SE2050356A1 - Method and device for producing direct reduced metal - Google Patents
Method and device for producing direct reduced metalInfo
- Publication number
- SE2050356A1 SE2050356A1 SE2050356A SE2050356A SE2050356A1 SE 2050356 A1 SE2050356 A1 SE 2050356A1 SE 2050356 A SE2050356 A SE 2050356A SE 2050356 A SE2050356 A SE 2050356A SE 2050356 A1 SE2050356 A1 SE 2050356A1
- Authority
- SE
- Sweden
- Prior art keywords
- hydrogen gas
- furnace space
- metal material
- charged
- furnace
- Prior art date
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Classifications
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B5/00—General methods of reducing to metals
- C22B5/02—Dry methods smelting of sulfides or formation of mattes
- C22B5/12—Dry methods smelting of sulfides or formation of mattes by gases
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B13/00—Making spongy iron or liquid steel, by direct processes
- C21B13/10—Making spongy iron or liquid steel, by direct processes in hearth-type furnaces
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B13/00—Making spongy iron or liquid steel, by direct processes
- C21B13/004—Making spongy iron or liquid steel, by direct processes in a continuous way by reduction from ores
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B13/00—Making spongy iron or liquid steel, by direct processes
- C21B13/12—Making spongy iron or liquid steel, by direct processes in electric furnaces
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/10—Reduction of greenhouse gas [GHG] emissions
- Y02P10/134—Reduction of greenhouse gas [GHG] emissions by avoiding CO2, e.g. using hydrogen
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Furnace Details (AREA)
Abstract
Method for producing direct reduced metal material, comprising the steps:a) charging metal material to be reduced into a furnace space (120);b) evacuating an existing atmosphere from the furnace space (120) so as to achieve an underpressure inside the furnace space (120);c) providing, in a main heating step, heat and hydrogen gas to the furnace space (120), so that heated hydrogen gas heats the charged metal material to a temperature high enough so that metal oxides present in the metal material are reduced, in turn causing water vapour to be formed; andd) condensing and collecting the water vapour formed in step c in a condenser (160) below the charged metal material;The invention is characterised in that said hydrogen gas in step c is provided without recirculation of the hydrogen gas, and in that the method further comprises the subsequently performed step of removing the reduced metal material from the furnace space (120), and storing and/or transporting the reduced metal material under an inert atmosphere.
Description
Method and device for producing direct reduced metal The present invention relates to a method and a device for producing direct reducedmetal, and in particular direct reduced iron (also known as sponge iron). ln particular, thepresent invention relates to the direct reduction of metal ore under a controlled hydrogen atmosphere to produce such direct reduced metal.
The production of direct reduced metal using hydrogen as a reducing agent is well-knownas such. For instance, in SE7406174-8 and SE7406175-5 methods are described in which acharge of metal ore is subjected to a hydrogen atmosphere flowing past the charge, which as a result is reduced to form direct reduced metal.
The present invention is particularly applicable in the case of batchwise charging and treatment ofthe material to be reduced.
There are several problems with the prior art, including efficiency regarding thermal lossesas well as hydrogen gas usage. There is also a control problem, since it is necessary to measure when the reduction process has been finalized.
The present invention solves the above described problems.
Hence, the invention relates to a method for producing direct reduced metal material,comprising the steps: a) charging metal material to be reduced into a furnace space; b)evacuating an existing atmosphere from the furnace space so as to achieve an underpres-sure inside the furnace space; c) providing, in a main heating step, heat and hydrogen gasto the furnace space, so that heated hydrogen gas heats the charged metal material to atemperature high enough so that metal oxides present in the metal material are reduced,in turn causing water vapour to be formed; and d) condensing and collecting the watervapour formed in step cin a condenser below the charged metal material; which methodis characterised in that said hydrogen gas in step cis provided without recirculation of thehydrogen gas, and in that the method further comprises the subsequently performed step Application text 2020~O3~30 l90028SE2 of removing the reduced metal material from the furnace space (120), and storing and/or transporting the reduced metal material under an inert atmosphere. ln the following, the invention will be described in detail, with reference to exemplifying embodiments of the invention and to the enclosed drawings, wherein: Figure la is a cross-section of a simplified furnace for use in a system according to thepresent invention, during a first operation state; Figure lb is a cross-section of the simplified furnace of Figure la, during a second opera-tion state; Figure 2 is a schematic overview of a system according to the present invention; Figure 3 is a flowchart of a method according to the present invention; and Figure 4 is a chart showing a possible relation between H2 pressure and temperature in a heated furnace space according to the present invention.
Figures la and lb share the same reference numerals for same parts.
Hence, figures la and lb illustrate a furnace l00 for producing direct reduced metalmaterial. ln Figure 2, two such furnaces 210, 220 are illustrated. The furnaces 2l0, 220may be identical to furnace l00, or differ in details. However, it is understood that every-thing which is said herein regarding the furnace l00 is equally applicable to furnaces 2l0 and/or 220, and vice versa.
Furthermore, it is understood that everything which is said herein regarding the presentmethod is equally applicable to the present system 200 and/or furnace l00; 2l0, 220, and vice versa.
The furnace l00 as such has many similarities with the furnaces described in SE7406l74-8and SE7406l75-5, and reference is made to these documents regarding possible designdetails. However, an important difference between these furnaces and the presentfurnace l00 is that the present furnace l00 is not arranged to be operated in a way where Application text 2020~03~30 l90028SE2 hydrogen gas is recirculated through the furnace 100 and back to a collecting containerarranged outside of the furnace 100, and in particular not in a way where hydrogen gas isrecirculated out from the furnace 100 (or heated furnace space 120) and then back intothe furnace 100 (or heated furnace space 120) during one and the same batch processing of charged material to be reduced. lnstead, and as will be apparent from the below description, the furnace 100 is arrangedfor batch-wise reducing operation of one charge of material at a time, and to operateduring such an individual batch processing as a closed system, in the sense that hydrogengas is supplied to the furnace 100 but not removed therefrom during the batch-wise reducing step. ln other words, the amount of hydrogen gas present inside the furnace 100 always in-creases during the reduction process. After reduction has been completed, the hydrogengas is of course evacuated from within the furnace 100, but there is no recirculation of hydrogen gas during the reduction step.
Hence, the furnace 100 is part of a closed system comprising a heated furnace space 120which arranged to be pressurized, such as to at least 5 bars, or at least 6 bars, or at least 8bars, or even at least 10 bars. An upper part 110 of the furnace 100 has a bell-shape. lt canbe opened for charging of material to be processed, and can be closed in a gas-tightmanner using fastening means 111. The furnace space 120 is encapsulated with refractory material, such as brick material 130.
The furnace space 120 is arranged to be heated using one or several heating elements121. Preferably, the heating elements 121 are electric heating elements. However, radia-tor combustion tubes or similar fuel-heated elements can be used as well. The heatingelements 121 do not, however, produce any combustion gases that interact directlychemically with the furnace space 120, which must be kept chemically controlled for thepresent purposes. lt is preferred that the only gaseous matter provided into the furnacespace during the below-described main heating step is hydrogen gas.
Application text 2020~03~30 l90028SE2 The heating elements 121 may preferably be made of a heat-resistant metal material, such as a molybdenum alloy.
Additional heating elements may also be arranged in the heated furnace space 120. Forinstance, heating elements similar to elements 121 may be provided at the side walls ofthe furnace space 120, such as at a height corresponding to the charged material or atleast to the container 140. Such heating elements may aid heating not only the gas, but also the charged material via heat radiation.
The furnace 100 also comprises a lower part 150, forming a sealed container together with the upper part 110 when the furnace is closed using fastening means 111.
A container 140 for material to be processed (reduced) is present in the lower part 150 ofthe furnace 100. The container 140 may be supported on a refractory floor of the furnacespace 120 in a way allowing gas to pass beneath the container 140, such as along open orclosed channels 172 formed in said floor, said channels 172 passing from an inlet 171 forhydrogen gas, such as from a central part of the furnace space 120 at said furnace floor,radially outward to a radial periphery of the furnace space 120 and thereafter upwards toan upper part of the furnace space 120. See flow arrows indicated in Figure 1a for these flows during the below-described initial and main heating steps.
The container 140 is preferably of an open constitution, meaning that gas can pass freelythrough at least a bottom/floor of the container 140. This may be accomplished, for instance, by forming holes through the bottom of the container 140.
The material to be processed comprises a metal oxide, preferably an iron oxide such asFezOg and/or Fe3O4. The material may be granular, such as in the form of pellets or balls.One suitable material to be charged for batch reduction is rolled iron ore balls, that havebeen rolled in water to a ball diameter of about 1-1.5 cm. lf such iron ore additionallycontains oxides that evaporate at temperatures below the final temperature of the Application text 2020~03~30 l90028SE2 charged material in the present method, such oxides may be condensed in the condenser160 and easily collected in powder form. Such oxides may comprise metal oxides such as Zn and Pb oxides.
Advantageously, the furnace space 120 is not charged with very large amounts of materialto be reduced. Each furnace 100 is preferably charged with at the most 50 tonnes, such asat the most 25 tonnes, such as between 5 and 10 tonnes, in each batch. This charge maybe held in one single container 150 inside the furnace space 120. Depending on through-put requirements, several furnaces 100 may be used in parallel, and the residual heatfrom a batch in one furnace 220 can then be used to preheat another furnace 210 (see Figure 2 and below).
This provides a system 200 which is suitable for installation and use directly at the miningsite, requiring no expensive transport of the ore before reduction. lnstead, direct reducedmetal material can be produced on-site, packaged under a protecting atmosphere and transported to a different site for further processing.
Hence, in the case of water-rolled iron ore balls, it is foreseen that the furnace 100 may beinstalled in connection to the iron ore ball production system, so that charging of themetal material into the furnace 100 in the container 140 can take place in a fully automat-ed manner, where containers 140 are automatically circulated from the iron ore ballproduction system to the system 100 and back, being filled with iron ore balls to bereduced; inserted into the furnace space 120; subjected to the reducing hydrogen/heatprocessing described herein; removed from the furnace space 120 and emptied; takenback to the iron ore ball production system; refilled; and so forth. I\/|ore containers 140may be used than furnaces 100, so that in each batch switch a reduced charge in a particu-lar container is immediately replaced in the furnace 100 with a different container carry-ing material not yet reduced. Such a larger system, such as at a mining site, may be im-plemented to be completely automated, and also to be very flexible in terms of through- put, using several smaller furnaces 100 rather than one very large furnace.
Application text 2020~03~30 l90028SE2 Below the container 140, the furnace 100 comprises a gas-gas type heat exchanger 160,which may advantageously be a tube heat exchanger such as is known per se. The heatexchanger 160 is preferably a counter-flow type heat exchanger. To the heat exchanger160, below the heat exchanger 160, is connected a closed trough 161 for collecting andaccommodating condensed water from the heat exchanger 160. The trough 161 is alsoconstructed to withstand the operating pressures of the furnace space 120 in a gas-tight mannef.
The heat exchanger 160 is connected to the furnace space 120, preferably so thatcool/cooled gases arriving to the furnace space 120 pass the heat exchanger 160 alongexternally/peripherally provided heat exchanger tubes and further through said channels172 up to the heating element 121. Then, heated gases passing out from the furnacespace 120, after passing and heating the charged material (see below), pass the heatexchanger 160 through internally/centrally provided heat exchanger tubes, therebyheating said cool/cooled gases. The outgoing gases hence heat the incoming gases both bythermal transfer due to the temperature difference between the two, as well as by thecondensing heat of condensing water vapour contained in the outgoing gases effectively heating the incoming gases.
The formed condensed water from the outgoing gases is collected in the trough 161.
The furnace 100 may comprise a set of temperature and/or pressure sensors in the trough161 (122); at the bottom of the furnace space 120, such as below the container 140 (123)and/or at the top of the furnace space 120 (124). These sensors may be used by control unit 201 to control the reduction process, as will be described below. 171 denotes an entry conduit for heating/cooling hydrogen gas. 173 denotes an exit conduit for used cooling hydrogen gas.
Between the trough 161 and the entry conduit 171 there may be an overpressure equili- bration channel 162, with a valve 163. ln case an overpressure builds up in the trough 161, Application text 2020~03~30 l90028SE2 due to large amounts of water flowing into the trough 161, such an overpressure maythen be released to the entry conduit 171. The valve 163 may be a simple overpressurevalve, arranged to be open when the pressure in trough 161 is higher than the pressure inthe conduit 171. Alternatively, the valve may be operated by control device 201 (below) based on a measurement from pressure sensor 122.
Condensed water may be led from the condenser/heat exchanger 160 may be led downinto the trough via a spout 164 or similar, debouching at a bottom of the trough 161, suchas at a local low point 165 of the trough, preferably so that an orifice of said spout 164 isarranged fully below a main bottom 166 of the trough 161 such as is illustrated in Figure1a. This will decrease liquid water turbulence in the trough 161, providing more controlla- ble operation conditions.
The trough 161 is advantageously dimensioned to be able to receive and accommodate allwater formed during the reduction of the charged material. The size of trough 161 canhence be adapted for the type and volume of one batch of reduced material. For instance,when fully reducing 1000 kg of Fe3O4, 310 liters of water is formed, and when fully reduc- ing 1000 kg of FezOg, 338 liters of water is formed. ln Figure 2, a system 200 is illustrated in which a furnace of the type illustrated in Figures1a and 1b may be put to use. ln particular, one or both of furnaces 210 and 220 may be of the type illustrated in Figures 1a and 1b, or at least according to the present claim 1. 230 denotes a gas-gas type heat exchanger. 240 denotes a gas-water type heat exchanger.250 denotes a fan. 260 denotes a vacuum pump. 270 denotes a compressor. 280 denotesa container for used hydrogen gas. 290 denotes a container for fresh/unused hydrogen gas. V1-V14 denote valves. 201 denotes a control device, which is connected to sensors 122, 123, 124 and valves V1-V14, and which is generally arranged to control the processes described herein. Thecontrol device 201 may also be connected to a user control device, such a graphical user Application text 2020~03~30 l90028SE2 interface presented by a computer (not shown) to a user of the system 200 for supervision and further control.
Figure 3 i||ustrates a method according to the present invention, which method uses asystem 100 of the type generally illustrated in Figure 3 and in particular a furnace 100 ofthe type generally illustrated in Figures 1a and 1b. ln particular, the method is for produc- ing direct reduced metal material using hydrogen gas as the reducing agent.
After such direct reduction, the metal material may form sponge metal. ln particular, themetal material may be iron oxide material, and the resulting product after the directreduction may then be sponge iron. Such sponge iron may then be used, in subsequent method steps, to produce steel and so forth. ln a first step, the method starts. ln a subsequent step, the metal material to be reduced is charged into the furnace space120. This charging may take place by a loaded container 140 being placed into the furnacespace 120 in the orientation illustrated in Figures 1a and 1b, and the furnace space 120 may then be closed and sealed in a gas-tight manner using fastening means 111. ln a subsequent step, an existing atmosphere is evacuated from the furnace space 120, sothat an underpressure is achieved inside the furnace space 120 as compared to atmos-pheric pressure. This may take place by valves 1-8, 11 and 13-14 being closed and valves 9-10 and 12 being open, and the vacuum pump sucking out and hence evacuating thecontained atmosphere inside the furnace space 120 via the conduit passing via 240 and250. Valve 9 may then be open to allow such evacuated gases to flow out into the sur-rounding atmosphere, in case the furnace space 120 is filled with air. lf the furnace space 120 is filled with used hydrogen gas, this is instead evacuated to the container 280. ln this example, the furnace atmosphere is evacuated via conduit 173, even if it is realized that any other suitable exit conduit arranged in the furnace 100 may be used.
Application text 2020~03~30 l90028SE2 ln this evacuation step, as well as in other steps as described below, the control device201 may be used to control the pressure in the furnace space 120, such as based upon readings from pressure sensors 122, 123 and/or 124.
The emptying may proceed until a pressure of at the most 0.5 bar, preferably at the most 0.3 bar, is achieved in the furnace space 120. ln a subsequent initial heating step, heat and hydrogen gas is provided to the furnacespace 120. The hydrogen gas may be supplied from the containers 280 and/or 290. Sincethe furnace 100 is closed, as mentioned above, substantially none of the provided hydro-gen gas will escape during the process. ln other words, the hydrogen gas losses (apartfrom hydrogen consumed in the reduction reaction) will be very low or even non-existent.lnstead, only the hydrogen consumed chemically in the reduction reaction during thereduction process will be used. Further, the only hydrogen gas which is required duringthe reduction process is the necessary amount to uphold the necessary pressure andchemical equilibrium between hydrogen gas and water vapour during the reduction pFOCeSS.
As mentioned above, the container 290 holds fresh (unused) hydrogen gas, while contain-er 280 holds hydrogen gas that has already been used in one or several reduction stepsand has since been collected in the system 200. The first time the reduction process isperformed, only fresh hydrogen gas is used, provided from container 290. During subse-quent reduction processes, reused hydrogen gas, from container 280, is used, which is topped up by fresh hydrogen gas from container 290 according to need.
During an optional initial phase of the initial heating step, which initial phase is one ofhydrogen gas introduction, performed without any heat provision up to a furnace space120 pressure of about 1 bar, valves 2, 4-9, 11 and 13-14 are closed, while valves 10 and 12are open. Depending on if fresh or reused hydrogen gas is to be used, valve V1 and/or V3is open.
Application text 2020~03~30 l90028SE2 lO As the pressure inside the furnace space 120 reaches, or comes close to, atmosphericpressure (about 1 bar), the heating element 121 is switched on. Preferably, it is theheating element 121 which provides the said heat to the furnace space 120, by heatingthe supplied hydrogen gas, which in turn heats the material in the container 140. Prefera-bly, the heating element 121 is arranged at a location past which the hydrogen gas beingprovided to the furnace space 120 flows, so that the heating element 121 will be substan-tially submerged in (completely or substantially completely surrounded by) newly provid-ed hydrogen gas during the reducing process. ln other words, the heat may advantageous-ly be provided directly to the hydrogen gas which is concurrently provided to the furnacespace 120. ln Figure 1a and 1b, the preferred case in which the heating element 121 is arranged in a top part ofthe furnace space 120 is shown.
However, the present inventor foresee that the heat may be provided in other ways to thefurnace space 120, such as directly to the gas mixture inside the furnace space 120 at alocation distant from where the provided hydrogen gas enters the furnace space 120. lnother examples, the heat may be provided to the provided hydrogen gas as a locationexternally to the furnace space 120, before the thus heated hydrogen gas is allowed to enter the furnace space 120.
During the rest of the said initial heating step, valves 5 and 7-14 are closed, while valves 1-4 and 6 are controlled by the control device, together with the compressor 270, to achieve a controlled provision of reused and/or fresh hydrogen gas as described in the following.
Hence, during this initial heating step, the control device 201 is arranged to control theheat and hydrogen provision means 121, 280, 290 to provide heat and hydrogen gas tothe furnace space 120 in a way so that heated hydrogen gas heats the charged metalmaterial to a temperature above the boiling temperature of water contained in the metal material. As a result, said contained water evaporates.
Application text 2020~03~30 l90028SE2 ll Throughout the initial heating step and the main heating step (see below), hydrogen gas issupplied slowly under the control of the control device 201. As a result, there will be acontinuously present, relatively slow but steady, flow of hydrogen gas, vertically down-wards, through the charged material. ln general, the control device is arranged to contin-uously add hydrogen gas so as to maintain a desired increasing (such as monotonicallyincreasing) pressure curve inside the furnace space 120, and in particular to counteractthe decreased pressure at the lower parts of the furnace space 120 (and in the lower partsof the heat exchanger 160) resulting from the constant condensation of water vapour inthe heat exchanger 160 (see below). The total energy consumption depends on theefficiency of the heat exchanger 160, and in particular its ability to transfer thermal energyto the incoming hydrogen gas from both the hot gas flowing through the heat exchanger160 and the condensation heat of the condensing water vapour. ln the exemplifying caseof FezOg, the theoretical energy needed to heat the oxide, thermally compensate for theendothermic reaction and reduce the oxide is about 250 kWh per 1000 kg of FezOg. For Fe3O4, the corresponding number is about 260 kWh per 1000 kg of Fe3O4.
An important aspect of the present invention is that there is no recirculation of hydrogengas during the reduction process. This has been discussed on a general level above, but inthe example shown in Figure 1a this means that the hydrogen gas is supplied, such as viacompressor 270, through entry conduit 171 into the top part of the furnace space 121,where it is heated by the heating element 121 and then slowly passes downwards, pastthe metal material to be reduced in the container 140, further down through the heatexchanger 130 and into the trough 161. However, there are no available exit holes fromthe furnace space 120, and in particular not from the trough 161. The conduit 173 isclosed, for instance by the valves V10, V12, V13, V14 being closed. Hence, the suppliedhydrogen gas will be partly consumed in the reduction process, and partly result in anincreased gas pressure in the furnace space 120. This process then goes on until a full or desired reduction has occurred ofthe metal material, as will be detailed below.
Hence, the heated hydrogen gas present in the furnace space 120 above the charged material in the container 140 will, via the slow supply of hydrogen gas forming a slowly Application text 2020~03~30 l90028SE2 12 moving downwards gas stream, be brought down to the charged material. There, it will form a gas mixture with water vapour from the charged material (see below).
The resulting hot gas mixture will form a gas stream down into and through the heatexchanger 160. ln the heat exchanger 160, there will then be a heat exchange of heatfrom the hot gas arriving from the furnace space 120 to the cold newly provided hydrogengas arriving from conduit 171, whereby the latter will be preheated by the former. lnother words, hydrogen gas to be provided in the initial and main heating steps is preheat- ed in the heat exchanger 160.
Due to the cooling of the hot gas flow, water vapour contained in the cooled gas willcondense. This condensation results in liquid water, which is collected in the trough 161,but also in condensation heat. lt is preferred that the heat exchanger 160 is furtherarranged to transfer such condensation thermal energy from the condensed water to the cold hydrogen gas to be provided into the furnace space 120.
The condensation of the contained water vapour will also decrease the pressure of the hotgas flowing downwards from the furnace space 120, providing space for more hot gas to pass downwards through the heat exchanger 160.
Due to the slow supply of additional heated hydrogen gas, and to the relatively highthermal conductivity of hydrogen gas, the charged material will relatively quickly, such aswithin 10 minutes or less, reach the boiling point of liquid water contained in the chargedmaterial, which should by then be slightly above 100°C. As a result, this contained liquid water will evaporate, forming water vapour mixing with the hot hydrogen gas.
The condensation of the water vapour in the heat exchanger 160 will decrease the partialgas pressure for the water vapour at the lower end of the structure, making the watervapour generated in the charged material on average flow downwards. Adding to thiseffect, water vapour also a substantially lower density than the hydrogen gas with which itmixes.
Application text 2020~03~30 l90028SE2 13 This way, the water contents of the charged material in the container 140 will graduallyevaporate, flow downwards through the heat exchanger 160, cool down and condense therein and to up in liquid state in the trough 161. lt is preferred that the cold hydrogen gas supplied to the heat exchanger 160 is room tempered or has a temperature which is slightly less than room temperature. lt is realized that this initial heating step, in which the charged material is hence driedfrom any contained liquid water, is a preferred step in the present method. ln particular,this makes it easy to produce and provide the charged material as a granular material,such as in the form of rolled balls of material, without having to introduce an expensive and complicating drying step prior to charging of the material into the furnace space 120.
However, it is realized that it would be possible to charge already dry or dried materialinto the furnace space 120. ln this case, the initial heating step as described herein wouldnot be performed, but the method would skip immediately to the main heating step (below). ln one embodiment of the present invention, the provision of hydrogen gas to the furnacespace 120 during said initial heating step is controlled to be so slow so that a pressureequilibrium is substantially maintained throughout the performance of the initial heatingstep, preferably so that a substantially equal pressure prevails throughout the furnacespace 120 and the not liquid-filled parts of the trough 161 at all times. ln particular, thesupply of hydrogen gas may be controlled so that the said equilibrium gas pressure doesnot increase, or only increases insignificantly, during the initial heating step. ln this case,the hydrogen gas supply is then controlled to increase the furnace space 120 pressureover time only after all or substantially all liquid water has evaporated from the chargedmaterial in the container 140. The point in time when this has occurred may, for instance,be determined as a change upwards in slope of a temperature-to-time curve as measuredby temperature sensor 123 and/or 124, where the change of slope marks a point at which Application text 2020~03~30 l90028SE2 14 substantially all liquid water has evaporated but the reduction has not yet started. Alter-natively, hydrogen gas supply may be controlled so as to increase the pressure once ameasured temperature in the furnace space 120, as measured by temperature sensor 123and/or 124, has exceeded a predetermined limit, which limit may be between 100°C and 150°C, such as between 120°C and 130°C. ln a subsequent main heating step, heat and hydrogen gas is further provided to thefurnace space 120, in a manner corresponding to the supply during the initial heating stepdescribed above, so that heated hydrogen gas heats the charged metal material to atemperature high enough in order for metal oxides present in the metal material to be reduced, in turn causing water vapour to be formed.
During this main heating step, additional hydrogen gas is hence supplied and heated,under a gradual pressure increase inside the furnace space 120, so that the charged metalmaterial in turn is heated up to a temperature at which a reduction chemical reaction is initiated and maintained. ln the example illustrated in Figures la and lb, the topmost charged material will hencebe heated first. ln the case of iron oxide material, the hydrogen gas will start reducing thecharged material to form metallic iron at about 350-400°C, forming pyrophytic iron and water vapour according to the following formulae: FG2Û3 -l- 31-12 =FG304 + 4H2 2FG + 3H2Û2FG -I- 4H2Û This reaction is endothermal, and is driven by the thermal energy supplied via the hot hydrogen gas flowing down from above in the furnace space 120.
Hence, during both the initial heating step and the main heating step, water vapour isproduced in the charged material. This formed water vapour is continuously condensedand collected in a condenser arranged below the charged metal material. ln the example shown in Figure la, the condenser is in the form of the heat exchanger 160.
Application text 2020~O3~30 l90028SE2 According to the invention, the main heating step, including said condensing, is performeduntil an overpressure has been reached in the furnace space 120 in relation to atmospher-ic pressure. The pressure may, for instance, be measured by pressure sensor 123 and/or124. As mentioned above, according to the invention no hydrogen gas is evacuated fromthe furnace space 120 until said overpressure has been reached, and preferably no hydro-gen gas is evacuated from the furnace space 120 until the main heating step has been completely finalized.
More preferably, the supply of hydrogen gas in the main heating step, and the condensingof water vapour, is performed until a predetermined overpressure has been reached inthe furnace space 120, which predetermined overpressure is at least 4 bars, more prefer- ably at least 8 bars, or even about 10 bars in absolute terms.
Alternatively, the supply of hydrogen gas in the main heating step, and the condensing ofwater vapour, may be performed until a steady state has been reached, in terms of it nolonger being necessary to provide more hydrogen gas in order to maintain a reachedsteady state gas pressure inside the furnace space 120. This pressure may be measured inthe corresponding way as described above. Preferably, the steady state gas pressure maybe at least 4 bars, more preferably at least 8 bars, or even about 10 bars. This way, a simple way of knowing when the reduction process has been completed is achieved.
Alternatively, the supply of hydrogen gas and heat in the main heating step, and thecondensing of water vapour, may be performed until the charged metal material to bereduced has reached a predetermined temperature, which may be at least 600°C, such asbetween 640-680°C, preferably about 660°C. The temperature of the charged materialmay be measured directly, for instance by measuring heat radiation from the charged material using as suitable sensor, or indirectly by temperature sensor 123. ln some embodiments, the main heating step, including said condensation of the formed water vapour, is performed during a continuous time period of at least 0.25 hours, such as Application text 2020~03~30 l90028SE2 16 at least 0.5 hours, such as at least 1 hour. During this whole time, both the pressure and temperature of the furnace space 120 may increase monotonically. ln some embodiments, the main heating step may furthermore be performed iteratively,in each iteration the control device 201 allowing a steady state pressure to be reachedinside the furnace space 120 before supplying an additional amount of hydrogen gas intothe furnace space. The heat provision may also be iterative (pulsed), or be in a switched on state during the entire main heating step. lt is noted that, during the performing of both the initial heating step and the main heat-ing steps, and in particular at least during substantially the entire length of these steps,there is a net flow downwards of water vapour through the charged metal material in the container 140.
During the initial and main heating steps, the compressor 270 is controlled, by the controldevice 201, to, at all times, maintain or increase the pressure by supplying additionalhydrogen gas. This hydrogen gas is used to compensate for hydrogen consumed in the reduction process, and also to gradually increase the pressure to a desired final pressure.
The formation of water vapour in the charged material increases the gas pressure locally,in effect creating a pressure variation between the furnace space 120 and the trough 161.As a result, formed water vapour will sink down through the charged material and con-dense in the heat exchanger 160, in turn lowering the pressure on the distant (in relationto the furnace space 120) side of the heat exchanger 160. These processes thus create adownwards net movement of gas through the charge, where newly added hydrogen gas compensates for the pressure loss in the furnace space 120.
The thermal content in the gas flowing out from the furnace space 120, and in particularthe condensing heat of the water vapour, is transferred to the incoming hydrogen gas in the heat exchanger 160.
Application text 2020~03~30 l90028SE2 17 Hence, this process is maintained as long as there is metal material to reduce and watervapour hence is produced, resulting in said downwards gas movement. Once the produc-tion of water vapour stops (due to substantially all metal material having been reduced),the pressure equalizes throughout the interior of the furnace 100, and the measuredtemperature will be similar throughout the furnace space 120. For instance, a measuredpressure difference between a point in the gas-filled part of the trough 161 and a pointabove the charged material will be less than a predetermined amount, which may be atthe most 0.1 bars. Additionally or alternatively, a measured temperature differencebetween a point above the charged material and a point below the charged material buton the furnace space 120 side of the heat exchanger will be less than a predeterminedamount, which may be at the most 20°C. Hence, when such pressure and/or temperaturehomogeneity is reached and measured, the main heating step may end by the hydrogen gas supply being shut off and the heating element 121 being switched off.
Hence, the main heating step may be performed until a predetermined minimum temper-ature and/or pressure has been reached, and/or until a predetermined maximum temper-ature difference and/or maximum pressure difference has been reached in the heatedvolume in the furnace 100. Which criterion(s) is/are used depends on the prerequisites,such as the design of the furnace 100 and the type of metal material to be reduced. lt isalso possible to use other criteria, such as a predetermined main heating time or thefinalization of a predetermined heating/hydrogen supply program, which in turn may be determined empirically. ln a subsequent cooling step, the hydrogen atmosphere in the furnace space 120 is thencooled to a temperature of at the most 100°C, preferably about 50°C, and is thereafter evacuated from the furnace space 120 and collected. ln the case of a single furnace 100/220, which is not connected to one or several furnaces,the charged material may be cooled using the fan 250, which is arranged downstream ofthe gas-water type cooler 240, in turn being arranged to cool the hydrogen gas (circulatedin a closed loop by the fan 250 in a loop past the valve V12, the heat exchanger 240, the Application text 2020~03~30 l90028SE2 18 fan 250 and the valve V10, exiting the furnace space 120 via exit conduit 173 and againentering the furnace space 120 via entry conduit 171). This cooling circulation is shown by the arrows in Figure 1b.
The heat exchanger 240 hence transfers the thermal energy from the circulated hydrogengas to water (or a different liquid), from where the thermal energy can be put to use in asuitable manner, for instance in a district heating system. The closed loop is achieved by closing all valves V1-V14 except valves V10 and V12.
Since the hydrogen gas in this case is circulated past the charged material in the container140, it absorbs thermal energy from the charged material, providing efficient cooling of the charged material while the hydrogen gas is circulated in a closed loop. ln a different example, the thermal energy available from the cooling of the furnace100/220 is used to preheat a different furnace 210. This is then achieved by the controldevice 201, as compared to the above described cooling closed loop, closing the valve V12and instead opening valves V13, V14. This way, the hot hydrogen gas arriving from thefurnace 220 is taken to the gas-gas type heat exchanger 230, which is preferably a coun-ter-flow heat exchanger, in which hydrogen gas being supplied in an initial or main heatingstep performed in relation to the other furnace 210 is preheated in the heat exchanger230. Thereafter, the somewhat cooled hydrogen gas from furnace 220 may be circulatedpast the heat exchanger 240 for further cooling before being reintroduced into the fur-nace 220. Again, the hydrogen gas from furnace 220 is circulated in a closed loop using the fan 250.
Hence, the cooling of the hydrogen gas in the cooling step may take place via heat ex-change with hydrogen gas to be supplied to a different furnace 210 space 120 for per-forming the initial and main heating steps and the condensation, as described above, in relation to said different furnace 210 space 120.
Application text 2020~03~30 l90028SE2 19 Once the hydrogen gas is insufficiently hot to heat the hydrogen gas supplied to furnace210, the control device 201 again closes valves V13, V14 and reopens valve V12, so that the hydrogen gas from furnace 220 is taken directly to heat exchanger 240. lrrespectively of how its thermal energy is taken care of, the hydrogen gas from furnace220 is cooled until it (or, more importantly, the charged material) reaches a temperatureof below 100°C, in order to avoid reoxidation of the charged material when later beingexposed to air. The temperature of the charged material can be measured directly, in asuitable manner such as the one described above, or indirectly, by measuring in a suitable manner the temperature ofthe hydrogen gas leaving via exit conduit 173.
The cooling of the hydrogen gas may take place while maintaining the overpressure of thehydrogen gas, or the pressure of the hydrogen gas may be lowered as a result of the hothydrogen gas being allowed to occupy a larger volume (of the closed loop conduits and heat exchangers) once valves V10 and V12 are opened. ln a subsequent step, the hydrogen gas is evacuated from the furnace 220 space 120, andcollected in container 280. This evacuation may be performed by the vacuum pump 260,possibly in combination with the compressor 270, whereby the control device opensvalves V3, V5, V6, V8, V10 and V12, and closes the other valves, and operates the vacuumpump 260 and compressor 270 to displace the cooled hydrogen gas to the container 280for used hydrogen gas. The evacuation is preferably performed until a pressure of at the most 0.5 bars, or even at the most 0.3 bars, is detected inside the furnace space 120.
Since the furnace space 120 is closed, only the hydrogen gas consumed in the chemicalreduction reaction has been removed from the system, and the remaining hydrogen gas isthe one which was necessary to maintain the hydrogen gas/ water vapour balance in thefurnace space 120 during the main heating step. This evacuated hydrogen gas is fully useful for a subsequent batch operation of a new charge of metal material to be reduced.
Application text 2020~03~30 l90028SE2 ln a subsequent step, the furnace space 120 is opened, such as by releasing the fasteningmeans 111 and opening the upper part 110. The container 140 is removed and is replaced with a container with a new batch of charged metal material to be reduced. ln a subsequent step, the removed, reduced material may then be arranged under an inertatmosphere, such as a nitrogen atmosphere, in order to avoid reoxidation during transport and storage.
For instance, the reduced metal material may be arranged in a flexible or rigid transportcontainer which is filled with inert gas. Several such flexible or rigid containers may bearranged in a transport container, which may then be filled with inert gas in the spacesurrounding the flexible or rigid containers. Thereafter, the reduced metal material can be transported safely without running the risk of reoxidation.
The following table shows the approximate equilibrium between hydrogen gas H2 and water vapour H20 for different temperatures inside the furnace space 120: temperature (°c)= 400 450 500 550 600H2 (ve|-%)= 95 87 82 78 76H20 (ve|-%): 5 18 18 22 24 At atmospheric pressure, about 417 m3 hydrogen gas H2 is required to reduce 1000 kg of FezOg, and about 383 m3 hydrogen gas H2 is required to reduce 1000 kg of Fe3O4.
The following table shows the amount of hydrogen gas required to reduce 1000 kg ofFezOg and Fe3O4, respectively, at atmospheric pressure and in an open system (according to the prior art), but at different temperatures: temperature (°c)= 400 450 500 550 600Nm* H2 / terme Fezog; 8340 8208 2317 1895 1788Nm* H2 / terme Fe3o4= 7660 2946 2128 1741 1596 Application text 2020~03~30 l90028SE2 21 The following table shows the amount of hydrogen gas required to reduce 1000 kg of FezOg and Fe3O4, respectively, at different pressures and for different temperatures: temperature (°c)= 400 450 500 550 600 Nma H2 / tonne FezOg: 1 bar 8340 3208 2317 1895 17382 barS 4170 1604 1158 948 8693 barS 2780 1069 772 632 5794 barS 2085 802 579 474 4345 barS 1668 642 463 379 3486 barS 1390 535 386 316 290Nma H2 / tonne Fe3O4: 1 bar 7660 2946 2128 1741 15962 barS 3830 1473 1064 870 7983 barS 2553 982 709 580 5324 barS 1915 737 532 435 3995 barS 1532 589 426 348 3196 barS 1277 491 355 290 266 As described above, the main heating step according to the present invention is preferablyperformed up to a high pressure and a high temperature. During the majority of the mainheating step, it has been found advantageous to use a combination of a heated hydrogen gas temperature of at least 500°C and a furnace space 120 pressure of at least 5 bars.
Above, preferred embodiments have been described. However, it is apparent to theskilled person that many modifications can be made to the disclosed embodiments without departing from the basic idea of the invention.
For instance, the geometry of the furnace 100 may differ, depending on the detailed prerequisites.
Application text 2020~03~30 190028SE2 22 The heat exchanger 160 is described as a tube heat exchanger. Even if this has been foundto be particularly advantageous, it is realized that other types of gas-gas heat exchang- ers/condensers are possible. Heat exchanger 240 may be of any suitable configuration.
The surplus heat from the cooled hydrogen gas may also be used in other processes requiring thermal energy.
The metal material to be reduced has been described as iron oxides. However, the presentmethod and system can also be used to reduce metal material such as the above men-tioned metal oxides, such as of Zn and Pb, that evaporate at temperatures below about 600°C.
The present direct reduction principles can also be used with metal materials havinghigher reduction temperatures than iron ore, with suitable adjustments to the construc- tion of the furnace 100, such as with respect to used construction materials.
Hence, the invention is not limited to the described embodiments, but can be varied within the scope of the enclosed claims.
Application text 2020~03~30 l90028SE2
Claims (16)
1. Method for producing direct reduced metal material, comprising the steps: a) charging metal material to be reduced into a furnace space (120); b) evacuating an existing atmosphere from the furnace space (120) so as to achieve anunderpressure inside the furnace space (120); c) providing, in a main heating step, heat and hydrogen gas to the furnace space (120),so that heated hydrogen gas heats the charged metal material to a temperature highenough so that metal oxides present in the metal material are reduced, in turn caus-ing water vapour to be formed; and d) condensing and collecting the water vapour formed in step c in a condenser (160)below the charged metal material; c h a r a c t e r i s e d i n that said hydrogen gas in step c is provided without recirculation of the hydrogen gas, and in that the method further comprises the subse- quently performed step of removing the reduced metal material from the furnace space (120), and storing and/or transporting the reduced metal material under an inert atmos- phere.
2. Method according to claim 1, c h a r a c t e r i s e d i n that steps c and d are performed at least until a hydrogen atmosphere overpressure has been reached inside the furnace space (120), and in that no hydrogen gas is evacuated from the furnace space (120) until said overpressure has been reached.
3. Method according to claim 1 or 2, c h a r a c t e r i s e d i n that the material charged in step a is at the most 50 tonnes, preferably at the most 25 tonnes, preferably between 5 and 10 tonnes of such material.
4. Method according to any one ofthe preceding claims, c h a r a c t e r i s e di n that the method steps a-d are performed in a system (200) provided directly at a mining site, whereby direct reduced metal material is produced at said mining site using Application text 2020~03~30 l90028SE2 24 said steps, thereafter packaged under a protecting atmosphere and thereafter transport- ed to a different site for further processing.
5. Method according to any one ofthe preceding claims, c h a r a c t e r i s e di n that the method further comprises cooling the charged material, after step d, bycirculating said hydrogen gas past the charged material, whereby the hydrogen gas is heated by the charged material and cooled by heat exchange using a heat exchanger.
6. Method according to claim 5,c h a r a c t e r i s e d i n that the cooling ofthe charged material is performed until the charged material reaches a temperature of below 100°C.
7. Method according to any one ofthe preceding claims,c h a r a c t e r i s e d i n that said inert atmosphere is a nitrogen atmosphere.
8. Method according to any one ofthe preceding claims, c h a r a c t e r i s e d i n that the method further comprises the step of providing the reduced metal materialinto a first transport container which is filled with inert gas, wherein several such firsttransport containers are provided into a second transport container, in turn being filled with inert gas in the space surrounding said first transport containers.
9. Method according to any one ofthe preceding claims, c h a r a c t e r i s e d i n that step c further comprises, in an initial heating step, providing heat and hydrogengas to the furnace space (120), so that heated hydrogen gas heats the charged metalmaterial to a temperature above the boiling temperature of water contained in the metal material, causing said contained water to evaporate.
10. Method according to any one of the preceding claims, c h a r a c t e r i s e di n that hydrogen gas to be provided in step c is preheated in a heat exchanger (160),which heat exchanger (160) is arranged to transfer thermal energy from the evaporated water to the hydrogen gas to be provided in step c. Application text 2020~O3~30 l90028SE2
11. Method according to any one of the preceding claims, c h a r a c t e r i s e di n that the main heating step of step c and the condensing in step d are performed until a predetermined pressure has been reached.
12. Method according to any one of claims 1-10, c h a r a c t e r i s e d i n that the main heating step in step c and the condensing in step d are performed until asteady state is reached, in terms of it no longer being necessary to provide more hydrogengas in order to maintain a reached steady state gas pressure inside the furnace space (120).
13. Method according to any one ofthe preceding claims, c h a r a c t e r i s e di n that the main heating step in step c and the condensing in step d are performed until the charged metal material to be reduced has reached a predetermined temperature.
14. Method according to any one ofthe preceding claims, c h a r a c t e r i s e di n that, during the performing of step c, there is a net flow downwards of water vapour through the charged metal material.
15. Method according to any one ofthe preceding claims, c h a r a c t e r i s e d i n that the method further comprises the steps of e) after steps c and d are finished, cooling the hydrogen atmosphere to at the most100°C; and f) after step e is finished, evacuating the hydrogen atmosphere from the furnace space (120) and collecting the hydrogen gas of the evacuated hydrogen atmosphere.
16. Method according to any one ofthe preceding claims,c h a r a c t e r i s e d i n that steps c and d are performed during at least 0.25 hours. Application text 2020~O3~30 190028SE2
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