SE181156C1 - - Google Patents
Info
- Publication number
- SE181156C1 SE181156C1 SE181156DA SE181156C1 SE 181156 C1 SE181156 C1 SE 181156C1 SE 181156D A SE181156D A SE 181156DA SE 181156 C1 SE181156 C1 SE 181156C1
- Authority
- SE
- Sweden
- Prior art keywords
- composition according
- sulfide
- thioether
- poly
- composition
- Prior art date
Links
- -1 polyethylene Polymers 0.000 claims description 70
- 239000000463 material Substances 0.000 claims description 31
- 239000004698 Polyethylene Substances 0.000 claims description 29
- 229920000573 polyethylene Polymers 0.000 claims description 29
- 229920000642 polymer Polymers 0.000 claims description 27
- 239000000203 mixture Substances 0.000 claims description 24
- 239000006229 carbon black Substances 0.000 claims description 18
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 14
- 239000002245 particle Substances 0.000 claims description 12
- LUFPJJNWMYZRQE-UHFFFAOYSA-N benzylsulfanylmethylbenzene Chemical compound C=1C=CC=CC=1CSCC1=CC=CC=C1 LUFPJJNWMYZRQE-UHFFFAOYSA-N 0.000 claims description 11
- 229910052799 carbon Inorganic materials 0.000 claims description 11
- 125000003118 aryl group Chemical group 0.000 claims description 10
- LKMCJXXOBRCATQ-UHFFFAOYSA-N benzylsulfanylbenzene Chemical compound C=1C=CC=CC=1CSC1=CC=CC=C1 LKMCJXXOBRCATQ-UHFFFAOYSA-N 0.000 claims description 10
- 125000004432 carbon atom Chemical group C* 0.000 claims description 10
- 125000001424 substituent group Chemical group 0.000 claims description 9
- 229910052717 sulfur Inorganic materials 0.000 claims description 9
- 125000004434 sulfur atom Chemical group 0.000 claims description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 7
- 150000003568 thioethers Chemical class 0.000 claims description 7
- 239000004743 Polypropylene Substances 0.000 claims description 4
- 229920001155 polypropylene Polymers 0.000 claims description 4
- 229920001577 copolymer Polymers 0.000 claims description 3
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 claims description 3
- 125000000467 secondary amino group Chemical group [H]N([*:1])[*:2] 0.000 claims description 3
- 229920001748 polybutylene Polymers 0.000 claims description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 2
- CRSBERNSMYQZNG-UHFFFAOYSA-N 1-dodecene Chemical compound CCCCCCCCCCC=C CRSBERNSMYQZNG-UHFFFAOYSA-N 0.000 claims 1
- YHQXBTXEYZIYOV-UHFFFAOYSA-N 3-methylbut-1-ene Chemical compound CC(C)C=C YHQXBTXEYZIYOV-UHFFFAOYSA-N 0.000 claims 1
- LDTAOIUHUHHCMU-UHFFFAOYSA-N 3-methylpent-1-ene Chemical compound CCC(C)C=C LDTAOIUHUHHCMU-UHFFFAOYSA-N 0.000 claims 1
- 238000003889 chemical engineering Methods 0.000 claims 1
- 229920001519 homopolymer Polymers 0.000 claims 1
- TUJKJAMUKRIRHC-UHFFFAOYSA-N hydroxyl Chemical compound [OH] TUJKJAMUKRIRHC-UHFFFAOYSA-N 0.000 claims 1
- 230000000087 stabilizing effect Effects 0.000 claims 1
- 239000003963 antioxidant agent Substances 0.000 description 18
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 13
- 229910052760 oxygen Inorganic materials 0.000 description 13
- 239000001301 oxygen Substances 0.000 description 13
- 230000003078 antioxidant effect Effects 0.000 description 11
- 238000006243 chemical reaction Methods 0.000 description 11
- 230000003647 oxidation Effects 0.000 description 11
- 238000007254 oxidation reaction Methods 0.000 description 11
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 10
- 239000000523 sample Substances 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 239000000047 product Substances 0.000 description 7
- 230000000694 effects Effects 0.000 description 6
- 238000002474 experimental method Methods 0.000 description 6
- 239000004215 Carbon black (E152) Substances 0.000 description 4
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- 229930195733 hydrocarbon Natural products 0.000 description 4
- 150000002430 hydrocarbons Chemical class 0.000 description 4
- 230000007246 mechanism Effects 0.000 description 4
- 230000001590 oxidative effect Effects 0.000 description 4
- 230000000979 retarding effect Effects 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- KCXMKQUNVWSEMD-UHFFFAOYSA-N benzyl chloride Chemical compound ClCC1=CC=CC=C1 KCXMKQUNVWSEMD-UHFFFAOYSA-N 0.000 description 3
- 229940073608 benzyl chloride Drugs 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- 238000010998 test method Methods 0.000 description 3
- RMVRSNDYEFQCLF-UHFFFAOYSA-N thiophenol Chemical compound SC1=CC=CC=C1 RMVRSNDYEFQCLF-UHFFFAOYSA-N 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 2
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 2
- 150000001721 carbon Chemical group 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000004020 conductor Substances 0.000 description 2
- 239000013068 control sample Substances 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 2
- 229910052753 mercury Inorganic materials 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- 238000001953 recrystallisation Methods 0.000 description 2
- 238000010992 reflux Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- PHCKFVVLVZFFLU-VQHVLOKHSA-N (e)-dodec-4-ene Chemical compound CCCCCCC\C=C\CCC PHCKFVVLVZFFLU-VQHVLOKHSA-N 0.000 description 1
- DPPMDDDXHSQTCP-UHFFFAOYSA-N 1-benzyl-3-(3-benzyl-2-methylphenyl)sulfanyl-2-methylbenzene Chemical compound CC1=C(C=CC=C1CC1=CC=CC=C1)SC1=C(C(=CC=C1)CC1=CC=CC=C1)C DPPMDDDXHSQTCP-UHFFFAOYSA-N 0.000 description 1
- YKBJBHGUHLPSKP-UHFFFAOYSA-N 1-benzylsulfanyl-2-methylbenzene Chemical compound CC1=CC=CC=C1SCC1=CC=CC=C1 YKBJBHGUHLPSKP-UHFFFAOYSA-N 0.000 description 1
- MBUXXBSMIZCCQC-UHFFFAOYSA-N 1-benzylsulfanyl-3-ethylbenzene Chemical compound C(C1=CC=CC=C1)SC=1C=C(C=CC=1)CC MBUXXBSMIZCCQC-UHFFFAOYSA-N 0.000 description 1
- NCFBFSBVVDRQBK-UHFFFAOYSA-N 1-benzylsulfanyl-3-methylbenzene Chemical compound CC1=CC=CC(SCC=2C=CC=CC=2)=C1 NCFBFSBVVDRQBK-UHFFFAOYSA-N 0.000 description 1
- VCMADTQZCBWKAB-UHFFFAOYSA-N 1-benzylsulfanyl-4-methylbenzene Chemical compound C1=CC(C)=CC=C1SCC1=CC=CC=C1 VCMADTQZCBWKAB-UHFFFAOYSA-N 0.000 description 1
- PPKVYPHFLZUHHD-UHFFFAOYSA-N 1-benzylsulfanylanthracene Chemical compound C=1C=CC2=CC3=CC=CC=C3C=C2C=1SCC1=CC=CC=C1 PPKVYPHFLZUHHD-UHFFFAOYSA-N 0.000 description 1
- DCDUWZAHMMXKRE-UHFFFAOYSA-N 1-benzylsulfanylnaphthalene Chemical compound C=1C=CC2=CC=CC=C2C=1SCC1=CC=CC=C1 DCDUWZAHMMXKRE-UHFFFAOYSA-N 0.000 description 1
- WPWHSFAFEBZWBB-UHFFFAOYSA-N 1-butyl radical Chemical group [CH2]CCC WPWHSFAFEBZWBB-UHFFFAOYSA-N 0.000 description 1
- JFUIKBMVHBMBCL-UHFFFAOYSA-N 1-ethyl-4-(4-ethylphenyl)sulfanylbenzene Chemical compound C1=CC(CC)=CC=C1SC1=CC=C(CC)C=C1 JFUIKBMVHBMBCL-UHFFFAOYSA-N 0.000 description 1
- KSNHTGCKCRCBFB-UHFFFAOYSA-N 2-[[(2-hydroxyphenyl)-phenylmethyl]sulfanyl-phenylmethyl]phenol Chemical compound OC1=CC=CC=C1C(C=1C=CC=CC=1)SC(C=1C(=CC=CC=1)O)C1=CC=CC=C1 KSNHTGCKCRCBFB-UHFFFAOYSA-N 0.000 description 1
- SPVOWXUGOYQTBZ-UHFFFAOYSA-N 2-benzyl-1-(2-benzyl-4-methylphenyl)sulfanyl-4-methylbenzene Chemical compound CC1=CC(=C(C=C1)SC2=C(C=C(C=C2)C)CC3=CC=CC=C3)CC4=CC=CC=C4 SPVOWXUGOYQTBZ-UHFFFAOYSA-N 0.000 description 1
- QRQPUJRXMQTTLU-UHFFFAOYSA-N 2-benzylsulfanylnaphthalene Chemical compound C=1C=C2C=CC=CC2=CC=1SCC1=CC=CC=C1 QRQPUJRXMQTTLU-UHFFFAOYSA-N 0.000 description 1
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 1
- 229920001342 Bakelite® Polymers 0.000 description 1
- YDDQZBAPBNFZMA-UHFFFAOYSA-N C(C(C)C)C(C1=CC=CC=C1)(C1=CC=CC=C1)SC(C1=CC=CC=C1)(CC(C)C)C1=CC=CC=C1 Chemical compound C(C(C)C)C(C1=CC=CC=C1)(C1=CC=CC=C1)SC(C1=CC=CC=C1)(CC(C)C)C1=CC=CC=C1 YDDQZBAPBNFZMA-UHFFFAOYSA-N 0.000 description 1
- JGPMMPBANJYIHK-UHFFFAOYSA-N C(C(C)C)C=1C(=C(C=CC=1)SC1=C(C(=CC=C1)CC(C)C)CC1=CC=CC=C1)CC1=CC=CC=C1 Chemical compound C(C(C)C)C=1C(=C(C=CC=1)SC1=C(C(=CC=C1)CC(C)C)CC1=CC=CC=C1)CC1=CC=CC=C1 JGPMMPBANJYIHK-UHFFFAOYSA-N 0.000 description 1
- NDDQNXXVJLATKQ-UHFFFAOYSA-N C(C)(C)C(C1=CC=CC=C1)(C1=CC=CC=C1)SC(C1=CC=CC=C1)(C(C)C)C1=CC=CC=C1 Chemical compound C(C)(C)C(C1=CC=CC=C1)(C1=CC=CC=C1)SC(C1=CC=CC=C1)(C(C)C)C1=CC=CC=C1 NDDQNXXVJLATKQ-UHFFFAOYSA-N 0.000 description 1
- YUQDDUKBUMNCEN-UHFFFAOYSA-N C(C)(C)C=1C(=C(C=CC=1)SC1=C(C(=CC=C1)C(C)C)CC1=CC=CC=C1)CC1=CC=CC=C1 Chemical compound C(C)(C)C=1C(=C(C=CC=1)SC1=C(C(=CC=C1)C(C)C)CC1=CC=CC=C1)CC1=CC=CC=C1 YUQDDUKBUMNCEN-UHFFFAOYSA-N 0.000 description 1
- NQXICYFDLHBKQL-UHFFFAOYSA-N C(CC)C(C1=CC=CC=C1)(C1=CC=CC=C1)SC(C1=CC=CC=C1)(CCC)C1=CC=CC=C1 Chemical compound C(CC)C(C1=CC=CC=C1)(C1=CC=CC=C1)SC(C1=CC=CC=C1)(CCC)C1=CC=CC=C1 NQXICYFDLHBKQL-UHFFFAOYSA-N 0.000 description 1
- SIGXNKXBZLLCMB-UHFFFAOYSA-N C(CC)C=1C(=C(C=CC=1)SC1=C(C(=CC=C1)CCC)CC1=CC=CC=C1)CC1=CC=CC=C1 Chemical compound C(CC)C=1C(=C(C=CC=1)SC1=C(C(=CC=C1)CCC)CC1=CC=CC=C1)CC1=CC=CC=C1 SIGXNKXBZLLCMB-UHFFFAOYSA-N 0.000 description 1
- LRBORPZAXYCBMM-UHFFFAOYSA-N C(CCC)C(C1=CC=CC=C1)(C1=CC=CC=C1)SC(C1=CC=CC=C1)(CCCC)C1=CC=CC=C1 Chemical compound C(CCC)C(C1=CC=CC=C1)(C1=CC=CC=C1)SC(C1=CC=CC=C1)(CCCC)C1=CC=CC=C1 LRBORPZAXYCBMM-UHFFFAOYSA-N 0.000 description 1
- NOYQZLNZEYXRDJ-UHFFFAOYSA-N CC(C)(C)C(C1=CC=CC=C1)(C1=CC=CC=C1)SC(C(C)(C)C)(C1=CC=CC=C1)C1=CC=CC=C1 Chemical compound CC(C)(C)C(C1=CC=CC=C1)(C1=CC=CC=C1)SC(C(C)(C)C)(C1=CC=CC=C1)C1=CC=CC=C1 NOYQZLNZEYXRDJ-UHFFFAOYSA-N 0.000 description 1
- FRUQMWGLHVECFQ-UHFFFAOYSA-N CC1=C(C(=CC=C1)SC2=CC=CC(=C2CC3=CC=CC=C3)C)CC4=CC=CC=C4 Chemical compound CC1=C(C(=CC=C1)SC2=CC=CC(=C2CC3=CC=CC=C3)C)CC4=CC=CC=C4 FRUQMWGLHVECFQ-UHFFFAOYSA-N 0.000 description 1
- LMSDKHVHXLXABO-UHFFFAOYSA-N CCC(C)C(C1=CC=CC=C1)(C1=CC=CC=C1)SC(C(C)CC)(C1=CC=CC=C1)C1=CC=CC=C1 Chemical compound CCC(C)C(C1=CC=CC=C1)(C1=CC=CC=C1)SC(C(C)CC)(C1=CC=CC=C1)C1=CC=CC=C1 LMSDKHVHXLXABO-UHFFFAOYSA-N 0.000 description 1
- VWPODPFIOJCWMW-UHFFFAOYSA-N CCC1=CC=CC(SC2=C(CC3=CC=CC=C3)C(CC)=CC=C2)=C1CC1=CC=CC=C1 Chemical compound CCC1=CC=CC(SC2=C(CC3=CC=CC=C3)C(CC)=CC=C2)=C1CC1=CC=CC=C1 VWPODPFIOJCWMW-UHFFFAOYSA-N 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 241000218657 Picea Species 0.000 description 1
- 235000014548 Rubus moluccanus Nutrition 0.000 description 1
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- GHHUDOBZZGBMHZ-UHFFFAOYSA-N [2-(1,2-diphenylpropan-2-ylsulfanyl)-1-phenylpropan-2-yl]benzene Chemical compound C1(=CC=CC=C1)CC(C)(C1=CC=CC=C1)SC(CC1=CC=CC=C1)(C)C1=CC=CC=C1 GHHUDOBZZGBMHZ-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- 125000000958 aryl methylene group Chemical group 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 239000004637 bakelite Substances 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- BTNRQGYYIMWJRV-UHFFFAOYSA-N butylsulfanylmethylbenzene Chemical compound CCCCSCC1=CC=CC=C1 BTNRQGYYIMWJRV-UHFFFAOYSA-N 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000002178 crystalline material Substances 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 230000002500 effect on skin Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000003517 fume Substances 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 230000033444 hydroxylation Effects 0.000 description 1
- 238000005805 hydroxylation reaction Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- SNVLJLYUUXKWOJ-UHFFFAOYSA-N methylidenecarbene Chemical group C=[C] SNVLJLYUUXKWOJ-UHFFFAOYSA-N 0.000 description 1
- 125000001624 naphthyl group Chemical group 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000005297 pyrex Substances 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 229910052979 sodium sulfide Inorganic materials 0.000 description 1
- GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SE181156T |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SE181156C1 true SE181156C1 (enrdf_load_stackoverflow) | 1962-01-01 |
Family
ID=41969360
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SE181156D SE181156C1 (enrdf_load_stackoverflow) |
Country Status (1)
| Country | Link |
|---|---|
| SE (1) | SE181156C1 (enrdf_load_stackoverflow) |
-
0
- SE SE181156D patent/SE181156C1/sv unknown
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