SA516380396B1 - Improved Selective Ammoxidation Catalysts - Google Patents

Improved Selective Ammoxidation Catalysts

Info

Publication number
SA516380396B1
SA516380396B1 SA516380396A SA516380396A SA516380396B1 SA 516380396 B1 SA516380396 B1 SA 516380396B1 SA 516380396 A SA516380396 A SA 516380396A SA 516380396 A SA516380396 A SA 516380396A SA 516380396 B1 SA516380396 B1 SA 516380396B1
Authority
SA
Saudi Arabia
Prior art keywords
improved selective
ammoxidation catalysts
selective ammoxidation
mixtures
catalysts
Prior art date
Application number
SA516380396A
Other languages
Arabic (ar)
Inventor
جي بيسيسكير تشارلز
إف برازديل جيمس
إيه توفت مارك
جي سيلي مايكل
Original Assignee
انيوس يوروب ايه جي
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by انيوس يوروب ايه جي filed Critical انيوس يوروب ايه جي
Publication of SA516380396B1 publication Critical patent/SA516380396B1/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/889—Manganese, technetium or rhenium
    • B01J23/8898—Manganese, technetium or rhenium containing also molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8878—Chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C07C253/24—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons
    • C07C253/26—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons containing carbon-to-carbon multiple bonds, e.g. unsaturated aldehydes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00—Carboxylic acid nitriles
    • C07C255/01—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms
    • C07C255/06—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms of an acyclic and unsaturated carbon skeleton
    • C07C255/07—Mononitriles
    • C07C255/08—Acrylonitrile; Methacrylonitrile
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

A catalytic composition useful for the conversion of an olefin selected from the group consisting of propylene, isobutylene or mixtures thereof, to acrylonitrile, methacrylonitrile, and mixtures thereof. The catalytic composition comprises a complex of metal oxides comprising bismuth, molybdenum, iron, cerium and other promoters, with a desirable composition. Fig. 1
SA516380396A 2014-05-29 2016-11-29 Improved Selective Ammoxidation Catalysts SA516380396B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US14/290,380 US20150343427A1 (en) 2014-05-29 2014-05-29 Selective ammoxidation catalysts
PCT/US2014/040007 WO2015183283A1 (en) 2014-05-29 2014-05-29 Improved selective ammoxidation catalysts

Publications (1)

Publication Number Publication Date
SA516380396B1 true SA516380396B1 (en) 2021-05-16

Family

ID=51014643

Family Applications (1)

Application Number Title Priority Date Filing Date
SA516380396A SA516380396B1 (en) 2014-05-29 2016-11-29 Improved Selective Ammoxidation Catalysts

Country Status (12)

Country Link
US (2) US20150343427A1 (en)
EP (1) EP3148691A1 (en)
JP (1) JP6526062B2 (en)
KR (1) KR20170015900A (en)
CN (1) CN107073455B (en)
BR (1) BR112016027658B1 (en)
MX (1) MX2016015442A (en)
MY (1) MY177458A (en)
RU (1) RU2668554C2 (en)
SA (1) SA516380396B1 (en)
TW (1) TWI642477B (en)
WO (1) WO2015183283A1 (en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20180100178A (en) * 2016-01-09 2018-09-07 어센드 퍼포먼스 머티리얼즈 오퍼레이션즈 엘엘씨 Catalyst Compositions and Process for Direct Production of Hydrogen Cyanide in an Acrylonitrile Reactor Feed Stream
US10626082B2 (en) 2016-10-11 2020-04-21 Ineos Europe Ag Ammoxidation catalyst with selective co-product HCN production
CN109261150A (en) * 2018-09-26 2019-01-25 中国科学院生态环境研究中心 A kind of low-temperature ammonia selective oxidation catalyst and preparation method thereof, purposes and application method
KR102519507B1 (en) * 2019-09-30 2023-04-07 주식회사 엘지화학 Ammoyidation catalyst for propylene, manufacturing method of the same catalyst, and ammoyidation methode using the same catalyst
WO2023223295A1 (en) * 2022-05-20 2023-11-23 Ineos Europe Ag Catalyst for the manufacture of acrylonitrile

Family Cites Families (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA742727A (en) 1962-11-28 1966-09-13 The Standard Oil Company Process for preparing olefinically unsaturated nitriles
US4503001A (en) 1970-10-30 1985-03-05 Standard Oil Company (Indiana) Process for the manufacture of acrylonitrile and methacrylonitrile
US4767878A (en) 1971-02-04 1988-08-30 The Standard Oil Company Process for the manufacture of acrylonitrile and methacrylonitrile
US4863891A (en) 1971-02-04 1989-09-05 The Standard Oil Company Catalyst for the manufacture of acrylonitrile and methacrylonitrile
US4766232A (en) 1973-06-04 1988-08-23 The Standard Oil Company Production of unsaturated nitriles using catalysts containing boron, gallium or indium
JPS5245692B2 (en) 1973-10-16 1977-11-17
US4040978A (en) 1975-11-28 1977-08-09 Monsanto Company Production of (amm)oxidation catalyst
US4168246A (en) 1975-11-28 1979-09-18 Monsanto Company Production of (amm)oxidation catalyst
US4377534A (en) 1978-02-27 1983-03-22 The Standard Oil Co. Production of unsaturated nitriles
US5093299A (en) 1990-01-09 1992-03-03 The Standard Oil Company Catalyst for process for the manufacture of acrylonitrile and methacrylonitrile
US5212137A (en) 1990-01-09 1993-05-18 Standard Oil Company Catalyst for the manufacture of acrylonitrile and methacrylonitrile
CN1021638C (en) 1990-11-05 1993-07-21 中国石油化工总公司 Fluidized catalyst for acrylonitrile
JP3214984B2 (en) * 1993-08-10 2001-10-02 旭化成株式会社 Catalyst composition used for ammoxidation and method for producing acrylonitrile or methacrylonitrile using the same
US5658842A (en) 1993-08-10 1997-08-19 Asahi Kasei Kogyo Kabushiki Kaisha Ammoxidation catalyst composition, and process for producing acrylonitrile or methacrylonitrile using the same
JP3497558B2 (en) * 1994-05-12 2004-02-16 旭化成ケミカルズ株式会社 Ammoxidation catalyst composition and method for producing acrylonitrile or methacrylonitrile using the same
US5834394A (en) 1996-08-06 1998-11-10 China-Petro-Chemical Corporation Fluidized-bed catalyst for propylene ammoxidation to acrylonitrile
US6458742B1 (en) * 2000-08-17 2002-10-01 The Standard Oil Company Catalyst for the manufacture of acrylonitrile
US7238827B2 (en) * 2002-09-27 2007-07-03 Basf Aktiengesellschaft Preparation of at least one partial oxidation and/or ammoxidation product of propylene
JP4688499B2 (en) * 2002-12-02 2011-05-25 イネオス・ユーエスエイ・エルエルシー Catalyst composition for the conversion of olefins to acrylonitrile and methacrylonitrile and process for the conversion
US7071140B2 (en) * 2002-12-02 2006-07-04 The Standard Oil Company Catalyst for the manufacture of acrylonitrile
DE102005022798A1 (en) * 2005-05-12 2006-11-16 Basf Ag Preparing final products by partial oxidation of propylene, useful as intermediate for polymer, comprises subjecting propane to dehydrogenation, separating and subjecting the gas mixture in heterogeneous catalyzed gasphase-partial oxidation
WO2006120233A1 (en) * 2005-05-12 2006-11-16 Basf Aktiengesellschaft Method for the production of at least one final product by partial oxidation and/or ammoxidation of propylene
ES2449580T3 (en) * 2006-10-26 2014-03-20 Mitsubishi Rayon Co., Ltd. Fluidized bed catalyst to produce acrylonitrile and process to produce acrylonitrile
US8455388B2 (en) * 2010-03-23 2013-06-04 Ineos Usa Llc Attrition resistant mixed metal oxide ammoxidation catalysts
US8153546B2 (en) 2010-03-23 2012-04-10 Ineos Usa Llc Mixed metal oxide ammoxidation catalysts
US9433929B2 (en) * 2011-09-21 2016-09-06 Ineos Europe Ag Mixed metal oxide catalysts
CN103418400A (en) 2012-05-16 2013-12-04 中国石油化工股份有限公司 Fluidized-bed catalyst for preparing unsaturated nitrile by ammoxidation
MY177749A (en) * 2012-09-28 2020-09-23 Asahi Kasei Chemicals Corp Oxide catalyst and method for producing the same, and methods for producing unsaturated aldehyde, diolefin, and unsaturated nitrile

Also Published As

Publication number Publication date
RU2668554C2 (en) 2018-10-02
MY177458A (en) 2020-09-16
EP3148691A1 (en) 2017-04-05
US20150343427A1 (en) 2015-12-03
JP2017517393A (en) 2017-06-29
TWI642477B (en) 2018-12-01
US20190001310A1 (en) 2019-01-03
BR112016027658A2 (en) 2017-08-15
KR20170015900A (en) 2017-02-10
MX2016015442A (en) 2017-03-23
WO2015183283A1 (en) 2015-12-03
US10780427B2 (en) 2020-09-22
CN107073455B (en) 2021-02-26
RU2016152078A (en) 2018-07-03
RU2016152078A3 (en) 2018-07-03
TW201600171A (en) 2016-01-01
JP6526062B2 (en) 2019-06-05
CN107073455A (en) 2017-08-18
BR112016027658B1 (en) 2021-09-28

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