and/or to a reducing agent pressurization apparatus and/or to a reducing agent pre-heating device and is adapted to control the reducing agent flow regulating apparatus and/or to a reducing agent pressurization apparatus and/or to a reducing agent pre-heating device to provide adjustment of flow and/or pressurization and/or second thermal energy of the hydrogen gas containing reducing agent and/or hydrogen gas to be introduced into the direct reduction facility.
These or at least one of said objects has been achieved by a metal material production configuration adapted for direct reduction of a metal oxide material holding a first thermal energy into a reduced metal material; the metal material production configuration comprises; a high-temperature electrolysis unit configured to produce a hydrogen gas; a metal oxide material provider unit configured to provide the metal oxide material holding the first thermal energy; a direct reduction facility comprising; a metal oxide material charging inlet device; a reducing agent inlet device configured to introduce a hydrogen gas containing reducing agent holding a second thermal energy; a control circuitry configured to control the direct reduction of the metal oxide material; wherein the metal material production configuration is adapted to reduce the metal oxide material by using the first thermal energy of the metal oxide material to heat or further heat the introduced hydrogen gas containing reducing agent toward a required reaction temperature for providing a chemical reaction between the hydrogen gas containing reducing agent and the metal oxide material; and wherein the direct reduction facility comprises a gas outlet device configured for removing a high-temperature exit gas from the direct reduction facility; wherein the metal material production configuration comprises; a first fluid line arrangement configured to fed a high-temperature water steam ofthe high-temperature exit gas to the high- temperature electrolysis unit; a second fluid line arrangement configured for fluid communication and configured to feed the hydrogen gas from the high-temperature electrolysis unit to the direct reduction facility.
Alternatively, the metal material production configuration comprises a reducing agent supply configured to add the hydrogen gas to a primary reducing agent for providing the hydrogen gas containing reducing agent.
Alternatively, the control circuitry is electrically coupled to a heat exchange device of the first fluid line arrangement, which heat exchange device is configured to transfer heat energy from the high-temperature water steam to the hydrogen gas produced by the high- temperature electrolysis unit. ln such way is achieved that the heat energy of the high-temperature water steam is lowered for adaption of the heat energy of the high-temperature water steam to be fed to the high-temperature electrolysis unit for reaching efficient operation of the high- temperature electrolysis unit at the same time as a portion ofthe heat energy and/or the recovered third thermal energy from the high-temperature water steam is re-used for pre- heating the hydrogen gas and/or the hydrogen gas containing reducing agent.
Alternatively, the hydrogen gas is fed from the high-temperature electrolysis unit to the reducing agent pre-heating device and/or directly into the direct reduction facility via the heat exchange device configured to transfer heat energy from the high-temperature water steam to the hydrogen gas produced by the high-temperature electrolysis unit.
Alternatively, the high-temperature electrolysis unit is coupled to the direct reduction facility via a second fluid line arrangement configured for fluid communication and configured to feed the hydrogen gas from the high-temperature electrolysis unit to the direct reduction facility. ln such way is utilized the high temperature of the metal oxide material holding the first thermal energy for providing the chemical reaction in the upper interior portion, thus causing the high-temperature exit gas.
Alternatively, the metal material production configuration comprises a reducing agent supply coupled to the direct reduction facility via a third fluid line arrangement configured for fluid communication and adapted to feed the hydrogen gas containing reducing agent to the direct reduction facility from the reducing agent supply, wherein the second fluid line arrangement comprises the third fluid line arrangement and/or the reducing agent supply and/or the reducing agent pre-heating device. 26 ln such way is achieved that the second fluid line arrangement is adapted to transfer and/or configured to add the hydrogen gas produced by the high-temperature electrolysis unit to the hydrogen gas containing reducing agent to be introduced into the direct reduction facility.
Alternatively, the high-temperature electrolysis unit is configured to produce a hydrogen gas to be added to the hydrogen gas containing reducing agent, which high-temperature electrolysis unit is coupled to the top gas out|et and the reducing agent in|et device.
These or at least one of said objects has been achieved by a data program comprising a program code readable on a computer of the control circuitry, which data program is programmed for causing the metal material production configuration according to any of claims 9 to 12 to execute the method steps of: providing the metal oxide material, holding the first thermal energy, by means of the metal oxide material provider unit; charging the metal oxide material, holding the first thermal energy, into a direct reduction facility; introducing a hydrogen gas containing reducing agent, holding a second thermal energy, into the direct reduction facility; reducing the metal oxide material by using the first thermal energy of the metal oxide material to heat or further heat the introduced hydrogen gas containing reducing agent toward a required reaction temperature for providing a chemical reaction between the hydrogen gas containing reducing agent and the metal oxide material; removing a high-temperature exit gas from the direct reduction facility; feeding a high- temperature water steam to of the high-temperature exit gas to a high-temperature electrolysis unit configured to produce a hydrogen gas; and introducing the hydrogen gas into the direct reduction facility.
Alternatively, the data program further is programmed for causing the metal material production configuration to execute the exemplary method steps herein disclosed.
These or at least one of said objects has been achieved by a data medium, configured for storing the data program, wherein the data medium comprises the program code being readable on the computer for performing the method steps herein disclosed.
Thereby is achieved production of a direct reduced metal material that may comprise reduced metal ore particles bond to each other forming metal pellets of heat treated and/or 27 heat hardened and/or passivated reduced metal material. Such pellet comprising reduced iron material may be called Iron drop""'.
Alternatively, the reduction facility is configured for permitting the reduced metal material and the metal oxide material subject to direct reduction to descend downward from the upper interior portion toward the lower interior portion, whereas the second thermal energy of the introduced hydrogen gas containing reducing agent decreases the cooling rate of the metal oxide material.
Alternatively, the heat energy of the first thermal energy may be higher than the heat energy of the second thermal energy.
Alternatively, the heat energy of the second thermal energy may be higher than the heat energy of the first thermal energy. ln such way is achieved that the introduced hydrogen gas containing reducing agent, disregarding the energy level of the heat energy of the second thermal energy, will decrease the cooling rate of the metal oxide material descending in the reduction facility.
Alternatively, a major part of the heat energy required for the chemical reaction in the upper interior portion ofthe direct reduction facility is provided by the first thermal energy.
Alternatively, a major part of the heat energy required for the chemical reaction further down in the direct reduction facility is provided by the second thermal energy and/or the first thermal energy. Alternatively, the metal ore material comprises iron ore material.
Alternatively, the iron ore material comprises hematite material and magnetite material.
|H Alternatively, the wording "metal oxide materia may mean a metal ore or iron ore that has been subject to oxidation and/or sintering and which comprises other elements and/or minerals than iron, such as natural alloy elements or minerals of less quantity not constituting alloys.
Alternatively, the iron ore may comprise introduced additives such as quartzite, lime, olivine, different binders etc. 28 Alternatively, the step of adjusting the second thermal energy by means of the control circuitry involves controlling the adaptation of the actual reaction temperature toward a required reaction temperature for providing direct reduction of the metal oxide material and/or sintering and/or heat treatment of the reduced metal material during a pre- determined time period for reaching passivation ofthe reduced metal material.
Alternatively, the control circuitry is electrically coupled to a first top gas pressure sensor device ofthe first fluid line arrangement configured to detect the actual pressure of the high-temperature exit gas removed from the direct reduction facility.
Alternatively, the control circuitry is electrically coupled to a top gas flow sensor device of the first fluid line arrangement configured to detect the actual flow rate of the high- temperature exit gas removed from the direct reduction facility.
Alternatively, the control circuitry is electrically coupled to a top gas temperature sensor device ofthe first fluid line arrangement configured to detect the actual temperature of the high-temperature exit gas removed from the direct reduction facility.
Alternatively, the control circuitry is electrically coupled to a hydrogen gas pressure sensor device ofthe second fluid line arrangement configured to detect the actual pressure of the hydrogen gas to be fed into the direct reduction facility.
Alternatively, the control circuitry is electrically coupled to a hydrogen gas flow sensor device ofthe second fluid line arrangement configured to detect the actual flow rate ofthe hydrogen gas to be fed into the direct reduction facility.
Alternatively, the control circuitry is electrically coupled to a hydrogen gas temperature sensor device of the second fluid line arrangement configured to detect the actual temperature of the hydrogen gas to be fed into the direct reduction facility.
Alternatively, the control circuitry is electrically coupled to a reducing gas temperature sensor device of the second fluid line arrangement configured to detect the actual temperature of the hydrogen gas containing reducing agent to be fed into the direct reduction facility.
The required reaction temperature may be defined as required heat energy. 29 The required reaction temperature may be defined as required heat energy for direct reduction in the direct reduction facility at a selected pressure. ln such way utilization ofthe high heat energy ofthe first thermal energy generated by the metal oxide material provider unit is provided to reach the required reaction temperature.
Alternatively, the control circuitry is adapted to control the pressure ofthe high- temperature exit gas and/or the flow rate ofthe high-temperature exit gas and/or the temperature ofthe high-temperature exit gas removed from the direct reduction facility and/or the pressure ofthe hydrogen gas and/or the flow rate of the hydrogen gas and/or the temperature of the hydrogen gas to be fed into the direct reduction facility.
Alternatively, the pressurization ofthe interior of the direct reduction facility is achieved by means of the introduction of pressurized pre-heated hydrogen containing reducing agent and/or by regulating the flow ofthe high-temperature exit gas removed from the direct reduction facility.
Alternatively, the control circuitry is electrically coupled to a top gas removing apparatus, wherein the control circuitry is adapted to control the top gas removing apparatus to regulate the flow ofthe high-temperature exit gas removed from the direct reduction facility.
Alternatively, the metal oxide material subject to direct reduction descends downward from the upper interior portion toward the lower interior portion, whereas the second thermal energy of the introduced hydrogen gas containing reducing agent decreases the cooling rate of the metal oxide material holding the first thermal energy.
Alternatively, the removed high-temperature exit gas comprises a high energy content due to its high temperature generated by the newly charged metal oxide material, whereas the high-temperature comprises a high content of high-temperature water steam. ln such way efficient reduction of the metal oxide material is achieved by means ofthe high temperature ofthe charged metal oxide material into the upper interior portion, which reduction requires high temperature for providing the endothermal chemical reaction causing the production of high-temperature exit gas comprising high-temperature water Steam.
Alternatively, in a next step the descending metal oxide material in the direct reduction further heats the hydrogen gas containing reducing agent to the required reaction temperature, which hydrogen gas containing reducing agent moves upward in the direct reduction facility (counter-current the descending metal oxide material).
Alternatively, the chemical reaction is mainly or entirely an endothermal chemical reaction, which requires a high temperature corresponding to the required reaction temperature.
Alternatively, further down in the direct reduction facility, the second thermal energy of the hydrogen gas containing reducing agent decreases the cooling rate of the first thermal energy of the metal oxide material descending downward in the direct reduction facility. ln such way, the required reaction temperature is provided also further down in the direct reduction facility by means of the hydrogen gas containing reducing agent, providing that a major part of the first thermal energy can be consumed further up the direct reduction facility.
Alternatively, the introduced hydrogen gas containing reducing agent holds a second thermal energy that decreases the cooling rate of the metal oxide material descending in the reduction facility.
These or at least one of said objects has been achieved by a direct reduction facility comprising a metal oxide material charging inlet device, a reducing agent inlet device configured to introduce a hydrogen gas containing reducing agent holding a second thermal energy; which direct reduction facility is characterized by the features according to any of claims 9 to 14. Alternatively, the metal oxide material comprises iron ore oxide material. Alternatively, the direct reduced metal material comprises sponge iron.
Alternatively, the direct reduction facility is formed as a direct reduction shaft. 31 The wording "iron ore" may mean iron ore including introduced additives such as quartzite, silicon, lime etc.
The wording "heat treatment" may be changed to the wording "heat hardening".
Alternatively, the metal oxide material comprises nickel ore oxide material or copper ore oxide material.
Alternatively, the direct reduced metal material comprises nickel material or copper material.
Alternatively, the wording "high-temperature exit gas" may be changed to the wording "high-temperature top gas".
Alternatively, the wording "high-temperature exit gas" may be changed to the wording "high-temperature sideways gas".
Alternatively, the wording "high-temperature exit gas" may be changed to the wording "high-temperature bottom gas".
Alternatively, the wording "gas outlet device" may be changed to the wording "top gas outlet device".
Alternatively, the wording "gas outlet device" may be changed to the wording "sideways gas outlet device".
Alternatively, the wording "gas outlet device" may be changed to the wording "bottom gas outlet device".
Alternatively, the high-temperature exit gas may be removed from the direct reduction facility from at least one outlet.
Alternatively, the high-temperature exit gas may be removed from the direct reduction facility from the top gas outlet device and/or the sideways gas outlet device and/or the bottom gas outlet device.
The present disclosure may not be restricted to the examples described above, but many possibilities to modifications, or combinations of the described examples thereof should be 32 apparent to a person with ordinary skill in the art without departing from the basic idea as defined in the appended claims.
BRIEF DESCRIPTION OF THE DRAWING Hereinafter, the invention will be described with reference to examples and accompanying schematic drawings, wherein for the sake of clarity and understanding of the invention some details of no importance may be deleted from the drawings.
Fig. 1 illustrates a metal material production configuration adapted for reduction of a metal oxide material according to a first example; Fig. 2 illustrates a metal material production configuration adapted for reduction of a metal oxide material according to a second example; Fig. 3 illustrates a metal material production configuration adapted for reduction of a metal oxide material according to a third example; Fig. 4 illustrates a flow diagram of a metal material production configuration adapted for reduction of a metal oxide material according to a fourth example; Fig. 5 illustrates a phase diagram of iron phase domains as a function of oxidizing power of hydrogen gas and temperature; Figs. 6-7 illustrate flowcharts showing exemplary methods of direct reduction of a metal oxide material into a reduced metal material; and Fig. 8 illustrates a control circuitry of an exemplary metal material production configuration.
DETAILED DESCRIPTION Fig. 1 illustrates a metal material production configuration 1 according to a first example provided for direct reduction ofa metal oxide material 5 into a reduced metal material 16. The metal material production configuration 1 is adapted for direct reduction ofthe metal oxide material 5 holding a first thermal energy. The metal material production configuration 33 1 comprises a metal oxide material provider unit 3, such as a metal oxide pelletizing plant (not shown) or metal oxide material pre-heating plant (not shown), configured for causing the first thermal energy, e.g. heat energy containing a temperature of about 900 °C to about 1500 °C, preferably about 1000 °C to about 1400 °C.
The metal oxide material 5 holding the first thermal energy is fed to and is charged, via a metal oxide material charging inlet device a, into an upper interior portion UP of a direct reduction facility 7 of the material production configuration 1, wherein the first thermal energy of the charged metal oxide material 5 to great extent corresponds with that generated by the metal oxide material provider unit 3. The direct reduction facility 7 is adapted for direct reduction ofthe metal oxide material 5 holding the first thermal energy, wherein the metal oxide material 5 is direct reduced into the reduced metal material 16.
The direct reduction facility 7 comprises a reducing agent inlet device b configured to introduce a hydrogen gas containing reducing agent 8 holding a second thermal energy, which second thermal energy is generated by means of a reducing agent pre-heating device 18 and/or a heat exchange device (not shown).
The hydrogen gas containing reducing agent 8 comprises a hydrogen gas H produced by means of a high-temperature electrolysis unit 21 and is introduced into the direct reduction facility 7 via the reducing agent inlet device b.
The high-temperature electrolysis unit 21 of the metal material production configuration 1 is configured to produce the hydrogen gas H, forming the hydrogen gas containing reducing agent 8. The high-temperature electrolysis unit 21 operates by means of a high-temperature water steam 14 of a high-temperature exit gas 12 removed from the direct reduction facility 7 via a gas outlet device c ofthe upper interior portion UP of the direct reduction facility 7, and is fed to the high-temperature electrolysis unit 21. The high-temperature electrolysis unit 21 operates to separate an oxygen gas (not shown and is alternatively fed to the metal oxide pelletizing plant for oxidization of metal ore material) and the hydrogen gas H from the water of the high-temperature water steam 14 by running an electrical current through the water. The electrical current may be provided by re-generative energy produced by a renewable energy source (not shown). 34 A control circuitry 50 of the metal material production configuration 1 is provided to control the direct reduction ofthe metal oxide material 5 and the chemical reaction. The control circuitry 50 is electrically coupled to the reducing agent pre-heating device 18 and is adapted to control the heat energy of the second thermal energy adapted for the direct reduction of the metal oxide material 5, wherein the first thermal energy of the metal oxide material 5 heats or further heats the introduced hydrogen gas containing reducing agent 8 toward a required reaction temperature for providing a chemical reaction between the hydrogen gas containing reducing agent 8 and the metal oxide material 5.
The metal material production configuration 1 comprises a first fluid line arrangement FL' configured for fluid communication and adapted to feed the high-temperature water steam 14 to the high-temperature electrolysis unit 21.
The first fluid line arrangement FL' may comprise a filter device (not shown) configured to separate the high-temperature water stem 14 from the high-temperature exit gas 12 and cooling down the high-temperature water stem 14 by means of the heat exchange device and/or by adding water to the high-temperature water stem 14 before introducing it into the high-temperature electrolysis unit 21.
The metal material production configuration 1 further comprises a second fluid line arrangement FL" configured for fluid communication and adapted to feed the hydrogen gas H from the high-temperature electrolysis unit 21 into the direct reduction facility 7.
The reduced metal material is discharged via an outlet d of a lower interior portion LP ofthe direct reduction facility 7. The lower interior portion LP may be cone-shaped and narrows toward the outlet d.
Alternatively, the reduction facility 7 is configured for permitting the reduced metal material 16 and the metal oxide material 5 subject to direct reduction to descend downward from the upper interior portion UP toward the lower interior portion LP, whereas the second thermal energy of the introduced hydrogen gas containing reducing agent 8 decreases the cooling rate ofthe metal oxide material 8.
Alternatively, the heat energy of the first thermal energy is higher than the heat energy of the second thermal energy.
Alternatively, the heat energy ofthe second thermal energy is higher than the heat energy of the first thermal energy. ln such way is achieved that the introduced hydrogen gas containing reducing agent, disregarding the energy level of the heat energy of the second thermal energy, will decrease the cooling rate of the metal oxide material 5 descending in the reduction facility 7.
Alternatively, the major part of the heat energy required for the chemical reaction in the upper interior portion of the direct reduction facility 7 is provided by the first thermal energy, whereas the major part of the heat energy required for the chemical reaction further down in the direct reduction facility 7 is provided by the second thermal energy and/or the first thermal energy.
Fig. 2 illustrates, according to a second example, a metal material production configuration 1 adapted for direct reduction of a metal oxide material 5 holding a first thermal energy into a reduced metal material 16 to be discharged from a direct reduction facility 7. A metal oxide material provider unit 3, such as a metal oxide pelletizing plant (not shown) or metal oxide material pre-heating plant (not shown), is configured for providing the first thermal energy.
The metal oxide material 5 is charged via a metal oxide material charging inlet device a into an upper interior portion UP of a direct reduction facility 7.
The direct reduction facility 7 further comprises a reducing agent inlet device b configured to introduce a hydrogen gas containing reducing agent 8 holding a second thermal energy, which second thermal energy is generated by means of a reducing agent pre-heating device 18 and/or a heat exchange device 24.
A high-temperature exit gas 12 is removed from the direct reduction facility 7 via a gas outlet device c ofthe upper interior portion UP. The high-temperature exit gas 12 is fed from the gas outlet device c to a filter device 22. The filter device 22 is configured to separate dust particles or other substances, from the high-temperature exit gas 12.
Preferably, a high-temperature water steam 14 is separated from the high-temperature exit gas 12 by means of a separation unit (not shown) and is fed to the heat exchange device 24.
Preferably, the high-temperature water steam 14 may be cooled down to a temperature being optimal for efficient high-temperature electrolysis. 36 The heat exchange device 24 comprises a process gas line system (not shown) configured to recover a third thermal energy from the high-temperature water steam 14. The third thermal energy of the process gas is transferred to the reducing agent pre-heating device 18 configured to pre-heat the hydrogen gas containing reducing agent 8 to be introduced into the direct reduction facility 7.
Alternatively, the gas outlet device c is coupled via a top gas fluid line arrangement to the filter device 22.
The metal material production configuration 1 comprises a first fluid line arrangement FL' configured for fluid communication and adapted to feed the high-temperature water steam 14 to a high-temperature electrolysis unit 21.
Alternatively, the filter device 22 is coupled to the heat exchange device 24 via a water steam fluid line arrangement ofthe first fluid line arrangement FL'.
Alternatively, the heat exchange device 24 is coupled to a high-temperature electrolysis unit 21 via fluid line arrangement.
The high-temperature water steam 14 that has been cooled down is fed to the high- temperature electrolysis unit 21 for production of hydrogen gas and oxygen gas. The high- temperature electrolysis unit 21 is configured to decompose the high-temperature water steam into the hydrogen gas and the oxygen gas by means electricity produced by a re- generative and/or fossil free energy source.
Alternatively, the high-temperature electrolysis unit 21 operates at temperature at about 100 °C to about 850 °C, preferably at about 300 °C to about 650 °C, or at about 300 °C to about 1050 °C, preferably at about 500 °C to about 850 °C.
Alternatively, the high-temperature electrolysis unit is configured to dissociate the high- temperature water steam into hydrogen gas and oxygen at temperatures between about 500 °C and 1100°C, preferably at about 600 °C to about 1000 °C.
Alternatively, the high-temperature electrolysis unit is configured to dissociate the high- temperature water steam into hydrogen gas and oxygen at temperatures higher than 1000 °C making use of the fact that the electrolysis efficiency increases with increasing operating tempeFatUFeS. 37 By making use of the high-temperature water steam produced by the direct reduction facility there is achieved a more energy efficient electrolysis than that of the conventional electrolysis achieved at room temperature.
The hydrogen gas containing reducing agent 8 comprises a hydrogen gas H produced by means of a high-temperature electrolysis unit 21 and is introduced into the direct reduction facility 7 via the reducing agent in|et device b.
The produced hydrogen gas H is mixed with a primary reducing agent BS for providing the hydrogen gas containing reducing agent 8, which is pre-heated by the reducing agent pre- heating device 18.
Alternatively, a primary reducing agent provider S is configured to provide the primary reducing agent BS.
Alternatively, the produced hydrogen gas H is fed directly into the direct reduction facility 7 after being pre-heated.
A control circuitry 50 of the metal material production configuration 1 is electrically coupled to the reducing agent pre-heating device 18 for adjusting the second thermal energy. The educing agent pre-heating device 18 may comprise an electric pre-heater (not shown) configured to pre-heat the hydrogen gas containing reducing agent 8.
The control circuitry 50 is adapted to control the required reaction temperature by adjusting the second thermal energy by means ofthe reducing agent pre-heating device 18.
The metal material production configuration 1 further comprises a second fluid line arrangement FL" configured for fluid communication and adapted to feed the hydrogen gas H from the high-temperature electrolysis unit 21 into the direct reduction facility 7.
The reduced metal material 16 is discharged via an outlet d of a lower interior portion LP of the direct reduction facility 7.
Fig. 3 illustrates a metal material production configuration 1 adapted for direct reduction of a metal oxide material 5 according to a third example. The metal material production configuration 1 is provided for direct reduction of the metal oxide material 5 holding a first 38 thermal energy, wherein the metal oxide material 5 is reduced into a reduced metal material 16.
A direct reduction facility 7 ofthe metal material production configuration 1 is provided for direct reducing the metal oxide material 5 by using the first thermal energy of the metal oxide material 5 to heat or further heat the introduced hydrogen gas containing reducing agent 8 toward a required reaction temperature for providing a chemical reaction between the hydrogen gas containing reducing agent 8 and the metal oxide material 5.
A metal oxide material provider unit 3, such as a metal oxide pelletizing plant (not shown) or a metal oxide material pre-heating plant (not shown), is configured for providing the first thermal energy of the metal oxide material to be charged into the direct reduction facility 7. The first thermal energy may be generated by a pelletization process provided by the metal oxide pelletizing plant, wherein the first thermal energy ofthe metal oxide material 5 may generated by means of an induration facility (not shown) ofthe metal oxide pelletizing plant.
The metal oxide material 5 holding the first thermal energy is charged into an upper interior portion UP of a direct reduction facility 7 via a metal oxide material charging inlet device a.
The direct reduction facility 7 further comprises a reducing agent inlet device b configured to introduce a hydrogen gas containing reducing agent 8 holding a second thermal energy, which second thermal energy is generated by means of a reducing agent pre-heating device 18 and/or a heat exchange device 24.
A high-temperature exit gas 12 is removed from the direct reduction facility 7 via a gas outlet device c ofthe upper interior portion UP. The high-temperature exit gas 12 is fed from the gas outlet device c to a filter device 22.
Alternatively, the filter device 22 is configured to remove dust particles from the high- temperature exit gas 12.
Alternatively, a separation unit (not shown) is configured to separate a high-temperature water steam 14 from the high-temperature exit gas 12, which high-temperature water steam 14 is configured for production of a hydrogen gas H.
Alternatively, the high-temperature water steam 14 is fed to a high-temperature electrolysis unit 21 via the heat exchange device 24. 39 ln such way is achieved that not oxidized hydrogen gas and dust particles or other substances are separated from the high-temperature exit gas 12.
The high-temperature water steam 14 is fed to the heat exchange device 24 and/or is injected with water, wherein the high-temperature water steam 14 being coo|ed down to a desired temperature for efficient high-temperature electrolysis provided by the high- temperature electrolysis unit 21 for production of the hydrogen gas H.
Alternatively, a control circuitry 50 (electrically coupled to the heat exchange device 24 is adapted to control the heat exchange device 24 to adjust the temperature of the coo|ed down high-temperature water steam 14 toward the desired temperature of the high- temperature water steam for efficient high-temperature electrolysis.
The high-temperature electrolysis unit 21 is configured to dissociate the high-temperature water steam into a hydrogen gas H and an oxygen gas. The oxygen gas (not shown) may be fed to the induration facility for providing oxidization of a metal ore material to produce the metal oxide material holding the first thermal energy.
By making use of the high-temperature water steam 14 produced by the direct reduction facility 7 there is achieved a more energy efficient electrolysis than that of conventional electrolysis achieved at room temperature.
The metal material production configuration 1 comprises a first fluid line arrangement FL' coupled between the gas outlet device c and the high-temperature electrolysis unit 21.
Alternatively, the first fluid line arrangement FL' comprises the filter device 22 and/or the separation unit and/or the heat exchange device 24.
The first fluid line arrangement FL' is configured for fluid communication and is adapted to feed the high-temperature water steam 14 to the high-temperature electrolysis unit 21 from the direct reduction facility 7 via the filter device 22 and/or the heat exchange device 24.
The metal material production configuration 1 further comprises a second fluid line arrangement FL" configured for fluid communication between the high-temperature electrolysis unit 21 and the direct reduction facility 7.
The second fluid line arrangement FL" is adapted to feed the hydrogen gas H (produced by the high-temperature electrolysis unit 21) from the high-temperature electrolysis unit 21 into the direct reduction facility 7.
Alternatively, the second fluid line arrangement FL" is configured to feed the hydrogen gas H from the high-temperature electrolysis unit 21 directly to the direct reduction facility 7 and/or via the heat exchange device 24 to the direct reduction facility 7 via a direct introduction line arrangement 33 ofthe second fluid line arrangement FL".
Alternatively, the second fluid line arrangement FL" is configured to feed the hydrogen gas H from the high-temperature electrolysis unit 21 via the reducing agent pre-heating device 18 configured to pre-heat the hydrogen gas H.
Alternatively, the pre-heating ofthe hydrogen gas H and/or the hydrogen gas containing reducing agent 8 is provided by the reducing agent pre-heating device 18 electrically coupled to the control circuitry 50 for controlling the heat energy of the second thermal energy of the hydrogen gas H and/or the hydrogen gas containing reducing agent 8 for reaching the required reaction temperature.
Alternatively, the reducing agent pre-heating device 18 comprises an electric pre-heater unit and/or a heat exchange device (not shown).
Alternatively, the second fluid line arrangement FL" is configured to feed the hydrogen gas H from the high-temperature electrolysis unit 21 to a reducing agent supply 30 for providing a hydrogen gas containing reducing agent 8. The reducing agent supply 30 comprises the reducing agent pre-heating device 18.
Alternatively, the reducing agent supply 30 is configured to feed the hydrogen gas containing reducing agent 8 comprising a primary reducing agent BS into the direct reduction facility 7 via the reducing agent inlet device b.
The primary reducing agent BS may be fed from a primary reducing agent provider S configured to provide the primary reducing agent BS. 41 The reducing agent supply 30 may be configured to provide a mixture of the hydrogen gas H (produced by the high-temperature electrolysis unit 21) and the primary reducing agent BS for providing the hydrogen gas containing reducing agent 8.
The reducing agent supply 30 is coupled to the direct reduction facility 7 via a third fluid line arrangement FL"' configured for fluid communication between the reducing agent supply 30 and the direct reduction facility 7.
The third fluid line arrangement FL"' may be configured to feed the hydrogen gas containing reducing agent 8 into the direct reduction facility 7 from the reducing agent supply 30 via the reducing agent inlet device b.
The third fluid line arrangement FL"' may be coupled to the second fluid line arrangement FL" for feeding the hydrogen gas H produced by the high-temperature electrolysis unit 21 via the direct introduction line arrangement 33 of the second fluid line arrangement FL" into the direct reduction facility 7.
The third fluid line arrangement FL"' may be coupled to the second fluid line arrangement FL" for feeding the hydrogen gas H to the reducing agent supply 30 for providing the hydrogen gas containing reducing agent 8.
The heat exchange device 24 may be coupled to the direct reduction facility 7 via a fourth fluid line arrangement FL"" configured for fluid communication between the heat exchange device 24 and the direct reduction facility 7.
The second fluid line arrangement FL" may comprise the fourth fluid line arrangement FL"" adapted to feed the hydrogen gas H produced by the high-temperature electrolysis unit 21 into the direct reduction facility 7 via the direct introduction line arrangement 33 of the second fluid line arrangement FL".
Alternatively, the produced hydrogen gas H is fed via the fourth fluid line arrangement FL"" to the reducing agent pre-heating device 18 for pre-heating the hydrogen gas H to be introduced into the direct reduction facility 7.
Alternatively, the produced hydrogen gas H is fed via the fourth fluid line arrangement FL"" to the third fluid line arrangement FL"' for adding the hydrogen gas H to the hydrogen gas containing reducing agent 8 to be introduced into the direct reduction facility 7. 42 Alternatively, the produced hydrogen gas H is fed via the heat exchange device 24 ofthe fourth fluid line arrangement FL"" for pre-heating the hydrogen gas H to be introduced into the direct reduction facility 7.
The high-temperature electrolysis unit 21 may be operated by means of electrical energy produced by a re-generative energy source RGE and by the introduced high-temperature water steam 14.
Alternatively, the control circuitry 50 is electrically coupled to the high-temperature electrolysis unit 21 and/or to the metal oxide material provider unit 3 and/or to the reducing agent pre-heating device 18 and/or to the reducing agent supply 30.
The pre-heating ofthe hydrogen gas H and/or the hydrogen gas containing reducing agent 8 to be introduced into the direct reduction facility 7 is provided for reaching the required FeaCtlOH temperature.
Alternatively, an excess hydrogen gas H' is separated from the high-temperature exit gas removed from the direct reduction facility is re-circulated and introduced into the direct reduction facility 7 via the second fluid line arrangement FL" and/or the third fluid line arrangement FL"'.
Alternatively, a water supply WS is configured to fed fresh water to the heat exchange device 24 for generating fresh hot water steam to be fed to the high-temperature electrolysis unit 21. The high-temperature electrolysis unit 21 is configured to produce hydrogen gas H from the fresh hot water steam to be fed to the direct reduction facility 7.
Fig. 4 illustrates a flow diagram of a metal material production configuration adapted for reduction of a metal oxide material according to a fourth example. A metal oxide material 5 holding a first thermal energy is charged into a reduction facility 7. The reduction facility 7 may be defined to have an upper interior portion UP, an intermediate interior portion IP and a lower interior portion LP.
Alternatively, the hydrogen gas containing reducing agent 8 holding a second thermal energy is introduced into the intermediate interior portion IP and flows upward meeting the downward moving metal oxide material, whereby the upper interior portion UP exhibits a required reaction temperature and functions as a counter current heat exchange zone for 43 providing the chemical reaction between the metal oxide material 5 and the hydrogen gas containing reducing agent 8.
Preferably, the hydrogen gas containing reducing agent 8 and/or the hydrogen gas H being pre-heated before being introduced into the direct reduction facility 7.
Alternatively, the metal oxide material 5 descends from the upper interior portion UP to the intermediate IP and/or the lower interior portion LP by means of gravity.
Alternatively, the temperature of the hydrogen gas containing reducing agent 8 introduced into the direct reduction facility 7 is controlled by a control circuitry (not shown) to produce a high-temperature exit gas 12 comprising more than about 60-80 % high-temperature water steam or more or substantially 100 % water steam. ln such way is achieved an excess volume of the hydrogen gas containing reducing agent and ensuring complete reduction ofthe metal oxide material.
Due to the high temperature of the charged metal oxide material 5, there is achieved an efficient direct reduction of the metal oxide material 5 in the upper interior portion UP, despite the fact that the hydrogen gas containing reducing agent 8 comprises a large amount of water steam.
Alternatively, the introduction ofthe hydrogen gas H may be provided into the intermediate interior portion IP and/or the lower interior portion LP.
The heat energy of the second thermal energy may be controlled by the control circuitry (not shown) for controlling a reducing agent supply (not shown) to adjust the heat energy of the second thermal energy of the hydrogen gas containing reducing agent 8 and/or the hydrogen gas H to be introduced into the direct reduction facility 7 for reaching a required reaction heat energy (required reaction temperature under specific pressure in the direct reduction facility 7).
Fig. 5 illustrates a phase diagram of iron phase domains as a function of oxidizing power of hydrogen gas and temperature, for the gas mixture Hz-HZO in direct reduction of an iron ore oxide material (hematite and/or magnetite and/or wüstite) into a reduced iron ore material. 44 The direct reduction takes place in two or three stages, depending on whether the temperature is above or below 570 °C. ln this case, hematite Fe203 is first reduced to magnetite Fe304, then to wüstite Fe0>< and finally to iron Fe. The diagram discloses that increasing content of water steam in the interior of the direct reduction facility requires higher temperature to obtain reduction of the iron ore oxide material.
The pre-heated hydrogen gas containing reducing agent, holding the second thermal energy, being introduced into the direct reduction facility ascends upward in the direct reduction facility and contacts the descending iron ore oxide material holding the first thermal energy.
Due to the charging ofthe iron ore oxide material holding the first thermal energy into the direct reduction facility it is possible to achieve direct reduction ofthe iron ore oxide material, even if the content of water steam in the hydrogen containing reducing agent is high (see phase diagram in Fig. 5 at position Q, e.g. H20 / (H20 + H2) quota about 0,9).
Preferably, further down in the direct reduction facility there is less content of water steam in the hydrogen gas containing reducing agent than in the upper part of the direct reduction facility, since the hydrogen to less extent has been used for the direct reduction. For example the hydrogen content may be twice as much as the water steam content in the hydrogen containing reducing agent (see phase diagram in Fig. 5 at position R, e.g. a H20/ (H20 + H2) quota about 0,3).
Alternatively, a control circuitry (not shown) is adapted to control the direct reduction in the direct reduction facility such that the reduced metal material is not re-oxidated.
The control circuitry may by electrically coupled to a reducing agent thermal energy adjusting device (not shown) and/or to a pressurization adjusting device (not shown) and/or to a reducing agent mass flow adjusting device (not shown) and/or to a means of a residence time period adjusting device (not shown) adapted to hold the iron oxide material during a specific residence time period in the direct reduction facility and/or to a reducing agent introduction/pressurizing device and/or a top gas removing device , for controlling the required reaction temperature.
The required reaction temperature is thus maintained by means ofthe control circuitry by adjusting the temperature of the hydrogen gas containing reducing agent and/or by adjusting the mass flow of the pre-heated hydrogen gas containing reducing agent fed into the direct reduction facility. ln such way, it is achieved that the reduced iron material not being re-oxidized in the direct reduction facility.
Alternatively, the control circuitry is adapted to control the reducing agent mass flow adjusting device to feed a relatively high flow of the pre-heated hydrogen gas containing reducing agent into the direct reduction facility to hold down the water steam burden in the direct reduction facility for providing an efficient direct reduction and fully direct reduced iron material.
By means of the second thermal energy of the pre-heated hydrogen gas containing reducing agent it is thus possibly to provide the direct reduction despite the fact that the content of water is relatively high further down in the direct reduction facility (see phase diagram in Fig. at position R).
Alternatively, the pre-heated hydrogen gas containing reducing agent introduced into the direct reduction facility may exhibit higher thermal heat the farther up the pre-heated hydrogen gas containing reducing agent ascends in the direct reduction facility, since the warmer iron ore oxide material heats the pre-heated hydrogen gas containing reducing agent for providing the required reaction temperature.
Alternatively, the pre-heated hydrogen gas containing reducing agent reduces the cooling rate ofthe iron ore oxide material descending in the direct reduction facility.
Alternatively, the pre-heated hydrogen gas containing reducing agent contains an increased amount of high-temperature water-steam the farther up the pre-heated hydrogen gas containing reducing agent ascends in the direct reduction facility. However, it is possible to reach efficient direct reduction ofthe iron ore oxide material (see phase diagram in Fig. 5 at position Q).
As shown in the diagram, hematite is to be reduced into magnetite at high temperature (e.g. 1200 °C), despite that the water content (position Q) ofthe pre-heated hydrogen gas containing reducing agent is high, direct reduction into magnetite still can be achieved. 46 ln such a way, the heat energy ofthe first thermal energy generated by the metal oxide material provider unit in combination with the heat energy of the hydrogen gas containing reducing agent 8 and/or the hydrogen gas H being utilized to reach the required reaction temperature. ln such way, it is achieved that the high temperature ofthe iron ore oxide material promotes an efficient direct reduction, despite the fact that the pre-heated hydrogen gas containing reducing agent will contain a high content of water-steam (see phase diagram in Fig. 5 at position Q).
Alternatively, any excess hydrogen gas being separated from the high-temperature exit gas removed from the direct reduction facility is re-circulated and introduced into the direct reduction facility. ln such way, a cost-effective use of hydrogen gas and energy efficient direct reduction process is achieved.
Figs. 6-7 illustrate flowcharts showing exemplary methods of direct reduction of a metal oxide material into a reduced metal material.
Fig. 6 illustrates a flowchart showing an exemplary method of direct reduction of a metal oxide material holding a first thermal energy into a direct reduced metal material by means of a metal material production configuration.
The method in Fig. 6 starts at step 601. Step 602 comprises adaption ofthe method. Step 603 comprises stop ofthe method. Step 602 may comprise the steps of; providing the metal oxide material, holding the first thermal energy, by means of a metal oxide material provider unit; charging the metal oxide material, holding the first thermal energy, into a direct reduction facility; introducing a hydrogen gas containing reducing agent, holding a second thermal energy, into the direct reduction facility; reducing the metal oxide material by using the first thermal energy of the metal oxide material to heat or further heat the introduced hydrogen gas containing reducing agent toward a required reaction temperature for providing a chemical reaction between the hydrogen gas containing reducing agent and the metal oxide material; removing a high-temperature exit gas from the direct reduction facility; feeding a high-temperature water steam ofthe high-temperature exit gas to a high- 47 temperature electrolysis unit configured to produce a hydrogen gas; and introducing the hydrogen gas into the direct reduction facility.
Alternatively, the hydrogen gas is added to the hydrogen gas containing reducing agent to be introduced into the direct reduction facility and/or introducing the hydrogen gas directly into the direct reduction facility. Alternatively, the first thermal energy is higher than the second thermal energy.
Fig. 7 i||ustrates a flowchart showing an exemplary method of direct reduction of a metal oxide material holding a first thermal energy into a direct reduced metal material by means of a metal material production configuration.
The method starts at step 701. Step 702 comprises providing the metal oxide material, holding the first thermal energy, by means of a metal oxide material provider unit. Step 703 comprises charging the metal oxide material, holding the first thermal energy, into a direct reduction facility. Step 704 comprises introducing a hydrogen gas containing reducing agent, holding a second thermal energy, into the direct reduction facility. Step 705 comprises reducing the metal oxide material by using the first thermal energy of the metal oxide material to heat or further heat the introduced hydrogen gas containing reducing agent toward a required reaction temperature for providing a chemical reaction between the hydrogen gas containing reducing agent and the metal oxide material. Step 706 comprises removing a high-temperature exit gas from the direct reduction facility. Alternatively, the first thermal energy is higher than the second thermal energy.
Step 707 comprises feeding a high-temperature water steam of the high-temperature exit gas to a high-temperature electrolysis unit configured to produce a hydrogen gas. Step 708 comprises adding the hydrogen gas to the hydrogen gas containing reducing agent to be introduced into the direct reduction facility and/or introducing the hydrogen gas directly into the direct reduction facility. Step 709 comprises-pre-heating the hydrogen gas and/or the hydrogen gas containing reducing agent to be introduced into the direct reduction facility for reaching the required reaction temperature. Step 710 comprises-providing the hydrogen gas containing reducing agent, to be introduced into the direct reduction facility, by adding the hydrogen gas to a primary reducing agent. 48 Step 711 comprises removing the high-temperature water steam contained in the high- temperature exit gas , which high-temperature water steam is generated by the chemical reaction between the metal oxide material and the hydrogen gas containing reducing agent. Step 712 comprises-adjusting the second thermal energy of the hydrogen gas containing reducing agent to be introduced into the direct reduction facility for reaching the- required reaction temperature. Step 713 comprises-feeding the high-temperature exit gas to the high-temperature electrolysis unit via a filter device configured for removing impurities.
Step 714 comprises-recovering a third thermal energy from the high-temperature water steam by means of a heat exchange device. Step 715 comprises operating the high- temperature electrolysis unit by means of electrical energy produced by a re-generative energy source, producing the hydrogen gas by means of the high-temperature electrolysis unit making use ofthe high-temperature water steam, and introducing the hydrogen gas into the direct reduction facility. Step 716 comprises stop of the method.
Fig. 8 illustrates a control circuitry 50 of an exemplary metal material production configuration 1. The control circuitry 50 comprises a computer (not shown). The control circuitry 50 is configured to control any exemplary method herein disclosed. The control circuitry 50 may comprise a non-volatile memory NVM 820, which is a computer memory that can retain stored information even when the control circuitry 50 or the computer is not powered. The control circuitry 50 further comprises a processing unit 810 and a read/write memory 850.
The NVM 820 comprises a first memory unit 830. A computer program (which can be of any type suitable for any operational database) is stored in the first memory unit 830 to be used for controlling the functionality of the control circuitry 50.
Furthermore, the control circuitry 50 comprises a bus controller (not shown), a serial communication port (not shown) providing a physical interface, through which suitable information being able to be transferred separately in one direction or in two directions.
The control circuitry 50 also comprises any suitable type of I/O module (not shown) providing input/output signal transfer, an A/D converter (not shown) for converting continuously varying signals from the temperature sensor devices for detecting temperatures of the metal oxide material holding the first thermal energy and/or 49 temperatures of the hydrogen gas containing reducing agent holding the second thermal energy introduced into the reduction facility and/or for detecting the required reaction temperature and/or a set of different monitoring units (not shown), into binary code suitable to be processed by the computer ofthe control circuitry 50.
The control circuitry 50 further comprises an input/output unit (not shown) for adaption to time and date. The control circuitry 50 also may comprise an event counter (not shown) for counting the number of event multiples that occur during the adjustment of the heat energy toward the required reaction temperature by adjusting the second thermal energy. Furthermore, the control circuitry 50 includes interrupt units (not shown) for providing a multi-tasking performance and real time computing. The NVM 820 also includes a second memory unit 840 for external controlled operation.
There is provided a data medium, adapted for storing a data program P that comprises driver routines configured for commanding operation ofthe metal material production configuration 1.
The data program P is adapted for operating the control circuitry 50 in performing any exemplary method described herein. The data program P comprises routines for executing the commands under operation ofthe metal material production configuration 1. The data program P comprises a program code, which is readable on the computer, for causing the computer to perform any exemplary method herein described.
The data program P further may be stored in a separate memory 860 and/or in the read/write memory 850. The data program P is in this embodiment stored in executable or compressed data format. lt is to be understood that when the processing unit 810 is described to execute a specific function that involves that the processing unit 810 executes a certain part of the program stored in the separate memory 860 or a certain part of the program stored in the read/write memory 850.
The processing unit 810 is associated with a signal (data) port 899 for communication via a first data bus 815, which signal (data) port 899 may be adapted to be electrically coupled to an electronic control circuitry of an operator station (not shown). ln such way is achieved that an operator via a display of the electronic control circuitry can control and monitor the metal material production configuration 1.
The non-volatile memory NVM 820 is adapted for communication with the processing unit 810 via a second data bus 812. The separate memory 860 is adapted for communication with the processing unit 810 via a third data bus 811. The read/write memory 850 is adapted to communicate with the processing unit 810 via a fourth data bus 814. The signal (data) port 899 may be connectable to data links of e.g. a network coupled to the control circuitry 50.
When data is received by the signal port 899, the data will be stored temporary in the second memory unit 840. After that the received data is temporary stored, the processing unit 810 will be ready to execute the program code, in accordance with any ofthe exemplary methods.
Preferably, the signals (received by the signal port 899) comprise information about operational status ofthe metal material production configuration 1.
The received signals at the signal port 899, such as a serial bus, may be used by the control circuitry 50 for controlling and monitoring the direct reduction and the required reaction tempeFatUFe.
The signals received by the signal port 899 can be used for historic data and data regarding operation ofthe metal material production configuration 1.
The metal material production configuration 1 may be configured to be coupled to a data network via the signal bus configured for electrical interface explicitly providing electrical compatibility and related data transfer, which data may include information about status of the metal material production configuration 1 and the temperature sensor devices. Data also may be manually fed to or presented from the computer via a suitable communication device, such as a display (not shown).
Separate sequences of the method may be executed by the computer, wherein the computer runs the data program P being stored in the separate memory 860 or in the read/write memory 850. When the computer runs the data program P, the method steps according to any example disclosed herein will be executed.
A data program product comprising a program code stored on a data medium may be provided, which product is readable on a suitable computer, for performing the exemplary method steps herein, when the data program P is run on the computer.
The present invention is of course not in any way restricted to the preferred examples described above, but many possibilities to modifications, or combinations ofthe described examples thereof should be apparent to a person with ordinary skill in the art without departing from the basic idea of the invention as defined in the appended claims.

Claims (18)

Claims
1. A method of direct reduction of a metal oxide material (5) holding a first thermal energy into a direct reduced metal material (16) by means ofa metal material production configuration (1); the method comprises; -providing the metal oxide material (5), holding the first thermal energy, by means of a metal oxide material provider unit (3); -charging the metal oxide material (5), holding the first thermal energy, into a direct reduction facility (7); -introducing a hydrogen gas containing reducing agent (8), holding a second thermal energy, into the direct reduction facility (7); the method further comprises the steps of; -reducing the metal oxide material (5) by using the first thermal energy of the metal oxide material (5) to heat or further heat the introduced hydrogen gas containing reducing agent (8) toward a required reaction temperature for providing a chemical reaction between the hydrogen gas containing reducing agent (8) and the metal oxide material (5); -removing a high-temperature exit gas (12) from the direct reduction facility (7); -feeding a high-temperature water steam (14) of the high-temperature exit gas (12) to a high-temperature electrolysis unit (21) configured to produce a hydrogen gas (H); and -introducing the hydrogen gas (H) into the direct reduction facility (7).
2. The method according to claim 1, wherein the method further comprises; -pre-heating the hydrogen gas (H) and/or the hydrogen gas containing reducing agent (8) to be introduced into the direct reduction facility (7) for reaching the required reaction tempeFatUFe.
3. The method according to claim 1 or 2, wherein the method further comprises; -forming the hydrogen gas containing reducing agent (8), to be introduced into the direct reduction facility (7), by adding the hydrogen gas (H) to a primary reducing agent (BS).
4. The method according to any of claim 1 to 3, wherein the method further comprises; -removing the high-temperature water steam contained in the high-temperature exit gas , which high-temperature water steam is generated by the chemical reaction between the metal oxide material (5) and the hydrogen gas containing reducing agent (8).
5. The method according to any of the preceding claims, wherein the method further comprises; -adjusting the second therma| energy of the hydrogen gas containing reducing agent (8) to be introduced into the direct reduction facility (7) for reaching the required reaction temperature.
6. The method according to any of the preceding claims, wherein the method further comprises; -feeding the high-temperature exit gas (12) to the high-temperature e|ectro|ysis unit (21) via a filter device (22) configured for removing impurities from the high-temperature water steam (14).
7. The method according to any ofthe preceding claims, wherein the method further comprises the step of; -recovering a third therma| energy from the high-temperature water steam by means of a heat exchange device (24).
8. The method according to any ofthe preceding claims, wherein the method further comprises the step of; -operating the high-temperature e|ectro|ysis unit (21) by means of electrical energy produced by a re-generative energy source; and -producing the hydrogen gas (H) by means ofthe high-temperature e|ectro|ysis unit (21) making use ofthe high-temperature water steam (14).
9. A metal material production configuration (1) adapted for direct reduction of a metal oxide material (5) holding a first thermal energy into a reduced metal material (16); the metal material production configuration (1) comprises; -a high-temperature e|ectro|ysis unit (21) configured to produce a hydrogen gas (H); -a metal oxide material provider unit (3) configured to provide the metal oxide material (5) holding the first thermal energy; -a direct reduction facility (7) comprising; -a metal oxide material charging inlet device (a); -a reducing agent inlet device (b) configured to introduce a hydrogen gas containing reducing agent (8) holding a second thermal energy; -a control circuitry (50) configured to control the direct reduction ofthe metal oxide material (5); characterized in that -the metal material production configuration (1) is adapted to reduce the metal oxide material (5) by using the first thermal energy of the metal oxide material (5) to heat or further heat the introduced hydrogen gas containing reducing agent (8) toward a required reaction temperature for providing a chemical reaction between the hydrogen gas containing reducing agent (8) and the metal oxide material (5); -the direct reduction facility (7) comprises a gas outlet device (c) configured for removing a high-temperature exit gas (12) from the direct reduction facility (7); -the metal material production configuration (1) comprises; -a first fluid line arrangement (FL') configured for fluid communication and adapted to feed a high-temperature water steam (14) of the high-temperature exit gas (12) to the high-temperature electrolysis unit (21); -a second fluid line arrangement (FL") configured for fluid communication and adapted to feed the hydrogen gas (H) from the high-temperature electrolysis unit (21) to the direct reduction facility (7).
10. The metal material production configuration (1) according to claim 9, wherein the metal material production configuration (1) comprises a reducing agent supply (30) configured to add the hydrogen gas (H) to a primary reducing agent (BS) for providing the hydrogen gas containing reducing agent (8).
11. The metal material production configuration (1) according to claim 9 or 10, wherein the reducing agent supply (30) is coupled to the direct reduction facility (7) via a third fluid line arrangement (FL"') configured for fluid communication and adapted to feed the hydrogen gas containing reducing agent (8) to the direct reduction facility from the reducing agent supply (30).
12. The metal material production configuration (1) according to any of claim 9 to 11, wherein a heat exchange device (24) is configured to recover a third thermal energy from the high-temperature water steam (14), which heat exchange device (24) is coupled to the direct reduction facility (7) via a fourth fluid line arrangement (FL"") adapted for feeding the hydrogen gas (H) pre-heated by means ofthe heat exchange device (24).
13. The metal material production configuration (1) according to any of claim 9 to 12, wherein the control circuitry (50) is electrically coupled to a reducing agent pre-heating device (18) for adjusting the second thermal energy of the hydrogen gas containing reducing agent (8) to be introduced into the direct reduction facility (7) for reaching the required FeaCtlOH temperature.
14. The metal material production configuration (1) according to any of claim 12 to 13, wherein the control circuitry (50) is electrically coupled to the heat exchange device (24) of the first fluid line arrangement (FL'), which heat exchange device (24) is configured to transfer heat energy from the high-temperature water steam (14) to the hydrogen gas (H) produced by the high-temperature electrolysis unit (21).
15. A data program (P) comprising a program code readable on a computer of the control circuitry (50), which data program (P) is programmed for causing the metal material production configuration (1) according to any of claims 9 to 14 to execute the method steps of: -providing the metal oxide material (5), holding the first thermal energy, by means of the metal oxide material provider unit (3); -charging the metal oxide material (5), holding the first thermal energy, into a direct reduction facility (7); -introducing a hydrogen gas containing reducing agent (8), holding a second thermal energy, into the direct reduction facility (7); wherein -reducing the metal oxide material (5) by using the first thermal energy ofthe metal oxide material (5) to heat or further heat the introduced hydrogen gas containing reducing agent (8) toward a required reaction temperature for providing a chemical reaction between the hydrogen gas containing reducing agent (8) and the metal oxide material (5); -removing a high-temperature exit gas (12) from the direct reduction facility (7); -feeding a high-temperature water steam to (14) of the high-temperature exit gas (12) a high-temperature electrolysis unit (21) configured to produce a hydrogen gas (H); and -introducing the hydrogen gas (H) into the direct reduction facility (7).
16. The data program (P) according to claim 15, wherein the data program (P) further is programmed for causing the metal material production configuration (1) to execute the method steps of any of claims 2-
17. A data medium, configured for storing the data program (P) according to claim 15 or 16, wherein the data medium comprises the program code being readable on the computer for performing the method according to any of claims 1 to
18. A direct reduction facility (7) comprising a metal oxide material charging inlet device (a), a reducing agent inlet device (b) configured to introduce a hydrogen gas containing reducing agent (8) holding a second thermal energy; which direct reduction facility (7) is characterized by the metal material production configuration (1) according to any of claims 9 to 14.
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WO2019219340A1 (en) * 2018-05-15 2019-11-21 Tata Steel Nederland Technology B.V. Method for the direct reduction of iron ore
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US20200385827A1 (en) * 2019-06-06 2020-12-10 Midrex Technologies, Inc. Direct reduction process utilizing hydrogen
WO2022129515A1 (en) * 2020-12-18 2022-06-23 Paul Wurth S.A. Smart hydrogen production for dri making

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