SE177969C1 - - Google Patents
Info
- Publication number
- SE177969C1 SE177969C1 SE177969DA SE177969C1 SE 177969 C1 SE177969 C1 SE 177969C1 SE 177969D A SE177969D A SE 177969DA SE 177969 C1 SE177969 C1 SE 177969C1
- Authority
- SE
- Sweden
- Prior art keywords
- bis
- effect
- mixtures
- hydroxymethylene
- heptene
- Prior art date
Links
- 239000000203 mixture Substances 0.000 claims description 18
- YVGGHNCTFXOJCH-UHFFFAOYSA-N DDT Chemical compound C1=CC(Cl)=CC=C1C(C(Cl)(Cl)Cl)C1=CC=C(Cl)C=C1 YVGGHNCTFXOJCH-UHFFFAOYSA-N 0.000 claims description 5
- 239000000417 fungicide Substances 0.000 claims description 2
- 239000000575 pesticide Substances 0.000 claims description 2
- 239000013543 active substance Substances 0.000 description 11
- 239000007921 spray Substances 0.000 description 7
- 230000000694 effects Effects 0.000 description 5
- 241001124076 Aphididae Species 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 3
- 241000238631 Hexapoda Species 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 230000000977 initiatory effect Effects 0.000 description 3
- QPUYECUOLPXSFR-UHFFFAOYSA-N 1-methylnaphthalene Chemical compound C1=CC=C2C(C)=CC=CC2=C1 QPUYECUOLPXSFR-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 241001425390 Aphis fabae Species 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 241000607479 Yersinia pestis Species 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 239000012141 concentrate Substances 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 241001414720 Cicadellidae Species 0.000 description 1
- 241000254173 Coleoptera Species 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 241000118205 Ovicides Species 0.000 description 1
- 241000219873 Vicia Species 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 description 1
- 238000010171 animal model Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 235000005583 doda Nutrition 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- 230000008029 eradication Effects 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 239000004009 herbicide Substances 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- 235000010333 potassium nitrate Nutrition 0.000 description 1
- 239000004323 potassium nitrate Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N29/00—Biocides, pest repellants or attractants, or plant growth regulators containing halogenated hydrocarbons
- A01N29/10—Halogen attached to an aliphatic side chain of an aromatic ring system
- A01N29/12—1,1-Di- or 1,1,1-trihalo-2-aryl-ethane or -ethene or derivatives thereof, e.g. DDT
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Plant Pathology (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Description
Uppfinnare: H Frensch, M Czech och L F Emmel Prioritet begard frdn den 19 :pint 1959 (Forbundsrepubliken Tgskland) Foreliggande uppfinning avser medel fOr bekampning av skadegorare, isynnerhet insekter. Inventors: H Frensch, M Czech and L F Emmel Priority claimed from 19 pint 1959 (Federal Republic of Germany) The present invention relates to pesticides, in particular insects.
Genom den tyska patentskriften 963 282 ar det kant, att 1,2,3,4,7,7-hexaklor-bicyklo-/2,2,1/-hepten-(2)-bis-5,6-(hydroximetylen)-sulfit med for-mein Cl CI lampar sig for bekampning av skadegorare i form av djur och svampar. German Patent Specification 963,282 states that 1,2,3,4,7,7-hexachlorobicyclo [2.2.1] heptene- (2) -bis-5,6- (hydroxymethylene) -sulfite with form-mein Cl CI is used to control pests in the form of animals and fungi.
Det har nu visat sig, att blandningar, bestaende av 1,2,3,4,7,7-hexaklor-bicyklo-/2,2,1J-hepten(2)-bis-5,6-(hydroximetylen)-sulfit och 2,2-bis-(4'- klor-feny1)-1,1,1-trikloretan i forhallandet 1: 3 till 1: 5 utova en potentierad synergistisk verkan. Blandningens verkan Overstiger alltsa den additiva verkan av de enskilda komponenterna. It has now been found that mixtures consisting of 1,2,3,4,7,7-hexachloro-bicyclo- / 2,2,1J-heptene (2) -bis-5,6- (hydroxymethylene) sulfite and 2,2-bis- (4'-chloro-phenyl) -1,1,1-trichloroethane in the ratio 1: 3 to 1: 5 exert a potentiated synergistic effect. Effect of the mixture Exceeds the additive effect of the individual components.
Blandningarna enligt uppfinningen Oro lampliga for bekampning av skadeinsekter, t. ex. skalbaggsarter, bladatande larver av bladsteklar, blasfotingar, framforallt emellertid for utrotning av bladloss. Det ma framhallas, att de namnda blandningarna ej astadkomma flagon skadegorelse bland nyttiga insekter, t. ex. bin. The mixtures according to the invention are suitable for controlling insect pests, e.g. beetle species, leaf-eating larvae of leafhoppers, blasphemous, above all, however, for the eradication of leaf louse. It must be pointed out that the mentioned mixtures do not cause flake damage among beneficial insects, e.g. bin.
Blandningarna enligt uppfinningen kunna med sarskild fOrdel anvandas i slutna rum pa. sadant satt, att man forangar den rena blandningen av de aktiva amnena. The mixtures according to the invention can with special advantage be used in closed rooms pa. in such a way that the pure mixture of the active substances is evaporated.
De kunna likasa anvandas i de mest olikartade doseringsformer, t. ex. sasom emulsionskoncentrat, sprutpulver, granulat, stoft, aerosoler, rokeller dimmedel. They can also be used in the most diverse dosage forms, e.g. such as emulsion concentrate, spray powder, granules, dust, aerosols, rokeller mist.
For framstallning av emulsionskoncentrat loses blandningen av de aktiva amnena i organiska losningsmedel, sasom aceton, toluen, xylen, metylnaftalen och liknande och fOrsattes med den erforderliga mangden av en lamplig emulgator, t. ex. oxetylerad nonylfenol, blandningar av nonjonogena och jonogena emulgatorer, t. ex. polyglykoletrar av alkoholer eller fenoler med kalciumsalter av alkylarylsulfonat. To prepare the emulsion concentrate, the mixture of the active substances in organic solvents, such as acetone, toluene, xylene, methylnaphthalene and the like, is dissolved and provided with the required amount of a suitable emulsifier, e.g. oxetylated nonylphenol, mixtures of nonionic and ionic emulsifiers, e.g. polyglycol ethers of alcohols or phenols with calcium salts of alkylarylsulfonate.
Vid sammansattningen av blandningarna enligt uppfinningen sasom sprutpulver fOrsatter man blandningen av de aktiva amnena med inerta bararmaterial, sasom kolloidalt falld kiselsyra eller i finaste form fordelad kiselsyra, bentonit, krita etc., avensom med de vanliga vdtmedlen. In the composition of the mixtures according to the invention as a spray powder, the mixture of the active substances is provided with inert bar material, such as colloidally precipitated silicic acid or in finest form distributed silica, bentonite, chalk, etc., as well as with the usual wetting agents.
Granulat och stoft framstallas pa sa satt, att man sprutar en losning eller smalta av de aktiva amnena pa en barare, t. ex. talk, eller blandar och darefter sammanmaler de fasta amnena med bararmaterialet. Slutligen kunna blandningarna enligt uppfinningen utformas som rok- eller dimmedel darigenom, att man forsatter det aktiva amnet med forbranningsbara medel, t. ex. tramp:51 och kaliumnitrat. Granules and dust are prepared in such a way that a solution or spray of the active substances is sprayed on a carrier, e.g. talc, or mix and then grind the solid substances with the bar material. Finally, the mixtures according to the invention can be designed as smoke or misting agents by continuing the active substance with combustible means, e.g. tramp: 51 and potassium nitrate.
Blandningarna eller sammansattningarna enligt uppfinningen kunna bibringas Rad verkan och anvandningsmojlighet genom ytterligare tillsattningar av insekticider, ovicider, fungicider, herbicider eller godningsmedel. The mixtures or compositions according to the invention can be imparted. Effect and possibility of use by further additions of insecticides, ovicides, fungicides, herbicides or fertilizers.
Blandningarnas overlagsna verkan framgar av foljande exempel. The overall effect of the mixtures is shown by the following example.
Exempel. Example.
Om av bladloss (Doralis fabae) angripna vaxter (Vicia fabae) besprutas med ett sprutmedel, som innehaller de aktiva amnena 2,2-bis-(4'-klorfeny1)- 1,1,1-trikloretan och 1,2,3,4,7,7-hexaklor-bicyklo/2,2,1/-hepten-(2)-bis-5,6-(hydroximetylen)-sulfit i blandningsforhallandet 4: 1, falla bladlossen mycket snabbt ner fran vaxterna, narmare bestamt otvetydigt snabbare On frail de voider, som endast behandlats med eLL sprutmedel av antingen den ena eller andra blandningskomponenten med samma koncentrationer aktivt amne — raknat pa. cV CI\ 2- - mangden aktivt amne i komhinationssprutmedDenna effekt dr desto mem anmarkningsvard, somena sidan 2,2-bis-(4'-klorfeny1)-1,1,1-tri- kloretan-sprutmedlet endast har en obetydlig verkan pa bladloss och andra sidan 1,2,3,4,7,7- hexaklor-bicyklo-/2,2,1/-hepten-(2)-bis-5,6-(hydroximetylen)-sulfit har en relativt lag begynnelseverkan. If plants infected with aphids (Doralis fabae) (Vicia fabae) are sprayed with a spray containing the active substances 2,2-bis- (4'-chlorophenyl) - 1,1,1-trichloroethane and 1,2,3, 4,7,7-hexachloro-bicyclo / 2,2,1 / -heptene- (2) -bis-5,6- (hydroxymethylene) -sulfite in the mixing ratio 4: 1, the aphids fall very quickly from the plants, more precisely unequivocally faster On frail de voids, which have only been treated with eLL spray of either one or the other mixture component with the same concentrations of active substance - shaved on. cV CI \ 2- - the amount of active substance in combination spray withThis effect has the remarkable value, as since the 2,2-bis- (4'-chlorophenyl) -1,1,1-trichloroethane spray only has an insignificant effect on aphids and on the other hand 1,2,3,4,7,7-hexachloro-bicyclo- / 2,2,1 / -heptene- (2) -bis-5,6- (hydroxymethylene) sulfite has a relatively low initial effect.
I tabellen anges i procent genomsnittsvardena frail tre forsok med vardera 250-400 forsoksdjur. Del visade sig darvid, att den forstarkta Nedfall efter an begynnelseverkan hos kombinationen enligt uppfinningen ej blott och bart dr en additiv verkan, utan att den beror pa en potentiering av hada aktiva amnena. The table shows the percentage of average values from three experiments, each with 250-400 experimental animals. It turned out in this case that the enhanced precipitation after an initial effect of the combination according to the invention not only has an additive effect, but that it is due to a potentiation of the active substances.
Forst& med Doralis fabae (begynnelseverkan). Understand & with Doralis fabae (initial effect).
Vardena aro genomsnittsvarden frail tre forsok. I tabellen ar A = 1,2,3,4,7,7-hexaklor-bicyklo-/2,2,1/-hepten-(2)-bis-5,6-(hydroximetylen)- sulfit och B = 2,2-bis-(4'-klorfeny1)-1,1,1-trikloretan. % aktivt amne timmar i %, ralmat pa dat totala talet befintliga bladlOss AB Totalt 1 2 3 6 7 8 0,020,08 0,1 10,6 59,82,3 94,96,97,98 0,010,01 0,06,6 41,2 66,6 87,0 91,6 94,8 95,6 0,005 0,02 0,05,0 25,2 46,0 73,0 79,0 85,0 88,0 0,02 1,13,3 21,8 59,69,75,3 80, 0,01 1,0 7,2 21,6 47,6 58,6 62,63,2 0,000 12,2 34,6 42,8 51,2 56,6 0,08 1 4,6 6,6 9,11,13,0 14, 0,04 0,8 3,0 5,7,2 10,2 12,14 0,02 0,2,0 3,5,2 6,2 7,0 7,8 obehandlade 0,0,6 1,0 1,6 2 2 2,3 PA de med B behandlade vaxterna fanns 48 tim efter besprutningen annu bladloss kvar: Antal % aktivt amne DOda Levande 0,08 81,6 181,6 0,01 54,6 203 0,02 49 354 Icke behandlade Icke raknade, riklig forekomst The values are the average value from three trials. In the table, A = 1,2,3,4,7,7-hexachloro-bicyclo- / 2,2,1 / -heptene- (2) -bis-5,6- (hydroxymethylene) -sulfite and B = 2 , 2-bis- (4'-chlorophenyl) -1,1,1-trichloroethane. % active substance hours in%, ralmat pa dat total number existing bladlOss AB Total 1 2 3 6 7 8 0.020.08 0.1 10.6 59.82.3 94.96.97.98 0.010.01 0.06, 6 41.2 66.6 87.0 91.6 94.8 95.6 0.005 0.02 0.05.0 25.2 46.0 73.0 79.0 85.0 88.0 0.02 1 , 13.3 21.8 59.69.75.3 80, 0.01 1.0 7.2 21.6 47.6 58.6 62.63.2 0.000 12.2 34.6 42.8 51 .2 56.6 0.08 1 4.6 6.6 9,11,13,0 14, 0.04 0,8 3,0 5,7,2 10,2 12,14 0,02 0,2 .0 3,5,2 6,2 7,0 7,8 untreated 0,0,6 1,0 1,6 2 2 2,3 PA the plants treated with B were left 48 hours after spraying annu leaf loss: Number% active substance DOda Live 0.08 81.6 181.6 0.01 54.6 203 0.02 49 354 Untreated Unshaven, abundant occurrence
Claims (1)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SE177969T |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SE177969C1 true SE177969C1 (en) | 1961-01-01 |
Family
ID=38408992
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SE177969D SE177969C1 (en) |
Country Status (1)
| Country | Link |
|---|---|
| SE (1) | SE177969C1 (en) |
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0
- SE SE177969D patent/SE177969C1/sv unknown
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