SA05260116B1 - Preform and methods of manufacturing the preform and a bottle - Google Patents

Abstract

Preform and methods of manufacturing the preform and a bottle Abstract The invention relates to the possibility of producing products containing a preformable material through embodiments, with preferred processes and devices. Products may be single-layer or multi-layer. Products can also be configured with multiple processes.

Description

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Preformed material and methods of manufacturing preformed material and a bottle

Preform and methods of manufacturing the preform and a bottle FULL DESCRIPTION BACKGROUND This invention relates to atricles products with formable material and more precisely to mono and multi-layer products articles) on formable materials and manufacturing methods for such products (2016169). o The products have generally been used to hold beverages and foodstuffs. The use of the products may become; such as plastic bowls; An alternative to all-glass or all-metal containers in beverage bottling is becoming increasingly popular. Advantages of plastic packaging include lighter weight; reduce the possibility of breakage compared to glass; and the potential for lower costs. The most common plastic used in beverage containers today is polyethylene terephthalate ("PET") (polyethylene terephthalate). 0 PET was first approved for use by the Food and Drug Administration (FDA) in direct contact with foodstuffs. PET containers are generally transparent; thin wall; Light weight; It has the ability to retain its shape by resisting the forces on the container walls by its compressed contents; Jia carbonated beverages PET resins are also fairly expensive and easy to process. Most PET bottles are made with a process that includes blow-molding of the preformed plastic; Which are manufactured by a process that includes injection molding or an extrusion process. Jia PET Bottle Heat Insulator may not be suitable for limiting thermal contact through the walls of PET bottles 0 It may be desirable to reduce heat transfer between the liquid inside the bottle and the environment around the bottle to maintain the temperature of the liquid inside the bottles. similarly; Most expensive food containers do not provide an effective thermal barrier to reduce 1" 41

Heat transfer through the vessel. It may be desirable to reduce heat transfer through containers or packages. In addition to lA products in the form of cand can have food packaging; And other synthetic properties; or isolation or any other unsuitable characteristics. 0 occurs many times or fluid storage. foods; or drinks; Jie carbonated soda in a container that may affect its contents in an undesirable way. due to bad luck; When food comes into contact with the surface of some of the materials of known products; The taste of food may change inappropriately. It may be desirable to retain the taste of foodstuffs in contact with the product.

0 0681362133 discloses a method for injecting preformed blow molded materials with a laminar structure having a shell of an injection moldable first synthetic resin that includes a core of a second injection moldable synthetic resin. Furthermore it; The reference shows that the final product can include a foamed core layer

Adee 179 2002/132100 Al describes the preparation of lightweight materials that include abrasives.

1 Extrusion blowing or injection molding of a resin of polypropylene, polystyrene, HD polyethylene or copolymers thereof and; Mix in it ALE microspheres for thermal expansion.

US 2001/0038074 Al discloses a cup with a base to receive the bottom of the container body and to reduce heat gain to the fluid components in the container body. The base cup is formed

A. Made of foam and includes a reverse layer on most of the outer surface

US Patent No. 179,716,816 discloses a method and apparatus for injection molding of thermoplastic materials using a novel valve unit to control the opening and closing of at least two flanges in a single injection nozzle. Furthermore it; US Patent No. 7,716,914 states that one of the layers of the multilayer product contains a “foam material”

Yo US Publication 2001/004002 discloses a method for producing a tubular preform using the injection molding method.

¢ The present invention is intended to provide a preformed material for blow molding of a PET bottle with a barrier suitable for limiting thermal contact through the walls of the resulting PET bottle. Furthermore it; The invention Mall aims to provide a method for producing a PET bottle and the invention Jal aims to provide a method for producing the said preformed material; In addition to providing a method for producing a bottle of the aforementioned preform. The stated and other purposes are fulfilled by claims 60 19 and 71. Useful embodiments can be derived from independent safeguards. General description of the invention in a preferred embodiment; Provides a method for forming a preformed material. At least 0% of the preformed material includes an expandable material that can react to form a thermal insulator or desired finish. The preform is heated to a temperature suitable for forming in a mold by blowing and at least part of the expandable material is expanded. The preformed material is blown to the shape of the bowl. in one of the arrangements; The preformed material is a single layer preformed material. In another order the preformed material VO is a multi-layered preformed material. In another embodiment, a process for making a foamed polymer product is provided comprising the processes for supplying the preformed material for the foamed polymer and forming the preformed material into a blow mold to the desired vessel shape. in one of the arrangements; The process involves preheating the preformed polymer 0 foamed material before it is blown into a mould; causing the foam cap. which includes microspheres to begin the expansion of microspheres - microspheres can be multiplied before forming in a blow mold; during blow molding; and/or after blow molding. In one embodiment the foamed polymer product comprises one lesser le YO layer of foam surrounding at least part of another layer actually comprising polyester The foam includes a carrier material ) for polymer and foaming agent

°

In the embodiment of AT ¢ a process for making a foamed product is provided. can contain

Lather on first component and second component. The first component can value when it is thermally activated. Optionally the first component comprises microspheres which are generally in the first state of expansion in one of the arrangements the second component is a material mixed with

2 first component. when the mixture is heated; The mixture expands to be generally a closed cell foam. in one embodiment; The mixture is formed into a preformed material containing fine pellets

Which expands from the first state of expansion to a second state of expansion. The preformed material is formed in a mold to the vessel containing microbeads which expand from a second state of expansion to a third state of expansion. in one of the arrangements; be a large part of the microbes

0 _ stretched in the first position. Optionally a large portion of the microspheres is generally partially expanded in the second position. optionally; A large portion of the microspheres is generally dilated in the third position.

in one embodiment; The preformed material comprises an assemblage of layers where one of the layers contains an extensible material. The preformed material is optionally formed into a container.

0 in an embodiment; Ludi J sald) An inner layer of the preformed material or vessel includes a suitable food and/or liquid and is the holding chamber of the preformed material or vessel. in one of the arrangements; Inner layer comprises of sale thermoplastic Second layer of preformed material or vessel includes ALE sabe for expansion incorporating polymer and microbeads. as a substitute

Ye The expandable material can be an inner or linear layer of the preformed material or vessel.

in one embodiment; The expandable material includes a carrier and a foaming agent. Preferably, the carrier should be a material that can be mixed with micro-pellets to form an extensible material. The carrier can be a thermoplastic material or a “pana (polymeric)” without

Yo Determination of Ethylene Acrylic Acid “(”EAA”) (ethylene acrylic acid) “(”EVA”) (ethylene vinyl acetate) linear low density polyethylene (” LLDPE") polyethylene) poly(hydroxyamino ethers).

: ((("PHAE") ethers)) Polyethylene terephtalate «("PET") (polyethylene terephtalate) and Al copolymers (copolymers) 5 including PETG (polyethylene terephtalate glycol) Polyethylene (“PE”) (polyethylene) Polypropylene (“PP”) (polypropylene) Polystyrene (“PS”) (polystyrene) Material © cellulose Paste; Terminator mixtures and the like. in one embodiment; The foaming agent comprises fine globules that expand upon heating and cooperate with the carrier to produce foam. in one of the arrangements; Blowing agent comprises EXPANCEL® microspheres in preferred embodiments; The expandable material has insulating qualities to prevent heat transfer through the walls of the container containing the expandable material. The stretchy material can be used to keep 0 food temperature; Liquids; or similar. in one embodiment; when the liquid is in the bowl; The expandable material of the bowl reduces heat transfer between the liquid Jala bowl and the environment around the bowl. in one of the arrangements; A vessel can hold a refrigerated liquid where the expandable material is a thermal insulator preventing heat transfer from the environment to the refrigerated liquid. In an Aly form, the vessel can have a heated liquid inside, where the expandable material is a Ye-thermal insulator that reduces heat transfer from the liquid to the environment surrounding the vessel. Although use with food and beverages is preferred; These bowls can also be used with non-food items. in one embodiment; Bale foaming is extruded to produce sheets that form into containers to hold food; or trays; or bottles; and similar. Optionally the plates are shaped into ye shaped clam shells which adjust to hold the food. Sheets can be formed into a vessel or in more than one process; Example; Thermoforming or thermoforming process. In another embodiment the product is fed with the foaming material which is a coating on the paper or wood pulp based material or vessel. in one of the arrangements; The foaming agent is mixed with the paste. optionally; The foaming agent and the paste can be mixed to form a generally homogeneous mixture which (say) is formed into the desired shape. The mixture can be heated before, during and/or after forming the mixture to cause expansion of at least part of the foaming component of the mixture. Thinner

no

in another embodiment; preformed sald comprises at least a first layer comprising a material suitable for food contact and a second layer comprising a thermoplastic; die polypropylene optional first layer includes thermoplastic material; Mql 1 and layer All on polypropylene foam and 0 min pellets. Optionally the first layer includes PET and the second layer optionally contains almost or entirely polypropylene; The first layer contains a phenoxy type of thermoplastic and the second layer contains a cs Al material such as polypropylene The preformed material can be formed into a container in one or more processes

like; Blow molding process.

0 in an embodiment; The method for producing a bottle involves feeding a preform with an inner layer of PET and an outer layer containing APP The preform is heated to a temperature not typically suitable for processing PP The preform is then molded in a blow mold into a bottle After heating the preformed material. in one of the arrangements; The outer layer contains foaming material. in one of the arrangements; class contains

External CPP mostly or entirely on 1

In another embodiment, the preformed material includes an inner layer lg which includes a flange defining at least part of the preformed opening. An outer layer surrounds the inner layer and delineates a suitable portion for a necked assembly of preformed material and is an outer surface for a body portion of the preformed material.

ve In another embodiment there is a tube comprising a first layer and a second layer. in one embodiment; The first layer includes a thermoplastic Lal material such as PET and the second layer includes a similar or different thermoplastic material; PP (Jie) and foaming agent. Optionally the first layer includes PET as base and the second layer includes PP as foaming material base. In one arrangement; the tube is formed by joint slotting process. Optionally the tube can be blow molded into a container. (Lola) can Use the tube as a fluid line

Yo for the delivery of passable liquids. In the AT embodiment the preformed material comprises an inner layer and an outer layer. The outer layer surrounds the inner layer and defines a suitable part for cervical installation of a previous material

A

Formation. The outer layer also forms the outer surface of a body part of the preformed material. In another embodiment, an apparatus for molding preformed materials comprises a core section of a mold containing a mold cavity section and a section of the mold cavity core section) The template is on a delivery system. The die core segment and the die cavity segment cooperate to define a gap when 0 the core segment and the die cavity segment are in the closed position. The jointing system forms the bonding material inside the gap. Optionally the device also includes an exhaust cycle (running pipe network) in fluid contact with the cavity. In another embodiment, the method of forming the preformed material involves placing a portion of the preformed material on a rotating screw of the die. A binder is connected from the output of the delivery system 0 formed within the cavity section defining the cavity. covers at least part of the material preformed with the binder. and a neck portion in some embodiments; The preformed material includes a neck part, the body part has a parietal part and a terminal apex, and the body portion has a first layer and a second layer; The first layer includes a stretchable material. In some embodiments; 0 the expandable material is prepared to be stretched by heat treatment. In some embodiments, the preformed material includes a grooved neck portion and a body portion. The body portion includes a parietal portion and an end apex. The body part includes an expansion material which is less than about 76560 wt. of the preformed material. In some ALG by weight of preformed material. may 7,710 incarnations; The expandable material comprises less than 0 The expandable material optionally includes microbeads and a thermoplastic carrier selected from and combinations thereof. “PET (polypropylene) The group consisting of polypropylene in some embodiments; The method of producing the preformed material includes the formation of an initial layer of the preformed material. A second layer consists of the preformed material and includes an extensible and oriented material. in some arrangements; The first layer is formed by injecting a primer comprising polyester Yo through an edge into a space defined by half of the cavity mold and half of the core mold to form the (polyester) product. The product includes an inner surface and an outer surface. The second layer is formed by injecting a thinner material

Expandable in a second space defined on the outer surface of the product consisting of the first injected material and the second mold cavity half to form a second layer of preformed material. in some embodiments; The method of producing a bottle involves providing a preformed material with a neck part and a body part. The preform is heated such that the Lida expands at least from the _© portion of the preform to form foam. The preform is blow molded into a bottle containing foam. in some embodiments; The product includes a thread part and a body part. The body part includes a first layer and a second layer. The first layer has an upper end that ends below the grooves of the neck part and includes foaming material. The second layer is placed inside the first 0 layer. in some embodiments; the product is a preformed material; bottle; container; etc. The second layer includes a material suitable for food contact. For example, the second layer includes a material that includes at least one material selected from a group consisting of thermoplastic materials of the type “phenoxy” polypropylene “polyester” and combinations thereof. :

#0 in some embodiments; The bottle includes a neck part and a body part. The body part has an inner layer of polyester and an outer layer of foaming material. The foaming material includes polypropylene inner layer and outer layer defining at least part of the body part wall. in some embodiments; The method of making pre-formed, multi-layered ale includes:

0 Providing the pre-formed substrate that was manufactured by any of the methods known in the art. The preformed substrate is placed in a specific cavity between the first mold part and the second Co MEH part. The first material is injected from the outlet of the first mold part into the cavity on the substrate. Adaptation of the primary material to form a layer on the preformed underlying material. is injected

A second material from the molten material gate of the first mold part on the preformed material

Ye: Substratum. in some arrangements; The first material includes a binder. in some embodiments; The first material is used to encapsulate at least one part; An essential part of the body part of the preformed substrate is preferred. The second material can be directly injected onto the first material to form a layer

supernatural

Ya external. voluntarily The unused portion of the raw material can be removed from the cavity by means of a drainage system. in some arrangements; The first die segment is a cavity section and the second die segment is a core segment. In some embodiments; The method of injecting material into a mold for molding a product involves providing an injection mold that is movable between an open position and a closed position. The template includes a heart sector and a cavity © sector. The material is delivered through a first gate of the cavity section. The melt is delivered to the cavity section. in some arrangements; The product is an AB preform through the preform gate or a cover. voluntarily The conductive material through the first gate may include a fluid containing a binder.

0 in some embodiments; The preform and container molding mold includes a core segment and a cavity segment that are movable between an open position and a closed position. The core segment and lumen segment define a cavity when the core segment and lumen segment are in a closed position. Les gate in the bore section to inject the melt into the bore. An outlet is located in the cavity profile and prepared to inject the first material from an inlet line into the cavity. Entrance is specified in

0 Cavity section It is equipped to take the material into the cavity and deliver the material to the output line. In some arrangements the gate is placed in the bore section space to mold an end cap of the preformed material. voluntarily Both gates diverge; The outlet and inlet are separated from each other and form a molding surface for the cavity segment.

in some embodiments; The product molding die includes a first die segment that defines a surface

YS first molding. A second die sector defines a second molding surface. The first mold segment and the second mold segment cooperate to form a cavity in the shape of the product. The mold delivery system includes a fluid source and a feeding line. The feed line fluidly communicates with the fluid source and outlet. The port is placed along with the first die sector or the second die sector. The drain system includes an inlet positioned parallel to the first die sector or the second die sector. Drainage system includes

YO is a discharge line in preventive contact with the bore. The gate of the melted material is placed parallel to the second heart sector, in order to prepare for the delivery of the melted material to the cavity. In some arrangements it includes a system

11 Delivery on a valve system configured to optionally control the amount of fluid delivered to the bore. voluntarily The recess takes the form of the preformed material or cap. and one half of the recess are fitted lf in some embodiments; The product production mold includes half an interlock to create a cavity for molding the preformed material. Half of the cavity includes a gate.

0 The die contains a means of delivering the packing material into the cavity and a means of removing the packing material which is delivered by the means of delivering the packing material from the cavity. voluntarily The product may be a preformed sale or a cover. The gate diverges from the means of delivery of the packing material and the means of removing the packing material.

In some preferred embodiments thin plates include; preformed materials; vessels; 0 and products on PETG and “(polypropylene) and manufacturing methods are the same; be exposed. In one embodiment polypropylene may be grafted or modified with maleic anhydride (glycidyl methacrylate) acryl methacrylate and/or similar compounds to improve adhesion ( adhesion) in another embodiment polypropylene further comprises '10 fine particles of aa' fine matter 0 aa in another embodiment polypropylene comprises: very fine particles and is Grafted or modified with maleic anhydride glycidyl methacrylate acryl methacrylate and/or similar compounds. Thin sheets can be manufactured; Thin sheets; preformed materials; containers and products can be formed through injection molding; over molding; under molding; blow molding; injection molding; molding (Ells). extrusion-associated forming; injection expanding molding in a blow mold; and other processes declared lee herein and/or known to those skilled in the process. Yo in some unlimited incarnations; The product material may include one or more layers or portions having one or more of the following useful properties: insulating layer; barrier layer “all” UV protective layers; Protective layer (Jha) vitamin protective layer » yen resistance layer

for wear; etc); contact layer (AR) non-flavoring layer; non-discoloring film; high tenacity film; Compliant layer Tei layer Gas scavenging layer (eg oxygen, carbon dioxide, etc.); layer or part suitable for hot fill applications; Layer having a fusion strength suitable for forming (Full toughness; sale] ALE; rotation (after consumer and/or after industry); fineness; etc. In one embodiment; sald) single or many layers comprise one or more materials Of the following materials: PET (including recycled PET and/or preform) – PETG foam; Polypropylene is a phenoxy type of thermoplastic; Polyolefins A mixture of thermoplastic phenoxy-polyolefin 0 and/or combinations thereof. Brief Explanation of Drawings Figure 1 is a preformed material used as a starting material for vessel formation. appearance ? It is a cross-section of the preformed material in the form 1. Figure 1. It is a cross-section of a blow molding device of the type that VO can use to make a preferred container. i Se form; A side view of a container made of preformed material. : the © figure is a transverse glade of preformed, multi-layered material. Fig. 1 is a cross-section of a multi-layered container made of preformed multi-layered material in Fig. 0a. Fig. 1 is an enlarged view of the container in Fig. 1 taken with 7. Fig. A is a cross-section of a preformed material. layered. Figure (JA) is an enlarged view of the preformed material in Figure A taken with 4(a). Figure 4 is a cross section of the preformed material containing a narrow layered section. Yo Figure 0 is a cross section of preformed, multi-layered material according to another embodiment.

l Fig. 11 is a cross-section of a multi-layered preformed material where the inner layer is located within the preformed material. Figure 0 is a cross-section of a multilayer preformed material with an inner layer and an outer layer defining the narrow part. ° Figure (NY) is a preformed cross section of gal with many layers each having an inner layer and an outer layer defining the narrow portion. (GY JSS is a cross section of preformed material having an inner layer and an outer layer defining the narrow portion. Fig. 1 is a cross-section of a preformed material having an inner layer with a raised edge. 0 Fig. 0() (VT) are enlarged cross-sections of sections of multilayered preformed materials according to some embodiments. VE fig. It is a cross-section of a preformed material, sane, layered with an inner layer having a bonding structure. (hye) is a cross-section of a container made of preformed material in the form cua (VE Vo) attached to the Lele ols (closure) Gl tool Fig. 1(b) is an enlarged view of part of the receptacle and sealer Fig. 4 1(a) taken together with (NE) Fig. 1(c) is an enlarged view of part of the receptacle and sealer as per embodiment AT Fig. 0))( It is a cross-section of a part of the preformed material having a narrow part, Te, without threads. Fig. 11(b) It is a cross-section of the preformed material in Fig. 01(a). Fig. 11(c) It is a cross-section of a section of a preformed material with many parts. Fig. 11 is a cross-section of preformed material according to another embodiment. Fig. 117 is a cross-section of preformed material according to another embodiment. Yo Figure VA is a perspective view of a sealing device suitable for sealing a vessel. Fig. 19 is a cross-section of a multilayer sealer with an inner layer.

Y¢ is a cross-section of a multi-layered sealer having an inner layer spanning 10 Figs the length of the sealer sides. The layers. sane Fig. 1?(a)-1"(e) are cross-sections Sealers are cross-sections of sheets. (YY Fig. 7? ()- is a perspective view of a preferred embodiment of the preformed material. YY Fig. ° is a side view of a preferred embodiment of packaging including a container It has a YE motif and a sealing device. (label) Card according to another embodiment. Ble is a side view of a container and YO Fig. 76?() is a perspective view of a container. A perspective view of the tray. (YT JSS 5) A schematic view of an embodiment of a lamellar generation system with a melting duct. Figure YY Made of (lamellar material) A cross-section of a laminated material (0 YV Figure YY Melting Stream Laminated Generator in the shape of a cross-section of a type mold that can be used to make the precursor material YA JSS A 1. Forming and special in the form of ve: a cross section of a type mold that can be used to make an outer layer Glad is YA form 0 of preformed and special shape material It is a cross-section of a mold of a type that can be used to make an inner layer Ye form AY of preformed and special shape material is a sector Cross section of a mold of a type that can be used for the manufacture of an outer layer TY Fig. 11. For preformed and special material in the form of TY It is a cross section of a mold of a type that can be used for the manufacture of a cover. Fig. YY of its use for the manufacture of an outer layer (Say It is a cross-section of a VY-type mold, Fig. 01., for the cover of a special shape, which represents a formed mold for the manufacture of pre-formed, multi-layered materials that include bonding layers on the YE-shape. 4.3 A cross-section of the template and the template system of the YO-shape

1 © Fig. + is a cross-section of a mold in the shape of Yo, taken along lines FT. Fig. TV is a separate view Blas of the space for the shape of ©* taken along lines 7 ?+-/7. The TA figure is a cross-section of a modified template of the vo-shape taken along lines oo 1 - A Fig. 4 is a separate closed view of the space for the ©-shape taken along the lines FV=YY Fig. 40 A cross-section view of a thin sheet of material.

Yee hereby warrants all patents and published books mentioned herein by reference to them in their entirety. Except as described hereinafter they may be embodiments; Advantages; systems. devices; Material; Certain processes and techniques described herein are similar to any embodiment; feature; System; len

material One or more processes and technologies described in US Patent Numbers PN (1 Neptabsorbent Net Calfnamet CTFOYEYT 404 FITTS) ve - 716887 1; US Patent Application Numbers 15/748015 (Publication No. “YoY” 003); 01/174643 (8) No. (YY SY Y custom CYT)

714 0); 01/149091 (Publication No. ¥ 01/330434 (+ YALE SY el) (Publication No. 01/114971 CERACA MAREE (Publication No. 4 00- 1701488 ); provisional application 10/017071, filed April 7 00 Request for my time Te foverry filed in May

0..4 780 My Time Request 20/585744 God Jul 7 - 0040; My Time Request 0/6 Filed Oct Yard A 20/171911 Deposited Oct YY

Ye and ask for my time 147004/10 Filed Jan 01 ©100 US Patent Application

No. APHPEP1.090A under the designation of single and multi-layer products and compression molding methods to make the same; and filed on the same day as the current application; US patent application

YO File No. APHPEPLOSIA under the name of single and multi-layer products and extrusion methods to make the same; and filed on the same day as the current application; And all of that goes into

This description is for reference. in addition; avatars can be applied; systems pictures.

hardware; MATERIALS The processes and techniques described herein in specific embodiments; or use it in combination with any one or more incarnations; systems photos; hardware; ol pall The processes and technologies disclosed in the above patents and applications. a- Products ° Products in preferred embodiments may include one or more LEs for molding. The products described herein can be single- or multi-layered (ie, two or more layers). in some embodiments; Products can be used for packaging; Jie beverage goods (including preformed items; containers; bottles; closures; etc.); Pial carton boxes and the like. Ve multilayer products may include an inner layer (ie, the layer in contact with the contents of the container) of a material approved by a regulatory agency (eg, FDA) or a material with regulatory approval for food contact (including beverages); pharmaceutical; makeup; etc. in other embodiments. The inner layer contains material(s) that are not approved by the food contact regulatory chart. The second layer 1 includes a second material; Inner layer: which can be similar or different from the material composing the product. The products can have as many layers as may be desired. It is intended that products may comprise one or more materials which are parts and not 'layers'. 1- Detailed description of Ye drawings with reference to Figures 1 and 7; Demonstrates preferred, pre-formed material “0 monolayer. La sac The preformed To has a narrow part TY and a body part TE The preformed 00 applied can have a single layer of material that can be blow molded. The preformed material Ye is preferably blown into a container to hold liquids; J gull Jie Jie (non-carbonated) fruit juice; celall YO and the like. voluntarily The 3+0 preform can be molded to other liquid holding containers. such as carbonaceous liquids (68:000880). The preformed material 1" shown can be suitable for forming an 11 ounce beverage bottle which will be

Very suitable for holding a carbonated beverage as used here. The term 'bottle' is an inclusive term and is used in its normal sense and may include 'a vessel without restriction (typically of glass and/or plastic and which has a relatively narrow neck or mouth) ; a container in the form of a bottle for storing a liquid (preferably a liquid); etc. The bottle may or may not have a 0 handle.

The preformed material 0 shown has a neck part, PY, which begins at the opening of M (form Jalal (Y). Ordinary and may include, without limitation, a part of the preformed material attached to the body part

0 The cervical part includes a narrow end. The cervical end, together with the cervical cylinder, is what is referred to here as the "cervical part". The neck part PY in the embodiment shown is also distinguished by the presence of cfr threads which provide a way to fix the cap or the Gl member of the bottle produced from the preformed material YY in a DIY shape The neck part may not form a YY to attach to the closing device or May contain non-threaded means to attach to the sealer. The body part is VE

º 0_ is known and is generally a cylindrical structure that extends from the bottom of the neck part TY and ends to the end cap 47. The end cap 47 shown is circular; On any dn the end cap can have other suitable shapes. The thickness of the preformed material will depend ;; on the total length of the preformed material + the desired wall thickness and the total volume of the resulting vessel.

X. Referring to the form oF the preformed material +” is placed in this blow molding process into a mold whose cavity is relative to the desired vessel shape. The preform Vo is then heated and expanded by forcing air or other suitable fluid into the preform to expand the preform Sal cavity; Configured for the PV container (Fig. 4). The blow molding method is described in detail below. An extended rod or any can be used

YO is also a similar method to assist in the blow molding process” as is known in the method.

Ya

in some embodiments; Blow molding machine can receive warm products Preformed materials such as sleeves; Preformed materials. etc.) to assist in the process of 0 (such as receiving materials YA blow molding;. as known in the method. The mold can preformed and warm Jie die casting machines from the injection molding machine Transfer of preformed material manufactured by a machine © can be done by coupling Heat WA preformed into an injection mold can rapidly supply to the underlying mold the preformed material one or more of the following: Reducing Blow molding time; Reducing the energy required to heat preforms to a temperature suitable for blow molding; and/or the like. Optionally, one or more delivery systems may be used to transfer preforms. ve preforms to and/or bottles away from the blow molding mold.eg the delivery system may include a shuttle system (eg linear or rotary shuttle system) to transport materials

YA The shuttle system can extend the preformed YA die into and/or away from the die

YA batches of preformed material or removal of blow molded bottles from the mold The delivery system may include a reciprocating and/or rotary delivery system. in some edn as 10 - incarnations; A rotary delivery system can be used to deliver preformed materials quickly to advantageously; YA rotary delivery systems can remove bottles from the mold YA the mold thus increasing the output. YA products move continuously around the mold It is expected that the delivery system can be used with a suitable die forming machine to form the material Preformed by blow molding Extrusion and then molded by blow molding» Shaping the material _ 0 The delivery system can include the collection of preformed cella and so on. In addition to the systems; Such as a rotating delivery system and a shuttle system that cooperate to transport products. Which can be formed from VY as the render reveals the container of with reference to the figure

Vi and body part VY on neck part YY The vessel Ye contains the preformed material as described above in relation to LY the attachment of the neck and body parts of the preformed material Yo The neck part 7 can be adjusted to attach to the locking device . The neck portion (cdl) features a pre-made material which is a method for securing the lid to the vessel. In the form of © 0 illustrated by the presence of the © threads.

my choice; The vessel wall can prevent “YY” and it is preferable to actually prevent; Gas transmission (example “CO), through the vessel wall 7 ?. In some embodiments, the vessel 7© actually includes closed foam cells that prevent fluid movement through the foam. The blow molding process is usually confined to the body part 4 For the © preformed material with neck part YY including any notches; the o(Pilfer) loosening ring and/or support ring retaining its original shape as the preformed material. On any dla any part(s) of the material can Preformed to be stretched and formed in a blow mold The vessel Lad © can be formed by cs a] processes such as extrusion or combinations of injection molding (Jt) processes on a part after extrusion). The vessel PY 0 can be formed by an extrusion process formed in a blow mold. Therefore the vessels described here can be formed from preformed materials (JEN extruded preformed material, etc. Referring to Fig. ©; a cross-section of a type One of the preformed material 0© is multi-layered having properties consistent with the preferred embodiment.The preformed material 50 preferably comprises primer 94 (single layer) uncoated in which the 0 is covered with an outer layer; 7©.-It is preferred; that the uncoated pre-formed sald) 9 comprise - ©©001700 polymer material; Such as polypropylene, polyester and/or other thermoplastic materials, and materials suitable for food contact are preferred. In one embodiment eg “the uncoated preform 74 physically comprises polypropylene in another embodiment the uncoated preform VA 00 physically comprises polyester” such as PET The preformed 00 multilayer material has a neck portion; VY and a particle of Vi are similar to the preformed substance 0 of Figs 1 and 7. in the embodiment shown; the outer layer 57 is nearly exposed to at least part of the body part TE of one embodiment; The outer layer OF is exposed by about a part of the aS and preferably the total area; From the surface of Ye the structural part TE of the inner layer (shown as the preformed material TA of Fig. 1); and ends at the base of the Adda support LFA The outer layer does not extend BOY The shown embodiment of the cervical part "? nor It is located on the inner surface of the inner layer 9, which is preferably made of .

1 either on oY a suitable material to touch the contents of the resulting vessel. The outer layer includes It can be bad of one or more materials. (Isa) Fine layers (Jha) One or many layers Generally homogeneous Generally heterogeneous or something in between. Although OY layer The outer layer can be other parts of the preformed material oF then the outer layer age is not the outer layer 7© can be at least part of the surface JB for example ©1 (just as the layer is injected The outer layer on a tube or preformed material 00 The inner part of the preformed material may be PY preform, which is open at both ends); or part of the neck part is not suitable for contact with foodstuffs. va The total thickness 56 of the preformed material is equal to the thickness of the preformed material (of the initial and not covered) (meaning inner layer 06) plus the thickness of the outer layer 0 which depends on the overall size and thickness of the covering required for the resulting vessel. 50 on the thermal properties; claw thickness of the preformed material; which may have any desired optical, insulating, and/or structural .50 in the container of the preformed material if a bonding layer is included the total thickness will include any bonding thickness. Preformed and layered vessels can contain a wide variety of thicknesses. Due to the disclosure Spd No

ld current; The specific and total layer thickness of the preform or vessel can be selected; at a point or for the entire vessel; to suit the manufacturing process; or a special bowl end use. In the embodiment shown the outer layer 57 is generally of equal thickness. However, no and/or the inner layer 08 to be equal and it is possible that of the need for the outer layer a thickness that varies along the longitudinal axis of the preformed material (Joel have them for example Ve ou can be used Preformed material is multi-layered for the production of containers. For example, ame ail in one of the L(V) shapes AY for vessel formation 00 Preformed material can be used between them as is AO with inner layer 08 To represent the OF layer or space, the outer layer 4e (oY) cooperates with the passage of air between the two layers A shown in figures + and NO. The YO layer, which is OF, can also be allowed. Passages can be formed between the AY layer They can characteristically insulate the vessel oF alternatively; the outer layer of loosely surrounds the inner layer can be sized

leached and formed to hold the inner layer of ©; so closely that the inner surface of the OF layer contacts the outer surface of the layer 54. In some embodiments; The AC layer can be A foam layer is similar; or not similar; of one or more layers OF 04. Even in another embodiment the AC layer may be a layer in which the layer OY is coupled to the inner layer 54. For example Jal 0 the layer 85 may be an adhesive or bonding layer which prevent; preferably effectively prevented; relative movement between the two layers 0 08 for example; The AO layer may be an adhesive layer which specifies the relative motion between the two layers OY 284. It is expected that some or none of the embodiments shown herein may be bonded together with a bonding layer or the like.

01 in one embodiment; At least one of the two layers 0f (OF) can be treated to increase or decrease the adhesion between the two layers 0 84. eg JE The outer surface of the inner 4© can be chemically treated so that the outer layer oY adheres to the inner 08 eg » A binder can be used to react and chemically treat one or more of the two layers ot ©" However, it is expected that any layer (any of the layers) can be modified to achieve

01 The desired interfacial reaction between layers. Article preformed. (bial) The two layers laa 0 (OY) can be attached directly

in some embodiments; A vessel includes a foaming material which preferably has insulating properties to prevent heat transfer through the walls of the vessel. when the liquid is in a container” such as container AY of the form eT for example; Wall forming foaming agent can reduce 84

0 The AY pot has heat transfer between the liquid contents and the environment around the AY pot For example (Jbl) The AY pot can hold chilled ingredients; Like a carbonated drink ¢ (carbonated) the foam is isolated from the AY vessel to prevent temperature changes of the cooled fluid. So the contents can remain refrigerated for the desired period of time despite the outside temperature surrounding it being greater than the liquid temperature. in edi format it can

Ye is a heated substance; jie hot drink; Inside the container AY where the wall AE can insulate the container AY to prevent heat transfer from the liquid to the environment around the container clad LAY The foaming agent of the container AY can make the surface temperature of the container AY where it is within the range of

YY

AY retains desired heat so that anyone can comfortably hold the pot

Got Ne mall with heated or cooled liquid. The thickness of the foam layer and the size and shape of the container can be varied to obtain the desired thermal characteristics of the container. Multi-layered in Te demonstrates a preferred embodiment of the preformed material ¢ A with reference to the shape of the encased and preformed material 01 cross sectional shape. One difference between the preformed material in Figure 0 is the relative thickness of the two layers in the cap-end area. In the preformed material 0 the formation is generally higher than the primary primary layer with a length of the outer layer cor formed with the preformed material OF the whole body part of the preformed material. The outer layer is thickest at 7+7 near cap tip 7; of which at 64 in the parietal part (Ja af on 66 0 in the parietal part TA is greater at φ and inversely; the thickness of the inner layer AT Ye is greater than at 107; in the cap-end area 47. The design of the material is earlier This forging is particularly useful when an external application of the primary preform material is made in the over-in-mold forging process to make a multi-layered primer, as described below, where certain advantages tend to include those related to the reduction of the forging cycle time in a mould. Two layers can be

CL _is homogeneous or may contain a collection of very fine layers. In embodiments 0 "7 is thinner at oY not shown; the other outer layer 10 is of preformed material than at 64 in wall 11 and conversely" the thickness of the SEY is near the end of the cap in the Ve region Less at 18 in the parietal part 16 more than at the inner layer optionally 54 (oY end cap 47). At least one of the two layers can be included

Alle on Ye ain ge of the preformed material (wall section) Figure (1) represents an enlargement of a wall section of the hyperinjection. The inner 4 layer of the preformed material © LIM represents the arrangement of the layers in the embodiment of oY is the layer The outer layer of the preformed material The outer layer OY the preform and the layer Laminate material) of the material as it will be made using og) comprise a collection of very fine layers of this type. 0 Definitely LIM Yo System Referring to Fig. 9; Another embodiment of a multi-layered raw material with a cross-section and 1 and 50 illustrates the initial difference between the coated preform 77 and the preformed material

YY

be placed on the OF segment in series; Is that the outer layer Ayo in the two forms NE as well as on the body part VY cervical Preformed materials and vessels can contain layers with a wide variety of thicknesses The thickness of a specific layer and the total thickness of the preformed material is chosen Mall relative. In seeing the reveal, the formation or the vessel; either at a particular point or throughout the entire vessel; To suit the capping process or oe for a special end use of the pot. Furthermore it; As discussed above for the layer, the layers may include the embodiments of the preformed material and the vessel oA (layers) in the form or several materials. The dala shown here is a single material; More than the devices and methods described herein can also be used to make raw materials that are three-layered or contain NYY. A three-layer embodiment of the preformed material is further illustrated. In Figure 0 of the AFT and VE outer layer the material shown there has two overlays; intermediate layer to accommodate a special formulation of 01. The relative thickness of the layers shown in the shape of the material may be varied or to allow the manufacture of different sized bottles; As would be understood by the adept at Except that the preformed material Leg (hana dual) can follow a method similar to that (ol _primary) it would have been previously covered by one of the methods for making the preformed material ©. << : Covering described herein including overformed in mould. 10180 Cross section of a type of preformed multilayer material 1 The figure shows It has characteristics according to the preferred embodiment. It is preferable to include. Preformed material 1360 on

AE and inner layer 117 Outer layer and body part A 17" multilayer on neck part 061 containing preformed material Y. Similar to the preformed material described above. Preferably outer layer VY For the cervical part 166 and the outer surface VE for the body part 165 for the outer surface 7 117 to be attached to the locking device. Fixing the outer layer 11” The outer surface can be machined ITY

AE about a large part; The whole portion is preferred. For the inner layer to 164 For the inner layer TA shown from the upper end 167 The outer layer extends Yo in the embodiment shown on 1164 The inner layer extends Te) YL Slot 119 of the preformed material Actually the neck part 167 is the length of the cervical part 177. So it can form the outer layer

TYE

Y¢ end AY) can be arranged in embodiments 11. kidneys as shown in Fig. 0" JA can be arranged at some point along the cervical segment 7?1.164 of the inner layer 08 upper In one embodiment non-VTE and outer VTE both inner layers shall contain at least about 797/0 of the weight of specified 1767 cervical portion;in one of the other embodiments not specified the outer layer shall comprise; .17 (or neck end) of the neck portion e outer layer 17 comprises at least about 750 of the weight of the neck portion. In one of the 730 more than 167 other indefinite embodiments also include outer layer

APY of the weight of the neck part Ly of the layer 177 is equal to the thickness 0610 of the preformed material 171 the total thickness which is based on the VE of the inner layer IVE plus the thickness of the outer TY is 0 167 The outer layer 177 The total volume of the resulting container. in one embodiment; The thickness of the outer and inner layers is 167. The outer two layers have VTE and the inner layer YE is actually greater than the thickness of Hal; The two layers may not have A as shown; Generally regular thickness. The VTE has a uniform thickness. For example; May have one or both VTE and the inner 117 the outer Ate varies along the length of the preformed material Kaw VTE ONY two layers 10 164 primer and preferably include the inner layer 167 the outer layer includes On foaming material 167 on another substance. For example; The outer layer may include (eg PET ie non-foamed; (polymer) and the inner layer 4 may include a polymer material that liaise etc. be primary (phenoxy) or post-consumer (recycled) Phenoxy PET contains a first material and a large part of the layer 117 A large part of the outer layer Ye contains a second material The first and second materials can be different or similar to each other's internal VTE. Layers Formation 083180 Cross-section view of preformed material 11 Figure Jas 01 will not be described as generally similar to preformed material 0810 Preformed material

VAs in detail. Preformed material VA includes many features of preformed material YO a large part of VAS designates inner layer VAY and outer layer VAS on inner layer containing inner layer 184 on A of preformed material 177 The inner surface

Yo embodiment 8A of preformed material 191 which is approximate to hole 188 end and designate APY for cervical part VAT outer surface VAY shown; Define the outer layer of course; The NYY layer of the cervical part VAY inner surface 185 inner layer 86 can be machined to bond with the sealing device. In the embodiment shown, The outer surface (VAY) designates the outer screw cap (Jia) modified to receive the grooved cap. VAS grooves © on VAs 168 although not shown; Preformed material 061 of preformed material 167 can contain more than two layers, for example, the outer layer may include a foaming material; (AE) a combination of layers comprising one or more of the following: material and/ Similarly, the inner layer of 1764 may comprise a PET (PP) plural of layers. A person of ordinary skill in the art can determine the dimensions and number of layers 0 of the VAY 1484 which constitute the preformed material described. Layers described above can be made of TY 164 similar or different materials as layers Optionally, a layer may cover at least part of the preformed material to prevent corrosion or wear, especially if at least part of pre-formed material manufactured from a covering layer cannot surround the notches in the part (Jad) - displacement material eg Ve or combinations thereof foamed PP PET which may include the source Or any thermoplastic materials. Similar to the previous material. 090 A view of a cross-section of the preformed material 11 representing the figure shown in Figure 71, except for what will be detailed in 1860 The preformed material 1090 The preformed after below .0 which extends down from 194 on an inner layer 090 includes the preformed material and specifies the inside of the preformed material. The inner layer 146 includes the edge of 91 The gap is a wide expression and is used according to its normal meaning. The expression “REST” as used here, the expression “NAY edge” o (lip) can include; without being specific; For one or more of the following: Flange Extruded Part; and fittings from that source Flange can act as a locking fitting Additional ATL YO form Preformed material can optionally have a combination of flanges.

YAY designates part of the inner surface 701 and at least part of the upper surface 08 of the preformed material. Flange 197 may have a fixed or various thickness depending on the desired characteristics of the neck portion .177 in some embodiments; including the embodiment shown; A Jel VAY flange fitting(s) (eg notches) is positioned to receive a VAY sealing tool. In some embodiments, a VAY flange means part of one or more notches; ridges; recesses; and/or other fittings for attachment With locking tool With continuous return of VY shape Edge 97 extends approximately at least part of the circumference of hole 191 and designates a layer of material Edge 197 preferably extends approximately the entire circumference of hole 1 So edge can be VAY Generally annular edge When the sealing device 0 is attached to the neck part 17 of the bowl of the preformed material 1900 the top surface Yao of the VAY flange can be a seal with the sealing device to prevent or block food from escaping flange 147 can block or prevent separation between inner layer 1194 and outer layer 144 one or more locking structure 1117 of Fig. 11” can Ne fu prevent relative movement between the inner layer 194 and outer layer-991. As used by Hana, the expression 'Gl structure' is a broad term and is used according to its normal meaning and may (aay 1 and without limitation) have one or more of the following: protrusions; surface treatments (eg rough surface); people of thorns; cams; thorns il pal hollows; bumps; the model with the distinctive structure; or something like that; Preferably to prevent or reduce movement between layers 144 and 194. Yr The VAY lock assembly can be configured with the inner layer 194 and/or the outer layer 149 in the embodiment shown; The VAY lock assembly is a protrusion extending from the outer surface of the inner layer 194 approx. in some embodiments; The VAY lock assembly is an annular protrusion extending circumferentially around the outer surface of the inner layer 194. The lock assembly 01 may be a continuous or discontinuous assembly. The inner layer 194 may contain one or more ve lock assemblies; Jie The pattern with a special structure (Jia) series of grooves. cams; and the like).

Yv In addition the lock fitting 1517 can be configured to have an inward or outward taper. For example, the Jal 194 inner layer may include a material that is elastomeric to an elastomer (eg PET) and a locking fitting that is provided to taper out during removal from the mold. In some embodiments the 194 outer layer includes a material Moderately hard (Jie) olefins (((olefins)©) that can be tapered out during removal from the mold. The outer layer 199 is machined to receive lock assembly (Jil) AY lock assembly VAY Active outer layer 199 to inner layer VE although not shown; a combination of lock assemblies 199 can be designated by the layers 199 044 which may be arranged within the neck part 11 and/or the body part VTE of the preformed material Ne in some 0 embodiments the inner layers 194 and outer 149 consist of materials that can bond or adhere to each other directly. In sal embodiments the inner layer 194 is bonded to the layer External V4 so that layers 194 and 1949 can be easily separated Sle (Pla sale) Rotation However; 140 of the previous article, 1949, spaced between the upper end. For the outer layer, vo formation. A skilled fabricator can choose the thickness of the layers 144 194 to achieve the thermal properties; durability; and/or other desirable properties of the das preformed material. Figures VY (NF) show modified embodiments of a portion of the preformed material 191 ! that extends VAY in Fig. 7 (at the edge of 1910). The preformed material contains NF in the form of the preformed material 0. In some embodiments other than ©19 the length of part of the upper surface of the cervical part T is less than approximately 790 of the specified wall thickness YAY; the length is 17 for edge to approximately 750+ VAY for edge LF in one of the unspecified embodiments; the length of “.”

LF of wall thickness 1 of the cervical part. in certain indefinite incarnations; The length of 8 Yo of edge 197 shall be approximately 755 7770, AYO or JA or ranges including such ratios for thickness T aad of the cervical portion. In the indefinite embodiment of AT; The length of the VAY edge is approx

Ya

LF to 7270 from the wall thickness of 7 for the cervical part. In another embodiment, the length 0 is approximately 740 less than the wall thickness 7 of the neck portion. YY0 edge ""?. Edge 777 extends inwards and defines the upper surface Defines the inner surface of the preformed material; or spacing between them. © edge length can have notches 17 Neck part VAY has similar or different About the length of the edge YYY that the neck part contains other fittings (sa on; ad to receive the closing tool. on the grooves; etc.) to connect with the closing tool. The lila preforms (example; cavities; formation described above) can be modified by adding one or more layers to achieve the desired properties. An insulating layer can be made on the body parts of the preforms. Preformed Material YY Figure 4 shows a modified embodiment of the preformed material which designates the 7017 coupling assembly formed to receive the 17 preform 707 on the neck portion of the locking tool. Its ordinary meaning, and may include, without being restricted to, a property such as a positive (eg, bump, hump, etc.) or a negative property (eg, a hole, a cavity, etc.). To attach to the latching device to keep the latching device in the desired position. © Coupling assembly 7097 shown is in the form of a cavity modified to receive part of the 0 closing device. Coupling assembly 707 may extend or extend approximately one or more portions of the preformed material Other embodiments The conjugation structure 707 extends approximately the entire circumference of the prematerial (BY 0 _ formation YY the conjugation structure Yo has a semi-circular (Jha) curve); a 7-shaped la or any other suitable cross-section of the material preformed. Although it is not shown; Mount 707 can be a protrusion; such as a throat bump; specified by optional YF overlay; The preformed material TY may consist of a combination of coupling assemblies yo such that sealers of various shapes may yo connect to the vessel made of the preformed material. The distance between top surface Yio Fittings YoY and Fitting Fig. 7097 is determined by the geometry of the sealing device used to seal and seal the preformed vessel XY

Figure 4 1(a) shows vessel 711 produced from the preformed material YoY of Fig. 4. A VAY sealer is attached to neck portion 17 of vessel 7111. The sealer is one-piece or polystyrene Sealer 713 can be temporarily or permanently attached to the vessel YAY The sealer 71 LIS can be removed from the vessel YI when the liquid is consumed. © In other embodiments a portion of the YOY sealer may be removed while a final portion of the YOY sealer is still Gale in vat 111 during consumption. The YF sealer can be semi-permanently or permanently attached to the 711 vat. If the sealer 707 is attached to the bowl in a calla-like form the sealer 707 can be withdrawn from the bowl .711 in one embodiment; If the YAY sealer is always attached to the vessel YY) vessel 711 and the TIT sealer will generally form one body 0. As shown in Figure 1(b); the upper surface Yeo of the preformed material and the sealing device can be ile YAY leakage YY) preferably either an airtight seal or any sealant that prevents the liquid from escaping between YOY bowl and YY sealing device optional; The 711 can have a removable gasket or wile. For example JA the vessel 711 may have a leakable pile tie Al DU membrane attached to the upper lip of the vessel; or part of the 70” sealant that can be removed. The removable sealant can have a small handle or loop to make it easier to grip and remove the sealant. alternatively; Pile leakage 1771 may be formed by a membrane or plate which may be broken or fragmented in order to open the vessel .711 in some embodiments; Ye The outer layer 707 of the vessel 711 is made of high strength material or generally hard material ' (eg 00); so that the flange 709 can be pressed between the sealer YY and the outer layer Y ov to ensure that the integrity of the leakage pile YY is maintained as shown in Figures 4 1(a) and 1(b); the sealer contains YAY on the X10 body and the TVA cap The 715 body can be attached to the YA cap with a YY hinge (Je) a die-cast yo material that acts like a live hinge or any fixture to allow movement). The cover 708 can be secured to the body 711 with a latch or a latch 7117 (latch) (fig. 4 ).(1) The YAY latch can be moved to move the cover 708 in order to open the YY locking device. Alternatively, it can

Ye from body 718 hinged pieces so that the cover can be removed y10 and body 718 the cover is in the open position; Components can be edited outside of 701 when the locker is .?0 ? attached to the end of the neck. After removing the required amount of food from the bowl 117 (YN) the desired amount of food is removed from the bowl 117; the lid 718 can be returned to the closed position and to re-seal the bowl. © Giving with the neck part. (Say In YAY form the body 716 can be coupled to the closing device alternatively; the TY can be on the neck part 705 for example; the body can be closed on one or the aid the NYY part has Body 8 is circularly coupled to the neck portion as a passive feature; 771 (clouser attaching structure) over accessory locking fittings

Yor permanently attached to the outer layer 711 as a cavity or cavity. The Ve body may be coupled by a welding or melting process (eg, induction welding); frictional interfacing adhesive, for the reception of many types of sealing devices; Like 711 and/or similar. bowl can be machined (or Bapco Closures Limited (England), seals produced by BAP®, similar seals); screw caps; pressure sealers; and/or something similar. 0 for the reception of shaped sealing devices 711 a skilled craftsman- can design the end of the neck of the vessel 0 different. Particularly very suitable 111 by continuous reference to Fig. 4 0 (a); The container (ite) is generally shaped during the 711 process for hot filling applications. The bowl holds a hot substance. After blow molding or hot filling; Final dimensions are preferred because they actually match the initial dimensions of the preformed material. 701 for vessel neck part 0 additionally; This results in a reduction in the dimensional differences of the neck-end notches. For example

PET example; The inner layer of 7484 is composed of food contact material; ml lt J material PP eta) contains materials that can be formed into a mold 7007 The outer layer includes homopolymers of crystalline or semi-crystalline material; lamellar. Homopolymers and compositions of that source ¢ and other refractory materials (copolymers Yo part Yar copolymers described herein) which are suitable for hot packaging. The outer layer provides dimensional stability even during and/or after hot filling and the width of the cervical layer 17 can be increased.

AR

From the ITY of stability to the dimensions of the cervical part (Jal or to reduce, to add or decrease; on 70092 the exterior on a material having thermal stability 17 is preferred; to include one of the layers constituting the cervical part is high; however The neck portion can also be made of materials with low thermal stability, especially for applications where hot filling is not required. ° Additionally, the dimensional stability of the 7007 outer layer ensures that the YOY sealer remains attached to the 711 vessel. For example, the coating 7007 may include a high strength material (eg PP) and can hold its shape thus preventing unintentional loosening of the lad coupling YOY from the bowl 711: Referring to Fig. 1(c) Vessel with necked portion has accessory sealing fittings 0 for occlusal fit. Neck portion in the embodiment shown has accessory sealing fitting 1717 in the form of positive feature; Jae protrusion; rim; and the like THAT AND SUITABLE FOR ATTACHING A YAY SETTING TOOL The locking attachment accessory 17717 can form annular projections extending circumferentially around the neck portion. The sealer 70 may have a one-piece or multi-piece fitting. The shown 111 receptacle contains Tapering wall forming the end of the neck. The 15 ÷ d taper from the end of the neck can be produced against the 711 snap-on cap and is leak-proof. 0 shows Fig. yo (part of preformed material 771 according to another embodiment. Preformed material YY. contains support ring 777 and body part 774 extending into Jind from it. First material 771 contains Slot 777 at its upper end Neck end of preformed material may or may not have notches In some embodiments the notches are attached to the neck portion ©oY?? of the preformed material It is expected that preformed 771 can be formed without a ring Backing Where the support ring and/or notches of the preformed material Optional Jay 7718 can be formed in subsequent operations Figure 11(b) shows the preformed material 771 after the YYA accessory locking fittings have been attached to the neck portion ©77 It is anticipated that notches; fittings associated with the YO occlusal cap; or other type of clamping or jointing fitting that may be attached to the neck portion of the YYO before or after the manufacture of the preformed 771 vessel. z vy can

YY. For preformed material Y YA (clouser mounting structure) Attachment of closing mounting structures after the preformed material has been molded; It is preferable to form in a mold by blowing it into a container. Preformed materials can contain other parts that are attached or linked to each other and to which at least one part is attached to each other. Figure 11(c) shows the preformed material in object 747 of the preformed material. The preformed material contains Yo from the neck end ©

Yor for the lower part You shown 774 on part 78 which is associated with the upper end of the preformed material ;77. Part 78 includes different materials and/or microcompositions in some 1507 (lower portion) much more than the lower portion (microstructure).

YY on a crystalline material. So the material is preformed YA embodiments; Part Includes Suitable for hot fill applications. The bottom 757 may be amorphous which facilitates the -0 blow molding process. in some embodiments; TOP 778 INCLUDES MATERIAL The skilled fabricator can select the material the YOY pre-material is different from the lower portion under or at the support ring. You may configure. in some embodiments; Top end placed to 11 (c) single-layer walls or (re in figures nd) have preformed materials : 8 multilayer. Ve may have preformed materials; including single and multilayer preformed materials Raw material containing 11 layers; described above and other forms and combinations.

YY. The preformed material .7174 die may be molded on a 777 taper and end in a blow mold to form a container in the form of a jar; For example. A jar or support ring 7700 other similar containers have a mouth or opening larger than the opening of the bottle. Material 0 shall preferably be formed to interface with a 1779 device and one or more YVA accessory sealing fittings embodying a primary material having a VY end snap closure or other type of sealing device. The figure, which has a YAY on the body part, shows a cervical YA without notches. Includes preform 780 and neck end 787. The preform may be YAY containing a tip suitable for blow molding into a container. The preforms shown in Figures YO may be single-layer or multilayer primers (eg have the layers described above). 17 and the formation of the preforms described above without a neck end. (Kay vy those depicted in Figures -1) 18 For the Jie process preformed materials can be subjected to selecting and blow molding. Nickel Ae Layers (eg preformed materials in abt both) in a similar manner. The vessels described above can be formed by various in-mould (M1©) processes (including extrusion by blow molding); eg Detailed description of the lids 7- As described above, the lids can be used to seal containers, as is used in Hanaa: The term “cover” is a broad term and is used according to its normal meaning and may include, without limitation, lid. (includes snap-on cap; inverted cap; o bottle cap; bottle cap 0 notched; sealing cap); crown (apical) cap; cork (natural or synthetic); cap seal BAP® perforated seal”; flange (quot; flange to cup); multi-piece lids (example or similar lid); Snap lids; Bapco Closures Limited (England) produced by and/or the like. Covers may contain one or more features that provide us with additional features. Some caps may contain one or more of the following: clear seal feature; call compartment; resistance knob for easy removal/placement of the cover; spill prevention feature; and fittings from that source. A one-piece or many-piece fitting forming for coupling to the vessel in the form of an Ake SU that may be permanent or temporary for example; The covering shown in Fig. 1(a) consists of several combinations 0 of a single-layer construction. VA expressions can be used as segments. The cap shown in the figure lala jl 'cap' and 'stopper' are interchanged here. It is envisaged that the lids can be used with juices; Fro boxes (especially boxes used to hold foodstuffs; ex.)” and cartons; canned food and other products. As used here, the expression 'bottle cap' is a common expression and is used according to its normal meaning and may include, but not be limited to, Ye bottle (Je) glass or plastic bottle Jie on a suitable cap to be attached to the bottle formed on Typical way to hold alcoholic beverages or juices) and may or may not contain

Ve contains lichenification. Bottle caps can typically be removed with a bottle opener, as is known in art. The term 'notched bottle cap' is a broad term and is used according to its normal meaning and may include; without limitation; A cap (eg screw cap) suitable for attaching to a grooved bottle. Given the current disclosure; Grooved cap avatars can be modified to create caps for bottles or other types of caps for different formulations. in some 0 embodiments; The lids can be grooved to a container or fixed to a container by several methods: “induction welding” (induction welding) “photosynthesis” (Jia) multi-step molding; adhesives; thermoforming; and the like. One embodiment of the 307 cap that can be associated with a product; As part VA the figure (Fig. vet on internal grooves 07 shows the neck of the vessel and in the shown embodiment; the cap contains 0

YoY which is shaped to mesh with the grooves of the neck part so that the lid () can be coupled to the bowl in a way that can be removed. The cap 07 can be attached to the container (eg bottle) to close the opening or to install a clear stopper or to attach the 01 to the main body TY the mouth of the bottle. Cap contains or 11 with 01 connector (or dry) coupled to body VOY anti-stopper; Such as collar when YY and modified so that the VY conductors are broken more. The size of the conductors Vo AA and the collar can be set indicating that 01 the cap 907 is removed from the receptacle; The body 0 cap 207 is thus separated from the accompanying vessel. Although it is not shown; Other types of clear sealant formulations may be used on the 901 body PVT treatment. The texture processing surface can contain; and/or something similar to facilitate interfacial interaction cig pad 0 surface; like grooves

Frictional FY with cap Ye and may or may not contain 01 relating to Fig. 90; The 707 housing on the Lad body shown includes an optional inner seal. It is YoY and the cover (liner) Alay includes YAY for the cover shown in the form of a liner that is contained within the outer part 906 the inner layer to be in contact with the food or liquid and may be FYE The liner can be modified 201. for the body a large part; Or FYE leak-proof with the lip that forms the opening of the bottle. So; The liner YO of the cover contact surface (LS) shall be part

Yo Active and passive insulating liner. Jie is insulating liner; YY E liner may be a flavor barrier. 06 Jill lining and compositions can be from that source, eg (carbon gas barrier that prevents or inhibits the passage of oxygen at a rate of «H]”; carbon dioxide; abrasive abilities; FYE Ah (01:01: 000; and the like within. In some embodiments the © (oxygen) oxygen scraping (Jl) gas scraping Fie against the lip of the bottle to prevent the liquid from escaping from the airtight vessel 04 liner can be pressed Gas barrier 06 Sealing by cap 207. In one embodiment the liner is ©1064 The liner is AT which prevents or dampens gas from escaping from the vessel. For example aie about a flavor barrier that can 0 (example; thermoplastic material) (polymer) consisting of a polymer WE can be the liner (Jl) which acts as a flavor barrier to ensure that the food is retained inside the container desired flavour. Does not impart flavor and/or odor to 901 to ensure that the body YE is delicious The liner can help; the food in the bowl. many times; Some flavorings and/or abrasives or polypropylene such as polyolefins (eg polyolefins) are used to form a container or lid eg bottle cap according to their physical properties. (polyethylene) (eg endurance; toughness; impact resistance; and/or strength).In certain embodiments Poly may appear to be preferable to properties lly one or more physical properties (polypropylene) unfortunately » It is for polypropylene (PET) as the physical (polymers) for Y-polymers in certain circumstances to reduce or disperse an unpleasant flavor on the contents of the bottle or (polypropylene) from the contents. So it may be (aromatic) Removing desirable flavors or aromatic components Able to distinguish the change PP A person consuming food that was previously in contact with a flavor preservative so that it is not affected (06 Aled) may include of ee with flavour. It is preferable to FYE the food in the bowl in general when the food comes into contact with the yo liner in contact with the foodstuff. FDA by Lede Flavor preservative is an approved material Car:

in some unspecified embodiments; The flavor preservative includes PET (as the first PET); phenoxy type of thermoplastic; and/or something similar. Body 01 is therefore made of an abrasive; Jie is made of polypropylene to provide the desired physical properties and the liner 14 includes PET as an effective flavor barrier © to ensure that the contents of the bowl retain the desired taste. The liner 314 is expected to be constructed of any material suitable for food contact with the container. in some embodiments; The liners 06 may be of a foaming agent described herein which may or may not alter the taste of the bowl contents. additionally; The thickness of the ©064 liner can be increased to prevent gas or other fluids from passing through the liner. Optionally the 906 liner can be of single-layer or multi-layer 0 construction. For example; The liner “1” may include an inner layer of PET (ie, the layer in contact with the container contents) and an outer layer of foaming material.

Liner 14” may contain a layer suitable for food contact and one or more layers acting as a barrier; Similar to the preformed materials described here and in some “an al on 0 . . Examples » Lining 06 can include a first layer and a second layer where the first layer 0 > includes foaming material and the second layer includes barrier material. So the second layer can reduce or prevent fluid migration through the liner 906 and the first layer insulates the cap YoY in some embodiments; Liner 16 contains a layer of PET and a second sale including layer. The PET layer is preferably the lowest layer in order to form a sealant with the lip of the container; maybe

Xe The second material is EVA or other suitable material to form part of the lining. in some embodiments; The liner ©06 in Fig. 19 can be primary and inserted into the body .301 eg the body 01 can form a perfect screw-on cap used to seal a bottle. The liner can be 906 by cutting off a portion of the plate; which will be described below. Then the cut out ?0© liner UW can be inserted into the body 01 YO and placed as shown in Figure NV alternatively; The liner 04 can be formed inside the body .0 for example; the liner PY can be formed by an in-moulding process, such as over molding. At least part of the liner 16 can be formed by a spray coating process.

vv (eg (polymer) monolayer liner can be sprayed and coated with a polymer or other material described herein) to produce a (phenoxy) phenoxy-type thermoplastic (PET) multilayer liner. or 01 in body 306 an additional feature can optionally be provided whereby the liner can be kept so that the liner remains attached to body 01 to body 704 attaching to the container and liner 0 can be attached to the container 90 lad after it is Separating the body from the bowl Alternatively, the TY can be mated

Fie and lining are detachable. For example; The liner can be moved “01 so that the body is an induction welding process. Jie then to the bowl opening by means of a welding process; ©01 to the body An additional feature is provided when at least part of the cover 207 is made of material to supply the 0 with an ergonomic gripping surface so that the user can hold the cap 907 comfortably. Body 01 comprises material of sufficient hardness; (e.g. PP (compressibility for a comfortable grip) (Jia) foaming material); and/or the like. In some embodiments the outer part 1 of body 01 may include foam to increase the footprint of the part The outer TY lid and to provide the user with greater leverage to easily open and close the 907 lid.For example, the VO lid YoY lid has an internal grooved surface that is shaped to match the grooved surface of the container externally.An enlarged external part can or is supplied 711 with greater leverage: so that the user can easily rotate the cap 07 to assemble and remove it from the container and favorably; the same or similar amount of material used in a conventional cap can be used to form a cap of a larger diameter. Embodiments At least part of the parts Y. can be foamed for a very lightweight cover due to the low density of the foam material Reducing the weight of the 707 cover can desirably reduce the transportation cost of the cover Amount of material used to form (TY) The foaming material of the lid (YY) Lila can reduce the lid; Because re-foaming material may contain a large number of voids. Yo The caps described herein can be similar to or different from the cap shown in Figure Les V9 Relates to Figure Fe The cap 370 with body 771 includes a part INTERIOR TYY AND OUTER FYE The wall © shown includes parts PTY;27. may appoint

Ya

At least part of the vessel interior can be shaped 300 Inner 777 by YY process Optional PPT Inner consists of one or more injection molding grooves; spray coating or other process described herein to form a portion of the product. on FEY thermoplastic materials in some embodiments not specified; The inner part includes “PET” and/or other materials (such as (polyolefin) polyolefin “(phenoxy) type © to 1”(e) unspecified embodiments of the lids. Figure shows (YY) are described here. The figures show the two components of a WEE part and an inner part of a VEY containing a YE outer part. Cover (a)"1

VEY is the part delineated by at least the two outer parts VEL of the inside of the vessel into which the inner part FE (eg notches) of the inner surface of the YEE cover and the inner part of the VEE is placed however; The FEY inner part is not to be placed inside the outer ©4400 covering You cover (YY). Malaga 754 Including layers combination Including layers Layer 767 External surface Ye Covering in one layer or FUE Can include Fe middle layer (including top of wall ) Cover SUA has a more grooved contact surface FT. Designates inner layer 1 ? (d); 1 Cover may contain parts or layers of varying thickness. As shown in the figure Includes part or layer At least one of the lid 370 has a thickener 77 has an upper portion 174 has an inner portion 176 the lid shown

NVI with a thickness greater than the thickness of the parietal part 0 YAY and which includes the YA band: Figure 17(e) shows a multilayer cover 7 with one or more connectors 284. May PAL for the cover YAY Attached to the inside to 1"(e) to any fitting(s) or design 18. Lids shown in figures (e) 71 to 08 are suitable for coupling with vessels. For example, lids in figures may have It is foreseen that the lids (0 USE) 71) on a similar construction to the lid of Figures 81-11(e) described herein may be attached to the vessels by a groove-joining process; Yo-welding or melting (eg; induction welding); or with adhesive; by means of frictional interaction; or similar. With straps however; the lids may not contain (0) YY -18 The lids are placed via shapes or may contain guides or other tamper-proof fittings. that the caps dd) on Figs. 81-1"(e) are shown as screw caps; Other types of caps (eg caps with a multi-piece construction; flange caps that open and close; a cap with a threaded connection on both ends; or the like) have similar assemblies.

° Lids may have a compartment or compartments shaped for storage. The compartments may contain extras that can be added to the contents of the accompanying container. Additives affect the properties of the ingredients in the bowl and may in Alls be solid; invasive and/or liquid. in some embodiments; Additives may affect one or more of the following: odor (eg additives can include a lubricating gas/liquid); flavour; color (eg; additive including (ima

0 dyes; etc); Nutritional content (eg additives including vitamins, protein, carbohydrates, etc.). formulations from that source. Additives can be delivered from the cap to the contents in the bowl for later ingestion, preferably to increase the fluidity and consumption experience. The compartment can release the additives while the cap is removed, so that the mixture is fresh. However, the compartment can be opened prior to or after removing the lid from the bowl

19.2. 0 some incarnations; The lid contains a chamber which can be broken (eg Lie) after detaching the lid from the bowl. The chamber may be broken by the process of punching, tearing, etc. The chamber may contain a fitting to release its contents. This fitting may be a pull stopper; Snap-on lid or other suitable fitting for releasing the contents of the chamber The containers may also be sealed with a seal which is detached from the lid.

Glad The seal can be attached to the container before the lid is attached. A _0 sealing process can be used to apply sealant to the neck end of the vessel after filling the vessel. The seal can be the same or different from the liners attached to the caps. The seals may be barriers (preferably) against spilling, to ensure the integrity of the contents of the container. In some cand) court chips de «5B incarnations; Sealant may include foil (preferably

Yo aluminum (aluminum) and applied to the vessel by welding process; Jie induction welding. anyway; The seal can be attached to the container using other suitable attachment operations; For example Jl can use adhesive.

$e Caps may have an inner surface suitable for attaching and securing locking fittings (eg grooves; occlusal cap fittings; and the like). The inner surface may be provided with a somewhat slippery surface to facilitate removal of the cap from the container. For example; The lid may contain a slippery or low friction olefin polymers binder (olefin polymers for example) it may stick or lock with the PET container of the container. If the lid is 0 Therefore, the cap (including snap caps, roll caps, and the like) may be relatively difficult to remove 17. Favorably, a cap with a slippery or low-friction material allows for reduced collar removal by easy cap removal. Low-friction or slippery material Provides enough friction to keep the lid attached to the accompanying container while allowing the appropriate lid to be removed; slippery or low-friction material can be selected to achieve the required 0 removal torque. Interior 377 includes lubricant PY The covering may include oY (referencing olefin or other material with a low coefficient of friction) and an outer part (Je) or a low-friction material c (olefin polymer); Such as olefin polymers on Dada YY polymer and other materials described herein..The coatings described herein may include a slippery (PET cele) 10 or low-friction material that forms an interface with the container and achieves the required removal torque . The slippery or low-friction coating material can be selected based on the bowl material in order to produce the desired frictional reaction. The lid is expected to be modified to join the (inner most layer) formwork described here with an edge gate to form the innermost layer with the vessel. 0 : Preformed, single and multilayer sheets J gall Detailed description -* Cross-section views of the plates. The thickness of the plates (YY, Fig. 7 represents ?(a) is more or less uniform or of varying thickness. The lamella of Fig. 7?(a) is a plate is a polylayer plate 7968 inclusive of the plate of Fig. YY Single-layer PAS (Jas) Desirable thickness depending on; foaming agent eg 3950 PAR as a card and at least part of the sheets shall be included

For example, TAS 90 sheets include foaming material to provide insulation for the packaging in which the Gab is labeled. Optionally, the TA sheet includes one or more bonding layers. For example, Jbl Sheet 790 may include a bonding layer between 2 Layers FA FAY Sheets can be used in multiple applications and can be shaped into several shapes eg (Jd) © _ Sheets (Jie) can be cut by thermoforming or die casting into sheets and/or the like it to the desired shape. A skilled craftsman can choose the shape; command and/or the desired sheet composition depending on the desired application. Figure YY shows preformed material 07 with many layers. The preformed material 0 is in the form of a channel with an actual tubular shape. The shape of the preformed material may be 07; in shape 0 generally circular, oval, polygonal (including rounded polygonal); formulations from that source; And the like. The preformed material shown 407 is generally of circular cross section. in some embodiments; The preformed material 07 may be a pipe modified for fluid delivery; It is preferable to adjust drinking fluids. The preformed material £0 may have an inner 0 layer £06 and an outer layer 407. In some embodiments; At least one of the two layers of 64604 fen may include a combination of layers (eg thin laminate material). The preform £07 may be a tube comprising a sabe suitable for contact with the food material and one or more additional materials having desirable physical properties (structural and thermal properties) jie. favorably Preferably the 504 inner layer in direct contact with fluid 0 does not significantly alter the flavor of the food item it comes into contact with. For example (Jal) Fluid carrier lines for beverage dispensing systems contain polyolefins as flavor abrasives. Favorably, the inner layer 464 would preferably not significantly alter the flavor of the fluid passing through the bore 408 preform 407. In another embodiment the outer layer £07 may provide improved physical properties to the preformed material 407. In the oA embodiment Yee the outer layer 407 may provide increased insulation and/or structural properties to the preformed material 407 eg; the outer layer £07 may In one embodiment it may be provided with increased impact resistance In some embodiments the 405 coating reduces heat transfer through walls

¢Y some embodiments; The outer layer 407 may have a high tensile strength (BLE Y the preformed material .407) so that the highly compressed fluid can be passed through the preformed material so the inner layer acts as a largely inert surface for food contact while the layer acts as Outer (layers) as insulation and/or resistance to external influences.° Of course, Preformed 407 can be used in many other applications. For example » Preformed 407 can be used in hospitals (Jl) as a lead line for medical fluids; manufacturing processes Devices Fluid systems (eg, digestible fluid dispensing systems) and/or the like Detailed packaging description: 01 One or more of the products described may be used alone or in combination in a variety of applications Jie packaging. Figure 4 shows 9 a £37 Slade filling system on a vessel 107, which can be made from the preformed materials described here. A lid ??41 Alen can be attached to the £Y vessel to seal the vessel. Figure YE is also shown Card 4560 is attached to the container 4710 which is in the shape of a bottle.. ve 0 card 4460 can attach to the bottle ye and may be monolayer or multilayer. Card 0 ;; optionally includes foaming agent. The £40 card is best paired with deck 47; For Ee receptacle Card 0 can be attached to the outer surface 447 with the Se shape removed. Card 4546 can be appended during and/or after receptacle configuration ELEY embodiment shown; The £1 card is in the form of an idle sleeve. in any shape or arrangement fe that surrounds at least part of the bottle. The tag is 00 appended (Sad to attach to the bottle and display information though not shown. Luli

Sa lala) with glass bottles; metal cans; or similar. 440 Card 440 Card £40 in other shapes or packaging. For example; Card (Add) can be attached to a box; carton; bottle (plastic bottle; glass bottle; etc. 4.40 cans; and other things discussed herein. Additional; Ye card can be printed optional The outer surface can be processed £57 per 0 card; to obtain a surface suitable for printing

Adhesive can be used to attach the £60 tag to the product. in one embodiment; After the tag is attached to the product; (Say) Spread card foaming £80 to obtain thermal insulation, fluid barrier, Alp layer and/or desired textural characteristics. Preferably set the foam by heating the card £60 Card material can be foamed before and/or after card laying 0 On the EY bowl 0 Of course the foaming material with card 4400 can be affixed directly to the product without the use of adhesives Figure Yo shows another embodiment of the bowl incorporating moldable material The bowl 0 may be similar or different from Vessels described above.In the embodiment shown, vessel 0 comprises lid 407; body 404; and handle £07 attached to body £08.0 Body can be virtually rigid or flexible. Handle 4076 is preferably shaped and sized for comfortable grip By user The body wall £06 may be a single-layer or multi-layer wall Vessel 05 may have any shape, including similar de SU shapes used to hold digestible liquids Vessel £04 can be shaped by extruding the molding process into a mold Blowing. in one embodiment; A plate (eg plates 4 or YA.) is used to form at least part of the vessel 41 by means of a thermoforming process. The E10 vessel may be in the form of a flexible pouch; a food container; or any suitable combination. For example, in one arrangement the sheets are shaped into clamshell packs that are shaped to hold food in Ye, hamburgers, Jie, in another arrangement, the sheets are shaped to form boxes (eg pizza boxes) In another embodiment, material and dimensions can be specified £10 vessel depending on the morphological characteristics; thermal properties; and/or other desired properties.eg. A £70 vessel may include foaming material for effective thermal insulation of the vessel .471 In Example AT a £10 vessel may have walls thick so that the container Yo 41.0 is generally rigid. The figure (YT) shows another product incorporating a formable material. In one embodiment the product 77 is in the form of a tray which is shaped to receive the food material.

¢£ Chinese 17 lbs from a plate during thermoforming. Optionally the tray NY can be configured to fit inside a bowl or box. Tray 567 (or other products described here) can be formed for heat treatment. In some embodiments the tray 467 can be used for reheating and reheating and the tray © can hold food items so that food items can be heated by; for example a heat lamp; microwave oven; oven; toaster heated water And the like. The exact composition of the Tray 77 can be configured based on the type and method of heat treatment. For example; The tray may include a crystalline material (eg, crystalline PET) to increase thermal stability. One or more layers of the tray may be heated during the thermoforming process to a temperature 0.0 higher than predetermined to cause crystallization of at least part of one of the layers. Therefore, at least part of Tray 477 can be crystallized during the manufacturing process. in some embodiments; Tray 77 can include; On a single or multi-layered sheet, Tray 77 contains a first layer of thermoplastic material and an Al layer (eg foam layer). The first layer may include a crystalline material (eg amorphous; partially crystalline or fully crystalline). The EY tray can be used to hold food for use in a microwave oven. naturally; products contain; cg AY is like a pizza box on a similar structure. Products can also be in the form of a box. The package may contain polymer materials as advertised here. The enclosure may include a layer of metal and one or more layers of another material. in some embodiments; A metal can (eg aluminum can 01) can be coated with Jie foaming thermoplastic material. Cover at least part of the outside and/or the inside of the can with foam. b. Crystal neck ends: preferably including plastic bottles and containers In some embodiments, one or more necking-end and/or neck-cylinder materials which are at least partially in the YO crystalline state Such preformed bottles and materials also comprise one or more layers of YY material.

m in some embodiments; The bottle is made by a process that involves blow molding of primary plastics. in some circumstances; It is preferable that the material in its primary plastic form be in an amorphous or semi-crystalline state because the materials in this state can be blow molded easily, as fully crystalline materials cannot be molded in general. anyway; Bottles made wholly of crystalline or semi-crystalline material may not have a suffix; Sufficient dimensional stability through standard Adee hot fill. In these circumstances, a bottle containing a crystalline material is preferred; Because it will retain its shape during hot filling operations. in some embodiments; The plastic bottle has the characteristics of both a crystalline bottle and an amorphous or semi-crystalline bottle. By blocking out at least part of the upper 0 part of the crystalline preformed material while keeping the body in the form of an amorphous or semi-crystalline initial sale (sometimes here referred to as "amorphous") one can make a starting material that will be molded Blow easily while maintaining the necessary dimensions in the neck area during the hot filling process. Some embodiments contain both crystalline and amorphous or semi-crystalline regions. This results in the formation of a raw material with sufficient strength to be used in widespread commercial applications. iLo

One or more of the embodiments described herein generally yield metamaterials having a crystal neck; : which are then blow molded into beverage containers typically. Preformed materials may be single layered; that; Includes 1 coat of base material; Or they may be multi-layered. The material in the example of these layers is a single substance or may be 0 a mixture of one or more substances. In one embodiment a product is supplied to have a neck part and a body part. The cervical part and the body part shall be one uniform layer of material. The body part is mainly amorphous or semi-crystalline; And the cervical part

Basically crystalline. With reference to Fig. 1 the preferred preformed material Ve is envisaged. The preformed YO material Ye may be made by injection molding and is known by art or by methods. declared here. Preformed material 1 has a neck part YY and a body part (VE) uniformly composed (i.e., as a single, or unitary) composition.

embodiments; Provides the constructive arrangement of the preformed material; when blow molded to dala) with greater dimensional stability and improved physical properties compared to a preformed material composed of separate cervical and body parts; which are linked together. by arriving as a crystalline state in the neck portion of the preformed material during the molding step;

0 The final dimensions are substantially the same as the initial dimensions; Other than when additional heating steps are used. cl) dimensional differences are reduced and dimensional stability is achieved. This results in consistent performance for the caps; Such as nicks on the neck Ales and reduce the abrasion rate of the molding process.

Whereas a preformed, amorphous material is preferred for blow molding.” A bottle with 0 greater crystalline property is preferred due to its dimensional stability during the hot filling process. Accordingly, the preformed material formed according to some embodiments generally has an amorphous body part and a generally crystalline neck part. for making crystalline parts and generally amorphous parts in the same preformed material; One needs to achieve different levels of heating and/or cooling in the mold in the areas where the crystalline parts will form compared to those where the 0-amorphous parts will generally form. Different levels of heating and/or cooling can be maintained by thermally insulating zones with different temperatures and grooved extrusion thermal insulation can be achieved; The core and/or cavity interface using a combination of high 0 | and low heat conductors as adjoining or detached materials on the meeting surfaces of these areas. Some of the preferred processes produce preform making within the preferred cycle times of 0 Ye for unwrapped preforms of similar size by standard methods used in preform production and additionally; The preferred processes are enabled by the design used for the tools and process techniques to allow the automatic production of crystalline and amorphous regions in special regions on the same preformed material. in one embodiment; Provide a mold for making the preformed material including a YO-neck part having a primary mold temperature control system (eg; cooling ducts; heating); a body part with a second temperature control system; and its core has a third temperature control system; in which the system is

B. The first is to control the temperature independent of the second and third systems to control the temperature. The cervical part is thermally isolated from the body and the core. Cooling of the mold in areas where the material surfaces are preformed and in which the material is generally amorphous or semi-crystalline is preferable can be achieved by a cooled fluid circulating through the mold cavity and core. in some embodiments; A mold construction is used similar to normal injection molding applications, except that there is a separate fluid circuit or electric heating system for the areas of the mold in which the crystalline portions of the preformed material will be formed. Mold body thermal insulation can be achieved; Die neck end and core section by using inserts with low thermal conductivity. It is preferable to finish the neck parts; neck end; and/or the neck cylinder of the mold 0 at a higher temperature to achieve laf quenching which induces crystallization of the material during quenching. The above embodiments as well as additional embodiments and technologies relating to preformed materials with both zones and amorphous or semi-crystalline are described in US Patents No. 3,717,514 to “Collette et. al.9l/47 to ¢Collette et. al US Patent Published No. 2003/0031814A1 to Hutchinson et. at. and PCT Publication No. MM 8/2401 WO to Kochet.al. ah 0c <- Detailed description of some of the preferred items: 1-0 General description of the preferred items additionally » Products described here can Described especially for a particular substance; Jie polyethylene terephthalate (PET) or polypropylene (PP) (polypropylene) 00 Preferred methods may be applicable to many thermoplastics ig AVI including those of polyester types (polyester) and polyolefin Suitable materials include, but are not limited to cs AY; foaming materials; Polymers and thermoplastics; thermoplastics such as polyesters polyolefins including polypropylene 5 and polyethylene polycarbonate polyamides (00178001085; including nylon compounds) (nylons) (example “6” “Nylon 66” “Nylon” (MXD6) polystyrene “(polystyrenes) epoxies” (acrylics) YY

EA

grafted and/or (polymers) blends; Polymers “copolymers” are copolymers or part thereof that have another group (monomers) modified (polymers) of -(olefin) modified polymers (polyesters) as a side group; such as Polyesters These materials are used alone or in combination with each other Examples of more specific materials include, but are not limited to covalent ethylene vinyl alcohol pads © J EVOH acetate (ethylene vinyl alcohol copolymer) (ethylene acrylic acid) (ethylene vinyl acetate) (linear low density polyethylene) linear low density polyethylene (“EAA”) (1,5-naphthalate) and \ 0¢— naphthalate (polyethylene 2,6-)-707 polyethylene «(“LLDPE”) (polyethylene terephthalate glycol) polyethylene terephthalate glycol (PEN) 0 poly(cyclohexylenedimethylene (©011); cyclohexylene dimethylene terephthalate polymer «(cycloolefin) circular olefin «(polystryrene) polystyrene cterephthalate] poly (methyl” (poly-4-methylpentene-1) 1- poly- ;- methylpentene (copolymer) copolymer polyvinyl (acrylonitrile) acrylonitrile «(poly(methyl methacrylate) methacrylate) styrene ¢ (polyvinylidine chloride) polyvinyl chloride «(polyvinyl chloride) chloride 0 acrylonitrile-butadiene-styrene e(acrylonitrile) acrylonitrile «(styrene) polybutylene terephthalate «(polyacetal) polyacetal «(acrylonitrile-butadiene-styrene) poly «(polysulfone) poly Sulfone <(ionomer) ionomer “(polybutylene terephthalate) ?- dioxy 01 Polytetra-fluoroethylene (polytetra-fluoroethylene) copolymers and copolymers (polytetramethylene 1,2-dioxybenzoate) ) benzoate 90 and ethylene terephthalate from ethylene isophthalate. Hana, the term “polyethylene terephthalate glycol padi LS (copolymer) refers to a copolymer” (01:16 (polyethylene terephthalate glycol) additional; cyclohexane (comonomer) to which a PET co-monomer of YO (011014) is added; in appreciable amounts (eg, approximately 8 or (preferably) amorphous (cyclohexane di-methanol) methanol PETG by weight) of mixture 017. In one embodiment; be yey item

£9 essential. We can obtain suitable PETG materials from many sources. One suitable source is Voridion, a division of Eastman Chemical Company. Other PET copolymers (copolymers) include CHDM at lower levels so that the resulting material remains crystalline or semi-crystalline. An example of a PET © copolymer containing low levels of CHDM is .Voridian resin 9921 in some embodiments; Say use of polymers that have been grafted or modified. In one embodiment polypropylene (©00170007160; or other polymers with a polar group including, without limitation, maleic anhydride) may be grafted or modified. “(maleic anhydride) glycidyl methacrylate “(glycidyl methacrylate) acryl <b SL Aw (acryl methacrylate) 0 and/or similar compounds to improve adhesion. In other embodiments polypropylene refers to poly Clarified polypropylene As cla is used, the term “clarified polypropylene” is broad and is used in its normal sense and may include, but not be limited to, polypropylene which includes inhibitors. Nucleation and/or filtering additives Polypropylene - 0.0 filter is generally a transparent material compared to a homopolymer or copolymer of agglomeration for polypropylene Inclusion of nucleation inhibitors helps prevent and/or reduce crystallinity that contributes to the cloudiness of polypropylene within polypropylene (Sa). Obtaining polypropylene filtered from Numerous Sources Je Daw Chemical 00 0 convert alternatives Say Addition of nucleation inhibitors to polypropylene An appropriate source of nucleation inhibitor additions is Optional Schulmar. Materials may contain microstructures Jie fine layers; microspheres; and constructs from that source. In certain embodiments the preferred materials may be primary; before it is consumed; after - its consumption; re-milled Recycled and/or federations from that source. Yo as used here includes “PET” but is not limited to; Modified PET and also PET mixed with other materials. An example of modified PET is IPA PET 'high' or =PET Modified IPA indicates PET with a TPA content greater than about 77 by weight preferably; Yves

including approximately 7-70 IPA by weight; It also includes about TPA 7100-8 by weight. PET may be pre- or post-consumer.; recycled or reground PET; polymers

PET + copolymers and formulations from that source. In embodiments of preferred methods and processes one or more layers may comprise dle layers © UV protective layers oxygen filtering layers oxygen insulating layers (©078); carbon dioxide filtering layers Carbon dioxide insulating layers and other layers as may be required for the special application. For broad expressions used according to their normal meaning and referring without limitation to materials that have permeability to oxygen and carbon dioxide less than one layer or more when used in preferred methods and processes. The expressions 'UV protection' and the like are broad expressions and are used within their normal meaning and indicate, without limitation, materials that have a UV absorption rate greater than one or more layers of the product. As Hana uses, the expressions 'filter or scrape oxygen' (oxygen) and the like with 0 are broad expressions used according to their normal meaning and denote, but not be limited to, substances having a lef rate of oxygen uptake by one or more layers of the product. As used (lia) the term 'oxygen insulator («078©6)" and the like is a broad term used in its normal sense and denoting, without limitation, active or passive substances in nature and slow transport of oxygen Jala (oxygen) and / or outside the product. carbon dioxide from one or more layers of the product.As used herein, the term “carbon dioxide buffer” and the like is a broad term used within its ordinary meaning and referring without limitation to active or passive substances in Nature YO and slow transfer of Jala (carbon dioxide) into and/or out of the product Without wanting to be bound by any theory students believe that in applications where a carbon product is involved (08:0008160); “Jie A soft drink (non-alcoholic); in a carbonated product

On top of it, one or more layers of the product containing a carbon dioxide filter to saturate the layer that contains (carbonation) allows an increase in carbon dioxide. The filtered carbon dioxide, which escapes into the atmosphere from the product, leaves the product layer first instead of the carbon dioxide contained inside. As used by Hana, the expressions “cross-link” or “cross-link” and the like are broad expressions and are used within their normal meaning and refer, without limitation, to covering materials that gradually differ from a small percentage of epoxy binding. The cross-linking material to be completely cross-linked includes thermo-hardening materials. The cross-linking ratio can be adjusted to provide the appropriate percentage of (epoxy) resistance to either chemical or mechanical use for special conditions. Hana Van 0 also uses the term 'binding material' ' is a broad expression used in its ordinary sense and denotes; without a liquid; or a suspension that includes a substance that helps bind two materials together Sle exclusive to including but not limited to adhesives; surface modifying agents; iin physically and / or the active substance, etc.?- Preferred substances.. | Alma 1

Tal) in a preferred embodiment the materials comprise thermoplastic materials. includes a preferred embodiment of thermoplastics (phenoxy) of thermoplastics.” A phenoxy type ‘phenoxy’ (thermoplastics); as this term is used herein includes a wide variety of materials including in One embodiment; the material comprises resins .544// WO 70477 those discussed in—a subset of epoxy resins (TPES) type 0 thermoplastics. Type-phenoxy phenoxy for thermoplastics; thermoplastics; hydroxy-phenoxy polymers are preferred, of which e (hydroxy-phenoxyether polymers) (polyhydroxyaminoether copolymers) is the most preferred additive. Polyhydroxyamino acid copolymers See eg US Patent Nos.: 1,800,017 Aspenchart (PHAE) Ye £0,YV0,A0Y 50, £1,44Y (0A) £,FVT OAT ELVA (1,011,11)

oY (WO) rolling mill (WO) burner (WO) cutting numbers/s PCT applications for TPEs in certain embodiments; 114155 is WO AAV E£3A thermoplastics used in phenoxy ) The phenoxy type Preferred embodiments preferably include one or more of the following species: (hydroxy-functional poly(amide ethers)) (1)(° de) or Ib dda which has repeating units represented by any of the formulas

OH 0 0 OH a | .

OCH,CCH,OAr——NHC——R'——CNHAr——OCH,CCH, 0A” 8 R rod IT

Lodo mdr) Ib n or oH and OH 1 am aa

R R 8 containing (poly(hydroxy amide ethers)) units (poly(hydroxyamide ethers)) (0) (1) dlc or IIb “la bis represented independently by any of the formulas

OH 0 0 | i 1 1

OCH,CCH;0Ar——NHC—R'——CNHAr ):

OHQ0

I 1 | | Ib

OCH,;CCH,0Ar ——CNH——R'——NHCAr , E , or Tol -] Sodium vo Ie oy (amide- and hydroxymethyl- (?) functional polyethers

TIT containing repeating units represented by the formula 40 polyethers) 7 7 ffm 111

R Xx R 1x n containing (hydroxy-functional polyethers)

IV by | 2 for alias formula 2 > 4 none Iv 7, (hydroxy-functional poly(ether (clad) 0

Vb or Va containing repeating units represented by the formulas sulfonamides) |

R 0==§==0 R 8

L

containing bis (poly(hydroxy ester ethers)) poly (hydroxy ester ethers) (1) 0 :71 represented by the formula rd 1

OHO c blah blah blah wr CH, vi

R 1-{x+y) R for 8 X n containing (hydroxy-phenoxyether polymers) (V) 'VII' repeating units of the formula

OH OH a vii

Lo containing (poly(hydroxyamino ethers)) poly (hydroxyamino ethers) (AM)

VII repeating units represented by the formula

Oh oh

{conforms vill 0 © where each Ar individually represents a binary aromatic group “LS” a divalently substituted aromatic group or a hetero aromatic group (Auli) or a combination of different divalent aromatic groups substituted aromatic groups or hetero aromatic groups where R is a single hydrogen or a hydrocarbyl group ( hydrocarbyl) 01 monovalent; Both Ar are divalent (aromatic) doles or a combination of divalent aromatic groups bearing amide or ¢ (hydroxymethyl) groups each Arp They are the same or different from Ar and individually bear a divalent aromatic group. Substituted or hetero aromatic group, or a combination of different bivalent aromatic groups. Substituted aromatic groups or hetero aromatic groups ¢ (hetero aromatic). Jie divalent aromatic group sal sill bivalent substituted aromatic group hetero aromatic bivalent; the alkylene group is divalent; a divalently substituted 0 (alkylene) quinine group or a divalently substituted hetero alkylene group; or a combination of these groups; Ry is individually a monovalent hydrocarbyl group; A is an amine group or a combination of a different amine group; X is an amine “(amine) arylenedioxy arylenedisulfonamido or 17 41 arylenedisulfonamido group

This is (arylenedicarboxy) or a combination of these groups; Ans is the set '"Cardo Alias "(cardo) by any of the formulas: rR? rR? Rr? rR? .© | a Rr? >(Or Rr? R! » R? 0 LN R? R? 7 Rr? ® ol R2 NR; NH where Y is zero (none); a covalent bond; or a bonding group, where © includes the appropriate bonding groups, for example, an oxygen atom a sulfur atom a carbon atom a carbonyl atom ([ c “his” “sulfonyl atom” or “dc gana” methylene or similar covalent bonding; “an integer from about 01 to about XO vee is 1.01 to 1; and l is a zero to .0,8. The term “predominantly hydrocarbylene” means a radical (SH 0 valence) that is a predominant hydrocarbon but may contain in form Optional on a small amount of a heteroatomic group such as oxygen, sulfur, imino, sulfonyl, o (sulfonyl), sulfoxyl, and the like It is preferable that the hydroxy- functional poly(amide ethers) Yo compounds of formula 1 be prepared with a repeating NN connection.

(hydroxyphenylamido)alkane (N.N'-bis(hydroxyphenylamido)alkane or (arene) with diglycidyl ether) 701071a:0) as described in US Patents £Y, 49A 50,0 A],0AA Aram N poly(hydroxy amide ethers) parabolized by © formula I and prepared by the connection of a bis(hydroxyphenylamido) alkane alkane) or arene or a combination of; or more of these compounds; such as “NUN bis=F)hydroxyphenyl) adipamide N.N'-bis(3-hydroxyphenyl) adipamide or “NN bis—F)hydroxyphenyl)glutaramide NN”-bis(3-<hydroxyphenyl) glutaramide with (epihalohydrin) Cos lle) as described in US Patent No. 0 4118 17 riyals. The amide- and hydroxymethyl-functionalized polyethers represented by formula II can be prepared, for example, by reacting diglycidyl ethers (0:81701071); Jie a diglycidyl ether of a “(bisphenol A) Ve with a dihydric phenol having an amido suspension; sad ” (amido) substituted with 17 and/or o(hydroxyalkyl) alkyl groups such as –YY bis( ;- hydroxyphenyl)acetamide (2,2-bis(4-hydroxyphenyl) acetamide) and m-dihydroxybenzamide (3,5-dihydroxybenzamide). These polyethers and their preparation are described in US Patent No. 5 L0,YVA, V0 2116096 ¥ Hydroxy-functional compounds can be prepared Hydroxy-functional polyethers represented by Formula IV as Jal allow a diglycidyl ether or combination of diglycidyl ethers to react with a diglycidyl ether alternatively dihydric phenol or a combination of dibydric phenols using the method described in US Patent No. 0, VTE EVY Ye; hydroxy functional compounds may be obtained for polyether by allowing dihydric phenol or a combination of dihydric phenols to react with epihalohydrin

(epihalohydrin) by the process described by Barnabeo and Hale in «Reinking

(1317) 7178 p. sulfonamides)) diaryl ~N'N or (N,N'-dialkyl) for (polymerizing)© as (diglycidyl ether) Lf) with diglycidyl (N, N'-diaryldisulfonamide) Sulfonamide

Described in US Patent No. 5917148 OV

. The representative poly(hydroxy ester ethers) compounds are prepared

with the formula VT by reacting AS compounds with diglycidyl ethers from

0 Aliphatic or aromatic acids Jie o(aliphatic or aromatic diacids) Diglycidyl terephthalate or flaky glycidyl ethers

(diglycidyl ethers) of dihydric phenols with; secondary acids

aliphatic or aromatic diacids such as adipic acid or

Isophthalic acid These polyester compounds are described in

‎Yo <<US Patent No. 81718708‎.

Hydroxy-phenoxyether polymers, represented by formula VII, are prepared by; Se monomer contact is nucleophilic

(dinucleophilic monomer): with at least one diglycidyl ether for cardo-bisphenol ¢ (cardo bisphenol) as 4:5-bis-£—

0 | ¢(9,9-bis(4-hydroxyphenyl)fluorene) phenolphthalein or phenolphthalimidine or cardo-bisphenol

(cardo bisphenol) substituted; bis(Jb)fluorene substituted (bisthydroxyphenyl)fluorene) substituted phenolphthalein or

Phenolphthalimidine is substituted under sufficient conditions to make groups

(dinucleophilic monomer) from nucleophilic monomer YO

To react with epoxy groups to form a polymer chain containing

Suspended hydroxy groups and covalent bonds for an imino ether c(ether) oA are described as ester or (sulfonamido) sulfone (imino) ester polymers. This is in an American patent (hydroxy-phenoxyether polymers) hydroxy-phenoxy ether

OVALYYY No. (poly(hydroxyamino ethers) Poly(hydroxyamino ethers) compounds (cap 17111 represented by the formula ((polyetheramines) or “PHAE”) © (diglycidyl ethers) are prepared and prepared in one contact or more compounds of diglycidyl ethers containing two atoms (amine) with an amine (dihydric phenol) for a dihydric phenol (amine) Cle sana under conditions sufficient to generate (amine hydrogens) hydrogen Amine with a polymer bond to form a polymer chain (epoxy) to react with epoxy groups and hydroxyl groups (ether) Covalently bonded to an ether Covalently bonded to an amine 0 Suspension. Compounds in US Patent No. 07975758. For example (hydroxyl) AD resorcinol copolymers can be made from resorcinol (polyhydroxyaminoether copolymers) “(hydroquinone diglycidyl ether) glycidyl ether” AD Hydroquinone “diglycidyl ether) or mixtures thereof (bisphenol A diglycidyl ether) Diglycidyl ether Jed bis 1 source. They are (hydroxy-phenoxyether polymers) forming hydroxy-phenoxy polymers Ether “(dihydric polynuclear phenol) condensation reaction products of a polynuclear dihydrin phenol which has the units (epibalohydrin) and epihalohydrin “(bisphenol A) A as a bisphenol is an Ar isopropylidene group where IV _bis represented by formula 0 The method for preparing these is described in US Patent (isopropylidene diphenylene) phenylene No. 70058574© in its entirety incorporated within reference. One of the preferred non-identified PAPHEN hydroxyl-phenoxy ether polymers (phenoxy resins) is the commercially available Phenoxy Associates Inc. of these materials but is cInchem. ® (Rock Hill, South Carolina) Other favorites available from ©

INCHEMREZ™ PKHH and PKHW Unlimited Bahaa Production Step

As ale, the preferred phenoxy materials are fixed solutions or water-based derivatives. It is preferable that the properties of the solutions/derivatives are not adversely affected when combined with water. Preferences range from about 7010 solids to about 75+ solids; It includes about 7700 Ve 75 770 5 156 5 A and ranges including © such percentages. Preferably, the material used is dissolved or dispersed in polar solvents. These include polar solvents; but it is not specific; on the water; Alcohols and glycol ethers See eg US Patents Nos. TYAYYO 7 and HLA GATE which describe some of the preferred phenoxy-type solutions and/or dispersants. Ye polyhydroxyaminoether copolymer (PHAE) is one of the preferred phenoxy materials represented by Formula VIII as a dispersion or solution. When the dispersion or solution is placed in a container it greatly reduces the rate of permeability of many gases through the walls of the container in a well known and appreciable manner. The dispersion or *©1 made from it contains -01 7270 solids. A solution/dispersion of PHAE Ye can be prepared by shaking or stirring PHAE in a solution of water and an organic acid: preferably acetic or phosphoric acid, and it can also be lactic. “(lactic) malic, (citric) glycolic acid and/or 0 mixtures thereof. PHAE dispersions/solutions also contain salts of organic acids produced by the reaction of polyhydroxyaminoethers with those acids. in some other incarnations preferred; Phenoxy thermoplastics are mixed or blended with other materials using methods known to those skilled in this field. In some embodiments adapters may be added to the mixture. When these adaptors are used one or more of the admixtures cilia is improved; These characteristics include coloration, degree of refining, and adhesion between the layer containing the mixture and the other layers. A preferred mixture contains one or more phenoxy thermoplastics and one or more polyolefins including polyolefin preferred over poly

“+ polypropylene In an embodiment polypropylene or other polyolefins may be grafted or modified using a polar molecule or monomer ©©000000)”_which includes; but not specified; maleic anhydrous; glycidyl methacrylate acryl methacrylate and/or similar compounds to increase compatibility.

The following PHAE solutions or dispersions are examples of stable solutions or dispersions of the phenoxy type used if one or more layers of resin as a liquid material on

example by dipping; the flow; or spray packaging. Described in WO 004929/04 and US Patent No. 647/1797. BLOX® resin is an experimental barrier material

Auda 0 eg XU-19061-00 is made with phosphoric acid manufactured by Dow Chemical Company. It was found that the dispersant PHAE

This particular one has the following typical properties: 7718 solids; specific gravity od Fe cf viscosity YE 01 centipoise (Brookfield) rpm; LVI has a temperature (RYT) and a molecular size between 1.45060 and 0 VA. Resins are

BLOX®599-29 10 resorcinol base has suitable materials and has yielded results: Excellent as a barrier material. This particular dispersion has been found to have the following typical properties: I solids; Specific Weight VY pH 5.0 Viscosity 10cP (Brookfield)

0001 and 00s temperature 77"C) and a molecular size between LVI rpm; 0 angstrom. Other variants of PHA chemistry can be

(polyhydroxyaminoether) 00 useful as crystalline forms based on an A base) hydroquinone 01817010715 Other suitable materials include solutions/dispersions

polyhydroxyaminoether manufactured by Imperial Chemicals ICI Ohio » USA) available under the name OXYBLOK. in embodiments af; PHAE solutions or dispersions It may be partially crossed

5 (semi-cross); (LIS) or to the degree specifically required for application by the addition of the appropriate crosslinker. The benefits of crosslinking include, but are not limited to, one or more of the following: improved chemical resistance. improved SE resistance; slow glow; slow surface tension.

“1” (formaldehyde) Examples of crosslinking materials include; but without limitation; Formaldehyde (aldehyde) or other members of the aldehyde family or substances can be (acetaldehyde) acetaldehyde from the material; That facilitates Tg configuration also that the appropriate junctions are able to change to (resin) own containers. Other suitable materials for the dispersion medium include resin

Jai .BLOX®4000 and resin 0 “BLOX®UR588-29 (BLOX®5000©) glycol celal calcohols on polar solvents such as of gall solvents used to dissolve these or mixtures thereof. Suitable materials also include but not There is a water embodiment, the preferred thermoplastics of the phenoxy type tower or (polymer) dispersion/polymer solution preparation ( Say soluble in aqueous acids. 0 solution of water and organic acid preferably (epoxy) stirrer for epoxy plastics but this can also be (phosphoric acid) or acetic acid Or citric acid, malic, lactic acid is preferred, the acid concentration in AT and/or mixtures thereof. It includes about AY mo preferably from about (polymer) a 0 polymer solution by weight depending on the total weight.In other embodiments the concentration is 2100-8 and may vary so acid 7710 may Less than about 75 or greater than about .tadesjet and its molecular weight.in (polymer) Jie polymer type, depending. Over some other preferred factors, the acid concentration ranges from about *,? to about 75 percent by weight

Te) dissolved in a preferred embodiment of this invention is a (polymer) in the amount of a uniform, free-flowing polymer of 0. in (polymer) to about 746. It is preferable to use a polymer solution to be prepared with a concentration of 701 (polymer) as an embodiment of this invention, the polymer solution is at 00 "degrees. After that (acetic acid) acetic acid 0 in (polymer) by dissolving a polymer, and while the solution is hot, it is diluted with about 7780 distilled water to obtain a polymer solution, the polymer solution has a concentration of 728. At higher concentrations is a polymer ) Ye is attributed to being more viscous. (polymer)

17+ Examples of preferred copolyesier materials and a method for their preparation are listed in US Patent No. 4597787498 for Jabarin in general they are prepared by heating a mixture of at least one reactant selected from isophthalic acid terephthalic acid and ©-,© alkyl esters (©-©) with YY 0 bis ("-(Ss)bis(2-hydroxyethoxy)benzene) 1,3) and optionally ethylene glycol, this mixture may also comprise one or more ester-forming dihydroxy hydrocarbons and/or a bis(4-8 -Hydroxyethoxyphenyl sulfone-1:4-8H.hydroxyethoxyphenyl(sulfone) Preferred copolyesters are available 0 from Mitsui Petrochemical Co., Ltd. (Japan) as B- 030 B010 and other compounds of this family.Preferred examples of polyamides include MXD-6 manufactured by Mitsubishi Gas Chemical (Japan).Other preferred polyamides include 6 Nylon 66 “Nylon Ye << polyamide materials are other preferred blends of polyamide | 0 and polyester which includes those of about 1-7270 polyester by weight; Preferably over about 701 -1 polyester by weight in which that polyester is PET or modified PET. In another embodiment the polyamide is a combination of polyamide 0 and polyester including those containing ZY = + polyamide by weight is more preferred about 7701-1 polyamide by weight; Whereas, polyester is preferred PET or 1-moth. These mixtures can be harmonized with the use of antioxidants or other substances. Examples of such materials include those listed in US Patent Application No. 0017477/ oY eng filed in YY Mar Yo 001 and cited herein by reference. Other preferred polyesters include but not limited to; PEN and PET/PEN (copolymers) ?*- Preferred Foaming Materials 1 1

“> as used in this invention; The term 'foaming material' has been used according to its original meaning which can include, without limitation, a foaming agent; a mixture of a foaming agent and a binder or carrier; an expanded cellular material; and/or a material with voids. The terms 'ald foam' and 'expanded material' are used interchangeably in this invention. Preferred foam materials may achieve one or more physical attributes that improve the thermal and/or structural properties of materials (eg containers) and may make the preferred embodiments have the ability to withstand the operating and physical stresses typically caused by containers. In a water embodiment the foam material gives structural support to the container. In the AT embodiment, the foam material is an insulating layer which can reduce the breakability of the container during operation. 0 for example; The foaming material can give abrasion resistance which can reduce the smashability of container during adee transportation. In another embodiment the protective layer of foam can increase the impact resistance of the container and thus prevent or reduce the breakability of the container. in addition to; In an embodiment the foam may give a gripping surface and/or increase the field or view of the container. In the water embodiment, the foaming agent comprises a foaming agent or blower and a carrier. In a water embodiment the foaming agent comprises expanding compositions (eg micro-pellets) which can expand and combine with the carrier to produce foam. For example, the foaming agent can be thermoplastic nanoparticles; Such as the EXPANCEL® microspheres sold under the AKzo Nobel name. 3. An embodiment of these microspheres can be 0 vacuum thermoplastic pellets incorporating thermoplastic shells encapsulating a gas. It is preferable when heating these fine pellets; That the thermal shell flows and the gas pressure increases, causing the micro-pellets to expand from their original position to another expansionary position. The expanded micro-pellets and at least part of the carrier may be the foamy portion of the material enumerated by this invention. The foaming material can be a bed comprising a single material (such as a homogeneous YO mixture of foaming agent and carrier); mixture or mixture of substances; Textile composed of two materials or ST two or more layers; A multitude of infinitesimal layers (crusts) which preferably contain at least two different materials. dally and microspheres can be

+ Fittings comprising materials that can produce gas through or from the fittings. In the water embodiment these microspheres are vacuum structures containing chemicals which produce or contain a gas whose increased pressure causes these structures to expand and/or explode. In another embodiment, nanospheres are assemblies made of and/or containing one or more substances which decompose or react to produce gas and which expand and/or implode the spheres. Optionally, these microspheres can be solidified. Optionally, these microspheres can be crusts filled with solids; Liquids and/or gases. The micro-pellets can have any shape and composition suitable for foam formation. For example (Jo) these globules may be spherical. Optionally the microspheres may be 0 in the form of a rectangular or oblique semi-spheroid. Optionally these ultrafine globules may contain any gas or mixture of gases suitable for expansion Pellets ARAN An embodiment of water this gas may include an inert gas such as nitrogen In an embodiment this gas is generally nonflammable However in some embodiments the inert gas and/or flammable gas For ignition these scales of infinitesimal “NO” pellets can be ignited. In some embodiments the foaming agent may include foaming or swelling agents as indicated by Art. In addition the foaming agent may be wholly or mostly a foaming agent Although some preferred embodiments contain microspheres that do not fracture or explode, some embodiments include microspheres that can fracture 0 explode; splinter and/or the like. The small part can be broken while the rest of the particles remain unbroken. In an embodiment of the Oia cle a major portion of the microspheres may burst and/or split when expanded. In addition to cally it YO different mixtures and extracts of microspheres can be used to form the foam material.

+ Micro-pellets can be made of any material suitable for expansion. In an embodiment these microbeads have a shell containing a thermoplastic resin; or similar as it is listed. The shell of a nanoball can contain a single substance or a mixture of two or more substances. For example, these microspheres may have an outer shell containing ethylene vinyl acetate (“EVA”) polyethylene terephthalate (“PET”) (polyethylene terephthalate) Polyamides (such as Nylon 6 and Nylon 66 polyethylene terephthalate glycol “(PETG) terephthalate glycol) PET copolymers (copolymers) and compounds thereof. cle the PET copolymer PET contains a Ve covalent monomer (CHDM comonomer) CHDM at a level between PET PETG another embodiment the IPA 1156 Jie (comonomers) are added to 7 For the formation of ultrafine spherical scales. The consistency appropriate to the type of material »volume and inert gas can be chosen to obtain the required expansion of the nanoparticles.In the water embodiment, the microspheres comprising the scales are composed of a high-temperature material (Jig) PETG 0 : or similar material) which has the ability to expand when subjected to high temperatures; Preferably without causing microparticles to explode. If the ultrafine pellets have a shell: made of a low-temperature material (such as BVA), then these pellets will break when exposed to high heat, and this is suitable for the operation of some conducting materials. PET Ja) Polypropylene has a degree high boil). in some circumstances; For example, Ye microspheres for EXPANCEL® can break down when operated at correspondingly high temperatures. Preferably, micro-pellets with first medium temperatures are used, emptying it with a carrier that has a high boiling point, in order to produce a foam material that is expandable and can be controlled without breaking the micro-pellets. For example microbeads can include a mild or medium temperature material (such as PETG) or a high temperature YO material (such as acrylonitrile) and may be suitable for high temperature applications. Thus, the foaming polymers blowing agent can be selected

Depending on the operating temperatures used.

The foam material can be an interfabric containing a carrier; It is preferable to mix this material with a blowing agent (such as microbeads) to form an expandable material. The carrier can be anal thermoplastic or a polymeric material such as ethylene acrylic acid (ethylene acrylic acid) ethylene (EVA) vinyl acetate © linear low density ("LLDPE") polyethylene polyethylene terephthalate glycol poly(hydroxyamino) ethers ©

PET (“PHAE”) ethers) polyethylene “(polyethylene) polypropylene (polypropylene) polystyrene (“PS”) (polystyrene) Ji pulp) paper pulp or 0 wood fibres; or a paste mixed with one or more polymers o(polymers) mixtures thereof or the like. However, other materials are suitable for carrying

A foaming agent can be used to obtain one or more thermal properties; synthetics; visual and/or other properties of the foam. In some embodiments the carrier material

By having characteristics (such as a high boiling coefficient) for the easy and rapid expansion of the growing pellets

EE is smaller and thus 'reduces cycle time and as a result increases productivity. Ve in preferred embodiments; The constituent material may include two or more. . Details Components that contain many components, each of which has different operating windows and/or

different physical. These components can combine so that the substance formed has one or more

desirable traits. The aspect ratio can be varied to produce the required playback window

0 and/or desired physical characteristics. For example. The first article can have a playback window similar to or different from the second article playback window. The playback window can for example depend on pressure; the heat; viscosity or something. So the components

The forming material can be mixed to obtain the required pressure and temperature to form the material.

In the embodiment of water, the union of the First Matter with All Matter can result in Matter

YO has a trigger window that is more demanding than the second material trigger window. For example, the first material may be suitable for operation in a larger range of temperatures and the second material may be suitable for operation in a lower temperature range. maybe

A material that is partly composed of the first and partly composed of the second material is suitable for operation over a temperature range greater than the narrow temperature range of the second material. In a water embodiment the actuation window of the multicomponent material is similar to the actuation window of the first substance 0 In another embodiment the constituent material comprises a layer consisting of a layer © or a tube comprising a layer consisting of PET and a layer consisting of polypropylene Material consisting of both PET and polypropylene (eg, extruded) can be operated in a wide temperature range similar to the appropriate temperature range for PET. The operating window can include several factors such as pressure; temperature; viscosity and/or the like. ve optionally; It is possible to vary the quantity of each ingredient in the material so as to obtain the desired operating window. Optionally the materials may be combined to produce a composite material suitable for operation in a desired temperature range; pressure, viscosity and/or the like. For example, the proportion of a material with a desired operating window can be increased and the proportion of a material with a lower and undesirable operating window can be decreased in order to obtain a material with an operating window that is very similar to or substantially identical to the operating window of the first material. caudally If the most-demanded operating window is between the first operating window for the first material and the second operating window for the second material, then the ratio of the first material and the second material can be chosen to obtain the desired operating window for the constituent material. Optionally, multiple materials with similar or different operating windows can be combined to obtain the desired operating window for the resulting material.

Y. In an embodiment of water the viscous properties (material integrity properties) of the forming material can vary by the variance of one or more elements having different viscosity properties. Jad substrate (PP Jie) can have great boiling strength and easy to break out (extrusion). PP can be combined with another material, PET Jia, which has ALB boiling point, which makes it difficult to break out; This is to form a material suitable for extrusion processes. For example, a layer of PP or any of

Jie) during PET co-extrusion process other strong materials can support a layer of Ye and poly PET co-extrusion horizontal or vertical). Thus, the substance formed, which consists of

TA

nor PP can be operated at a temperature suitable for (polypropylene) PET is suitable for processing in some embodiments; It is possible to choose the composition of the formed material in order to influence one or more of the dps all of the properties of the materials, for example the thermal properties; barrier qualities; visual qualities; viscous properties; The flavor profiles and/or some of the other 0 characteristics mentioned herein may be obtained using the compounds mentioned herein. | Material Enhancement Additives —¢ An advantage of the preferred methods described herein is their flexibility allowing the use of multiple effective additives. These additives are known to those skilled in the art for their ability to give 0 UV protection; (oxygen) CO2 insulators; Preferred additives can be prepared by methods known to those skilled in the art.For example, these additives can be mixed directly with the material under study, and they can be dissolved/dispersed in isolation and then added to the material under study, or they can be combined with the material by adding the solvent which is 0 and in In some embodiments, the preferred additives may be cll) the dispersant/solution of the material. In addition to its use alone as a single layer. In preferred embodiments the insulating properties of the layer can be improved by the addition of various additives. Additives are preferably found in an amount of about 7460 of the substance; It also includes es al by the weight of the material. in embodiments IV 7 To Je 770 JY on Ye by weight; Preferred ranges 71 These additions are preferably present in an amount less than or equal to 0.41 to about AY to about 70.00 for the material includes; but not specified; About to about 71 by 1.1 and about dey about 70.01 to about dey about weight. Also, in some embodiments, it is preferable for the additives to be stable under aqueous conditions. (resorcinol (m-dihydroxy dihydroxybenzene) —m) for example; Resorcinol derivatives Yo can be used in combination with different preferred materials as mixtures or additives or 5002©0©(((resorcinol)) in the composition of the material. The higher the content resorcinol (monomers) monomers

The higher the insulating properties of the material. Db Diglycidyl ether can be used in PHAE and hydroxyethyl ether (Say resorcinol) can be used in PET and some polymers and polyurethane insulation materials copolyesters

° “microparticles” or “materials with microparticles” may also be used. For convenience the term microparticles used herein will be used to refer to both microparticles and matter with a microparticle (diameter). These microscopic particles are thin; micron or near micron in size; Molecules of materials that increase the insulating properties of the material by creating a zigzag path for gas molecules, Alina, for example, oxygen (oxygen) and carbon dioxide.

0 carbon dioxide until they penetrate the substance. in other separate incarnations; The material with microscopic particles is present in an amount ranging from 70.059 to 71 by weight and includes 70.1 10.0 by weight and other ranges that include those quantities.

The product i.e. the connective base with ultrafine particles is a preferred type of microparticle material and is available through Southern Clay Products.

0 . Cloisite® microparticles are one of my favorites and are produced by Southern Clay Products in an embodiment of; The microparticles comprise monmorillonite modified with a quaternary ammonium salt. In other embodiments the microparticles comprise monmorillonite modified with a tertiary ammonium salt. In other embodiments the microparticles include

0 . Monmorillonite is natural. In other embodiments the microscopic particles consist of organic sludge as listed in US Patent 2977807977; Which was mentioned here as a reference and after part of the explanation of this request. Organic and inorganic microparticles can also be used and dissolved. Made and natural products are also suitable.

Another preferred type of microscopic material is a metal composite. for example

For example, a water-based aluminum oxide dispersion is a suitable compound

in microparticle form made available by BYK Chemie (Germany). It is known

Ye This type of microscopic material can give one or more of the following benefits: Thermal stability. Ty Increased resistance to abrasion; Increased scratch resistance » increased scratch Another type of microstructure includes preferred particles on a polymer-silicate composite including silicate (©017706-5111681m). In another preferred embodiment the polymer-silicate microsilicate polymer-silicate material (monmorillonite) © Nanocor and RTP are available. In another preferred embodiment the UV protection properties of the material can improve it by adding

The UV used gives UV protection with different additives. In a preferred embodiment the protection material is nanometer or less and more preferably PV nanometer or less; Preferably around Yor up to about 5086 nm or less. The 177 protection material can be used as an additive with layers to give 0 additional effectiveness or it can be applied alone as a single layer. Optimizing additives are preferred by weight but also include those 7710 to 1505 in the material with a percentage of about UV protection by weight. 2105 and 20 Jo JY IX LY dee 70.1 ratio is preferable to the addition of the 17 protection material in a suitable form for other materials. For example; The preferred 1773908 Milliken UV 390A Clear Shield® liquid is UV protection sale 0 i oily for which mixing is carried out with the help of first mixing the liquid with water; Preferably with equal weight ratios (ald) mithqal. This mixture is then added to a solution of 1773908 to give 701 and shaken. The resulting solution contains approx. Blox®599-29 as previously listed and in nm PET when applied to approx. 7900 UV protection. Another embodiment, the 17173908 solution is used as a single layer. In another application the preferred UV-protected 0 or absorbent modifier (polymer) 0 contains the other preferred but non-UV protected Bar ae UV protection polymer added as a concentrate. It includes protective materials and phenothiazines, phenothiazines (benzotriazoles) and benzotriazoles during the boiling phase process before UV protection materials can be added (382801160011021065). Usage; for example, before mold injection or extrusion or directly added to the encapsulated material in the form of Ye

Ciba «Milliken Convenience is available as a UV solution or dispersion. 4. Clariant protective materials

Ya

may be added to the material. In the CO embodiment, in other embodiments preferred the repellent properties of an activator which (amine) obtained with an amine (Say what is preferred) those properties will lal will react with carbon dioxide 60 to form a salt Gas-rich barrier. This active can be an (amine) acting as a carbon dioxide buffer (0©). This is a thermoplastic amine (resin) additive or it can be one or more moieties in a resin material. © monolayer or multilayer. To (oxygen) in other preferred embodiments it is possible to add purifying properties of an anthroquinone such as anthroquinone (oxygen) Preferred materials using suitable oxygen purifiers are (oxygen) The AT and other oxygen purifiers known as Art

Color-Matrix 5 BP Amoco manufactured by 21105073" (oxygen) 0 &Co; Cahill illustrated with US Patent No. 0878788 for Corporation and cited herein by reference. In one embodiment; Oxygen or other substances; including phenoxy to preferred oxygen-type materials with phenoxy-activating mechanisms in oxygen-type materials + different oxygen purifiers. Sweeps CO2 0 either gradually randomly or with a delayed action 0 until triggered by a specified firing pulse. In some embodiments it sweeps CO2 . . in the contents of the container (Je) or UV water Carbon dioxide, 0, during exposure to 0,1 in an amount ranging from about (oxygen) or a combination of them Preferably purified oxygen in a ratio of 701 to about 1,9 by weight; more preferably in an amount from about 72718 to about 75 by weight in relation to weight z 1 by weight and more preferably by an amount ranging from the total Ye of the overlay. In another preferred embodiment a top coat or top coat is applied from In order to obtain stronger chemical resistance than those obtained through the outer layer. in private embodiments; It is preferable that those layers or toppings be with a water or non-aqueous base and which (acrylics) or (polyesters) are polyesters © is a polyethylene terephthalate LIS optionally partially cross-linked or preferred base; However Sle (polyester) is polyester (polyethylene terephthalate)

YY

the AY) other. In some embodiments (polyesters) some polyesters may use the topcoat or topcoat application process listed in US Patent Application No. spray, flow coating process to form cma materials entitled (Tod [+VIA] covered, which is cited in this invention by reference. Polyester resin US No. 49977191 listed Polyester resin, US Patent No. 78 by weight ratio Polymer 0 78 to 7710 hydrated base Jeli containing product (glycol) Least Jal glycol by weight 740-01 (terephthalate polymer) .(oxyalkylated polyol) One 5 0—275 by weight of at least 0 alkylated oxy-polyol (sulfonated polyester Auf is a preferred compound Another is water-based poly resin “(Salsman) 18157101 listed in US Patent No. resin) and cited herein by reference. US Patent No. 5781770 is listed as soluble (sulfonated polyester resin) sulfonated jiu) Polyresin Slo Special Suspension by weight 75 + -710 for Water Dispersible Jel containing JE product with water or at least 1 salt by weight glycol 7450-7450 01 (terephthalate polymer) of one terephthalate polymer 5 0 775 by weight of at least one glycol having the property of (prepolymer resin) to produce an oxyalkylated polyol after ( prepolymer resin) A Cus (hydroxyalkyl) hydroxy alkyl carboxylic acid prepolymer resin is A mol of +15 mol acid to about 1.01 with about deli 0 gm of 001 alpha and beta each. ethylenically unsaturated (dicarboxylic acid), which ends with a precipitate (resin), thus producing a prepolymer resin and an ethylenically unsaturated (dicarboxylic acid) residue Jb from acid per mole of (sulfite) mol to about 1.0 moles of 1,8 sulfite and reacts with about an alpha ethylenically unsaturated (resin dicarboxylic acid) YO dicarboxylic acid resin ( sulfonated) has a sulfonated (resin) and beta end to obtain yy resin

A preferred water-based UAT (polymer) is that envelope illustrated by US Patent No. (Salsman) OVYTYVY and cited herein by reference. In particular, US Pat. No. 577777 listed Ally packaging compounds containing a reaction product for at least Lov by weight terephthalate polymer © and a mixture of glycols comprising an alkylated oxypolyol (oxyalkylated polyol) in the presence of a glycolysis catalyst in which the reaction product also reacts with a bifunctional organic acid and the acid weight ratio is

to glycols in the range 6:1 to 1:7. Whereas the foregoing examples are given as preferred water-based polymer compounds;

0 There are A water-based polymers suitable for use in the products and methods mentioned in this invention. By way of example, but not limited to, other suitable water-based compounds are listed in US Patent No. 4004777 (Date et al.) and cited herein by reference. The US patent EY EYYY listed a polyester resin dispersion ad (polyester resin) obtained by mixing a polyester resin

(polyester resin) Linear 0 with a surfactant agent of high alcohol / ethylene oxide. This mixture is melted and the product is dispersed by pouring into an aqueous solution of alkali under shaking conditions, specifically any. This dispersant was obtained by mixing a linear polymer resin with an additional high alcohol/ethylene oxide surfactant on the mixture and dispersing the product by pouring in

| Under shaking at a temperature of about (alkanol amine) the aforementioned mani-alkanolamine solution of a group consisting of (alkanol amine) 10" alkanolamine; and alkanolamine 0 "(diethanolamine) was chosen as the two ethanolamines «(monoethanolamine) from mono methyl ethanol mono methyl ethanolamine «(triethanolamine) triethanolamine diethylethanolamine «(mono ethylethanol amine) monoethylethanolamine amine

“(diethylethanolamine) 5-propanolamine “(propanol amine) butanol camine —N “(pentanol amine) phenylamine, (N-phenylethanolamine) and cannolamine (alkanolamine) for glycerin

The aforementioned alkanolamine present in the aqueous solution in an amount ranging from 0" to 78 by weight; said surfactant is an ethylene oxide additive for a high alcohol of which An alkyl group has at least A carbon atoms a phenol substituted alkyl or © sorbitan monoacylate in which the surfactant has a value of HLB at least AY in mass; eg US Patent No. (Allen) 1878771 describes a dispersion in a water-miscible liquid of water-soluble or swellable polymer particles that have been alee Reverse-phase polymerization in liquid 0 non-JB miscible with water containing a non-ionic compound selected from Cap alkylene glycol monoethers (Alkanoates) 4-R0) ial Baha Copp polykylene glycol monoclinic

(Cg-12 polyakylene glycol monoethers) and their C4 alkanoates. Materials of some embodiments may be cross-bonded to increase thermal stability at >05 . Multiple uses; For example in hot filling applications. In an embodiment the inner layers may comprise materials of low bandwidth while the outer layers may contain materials of high bandwidth or appropriate combinations thereof. Mie, the inner coating on the surface of PET may contain a material with weak cross-linking or no cross-linking such as 510©588-29,; And the outer cover contains other sales such as 0 2200-12468-48 manufactured by ICT, which has the ability to cross-link to achieve maximum adhesion to (Sa (PET) in addition to the appropriate additives, which have the ability to cross-link to one or More than layers. Cross-linkers can be chosen depending on the chemistry and reactivity of the resin or the material they are added to. For example, amine cross-linkers can be useful for cross-linking of resins©? (resins ) containing epoxide group If cross-linking additives are present, they are preferably present in an amount of about 71 to 701 in the weight ratio of the solution/dispersion coating; preferably about 71 to 25 and more preferably about 70.01 to 7021 in the rate of

Yo by weight. 74 LA 29 5 024 YY Weight; Also, these proportions include with one or more thermoplastic (TPE) epoxy. Optionally, epoxy elastomer (carbon) cross-linking agents can be used. in some embodiments; Some agents (such as the carbon part of the TPE that may represent the black TPE material) may also be coated on or combined with the black material or (carbon) _ of the material described herein. It is noted that other carbon©s (polymers) can be used to improve their use in polymers (Say) and other similar additives in material properties. Materials for some embodiments may contain a curing accelerator. As used herein, The term “curing accelerator” is a widely used term and is used in its original sense herein to include, without limitation, chemical cross-linking catalysts, heat-increasing agents, etc. As used here, the term thermal "is a widely used term and is used in its original sense herein to include; carbon (cia) transition metal compounds; IG radiation absorbing additive materials (but not limited to cobalt metal (cobalt) black nad). Suitable transition metals without (carbon) Transition metal compounds include, without limitation, (copper), copper (thadium), radium 0 d | (carboxylates), Jad 5 (metal carboxylates) Metal carboxylate and acetate (neodecanoate) preferred; without limitation to neodecanoate: heat enhancers may be used alone or in combination with one or more (acetate) other heat enhancers. Thermal enhancers may be added to the material and increase the temperature of the material during the Y process. Curing; Compared to the material without the thermal enhancers. For example; In some embodiments, the black (polymer) is added to the polymer (carbon) with the addition of thermal enhancers (eg, carbon (Say (IR glad) Jie) subjected to the polymerization process so that the temperature of the polymer is Without thermal enhancers subject to a suitable or inclined process. (polymer) is higher than excess polymer due to thermal enhancers increasing the rate of (polymer) curing YO polymer temperature and increasing production rates. In some embodiments; thermal enhancers have a degree yi Higher temperature of one of the layers of the material when the thermal promoters and the material are heated by a heating device (eg; an infrared heater).

Ave in some embodiments; Thermal enhancers are present in amounts ranging from about © to #17 to 50 ppm; Preferably about 1510 to 100 ppm; Preferably around 0;00 ppm; including about 100 ppm; Preferably around 75 to ©

Voeg Ton stack chan (Fou (Yuu) galak (AYO) 100 (AYO) bank VO dkpv ppm and ranges include these amounts. The amount of heat enhancer can be calculated based on the weight of the layer that includes the heat enhancer or The total weight of all layers comprising the product. (carbon) In some embodiments, the preferred thermal enhancer includes carbon 1 black which may be applied as a component of a coating material of (carbon) In an embodiment the carbon Ad is black. In order to accelerate the ripening of the coating material.When used as a component of a coating material, black is added to one or more of the coating materials before, during, and/or after carbon (carbon) is applied (covering, etc.) on The material under study. It is preferable that the coating material (Ve carbon black) be added to the coating material and stirred to ensure mixing. The heat Bay agent may include additional materials to obtain the desired properties of the material under study In another embodiment, when carbon black is used in the injection molding process, carbon black is added to the polymer mixture in a boiling phase process. Polymer comprising about © to Ave ppm » Yee preferred about 01 to about 151 ppm » Preferably about 50 Yo to about 50 ppm; Preferably about 75 to 100 ppm; Including a laf about Yo 00 KD meets VO but all your heart is a bank of tink to wrap tha Ver gTee in a million thermal boosters and ranges including these quantities. in an additional embodiment; The packing material is cured under radiation; such as infrared (IR) heating in 5 embodiments preferred; IR heating provides encapsulation that is more effective than curing using other methods. Other heat enhancers and treatments and methods of their use are disclosed in US Patent Application Serial No. 948715/01 registered on © November Yong under the name “alee”

except a catalyzed process for forming coated article, the disclosure of which is incorporated here by reference in full. In some embodiments it is preferable to add anti-bubble fie ll agents. In some preferred embodiments used for solutions, dispersants or foams form dispersions and/or bubbles which can interfere with preferred processes. Some way to avoid this interference is to add anti-foaming/bubble agents to the solution/dispersant. These agents include, but are not limited to, non-ionic surfactants (non-ionic) alkylene oxide base materials o (siloxane) and ionic surfactants ( onic) if anti-foaming agents are present, it is preferable to be present in an amount of 0 (about Logo) to about 70.7 of the solution/dispersions and preferably about 70.01 to about 70.7 but also those percentages include about Tak Bal Karak Val 3 (M La Alle 4 "wear 7,70 AY and other proportions include those quantities. In another embodiment, foaming agents may be added to the coating material so that the coating is foamed. In another embodiment the foaming agent reaction product is used. For example pads Ve < 0 limitation, appropriate foaming agents can be used. From azobisformamide azobisisobutyronitrile ¢(azobisisobutyronitrile) diazoaminobenzene ¢(diazoaminobenzene) 1111-dimethyl-1107-dinitrosoterephthalamide—N«N ¢(N,N-dimethyl) -N,N-dinitroso terephthalamide) dinitrosopentamethylene-tetraamine “(N,N-dinitrosopentamethylene-tetramine) benzene sulfonyl-hydrazide AU —VeV = p ju o(benzenesulfonyl-hydrazide) 0 sulfonylhydrazide (benzene) -1,3- : A ddisulfonyl hydrazide) phenylsulfone-?+-? A «(diphenylsulfon-3-3) sulfonyl hydrazide (((disulfonyl hydrazide) 4 ;- oxybis benzene sulfonyl hydrazide -4,4) —p coxybis benzene sulfonyl hydrazide) toluene sulfonyl paracarbide (p- toluene sulfonyl semicarbizide barium azodicarboxylate YO (butylamine nitrile) nitroureas trihydrazino triazine phenyl - Myl-urethane “(phenyl-methyl-urethane) —p sulfone hydrazide “(p-sulfonhydrazide) peroxides” (peroxides) diammonium thinner

Ya

(sodium bicarbonate) and sodium bicarbonate, (ammonium bicarbonate) carbonate, as is currently available in the market, foaming agents include; For example, but not exclusively

CEL-SPAN® (MIKROFINE® (HYDROCEROL®) #Belmomsa. (EXPANCEL® .PLASTRON® FOAM) to about 1. It is preferable that the foaming agent be present in the packaging material in an amount of about 2 by weight and more than 701 to about 1 by weight; more preferably from about 0 to about 70 by weight Modern foaming techniques are well known to about 1 preference by those skilled in the art using compressed gas which can be used to create foams in place of blowing agents 01 A bonding layer is preferred from a polymer having active groups, such as anhydrous and epoxies, which react with carboxyl and/or hydroxyl groups. On PET polymer chains, the bonding layer materials include, for example, but not limited to: Mitsui ADER® DU Pont BYNEL® Exxon Mobil's EVELOY® Arkema's LOTADER (Eastman's EPOLINE 0 D- METHODS AND SYSTEMS FOR MAKING LAMINAR MATERIAL NO A multi-component layer may also be made from a laminar melt stream which preferably contains at least two components. At least on two layers in which the melt current layers are parallel. Although the laminar melt stream can have at least two Ye layers; The laminar melt stream may contain many thin flakes. As the laminar melt stream can be made of two materials; The melt stream preferably includes alternating thin films of two materials and the materials used to form this stream are preferably Jia thermoplastic polymers; Which includes polyester, polyolefin ¢ (polyolefin) and other J sas (phenoxy) phenoxy materials as YO described here. These laminates may include mixtures of two or more materials. Laminated materials can include additives such as microparticles; Oxygen purifiers

Ya

(oxygen) ultraviolet absorbents; Matches and the like. in embodiment the stream

Melt Laminated Consists of reused polyester PET Jie and barrier material. There is some way to construct a laminar melt stream using a system similar to that done

It is explained in various patents for Schrenk US Patents OY YE 845/808 and 2,178,550 which are cited here by reference. Although this method is expected to be used in conjunction with other methods currently to obtain solute streams. By reference

Figure (TY) which shows a schematic embodiment of a laminar melt stream synthesis system 47; the system is shown

YY JS is some embodiment of a two-matter system but it is Lad understood that a system that includes

Three or more items will act the same way. The two materials used for composition were put together

0 Flakes in hoppers or inside EAC 5 EAE which are fed to two separate extruders FAY EAT respectively. In a preferred embodiment these extruders are EAT and 487; They are of the kind of screws that

Heat and pressure can be applied together to bring special materials to the melting point. is extruded

Materials at rates and thicknesses to obtain the required corresponding quantities of each material and a stream is combined

Dissolve the crucibles together to form a laminar dissolving stream (EAN) consisting of a wafer from each cylinder and preferably

Ca Arrange such that each sheet lies on top of the other. 19 <0

| The two-layer melt stream EAA coming out of the cylinders is placed on a wafer enlargement system E90 The £90 layer enlargement system shown the two-layer melt stream EAA is amplified into a multi-layer melt stream 97; Which has 01 chips in the embodiment shown as (YY Fig. 7?) showing a layout and is quite perfect in that it

0 Although, on average, the layers of laminated material are preferably parallel to each other and the laminated material can contain chips that are not parallel to each other and/or chips

Parallel in some places and not parallel in others.

The process of doubling the chips can be done in any of the ways. In the embodiment of what there is a person

First, a portion of the melt stream is divided into two segments perpendicular to the interface of the two chips. Then

YO These two layers are flattened so that each of those two pieces is equal to the length of the original piece before it was bisected in the first step; But only one half is equal to the first piece in thickness.

Then the two pieces are re-fused together to form one piece that has dimensions similar to the original piece

Ae but has £ chips; This is by sticking a piece on top of the other piece so that the parts of the chips are (meaning that the paste is in a direction perpendicular to the AO of the two materials, so that they are parallel to each other's melting current layers). Partition steps can be made; Flattening and reassembling several times to obtain thinner layers. The melt stream can be multiplied by performing the operations of splitting, flattening and regrouping several times to yield a single melt stream containing many of the flake parts of the element material. In that two-material embodiment the composition of the layers will alternate between the two materials. Other methods of flake formation include performing steps similar to those above but flattening the melt stream before partitioning or after reassembly. mutually; In either of these embodiments someone would rather bend the melt stream back on itself than break it into pieces. It is possible to make combinations of division and bending as well, but it is noted that bending and division will achieve relatively different results because bending will cause the single chip to double on itself. The product of the wafer doubling system passes out through an orifice such as a spout or a valve and is used to form the material or a multicomponent wafer with material 64 by injection or by placing the wafer melt stream in a mould.

yo In the two-material embodiment shown the composition of the chips generally alternates between the two materials. However in other embodiments any number of material may be taken into an elemental melt stream and then fed to a flake enlargement system 4900 which produces a lamellar melt stream at any desired repetition number and/or desired repetitive size of blocks or piles of material. For example in the embodiment of; The System 487 comprises three extruders which connect the material to a 2 lb foil enlargement system

Yep, the flakes enlargement system is 4900 stacks of flakes consisting of three materials. When the melting stream contains one or more materials that have gas-blocking properties, it is preferable to use the melting stream in such a way that the chips in the melting stream are parallel to one or more of the expanding surfaces of the material. For Jad in a container, the seams are preferably parallel to the length of the wall pieces or body part. Although parallel Yo is preferred; It may use other directions and define the scope of the invention. For example, one or more parts of a container wall may have chips parallel to each other and to the surface of the container wall while one or more of the other parts may have chips

AY

not be parallel to each other. The desired zigzag path through the container wall is estimated by the orientation and shape of the chips that make up the container. For example, the flakes are parallel to each other and the part of the wall can substantially increase the length of the path through the wall that is traversed by the gas molecule. Alternatively, the parallel layers crossing into the wall lead to a short or slightly tortuous fluid path through the wall Ade some as © and thus have less barrier material properties than the melt stream going in a parallel way. The formation which is listed here dl gall can be formed using the product of the foil melt current from a system such as the one shown. In some similar Ty incarnations; The foil melt includes materials with a melt temperature of 7.8 to facilitate machining and molding. However, the melting of chips can include different 0 materials. For example; The laminate material can include materials having a range of 7.5. The material of the laminate material can be selected depending on RYN (about 2000 dag) Structural properties; Barrier properties; Gold properties] Thermal properties Working properties and/or other properties Melt wafers can be formed and cooled; preferably-before one or more of their constituents are substantially broken Can skilled in the art Select materials 0 For shaping wafer material to achieve material stability Desirable suitable for the characteristics of the packaging and the end use chosen. Methods and equipment for making preferred tools: ——a Single-layer and multi-layer products (including packaging products such as caps; preforms; containers; bottles) can be formed. by a process of molding 0 'moulding' (eg; injection molding including associated injection molding). The name refers to a process that uses injection molding to inject Lal preferably made by AE forming one or more layers of material upon layer of injection. The terms “over-injection” or “over-forming” are used here to describe a YO encapsulation process in which a layer of material is injected onto an existing layer or pre-formed piece(s).

AY

One of the extrusion methods for manufacturing preformed parts on an injection machine involves union with a mold containing a preformed or core-and-socket mandrel. A first layer of preformed material is formed between the preform core and the first cavity of the preform core by injecting a molten polymer into the void space in the mold. The first layer remains on the core Lovie The forming core is pulled out of the cavity, moved, and inserted into a cavity in a second mould. A second layer of material is then injected over the first standing preform layer. The mandrel of the forming core and associated preformed material is then moved out of the cavity and the preformed material is moved from Forging core mandrel In some embodiments the over-injection process takes place while the substrate has not yet completely cooled 0 - The substrate may contain self-retained heat from the injection molding process then conducted on the substrate In some embodiments it may The substrate is at room temperature or some other temperature suitable for overmolding. For example Sar is overmolding products at room temperature with one or more layers of material. These may be The products have been stored for an extended period of time before being superformed. Lahan may use over-injection to apply one or more layers of Jia material(s) such that they include ALE expansion/foaming; (including recycled PET; PET prepared directly from crude); lamellar material isolating materials; Combined assemblies of terminators and/or other materials are shown here on top of a substrate (ie the substrate). in unspecified embodiments; 0 The substrate shall be in the form of a fixed piece, preferably with an inner surface for contact with foodstuffs. in some embodiments; The preformed PET substrate (Ju) includes 1 produced directly from the ore; A thermoplastic material of phenoxy type with conjoined groups terminated and/or the like. Products may have one or more layers or parts having one or more YO of the following distinguishing characteristics: insulating layer; barrier layer food contact layer; flavorless scraping layer; high tenacity coating; pliable layer bonding layer gas scavenging layer layer or portion suitable for hot filling applications; Fusible film suitable for extrusion.

AY

in some embodiments; The single-layer or multi-layer material comprising one or more recycled and/or produced directly from the ore); PET (including PET of the following materials: polypropylene) foam; For preformed parts; containers and lids. In some embodiments the products may include a foaming agent. The foaming agent may be prepared by a combination of a foaming agent and an inert material. In some embodiments the material is slit : generally preferred for a homogeneous mixture of Blowing agent The lea of the carrier and the foaming agent can vary the amount of the carrier and the foaming agent depending on the desired amount of one or more of the following: expansion properties; structural properties; thermal properties; charge pressure; and the like In some indefinite embodiments, the expandable/foaming material includes less than about 701 less than about 701 by weight; of foaming agent. in some unlimited incarnations; AN 721 or 7 2 4 ... << by weight of foaming agent. In 77-1 the expandable material/foaming agent includes about 1 foaming agent. Another embodiment not specifically includes the expandable material/by weight of the foaming agent. in another, unspecified incarnation; The acceptor includes ZT by weight foaming agent. It is contemplated that the TAY of Expanding/Blowing Agent on approx. The Expanding/Blowing Agent may contain any appropriate amount of foaming agent including: that which is greater than or less than the specific percentage mentioned above; depending on Ye desired properties of the foaming material. pellets of polypropylene (SE) in some embodiments; Carrier and foaming agent are shipped as micro-pellets; microspheres of polypropylene or similar material are preferred; in a hopper (a funnel-shaped box). The EXPANCEL® carrier and microbeads are heated to melt the carrier for efficient mixing of materials. When the YO mixture is heated; The microspheres may expand or become larger. It is preferred that the temperature of the mixture range in a range of temperatures that do not cause complete expansion or decomposition of a large part

At of microspheres. For example; If the temperature of the mixture has reached a sufficient temperature; The gas inside the microspheres may expand so that the Alle microspheres break or shatter. The molten foam can be co-extruded and preferably quickly quenched to work out the amount of expansion of the microbeads. Injection; etc); The microbeads (Ball Da) when the foaming material is heated to curing under one embodiment may be partially expanded from their generally unexpanded initial position. When these microspheres are partially expanded, they may retain their ability to undergo another expansion to increase the size of the microspheres. He prefers; That the pressure and temperature are such that make the pellets for the purpose of allowing further expansion of the micro pellets during formation Gul micro not completely expanded while the pressure of the foaming material can be increased to work to reduce; or bial by blowing; eg. 0 outright ban; for dilatation of microspheres. Then; The pressure and temperature of the foaming agent can be varied to obtain the desired amount of microbead expansion. Partially expanded micro-pellets may undergo further expansion when reheated (eg during the blow molding cycle) as shown herein. It is conceivable that the products can be prepared by any suitable method; Including yo SER coating (Y) “(dip or flow coating) dip or flow coating (V) but without limitation on dipping with a bed layer (£)” (flame spraying) ¥) “(spray coating) 0 (electrostatic powder (©) “(fluidized bed dipping) (v) injection-over-injection); and/or Sis (overmolding) overmolding (1)¢spray (including co-injection). For example, (injection molding) 0 7574716 indicates the preferred methods and equipment for performing the methods in US Patent No. which is incorporated herein by reference in its entirety 0014-9716 and USP No. its contents and forms part of this request. It is also envisaged that these methods and devices can be used to form the other products described herein. Preformed parts (US Patent No. Si) herein may be blow molded using the methods and apparatus indicated in the references And) Ye are included herein by reference in this application. 3 (POY 7 Methods and apparatus for preparing a product Includes foam -1

AO

product can be formed; Such as the preformed material Tr through injection molding by using an injection mold. Figure YA shows a Mold 500 having a cavity 500 marked with a core £99 and the part for the mold cavity 04 8. The mold (00) can form a product with an extensible/foamed material. in some embodiments; including the embodiment shown; © The foaming material is passed along line 009 and passes through a movable baffle 508 and into the cavity 5. The foaming material can fill the cavity 00 to form a preformed material Fe The foaming material inside the cavity 500 can be quickly cooled or quenched To work to limit the expansion of the foaming agent and can reduce turn times to work to increase production. The mold may have a baffle or an Airy valve (03) to prevent the expanding foam from backflowing. 01 The back pressure of the melt can be substantially sufficient to make the foaming material in the form of micro-pellets SE though; The back pressure shall serve to prevent the microspheres from over-expanding in order to allow blow-forming of the preformed material to the desired shape and/or allow AT expansion of the microspheres. The temperature of the melt can be varied depending on the back pressure of the melt. for example; Bale can cause expansive high temperature microspheres to expand. To inhibit or prevent expansion of the ABBA globules the back pressure can be increased to delegate the increased pressure through each of the microglobules. However, if the pressure of the melt is great, dan, the micro-pellets may break or shatter. Then; The pressure of the melt is preferably maintained over a range such that a large portion of the microspheres is not fully expanded or destroyed. BY Other incarnations. On Alla A some or all of the pellets may break upon full expansion to foam form Dla (open cell foam). in some embodiments; The molten material may undergo at least partial expansion before it is injected into the mold cavity eg .9000; After the melt is injected into the ore cavity, the screw of the extruder can be retracted to collect the YO melt for the next injection. after retrieval; The screw can be depressurized to reduce the melt pressure to achieve adjustable expansion of the fine pulleys in the melt. in one embodiment; The molten substance is not under pressure and thus thinner

The microspheres can expand freely. On any dlls the pressure can be applied to the melt to selectively control the expansion of the microspheres. Accordingly; The microspheres in the melt can expand partially or completely before the melt is injected into the cavity (dual 00s) the microspheres are in a state of expansion so that the 0 microspheres can undergo expansion again during; for example JB Preheating process of blow molding The melt containing the microbeads may be injected into the cavity 000 to form the preformed sale with expanded microbeads The preformed material with the expanded microbeads may then be formed into the containing vessel Generally fine, evenly distributed pellets.

01 The cavity 0000 can be heated to result in a generally uniform distribution of microspheres in the preformed material. Heat can cause a generally symmetrical distribution of the foaming agent. In some embodiments the melt may include polypropylene and microspheres. is injected into the cavity 000 ; which can be at dan temp of about 100#F (.7/8""C) to about 0*75F

Ae jee that the microspheres are 2 * 000 °C). It can ensure the cavity heated YY) Ne ovr uniformly throughout the preformed material. In another embodiment the cavity may be maintained at a temperature of about 100”F (15.1”C) to about 7#7F

(7110*C). In another embodiment the cavity 900 may be maintained at a temperature below about 100#F (RATT) cavity 5000 may be cooled at any time convenient to achieve the desired pellet distribution minute. In another embodiment also includes the article

Molten on polyethylene and micro-pellets. He could have a lumen

Glee Yo at a temperature of about 5/7*F (7.5 ?C) to about 0

(10©*“Celsius) to form a preformed material.” Evenly distributed fine pellets are generally preferred.

The preformed material which may have evenly distributed fine globules can then be formed

Ye molding it in the shape of a bowl; which it spins; It has fine pellets evenly distributed. The above temperatures depend on the particular materials used. on this part

YY

AY

An expert in the field may choose the material(s); processing standards; and design (Say of the invention; the mold for the production of various types of products. Z 5000 heat. The speed of the passage of the melt through the line 904 and the cavity can cause friction and then cause expansion of the microbeads in addition to the heat of the melt. It is It has a highly heat transfer material 00 that can act on the YA _ die shown in the figure © in order to hinder the expansion of the pellets 00000 rapid cooling of the molten material passing through the cavity forming part of or 5017 min. that the material with high heat transfer (flow velocity; pressure lia) forms the entire mold cavity 4 and then; the operating parameters are 0 temperature; mixture ratios; viscosity; and the like) depending on the form; size and other characteristics of the die. 0 in some embodiments; The pre-moulded cotton contained in it can easily be quickly cooled or quenched for retardation; or even times; Expansion of microbeads 50,000 lumen This allows microbeads; which may be partially extended; by forming a tight structure that can expand during blow molding and after the preformed material has cooled; It can be processed into 0,000 fine pellets. in one of the embodiments; The conventional AT cavity without Ve expansion is maintained at a suitable temperature to adjust the expansion rate of the microspheres during the die forming process. in “0°F” at approx. 5000 indefinite embodiment; cavity is maintained to approx. 180”°F (+7.7°C) to reduce or stop pellet expansion (Ried) on materials Jil depending on for example 0000 per minute. Cavity temperature can be selected Size and design of the preformed material The volume of the space filled by the foaming material and/or preform 0 ov. Curing parameters The curing temperature of the material can be selected or determined by the skilled debater after knowledge of the foaming composition (carrier; foaming agent; microspheres); desired degree of expansion; and/or other parameters. (a) Preparation of products by blow molding process Molded products can be produced by blow molding process

Mia, by extending blowing to form a vessel; 0 product in the form of a pre-formed material (Fig. ); It is preferable to cause an expansion of the micro-pellets. The material TY can be exposed to the container

AA

FIRE EXPANDED BLOW MOLDING PROCESS PLACED IN THE MOLD SHOWN IN THE JY PREFORMABLE WITH YA CAVITY INCLUDING EXPANDABLE MATERIAL IN THE MOLD “0 PREFERENCE AND EXPANSION” 0 VIEW to the desired vessel shape The preform is then heated and YA formed by expansion of the preform 30 to fill the cavity in the mold a vessel Expansion can be done by for example air forced into the interior of the ©

FE Generally the blow molding process is limited to the mass portion Ye Preformed material It is preferable to preheat the preformed material oF + before the preformed material is expanded to the blowing temperature range of the blow molding process. If the temperature of the previous material reaches the expansion temperature range; The micro-spheres present in the pre-formed substance are organs.; Or after (Jd) it may expand. The expansion temperature range Fe can be reached. Formation Ys Preferably; the micro-pellets of the LF material are heated elongation of the preformed material to the range of its expansion temperatures to cause partial expansion on The least for the preformed Fe pellets by blowing. 0 minutes before the preformed material is formed to the range of blowing temperatures; 00 is done after the preformed material temperature is raised: to work on the expansion of the material Pre.. Ve pass. Haag .to the inner part of the preformed material 10 It is generally preferred that the range of degrees of TY forming to the desired shape of the vessel Expansion temperature is similar to the range of blowing temperatures so that it can expand Microbeads come by heating or reheating for blow molding. Expandable material is expanded when air forces the preformed material to elongate and mold to desired shape. In another embodiment it can be blown to desired shape and then can be Vo The preformed cat is formed 0 to the range of expansion temperatures to induce expansion of the foam TY up to the vessel temperature to increase the rate of expansion of the microbeads; The temperature during the TY blow molding cycle of the vessel may increase and/or the blowing pressure may decrease. In order to reduce the rate of expansion of micropellets; The temperature during the blow molding cycle can be reduced and/or increased, the preformed material can be heated/cooled and the blowing pressure can be adjusted. From YO adjust the pressure as desired.

Ad of the mold YY The temperature of the walls oF can be adjusted by referring to the shape of the container [ve] in order to achieve the expansion of the foaming material in the preformed material YA It has a temperature adjustment system to work on adjusting the YA embodiments; The template is al in 1. The temperature control system can have heating ducts / FY walls temperature effectively. TY refrigeration or any suitable system to work to control the temperature of the walls ©

in some embodiments; For example; The walls “FY” are heated to cause the expansion of the microspheres in the vessel “TY” After the preformed material “00” is injection molded to form the vessel “YY”, the heated walls ?? continue the expansion of the microspheres in the vessel wall (FY Thus, the wall density decreases.In this way, the microspheres in the walls of the vessel YY can be stretched or elongated to prepare a more effective thermal insulation due to the microspheres

greatly extended. The walls of YY mold YA can be cooled with the purpose of blocking; or prevent dilation or hyperextension of microspheres. FY walls may be heated during one or more parts and cooled during one or more parts of the production cycle. The YY walls can be heated during a heating cycle to induce 1 min expansion of the microspheres as discussed above. After the micro-pellets are stretched as desired; The walls of the TY mold should preferably be cooled to reduce or preferably stop; Expansion of microspheres 0 times: another. Then; The TY walls can be heated during a first part and cooled during a second part of Adee blow molding. on A case; the walls?? It can be heated and/or cooled at any appropriate time during the blow molding process; for example; In another Ye embodiment the walls of the YY mold YA are cooled while the preformed material Foo is elongated from its initial position to the desired shape of the vessel. The preformed material can be heated 0 ; inflated and stretched until the wall of the preformed material contacts the cooled walls YY preferably; That the expandable material that makes up the preformed material (Pe) undergo local expansion as an elongated preformed material. When the preformed material YO thermally contacts the walls FF the heat is transferred from the preformed stretch “+0” to the mold YA to cool the wall AE of the preformed material that has been formed. Once the oF preform has cooled the expansion of the microspheres can be reduced or stopped. can be increased

The pressure in the mold, YA, to increase to reduce the rate of expansion of microbeads. The pressure can be reduced in the YA die to increase the expansion rate of the microbeads. The walls of the YY mold YA may have been surface treated or textured to achieve a desired foaming reaction during a blow molding process that may result in a rough © surface (with bumps and bumps) of the FY vessel eg (JB The surface of the YY wall can be rough or granular so when the outer surface of the PV pot contacts with the wall YY during blow molding, the outer surface of the TV pot will have a rough foamed surface. The rough surface of the wall 37 enables further expansion of the microbeads after at least part of the vessel comes into contact with the wall of the mold YA In any case, the surface of the wall 0 has been treated to achieve a suitable structure for the outer surface of the vessel AY in Another embodiment, for example, could be the wall? of Mold YA having a low friction finish, eg steam polish, to facilitate release of vessel FY from Mold 78. The low friction finish could be of Absolutely smooth surface to make it easier to release the bowl The YA die can be used to produce multi-layered bowls Ve such as the AY bowl in fig. multiple by injection molding process; such as concomitant injection; superstructure and the like. It is meant that united batches of injection molding can be made to produce different shapes of products. Y - (a) Preferred methods and devices for co-injection molding The YA figure shows mold 000 that can be used for co-injection or co-injection to form single-layer or multi-layer products; Respectively. Multilayer preformed pieces may be formed by an associated injection step in which a combination of materials is concurrently injected into the cavity ©0000 and in some embodiments; A first and a second material are injected together into the cavity 0 Yo to form a multilayer preformed sale 0 In the embodiment shown in Figure 1 a first sale can be injected forming the inner layer VTE and a secondary material Form the outer layer 167 together through the movable bulkhead A 00 to finish the inner layer 114 in alignment

on the inner surface of the preformed Te the flow of the primer forming the inner layer 4 can be stopped before the flux containing the preformer continues through the entire cavity 0000 hence; It can deliver one or more materials through the 508 diaphragm at different flow rates; at the same time or at different time intervals; 0 in varying amounts; And the like to create a desirable product. Preformed material 0610 can have a thin inner layer 164 in relation to the outer layer TY 138 is particularly preferred if the material making up the inner layer 4 is significantly higher La than the material making up the outer layer 167. For example JU some phenoxy thermoplastics may be lae more expensive than readily available materials; PET Jia Thus, the amount of thermoplastics of the type: phenoxy can be used as little as possible in order to reduce the cost of the preformed piece material Ae The preformed material VAL in the form of Lad VY through an associated injection molding process using the 5601 mold. An experienced 19-0 will readily recognize that the layers of preformed material VAL OTe can be varied to achieve desired properties of the preformed dot. Fig. OY (NY) shows alternative embodiments .Co. of preformed multi-layered pieces 0. Fig. NY shows preformed material (SYA: has an interlayer (VAL) and/or Outer layer (VAY) has a variable thickness. Layers shown 8710(b) (GV AE) have an admixture in the mass portion of the preformed material 0_. The inner layer VAS (0) has a slightly admixed mass fraction For the last layer of the narrow part, in general the thickness of the outer layer (GAY) is greater than the thickness of the inner layer 841(b). It also has an inner layer of 94 and an outer layer of 194 with Yo values. It is envisaged that the preformed pieces of Figures 11-; Mass of preformed material. US Patent No. 13777641 ay incorporated herein by reference is listed in its entirety and indicates methods, systems and products formed by one or more molding processes. In light of this disclosure, it is possible Using various combinations of systems to produce a wide range of products by using co-injection processes. (b) First Preferred Method and First Preferred Overforming Device ©

Multi-layer products can be formed by injection molding process; inclined by a supraforming process. Figure 75 shows an example of the 5710 template for overmolding. The mold can have oY.has half core YY5 and half cavity OVE shown in the closed position prior to over-injection. The OYE semi-recess includes a recess into which the uncoated product 0 is placed in the form of a substrate Oa) The aforementioned piece (OVA) can be used

Overforming is the process of depositing one or more layers on a substrate. Preformed material #74 can be single-layer or multi-layer preformed sale. The preformed material shown is a single layer preformed material that may comprise one or more of the following: (Je) PET eg PET (Vo direct distillation of crude and/or recycled PET); PP “polyester” 0 thermoplastic phenoxy thermoplastics and/or the like. OYA preformed material can also be similar to preformed parts in patent applications or patents

which are included for reference herein in this application. The OYA support ring (support ring) in the OYA preformed material can rest on an OFT flange and be held in place by the 77© half core; Which exerts pressure on the OTA support ring and thus prevents sedimentation of the narrow part of the bulk part of the preformed substrate. Includes one half of the core 77© of the mold on the core 400 8. The core 5460 selectively heats/cools the interior of the preformed material 74©; while 544 channels can heat/cool half the cavity; 07. For example, cooling YO is effected by fluid circulation through channels £07 in half core 277 of mold OY once the preformed material OYA has settled into the cavity of the mold; The bulk part of the preformed material is completely centered inside the cavity and preferably completely surrounded by a void space or iy cavity +00 and the preformed material placed in this way works; As a mandrel, the heart of the formation is eaten in the next injection process. After that, the molten material is introduced with the formed material from an injection unit through a 00% movable barrier and flows around ©0506 above into the mold cavity, preferably surrounding at least the mass part of the preformed material OYA the preformed material after Over Injection The over formed layer will take approximate size and shape OTA Forming 0.55 Ly gill The coating material may be heated to form a melt with a viscosity compatible for use in an injection molding machine. The temperature will vary for this injection temperature; Material and viscosity of materials (polymers) because the range of melting points in polymers (ws AY degree of molten oad may vary as a result of manufacturing date; chemical property; weight 0 discharge and other characteristics of the material. ie For the formation of the laminated preformed pieces shown here 0710 Molds in the form of © can be used with one 00 preformed 00 The preformed material can be phenoxy thermoplastic PET or more layers 0 54 also includes 2 (polyolefin- and polyolefin-phenoxy) (including phenoxy) 05 laminates; and/or other thermoplastics. sale (polypropylene) polypropylene (phenoxy) ) 0 in some embodiments; the rest of the layers may include 0 08 of the preforming material..... eg foam The stretchable/foamed eal may include the 0 0 forming material and/or ethylene acrylic acid (PET PP Sb) on a carrier Jie pellets to be mixed with a foaming agent (eg microspheres; (ethylene acrylic acid) 0 to produce a foaming agent. eg. It may include ( EXPANCEL® Precise

Expanding/foaming ALE on OY material and outer layer PET inner layer 0 on Foaming material can be delivered through the line PET The preformed material on the substrate and the septum to move 4 into the cavity 000 longer The injected expansion/7 die material is then cooled for the next removal. In light of this disclosure; An experienced person can dee NYO select the material(s) depending on the properties of the material(s) and the desired products made from it. ¢ Preparation of multi-layer products by blow molding (1) Multiple products can be formed Injection layers in a similar manner as single-layer products, except as described in more detail below. Other multilayer moldings in a similar way, in particular preformed multilayer © pieces containing foaming material. And extend it by 50 scenes in the desired bowl shape. After that, the preformed material is heated by forcing air into the inner part of the preformed material to work on the elongation and extension of the preformed material so that it fills the cavity, and then a multi-layered container is formed. Optionally 0 by means of an extension shank or other means of material supply 0 the preformed material may be extended preformed . 0 over material with processed products 50 in some embodiments; Contains preformed material

PET contains Of the same or different. The preformed material may include an inner layer of foamed and without PP (comprising of Sa 78 incorporating another material of OF and an outer layer preferably 1 0 PP mostly or entirely of oY foam ). The outer layer b The inner layer 4© and the outer layer 0 can be formed by blowing through a machining aperture on PP which is considerably wider than the machining aperture of the pre-cut. preforms manufactured entirely from preferably; The curing hole width may be increased regardless of the thickness of the inner layer to improve adhesion between the AG layer and the outer layer 07. Optionally the inner 0 layer 08 and the outer layer "*. In one embodiment; acts as a coupling agent or (eg. adhesive).

OY and an adhesion setting between the inner layer ©4 and the outer layer AC on the formation of a stretching layer composed of ALE in some embodiments; The © layer can be materialized through overforming by using injection molding to act on the injection of at least one layer (sle) (sle) of stretchable material over an upright formable (yo of etc) . The inner layer (phenoxy) may be a similar PET thermoplastic so that each of its Tg and carrier material of the foamed layer can be processed

It is of two layers 0X08 through preferred blowing temperature range values. As discussed in the lisa the range of expansion temperatures may be the range of temperatures that causes microspheres to expand. The range of expansion temperatures can be varied by varying the pressure applied to the material ALE for expansion. He prefers; The expansion temperature range is similar or agree with © Blowing temperature range for the two layers 0X 0% During the blow molding process the temperature of the preformed material can fall within the expansion temperature range to cause at least partial expansion of the microbeads. Then; The foaming agent of the foaming layer OF can expand (1) during reheating of the preformed material for blow molding; (Y) during expansion of the preformed material into the vessel shape; (©) after the vessel is face-formed cole and/or (;) 0 combined groups of (1) Ss (AY) (1) in some embodiments; the multilayered preform may be blown into a vessel having a suitable inner layer. (c) 2nd Preferred Method and 2nd Preferred Apparatus for Overforming The methods and apparatus described here can be modified to make the other preformed pieces shown here. Before the material is injected. The material may or may not have a preformed narrow finish. For example, the preformed material can be without a waist. The die 0: has a core part 011 and a cavity shaped part 5067 has a surface part For OTA cavity Mold 0 includes cavity 570 defined by core 577 of core part 51 and “0_hollow” part 0175. Line 5777© can charge melt through ove baffle and into cavity OV The cavity OV has a shape corresponding to the desired shape of a portion of preformed ale. In the embodiment cua gall the cavity OV is designed and sized to mold the inner layer 74 of the preformed material 0610 in the form of 11. On any dla the cavity OV YO can be sized and designed To create any desired product. For example; The cavity 5700 may have a corresponding shape forming an inner layer; Such as the inner layers of any of the preformed pieces shown above. The melt can be injected into the YY cavity

OV in the manner described above to create a die-cut product. The molded product can be removed from the hollow part (OTT) and then inserted into another hollow part (Sa) hollow part in form (91) for an overforming process. Overforming is performed using Adee injection molding using equipment similar to that © used to form the VTE inner layer as shown in the FY figure. It can be inserted into the hollow part 080. (Say that the layer 164 or the hollow part OAs specify a cavity or cavity 87 corresponding to the shape of the outer layer 7 of the preformed material VT of the form 11. face cole The melt is passed along line AE and passes through a diaphragm OAT 0 and into cavity 287. The melt can fill cavity 587 to form the outer layer ANY after the preformed material is cooled 01 in quantity (AIS) can be removed from mold cavity 087. After over-injection the overformed outer layer 167 will take the approximate size and shape of cavity 587. To perform the overforming process, it is preferable to heat the primer layer 114 which Ne << is intended to be superformed to its dan temperature greater than Tg and its own. In PET Ala the temperature is preferred to be about 001 to 100"C; most preferably about Ail A to about 75 LA AY If a temperature at or above the Lal temperature is used for PET which is about Augie Yo then care must be taken when cooling the PET in the previous material formation. Cooling shall be sufficient to reduce crystallization of the PET in the preformed material 0; particularly in the bulk part; Thus; The PET in Ala is amorphous and/or semi-crystalline preferred. ea The primary inner layer of YE may have been very recently injection molded and not completely cooled to a high temperature as is sometimes preferred for overmolding. The formed material is superheated to form a melt with a viscosity compatible with TO in an injection molding machine. For some materials such as foam &07; It is preferred that the injection temperature be in the range from about 751 “”F to 0©©”F.

Q after the overforming process; It is preferable that the pre-formed multi-layered material be cooled at least to a point where it can be removed from the mold or held without breaking and removed from the mold where further cooling may occur. if the bulk portion of the preformed material has been heated to a temperature close to or above the crystallization temperature of the material composing the bulk portion; © The cooling must be rapid and sufficient to ensure that the material is essentially in a semi-crystalline state when the preformed material is fully cooled. As a result of that process; Strong and effective bonding occurs between the primer material 1764 and the outer layer applied thereafter TY The final narrow layer may have a greater proportion of crystalline material to work for increased dimensional stability especially during the subsequent process Ste) blow molding; hot packing and the like). In the light of this 0 revelation; A person skilled in the art can choose the type and design of molds to make the single-layer and multi-layer products shown here. Dies, special processes, and other preformed embodiments can be found; including those of the foregoing; In light of this disclosure Hana and other details of molding processes (eg by injection-over-injection molding process) in US Patent No. 1707477 are incorporated herein by reference. 1 *- Special methods and devices. to prepare a cover (stopper) can cover; Like the covers shown in Figures 8-1"(e) by using an injection mold. The molds in Figures 1" and 77 are generally identical to those in Figures YA to oF) except as also detailed Here Fig. 1 shows a die 00 being designed to form at least part of the cap. The die ve is defined by a core part 07 having a Vet core and a recessed part VT in one embodiment; the material is passed through PET ia) including PET directly from ore and/or recycled 1; PP phenoxy-type thermoplastics PP stretchable/foaming material and/or material(s) ) other suitable in alignment with line 709 and passing through movable Sala 70# and into cavity 701 which is defined by core 7004 and hollow part Yo 206. Material may fill cavity 701 to form at least part of the cap. Determine the size of the bore 701 shown and its design in the form of the inner layer of the cap body. On the id case; the bore 701 can be designed to form the entire cap. Lad can include aA to form a belt and connecting parts between the body and belt 1011 optionally on part 701 bore cap. Caps shown above that have multiple layers can be formed by special overforming. VY mold can be placed YY epitaxial forming process. Shows form

VEL Template (TY) formed by template 1777 lined layer or substrate © position 776/1 having a heart-shaped part 774 and a hollow part 7710 the template (FY) Form with a VE body part in the suspensory part prior to over-injection.A bifurcated ring can be attached

YA on cavity VY of the substrate 7. The cavity part VEE and belt VEY include:

PY in which the non-laminated substrate is placed; it is a multi-layered part of the covering; However 1777 the substrate shown Ve is a multi-layered substrate. In some 17 Substratum Alls can be embodiments that are not specifically; 77 substrate may contain recycled PET directly from raw material and/or PET 7 and/or one or more of the following: thermoplastics (including phenoxy) PP (polyester) laminate material; terminator unions and/or similar (phenoxy) thermoplastic unions of the type phenoxy + 0. Substrate material 777 may also be a gauge cap used for sealing And that, 1777, a person skilled in the art can choose the size and shape of the lala substrate depending on the desired end use of the plug.

VEY substrate VEY in mold cavity; The volume of 1777 when the substratum settles, the VO material fills the cavity and is completely surrounded by a void space, Jala, preferably centered at the substratum 0 777; described in this way; as an inner forming mold in the next injection step. The melt for overforming is then introduced into the mold cavity from the injection unit by and flows around the substrate 777 preferably which is connected to the VOY part by the bulk diaphragm of at least the substrate 777. After over-injection; You will take the formation layer

Vou epitaxial volume and approximate shape of space Yo for the formation of the coated or multilayer seals shown herein. VE die-18 may be used in some unspecified embodiment of the invention; The payments are in the forms

17(e) f; May have one or more layers of PET based thermoplastic phenoxy polypropylene foaming material; and/or other thermoplastics. Optionally at least one of the seal layers can include ALE expansion/foaming. in some embodiments; The cover for © (fig. 19) can be made of layer 306 of primer (PET Sa) and outer layer of PP (eg PP with foam or without foam). The method and devices shown in The references which are included by reference herein in the application for the production of caps. For example Jal machines; molding apparatus and methods set forth in US Patent No. 1327477 lai (Figs.) = (Y€ -117 do 0) may be modified. For the production of sheeting (eg Jal) the molds may include a material highly capable of heat transfer; cooling ducts; oe insertion systems and/or similar. F- Methods and devices for placing a material on a substrate. 10. Systems for making products may contain one or more devices or systems that deposit a group of materials. Sa that the molds shown above have one or more delivery systems that deposit an underlying material; Jie is produced in the form of preformed material; stopper; And the like. The precipitate may form at least part of a bonding layer or other layer (Ol (barrier layer). For the sake of convenience, the connection systems provided here are initially discussed for Adi devices such as injection molding machines for the production of preformed parts. On dlls a delivery systems can be used to act on the connection of other materials (eg thermoplastics comprising barrier materials; foaming material; and the like) to substrates in the form of seals; primary (Se) bottles); sheets. tubes, etc. Referring to form (TE) connection system; 001 of molding device 011 can be used in various types of molding systems; Je injection molding system or compression molding system; eg YO. Molding devices may be It has a delivery system ;100 to improve the adhesion between the air and/or the material in passing the molded product.

Veo for the production of single and/or multiple preformed parts 0001 Molding System VY showing a figure that is similar to 0017 having a coupling system 100; and Mold 0001 layers. The molding system shall be, except as explained in detail below: (YA shown in Figure 500 for the mold and 5 for an overforming process. The TE in Figures 00117 is designed for the mold to be prepared for overforming of many preformed pieces and includes 0011 template shown © when 011# works together to define cavity 015 and socket part; 0107 on template part

YO in the closed position shown in Figure 0017 is the template

Vert includes a fluid delivery system 00117, the template Vos WE for the two figures is a fluid delivery system; Preferably a binder” in the cavity that serves to receive a fluid; pressurized fluid is preferred; from a fluid source. includes 0101 Ye charge line and slot 0001# on drain line 7 connects to die cavity 01011 drain system fluid delivery system ;100 injects fluid; Separate a fluid (YF (Fig. (Fig. 0177 Substrate .. ": Preformed:. After that, the preformed material is superimposed by a layer of material. NO prefers that the bonding fluid forms a bonding layer that adheres to a superimposed layer with the preformed substrate 1 By passing the fluid through the discharge line #0011 the fluid can be removed from the bore (Fig. ©). pump) at the same point in the alignment of the drain line Y. suction) to improve the flow of the binding fluid. and discharge to selectively controlled flow rates 0101 Pressurized Bonding and by Charge Line 0018 In some embodiments the bonding fluid is delivered to the bore #001011 through the bore and then a vacuum is drawn to remove unused bonding fluid. The YO drain system may not have a suction making device. For example, the exchange system might be 017

011 It has a discharge to the atmosphere directly or through a purification unit to remove any harmful substances on 7

VOCs Jue Environment The delivery system can be used to;100 work to deliver an item; packaging material preferred; to the heart 07 . in some embodiments; The material is a non-binding packaging material. As used by Hana, the term 'packing material' is a commonly used term and is used according to its meaning © ordinary cay polymer molten material and may include, without limitation, a fluid, material, and similar materials that serve to form Layer with all or Baal (©00170; Materials) Part of the surface of the product The layer in the mold. The coating material can give desired properties to the substrate. In some preferred embodiments, the coating material may be prepared to form a layer barrier) on surfaces. (polymer) A synthetic layer (eg binder layer; polymer layer 0 A common term would be “tie fluid) As used here, the term ‘binding fluid’ is used according to its ordinary meaning and may include; without specifying. on a fluid that may be applied to the preformed material to form a bonding layer; adhesive Or a layer with a specific function and may improve adhesion between materials. For example; The thermoplastic bonding fluid (polymers) can be a chemical that may improve adhesion between polymers of Vo elastomers; Other materials shown herein and combinations thereof. The cd ge binding fluid may include maleic anhydride (Sta) (anhydride polymers) with one or more acrylate copolymers (maleic anhydride) solvents. cael gb Acids; Adhesives; cross-linking agents and/or Ye mixtures of phenoxy/polyolefin (phenoxy) other adhesion-enhancing materials; Phenoxy The binding fluid may include one or more of the following: - (phenoxy/polyolefin) sprays and/or combinations thereof. The binding fluid can be selected depending on the eile of plasma particles; le materials that are in contact with the binding fluid. in some embodiments; The binding fluid forms a bonding layer in some embodiments; PET fluid prepared or designed to adhere a foam layer to the YO layer PET can be added stronger on the PP bonding layer to form a bonding layer causing layer adhesion. binding agents or similar) to the binding fluid ci chemicals; Sa particles) Additions Covey

01 To improve the adhesion properties of the bonding fluid. Then; The bonding fluid can form a layer

Ta bond eg binder layer of vessel 87 in Fig. 6. In some embodiments; The pl fluid includes one or more of the binders described above. in some cases; 'Connect' and 'bond' are used here interchangeably. The connection system can be configured; 100 at the FV TO connection as shown in Fig. Between the ribs of the die cavity surface YE

Nee preferably further away from movable baffle 0118 Alignment with mold cavity surface The movable diaphragm 6 may be designed to act on the injection of a material (eg molten; polymer 0118 molten Yooh. outlet is formed; and the like) into Bore (polymer) small 0 178. The outlet .0001#8 marked circumferentially around at least part of the bore 0 018 is large enough that no melt enters during injection. mutually; The outlet has 00101 on one or more individual slots or ports. Optionally charge line To selectively adjust the fluid flow through the charge line (VE) (fig. 0171) valve system if present; at any position along the OF line the valve system may be located 0. in Some embodiments, including the embodiment shown in Fig. 50; .00101..charging is done allowing 0.08 to reverse the direction of a set of bores. Valves or selectively prevents flow through the charging line though .0154 is buried in the material making up the hollow part .0171 Valve system

Se) could be located near exit 0171 that is not indicated. The valvular system

Are from the charge line (Va YA Output 0) in response to a pressure; eg positive pressures or 0171 The negative valving system can be actuated and may include one or more valves; eg a lever-type check valve. In one embodiment the lever-type check valve is a check valve on 00101 and a clamping part. The pressure in the charge line BS may act as a sphere with a combination of displacing the ball away from the clamping line; but the pressure present In the opposite direction Je Yo will push the ball towards the mounting part and prevent the flow in the reverse direction.It is preferable to also have a spring to deflect the ball in contact with the bearing.When the existing pressure fluctuates

01

in line charge 00101 on the deflection of the spring; the ball can be dislodged from the bearing allowing flow into the bore 018 (Fig. Vee A it can cause fluid to exit through the No Fe 0 valve system Alternatively the .0170 valve system can be mechanically adjusted regardless of the pressure For example the 017+ valve system can include One or more SA valves (movable diaphragm valves; ball valves; and the like). Valve system 11 can be actuated to deliver a set amount of bonding fluid to the bore

Da Ve The outlet V+YA (outlet) of the YO shape can be located at any position in the alignment of the die cavity surface NVA The position of the outlet 01748 can be measured on the desired fluid flow around the preformed material. For example; Die 0017 shown in YO figure has outlet 0178 located near or at the portion of die cavity 0 corresponding to the end cap of the preformed material. The fluid which is 10 : dissolved by the charge line 00101 may flow around the circumferential apex of the preform and continue upward along the bore 018 to the drain line 00106 thereby causing precipitation of material on at least part of the preform . Mold 0017 shown is designed to deposit the binding fluid on the bulk portion of the preformed material. As shown in FV figure the outlet 0178 is preferably configured with a distance of 0176 between about 0.05 oe oY (000 inches) and about 1.177 millimeters (000+ inches) and more Preferably about VY » 0.0 in oF (mm) in depth. because of its small size; The outlet 018 with a general wrench will not fill with the melt during injection but will enable the fluid (air-binding fluid, materials/or other fluids) to reach out of the outlet (gb) YA some embodiments; A fluid can pass ia) air; binding fluid etc.); Through outlet 01768 to remove any material through the outlet (Ye) NYA outlet Although it is clear that outlet 0178 can be placed at other locations in alignment with the surface (Je) VA for example; The outlet can be 0178 at a position in alignment with the corresponding 0108 surface (canal) narrow end layer and/or loop

$ A reinforcement from the preformed material. For example, output 0178 may be placed near the terminal apex region of the die; Below the reinforcement ring of the preformed material (JE) at the final narrow layer of the preformed area; or at the bulk portion of the preformed material. Also several exits 0178 can be placed in the NVA surface alignment ° A skilled person can Selects the size, shape, and position of the Vo YA outlet to achieve the desired deposition of material on the substrate.Ve YA outlets may be placed on the same or opposite side of the preformed material as an inlet designed to receive unused binding fluid.For example; Outlet 0178 may be spaced diagonally from outlet. In the embodiment shown, inlet 0176 and outlet 0178 are placed on the same side of preformed 0 material. Referring to Figure FO TE the drain line 0101 is designed To draw the fluid out of the cavity Vee A (Fig. YO) the drain line 0101 then connects the connecting fluid to the drain hole 00101 or the recirculation system so that the fluid can pass through the cavity #0018 times sec. The drain line 0101 could have a valve system 018 VO that could be similar to the valve system 0171 so it would not show more eal when running; After the preformed material is placed in mold 0070, the valve system 0 0 allows the fluid to flow through the charge line 0 and into the cavity LY er A is : shown in Figure 77 5 ¥V the bonding fluid TF It may flow through cavity 00118 and cover at least part of the outer surface of the preformed material. He prefers; that the binding fluid TF 0 encapsulates the aS portion of the preformed material forming the bounding inner surface of the cavity AeA in some embodiments; including the embodiment shown; The binding fluid TF forms a thin layer of material over most of the bulk portion of the preformed zone; or a continuous, generally structured or irregular envelope. on any condition; The binding fluid TF may coat any part of the preformed material exposed to the fluid. For example” (Say) encapsulate the threaded beam finished Yo and the bulk portion with eda jl fluid if bore #0018 is specified by both the threaded portion finished and the bulk portion of the preformed material.

01 can selectively set 0017 to improve the packaging of the preformed material; The mold for the shape of 01560 is the temperature of the preformed material. in one embodiment; The core heats or cools the preformed material to improve the encapsulation of the preformed material. Yo an experienced person in the art can choose the desired temperature of the preformed material depending on the properties of the bonding fluid that encapsulates the preformed material. as an alternative; Preformed 5 pieces can be electrostatically charged to improve the encapsulation of the preformed material. In other embodiments, the preformed material may be physically or chemically roughened or granulated to thermally improve the encapsulation of the material to enhance the preformed 0108 encapsulation. Optional mold cavity surfaces can be adjusted 0108 Preformed material. For example; The mold cavity surface can be cooled Generally remain in the gaseous phase. 0011# in particular to ensure that the gases in the cavity 0 The temperature of the binding material can be selectively adjusted. For example the oly load of the binder may include a binding fluid that has been heated to reduce the viscosity of the binding fluid to facilitate diffusion of the binding fluid. Flash heating and/or cooling units can be used to adjust the temperature of the binding material. By charging the binding fluid into cavity 001; (delivery system)

Veoh, the bonding fluid encapsulates the preformed material and may flow out of the cavity. 0018# NO. The preform has been encapsulated or after a period of sald) after it has been 0101. Jala drainage system: to reduce » It is preferable to stop the flow of 00154 at a predetermined time. The delivery system can operate iby The coating on the preformed material can form a layer of Ve eA fluid in the cavity with a substance that is then injected through the septum 17 to bind the preformed material Substratum If the binder is a solvent/solvent; The LY vA in cavity 00140 movable 0 can be 0011#8. The flow can be reduced or stopped and the discharge from the cavity tie inert gases (elon She) can be done on gas or steam delivery 00101 charge line working 01011 drain system can .001# nitrogen; or other gases) to clean the bore with this V+oA optionally due to the negative pressure causing removal of the gas or vapor in the bore by the method; One or more solvents may be removed in order to achieve the desired properties of the YO binder and/or superimposed material.

01 material jad ne during the injection of the melt; The valvular system preferably closes in some .001# up and fills the bore 0015400 fused through the movable septum by streamman 0018 embodiments; Excess of the binding fluid is lifted out of the mold cavity by the injected melt. Then; The molten stream causes removal of the binding fluid, for example; If the binding fluid is a gas then the gas can be #0001__ from the cavity by the advancing magma stream. The casing of 00118 can spread out of the cavity the binder formed on the preformed material by means of a stream the molten material 00018 stream. When the flux advances in alignment with the bore the flux can push and spread the binder around the surface of the preform to ensure that at least part of the bulk portion and preferably most or all of the bulk portion;0 is coated with the binder. A person experienced in the art can set the proper outlet location depending on the properties of the binder and the melt stream to achieve the desired binder layer 018 in the resulting vessel of the preformed material. During the injection of the melt stream; The system can open ove by reference to the shape of the system can encapsulate Veo A to allow the bonding fluid to escape from the 0174 valve bore 0 after a specified amount of melt stream has been injected to prevent or dampen 018 valvular as a substitute; The outlet YN can be the melt material to enter the discharge line has a small volume and thus the photographed material will not enter 0101 of the discharge line 4 from (sal) to a large extent in it; but it will enable the fluid (binding fluid Air and/or fluids 0101. Access to discharge line Ye Optional When injection completes; pressurized fluid supplied; preferably air to outlet to act as discharge may form between preformed material and cavity wall. 018 lbs. delivered / square inch (approx. YY at a pressure between about 0.178 MPa air supply to outlet) and more preferably 0.17 MPa) and 1051 psi (approx. ©" MPa). Other Embodiments; 1.14 psi (approx. 001 YO) without the aid of pressurized fluid from charge line Ve VA removes preformed material from die cavity

01 Similar connection systems can also be used in other parts of the mold; For example, a region. eg without limitation edd ll together to form fluid 0154 and hollow portion Ve oY optional core portion 0017 leakage can serve to inhibit or prevent bonding fluid from escaping into the surrounding mold and then ; if the binding fluid contains volatile organic compounds FO shown as © or other substances undesirable for the tracers or the environment; The VOCs can rotate and reuse 0017 molds. 001017 molds can contain the bonding fluid to also work with less waste. The binding fluid may be drained by or by some other means. If the binding fluid is suitable for release in 01011 drain system Jia can pass atmosphere then the binding fluid can be discharged to atmosphere. For example 0 and then may pass between part 0157 the bonding fluid between the preformed material and the flange: and exit into the atmosphere. Veo and the hollow part 0107 the core in 0017 can encapsulate the preformed material By means of a binder before the mold is in the completely closed position. The bonding material may be placed on the preformed substrate when, then; The material is encapsulated 2) 2 OF The preformed material is inserted into the shaft of the hollow part > 0 . Preformed with the binding material when the preformed material is almost or at least partially in: the part. hollow 4. In some embodiments; Delivery System 4 exits in one embodiment; LS operates in a partially open position or 0017 fluid when the mold is in motion when the mold 0011# moves to inject the binding fluid into the cavity 001 delivery system when the material Yo enters from an open position into The closed position shown in Fig. 0117 0 0 preformed in the hollow part; 5100; The bonding fluid flows upwards through the preformed cavity 0011. before the mold is sald) and encapsulates at least part of 001 may 0017 in the closed position; The binding fluid can escape into the atmosphere. Then; The template, for example; If the binder is placed before 0.0101 with or without the drain system, it is preferable not to have the 0.017 system in the closed position; The template 0017 will be the template ve in the closed position 0017 if the binding material is placed after the template is LY VY drained

01 Particularly where 0101 is not preferably a 0017 discharge system, the template binding fluid is suitable for discharge directly to the atmosphere. Vert has another embodiment of the delivery system;100. The delivery system shall be YA showing the shape of the bonding fluid (air etc.) to the bore Sa) for the injection or delivery of a fluid 00101 many inlets or 00101 the fluid can be connected in response to positive pressure in the charging line Veoh © By 00117 under negative pressure. In the embodiment shown, die #0011 is drawn into the cavity attached to each inlet. The delivery system; 100, which has many outlets, 000 charging lines

NYY may activate a more uniform encapsulation of preformed material 0 identifiable with apex area 0111 having an inlet FE delivery system located 10100; to form a unidirectional flow generally regulated through the 0111 peripheral. Inlet position Ye leads to conduction of binding fluid in 00101 some embodiments; The charging line BY A cavity is a liquid that submerges the end tip of the preformed material. After 100,000 quantities of binding fluid are delivered, the melt can be delivered to the bore through the 0.100 movable diaphragm. The molten substance spreads the binder on the surface. co Preformed Material. 0 Other devices can be used here to apply binder to products. For example, to be placed on the inner surface of the FY 170 (YA) the molds in the figures or the substrate shown can be modified. Optionally the delivery system can connect to the line that connects the material with a fluid charge; 0101 The JB charge line can lay the melt in a cavity. For example 0 hook to line through a movable baffle that encapsulates an underlying material. After the underlying material is encapsulated, the melt can be injected through the same line and baffle In the patent (YT) the template shown in Figure (Se) additionally, the insertion of the template US 7 and applications and patents that have been listed can inject a bonding fluid to work on both Ye Overlaying a preformed piece and assisting in the release of the preformed material. The laminated substrate can then be overformed. Jointing system (or Ja) systems can be used

For the connection of other materials (eg one or more of the materials indicated (Ua) on the products. For simplicity, devices are described as conducting a bonding fluid. However, it is understood in many cases that other materials may be connected by means of the devices shown above. For example, “JED may substitute the fluid or binder with a colorant; chemical; fusible substance; ©¢ (polymer) bale powder; barrier material; and/or other material suitable for coating at least part Substratum G- Products are generally preferred Detailed products shown herein include products with one or more materials Substance(s) may form one or more product layers Ye Preferably Ye gives product layers the same functionality It may be used as multiple layers Each layer has one or more functional properties Or as a single layer containing one or more functional components Products may be in the form of packages Sha preformed pieces Caps containers etc Materials are mentioned The methods, range values and embodiments shown herein are for example only and are not intended to limit the scope of the invention in any case.The products described herein may be composed of any suitable material described herein. Nevertheless; Some of the products and materials are discussed below. In light of this disclosure; Avatars and materials may be modified by a person experienced in the art to produce avatars and/or other alternative uses, clear modifications, and equivalent images. Of which. -1 General Description of Preferred Ingredients Products 90 0 Unlimited Products Include Foaming Products May include foaming agent. in some unlimited incarnations; The foaming material can form part of a block product or the narrow finished part of a preformed material. in some unlimited incarnations; Foaming agent includes less than about 74980 wt.; Also included are less than about 0 10 LA LA LA LA FALA KALA LA LAs by weight of the product (eg preformed sheeting; eles board etc.). in some unlimited incarnations; The foaming agent contains about ivo by weight of the product. in some unlimited incarnations; The foaming agent includes approximately 718-770 by weight of product. in

YY. wt. 70-701 Some unlimited incarnations; Foaming material is included around the product. In some embodiments the foaming includes more than about 790 wt. of the product. The foaming agent may constitute most or all of the product. Foaming material may result in products with a lower weight compared to conventional products and thus may desirablely reduce the cost of transportation Foaming material can reduce the amount of material used to form the products: Liad the products. Foaming may have a large number of voids. To stretch. For example; An ALE can involve placing foaming material from a material (Sa) at least part of a product onto an expandable material having an initial density that is reduced as sale of the expandable material expands. In some indefinite embodiments, there is a first material Preferably made of cele) first and second material; It is preferable that the AES material be stretchable; it has 0

JN JA JA 3446 The first one has a second density. The second density is about less and range values that include that percentage than JN GLY 0 Ne AY IY Jon the first density . in some unlimited incarnations; The second density is in the range of about 72650 to the first density. Then; The foaming material can be made with a density as low as 0 for an expandable material. It is contemplated that the products may contain: any suitable amount of Agent 1: foaming composition including those greater or less than the above mentioned special percentages depending on the desired use of the products. A (phenoxy) (b) Unlimited products that include a thermoplastic of the type phenoxy, for example, mixtures of (phenoxy) The products may include thermoplastics of the type phenoxy (((polyolefin-phenoxy) (example; A mixture of phenoxy-polyolefins (phenoxy) 0 Basia) or combinations thereof, in some embodiments other than (phenoxy) phenoxy-27 may be a part of the products; for example, the (phenoxy) part that the phenoxy-type thermoplastics form at least the inner surface of the preformed material; lid; container; etc. In some (phenoxy) unlimited embodiments; include phenoxy-type thermoplastics do IY JY of about 7270 wt.; also includes less than about Ji ve wt. of the product. In another unlimited embodiment; 20 Yo 27 Ve JAY 0 wt. 74-1 on about (phenoxy) The thermoplastic material includes phenoxy

from the product. in another unlimited embodiment; This material includes thermoplastic type by weight of the product. In another unspecified embodiment; 7159-1 contains approximately (phenoxy)phenoxy by weight of product. In another, unspecified embodiment, the elastomeric material 7275-17 comprises approx. by weight of the product. in some AV 00 thermoplastic phenoxy-type expanded or (phenoxy) embodiments; The thermoplastic material of the phenoxy type © from al forms a layer that is mixed with another material. In some embodiments the stretched layer includes material by weight of product. in some 721 forms about 7001 to phenoxy type incarnations; It includes a layer expanded on a phenoxy thermoplastic material by weight of the product. in some embodiments; A plastic material 71 to 70.1 forming about polyolefin (PET is) (polymer) is mixed with a thermoplastic (phenoxy) polymer of the type 0 phenoxy 0 FL AX JN dee in unions, including ) and may include more than (polyolefin) by weight of the product. It is assumed that 2710 clon 1# AX we NY ML These percentages can be by size in certain embodiments. May result from the thermoplastic material into products having one or more of the following properties: desirable removal of flavour;

CL for recirculation and/or other suitable properties ALE (oxygen) Oxygen barrier oN removal 0 Very particular for contact with foodstuffs. These percentages may result in desired effective (phenoxy) properties while reducing the amount of thermoplastic phenoxy-type material: thus a cost-saving product is prepared. With phenoxy-type thermoplastic (phenoxy) sale The use of different unions of (Sa) foaming material, and the like “(polypropylene) polypropylene” (polyethylene) – polyethylene 0 containers; and other packages of relatively larger sizes and with (JS) characteristics to produce Precut (phenoxy), especially when a thermoplastic material of the desired phenoxy type forms the surface of the packaging that comes into contact with foodstuffs.

PP and a layer containing PCT Desirable adhesion between a layer containing (phenoxy) phenoxy It is envisaged that the products may include any suitable amount of type 0 YO thermoplastics including those in excess and less than the mentioned special percentages (phenoxy) Phenoxy depending on the desired use of the products. edie

ARR

Products in the form of preformed pieces / containers: - “The foaming material may form one or more parts of the layers of the products (eg packages containing preformed parts and containers). The preformed material may include sale We 0 foaming material In some embodiments the preformed material ©1 in the form of an elastic material 1 includes foaming In some embodiments the preformed material may include formed through an injection process eg thermoplastic material of phenoxy type ((<001600). In We vo the preformed material includes . The preformed material is different materials. Fo where it includes the inner part and the outer parts of the preformed material, the co-injection material can be shaped into a desired shape. For example, 0 may have an inner part that includes one or more of the following: Thermoplastic material “0” Preformed material Expandable material/foam or similar. PETG PET “(phenoxy) One or more of the following: Polyvene The outer part of the preformed material (including polypropylene) includes ethylene terminators and the like. Optionally part may include (PET (PET) purified); The preformed material 0” can be coated with a film to improve its retention properties. For example, the preformed material can be coated with a barrier material. For example; The US patent application, serial number (©) which is incorporated herein by reference (0) VIMO 704 (Publication No. 214710/01 0) in its entirety, describes systems and methods for packaging preformed parts. This system and other systems may be used shown or listed here to form barrier layers as shown here. It is then possible to pass an overlay of the preformed material coated with another material to form an outer layer. ,

Fa It is preferable that the preformed material include an uncoated LO and then be coated with a polypropylene YO foam layer such as polypropylene (polypropylene) that is not laminated on a polymer material and / or materials (phenoxy ) Thermoplastic materials of phenoxy type, PETG PET, (polyester)

1 uncoated YA other thermoplastic. in some embodiments; The preformed material includes the preformed material os al in embodiments (polypropylene) principally polypropylene (polyester) principally polyester va either on a single material or on several materials (eg fine layers of Layer 0 may include foam in some embodiments not limited; layer 0 may include many of at least 2 materials) ©

JA. No he said nokal pal IY l 1 on about? If he said oY foamed and values that fall within the range of those percentages of the preformed material. In some m0 about 77 to about 74960 of pre-matter oF embodiments; The foamed layer includes about oY preform. in some unlimited incarnations; It may include the foamed layer of the preformed material. in some embodiments; It can contain 750 to about 0 to 0 of the preformed material. In some 72700 to approx 701 oY foamed layer 775 that the 7© foamed layer includes about 75 to approx 75 Say indefinite embodiments; of the preformed material. in some unlimited incarnations; The layer may include preformed material. It is envisaged that these percentages are 7700 less than about OY Foaming _Centigrade can be by weight or by volume in various embodiments. The foamed layer of its 1 0 0 preformed material may include #1 non-expanded foaming material. The outer layer may be OF 0.8 inch) to about vr oA) 1.7 mm thick Preferably average wall thickness of about Have a thickness of about OF The outer layer is carne other than AT inch). In embodiment +0 Y (mm in). in some embodiments; Average wall thickness taken only in alignment with Y (4.0 mm) 0" in some unlimited embodiments; includes .090 mass portion of preform XY; 50 preform wall low Less than about 7980 of the average OF outer layer

JN. Don't say the dA pallet is less than around Lad including 0.5 of the average wall thickness of the preformed material #2 AT LY ML A on microspheres that are either not expanded or expanded oY the foam layer may include homogeneous in general or OY the foam layer may be partially elim; For example, YO oY is generally heterogeneous. Although this is not shown: the foamed layer for example can 5.0 can form other parts of the preformed material

At least 16 or 0 part of the inner surface of the preformed material OY forms the foam layer

FY is part of the civilized part on one or more of the following: of in some embodiments; The inner layer can include (eg polypropylene) 0157 “(polyethylene) polyethylene without foaming; polypropylene foamed; polypropylene © purified); Terminated unions and the like. For example; It can include (polypropylene) (preferably (polypropylene) outer layer 0 of polypropylene 50. The preformed material is optional. A bonding layer can be superimposed between the two layers. PET foam) and an inner layer that includes .01600:0() and may include a thermoplastic phenoxy type 04 (OF 01) in some embodiments; a barrier layer may be superimposed between the two layers oof oF the barrier layer may act to inhibit or prevent ingress of and/ or the exit of one or more gases; ultraviolet radiation; and the like through the walls of a vessel made of preformed material -on in some embodiments; incorporating a second layer 08 on polypropylene 0 may be:- Polypropylene grafted or Vasa with dl dl anhydride (maleic anhydride) glycidyl methacrylate (acryl methacrylate) and/or similar compounds to improve adhesion. In one embodiment, polypropylene also includes nanoparticles.In an embodiment “AT includes polypropylene on nanoparticles and is grafted or modified with” (glycidyl methacrylate) 081616); glycidyl methacrylate anhydride) maleic anhydride _0 and/or similar compounds. (acryl methacrylate) Acryl methacrylate Referring to fig. The thickness is ££ preferably the wall thickness of the #7 outer layer of the AY vessel of approximately VT mm (+00 in) - 0.07 mm (10 in) - 1.54 mm 01 (inches); WAY YO 115 mm (in) - A 0.0 mm (17 in) ; © mm (YO), + inch); and values within this thickness range. in some embodiments; the thickness of the outer layer shall preferably be less than about 67 mm (7 in); Most preferred is 1.77 mm (10+ in) to A 0.0 mm

He was born 17 ( inches). The outer layer OF may include foam material having a thickness greater than about VAN mm (15, in) in some embodiments not specified; The OF coating has thicknesses in the range from about NYY mm (00 vy in) to about 178 mm (.,170 in).

° in some unlimited incarnations; The thickness is preferably £7 for the inner layer ;; The average thickness of the inner layer is preferred; © 1.177 mm (0 5 in) – 175 mm (© .07 in) – 0.10 mm (iE) in) – 0.27 mm (+1 in) YF mm (CA) in) - 84 mm (0.1 in) ; 8 mm (7 0.1 in) - 17 mm (0.1 in) ;

Y £0 mm (0 (+ inch)); and values that fall within the range of these thickness values. in some embodiments;

0 The inner layer 08 of the AY pan has a thickness of less than approx. 7.54 mm (+ inch) to give a less expensive food barrier. in some unlimited incarnations; The interlayer has a thickness in the range of about 1171 mm (00 vie in) to about 0.178 mm (0.075 in). The wall thickness of vessel $A can be chosen to achieve the desired characteristics of vessel AY

To improve the retention properties of the AY vessel the AY vessel may have a barrier layer. 0 one or more barrier layers may be formed on the inner surface of the inner layer 54 between the two layers cof co) on the outer part of the outer layer 7©; And the like. For example; The outer layer OF the vessel (or the preformed material from which the vessel is made) may be calinized with a barrier material using the methods shown here. For example a barrier layer may be formed by using devices; Methods and systems Anal In ll) US Ys No. 115971/01 (Publication No. 001 Ema VIAAS which is incorporated herein by reference in its entirety. Also in some embodiments the AY container includes a closed-cell foam principally They serve to inhibit the movement of fluid through the foam. For example, the foam can be a barrier that inhibits and preferably prevents the movement of CO gas, through the wall A of the vessel AY formed of preformed sald . Yo The preformed material in the form of 11 has an inner layer VTE that includes a first material, and it is preferable that the outer layer includes 117 over another sale. in some unlimited incarnations; Layer VY can contain about XY from 10 to 71 lvl

11 The values that fall within the range of those percentages of the substance JQ LAL .hal .lal 4 are less than about 7959 of the 117 preformed. in some embodiments; The foam layer includes the preformed material. In some embodiments layer 167 contains about 78 to about 78% of the preformed material. in some unlimited incarnations; Layer 4 can contain less than about 790 preforms. In some indefinite embodiments; 117 0 less than about 740 to about 74860 from the prefix 167 layer can include 7160 modulation. in some unlimited incarnations; Layer 177 can contain about 790 to 100% of the preformed material. in some unlimited incarnations; It can contain greater than about 7710 preforms. It is envisaged that these layer VY percentages by weight or by volume in different embodiments. in some embodiments; 0 VTE polymeric material can be placed on a foaming material and the inner layer may include 1167 that includes the layer (eg, produced directly from the ore or after it has been consumed / recycled). PET may, for example, “(polymeric)

Cada has JB on non-expanding foam. For example VY The foamed layer includes, for example (Ln not expanded or not expanded, LJ on microspheres 167). The foamed layer: When the material Led is formed, an insulating layer is desirable. Example VY The foamed layer may give Ve in the form of a container. 01 pre-formed .. It is preferable that a large part of the outer layer 67 includes foaming material and includes PET or other material for contact with foodstuffs. 1174 A large part of the inner layer and microspheres unstable PP in one of the unlimited embodiments; the foaming material includes and may include the PP on the 1767 also the outer layer includes AT for expansion. in an embodiment 0

VAY is preferred; 114 The inner layer contains a large part of the outer layer JPET 114 The inner layer contains 2127. In an unspecified embodiment; General on 167 The outer layer includes foaming material. May 1167 and the outer layer 164 contain large parts of the inner layer in metal on a foaming material and a material suitable for contact with VT 137. The two preformed materials include YO foodstuffs.

11

in some embodiments; A VUE inner class may contain one or more of the following:

PET is a phenoxy thermoplastic material (combining mixtures); foaming material

PET Sid) foaming; and/or other covering/coating suitable for food contact. may be

The outer layer VY includes one or more of the following: Foaming material (including PP)

© The Foam, 1:1 The Foam; etc); A material without foaming (eg a thermoplastic material of type

¢ (PP PET ”(phenoxy) or other suitable material to form the outer part of a material

preformed. in some embodiments; Preformed material 101 contains spandex

phenoxy-(phenoxy) in some unbounded embodiments" can

Including ale thermoplastics of at least phenoxy type of about JN 37,5

Say pray. no. no. no. no.

Percentages of preformed material. in some embodiments; The material includes thermoplastic

of the phenoxy type containing about 701 to about 770 by weight of matter

preformed. in some embodiments; The thermoplastic material includes a phenoxy type

(phenoxy) on most or all of the preformed material. The weight is relative to the elastic material

B 1# 0 _ thermoplastic of phenoxy type in specified form or mixture. It is conceivable that those

Percentages can be by weight or by volume in different embodiments. For example; in

cn "0 Some embodiments include the VTE layer on a phenoxy-type thermoplastic material

(phenoxy) form less than 701 of the preformed matter. Layer 114 could be its

A suitable thickness to form a layer in contact with food. It is preferable that the thickness be 1174 of the layer

0 internal VUE is less than VLA mm (0.100 in) to create an inexpensive layer in contact with the material

food. The thickness of the 71; inner VTE layer may be less than about 11 mm vert).

0.0 (4 inch) in mm FE I CST RIEL in turn then Cos

in) – 1.15 mm (eT) in) – 1.7 mm (oy A) in (oY mm Y) + 10 in);

5 mm (+01 in.) and the range values covered by that fish. In some embodiments it is

© Ltd.; The inner layer 1174 contains a thermoplastic material of the phenoxy type

(phenoxy) to thicknesses ranging from about 0.00 mm (eof inch) to approx

+ mm (007 in.). in some embodiments; The preformed material 0610 may be created

WA

By the Alf process where the inner and outer parts of the preformed material contain different materials. in some embodiments; The outer layer includes 167 on a first material, and it is preferable that the inner layer 1764 includes another material. For example, the outer layer may include 117 eo on polypropylene and the inner layer may include 74 PETG In another embodiment the outer layer may be polypropylene doped or modified with maleic anhydride (maleic anhydride) glycidyl methacrylate (glycidyl methacrylate) and/or similar compounds to improve Bla in an embodiment; Polypropylene also includes nanoparticles. 0 in another embodiment; Polypropylene contains nanoparticles and is doped or modified with maleic anhydride, glycidyl methacrylate, acryl methacrylate, and/or similar compounds. The preformed material may be 180 (Fig. VY) having the inner layer VASE the same or similar to the inner layer VTE and the outer layer A Blas VAY or similar to the inner layer ( © 220 1144 ) VF (fig. 091) The material may be preformed Outer TY 0: The outer layer 199 is the same or similar VTE The same or similar to the inner layer. The outer layer gives the desired interplay with the sealing composition 157. The Cua (149 outer layer) may have layers composed of identical or similar materials (VE (fig. 717) the material is preformed AT of the material Preformed 0 Preformed pieces and resulting vessels may be well suited for refractory applications, eg hot SL. In general, vessel 711 in Figure 1(a) can maintain its shape during hot melt operations. After forming Blown or hot forged, the final dimensions of the prepared part 197 of the Alas 711 vessel are the initial dimensions of the preformed material.Also this YO results in less changes in the dimensions of the threaded parts on the final prepared part. For example, the “YAY” inner layer can be formed from a food contact material. Maa PET Coating 7007 can include molded materials (eg most or

entirely of PP (PP and PET foaming agent crystalline laminate material; homopolymers; copolymers; other materials shown herein); Suitable for hot melt. The YF outer layer gives dimensional stability to the civil part 17 even during and after a hot dall. The width of the outer layer 70 can be increased or decreased to increase or decrease ©; Respectively; Dimensional stability of civilized finished part (APY) preferred; that one of the layers constituting the civilized final part 11 contains a material with high thermal ald; However, the civilized end part ITY can be made of materials with low thermal stability, especially when used without hot melting. (Lil) Dimensional stability of the 707 outer layer ensures that the 717 cap remains attached to the 711 0 receptacle in VE form (eg; the 007 PP outer layer can retain its shape thus preventing the cap 71 from unintentional 711 vessel disengagement.The preformed blocks shown above can be modified by adding one or more layers to achieve the desired properties.For example a barrier layer can be formed over the bulk portions of the preformed blocks.0 0 © Products in the form of lids: | The lids may include bale foaming. In some embodiments not limited; the material cle yl includes less than about 190 by weight; also includes less than about jao do per Denominator (for) Functional d/d for each JVo 0 and the values covered by those percentages of cover It is conceivable that these percentages could be by weight or by volume in different embodiments of 0. in some embodiments; The foaming material includes the values that are included in those percentages by weight of the cap. in unlimited embodiment; The foaming agent contains about 6 ½ wt. of the cap. in the embodiment of AT Unlimited; The foaming material includes approximately 0-11 by weight of the cap. in some embodiments; The cover mostly or entirely includes foaming material. For example (JB) the single-layer cover can be foamed. Yo Referring to Figure 4 at least part of the 307 cover includes foam. Layer 6 may include (¥) and/or the outer part ©11 on foaming material (PET ia) with foam;

YY ee sale on 11 with foam etc.). In one embodiment the outer part includes PP etc. PET (PP) on a non-foamed material (eg 704 and the overlay may include foaming material. The inside of the lids may include foaming material. In some embodiments; the parts may include The outer layers of the lids or without foaming material The lids may have similar inner layers and outer layers (parts) or (<a) YY (DY) of the two forms © consisting of materials having a WE may have Layer 1 that the cover (a) YY exhibits the desired structural, thermal, optical, barrier properties (Jal) and/or similar. PETG PET (PP PET) Layer 7714 consists of Ye in one embodiment ¢ another feature is set up when the outside of the cap is made of Erga la anid in a convenient gripping surface so that the user can comfortably slide the cap from the container. The outer part 011 of Fig. 14 may be foamed to increase the space occupied by the outer part 11 and the user may be provided with a greater level of arm strength for ease of opening and closing the lid b. Spiral with threaded surface on the outside of the bowl. The 301's enlarged exterior can give the Fig. 19 increased arm capacity so that the user can easily rotate the YoY cap on or over the cap. preferably The same or similar amount of material that makes up a conventional cap can be used to form the larger diameter cap. Then; Material cost for cover production can be reduced 17 000 The cover may include phenoxy-type thermoplastics in some unlimited embodiments; The phenoxy-type thermoplastic material includes less than about 775 by weight; and includes Lad less than about 1n Jot JY JY MM by weight ; from the cover. In some embodiments the phenoxy-type thermoplastic Yee includes values within the range of those percentages by weight of the cap. The weight is for the phenoxy thermoplastic material in diluted or blended form. in an indefinite embodiment; The material includes thermoplastic

1171 to 78 by weight from the cap. in embodiment 1,5 on about (phenoxy) of the type phenoxy on another (phenoxy) unspecified; The phenoxy-type thermoplastic material includes to 776 by weight of the cap. About 1 part of the (phenoxy) phenoxy-type thermoplastic material may form the inner surface of the cap. For example, a layer of thermoplastic material 0 may be applied.) 1? (Fig. 014 of the “09” layer on the inner surface (phenoxy) of the phenoxy type of the thermoplastic material of the phenoxy type PY Optionally, the layer can be made of a (phenoxy) part (<0”m. Phenoxy-type thermoplastic material can form vou of the cover You (a)); layer YY (form YE of the cover YEE at least of the layer ;) (c) “1 JS) (330) and/or Layer 314 of Cover YT Layer (SY) (Fig. 0 (Fig. FAL of Cover PAY) (Fig. 1?(d) Layer FV. Layer 374 of the cap for example. Of course, those layers may include a material (eg Material 71) and/or similar) that is laminated with the thermoplastic material that PP PET laminate; Phenoxy 0 The coatings shown above can have one or more barrier layers to improve their retention properties, eg an inner layer; one or more intermediate layers; and/or outer barrier layers can be formed by Use of the systems: (Publication No. 115719/01 and the methods set out in the US application by serial number, which are incorporated herein in their entirety and describe systems and methods for the formation of) 001;/.ALADC#0 barrier layers. in some embodiments; Covering materials can be modified to improve the particle (Se) retention properties. For example; The foaming material may have additives that improve the retention properties of the foaming agent. An experienced person in the art can choose to design the covers to achieve the desired retention properties. Layered Products — ¢ Yo Typical products can be layered products. A Jil layer can be placed between one or more parts or layers of products. For example

The products can have a bond layer superimposed between layers of materials. Products can have many bonding layers; It is preferable that one of the bonding layers be placed between a pair of adjacent layers. in some embodiments; Each group of adjacent pairs of layers is superimposed in one of the bonding layers.

° The container AY of form 1 has a (VISE) bonding layer Ao between the layers oF and the layer ;. in some unspecified embodiments; The layer includes one or more of the following: foaming material (including PP foamed; PET foamed; etc.); non-foaming material SU) thermoplastic materials of type PP «PET (phenoxy) terminator unions or other material suitable for forming the outer part of a preformed material. Layer includes; 5 on one or more of the following:

0 follows: PET phenoxy aged mixture (polyolefin-phenoxy) terminator conjugates or other suitable materials to form part of a vessel wall. in some embodiments; It includes oY outer layer over PP (foamed or without foam) and inner layer; 5 on 027. Binding Layer 85 may include adhesives; Thermoplastics of type phenoxy polyolefins or combinations thereof (for example, a mixture of

Ve polyolefin - phenoxy ((<0170150-0©00). Can: for bonding layer Ao preferably

To stick to both layers OY 8.06 gives phenoxy a desirable adhesion

Between an inner layer 08 containing PET and an outer layer OF containing PP eg.

The multilayer products shown in figures (EA

YS and 81-17(e) have one or more bonding layers; Single bond layer is preferred, between

At least two layers of products. For example, a bonding layer between

The two OY 0 layers of preformed material 776 (Fig. 3) can overlay the Aad layer

Between layers VFN 074 and/or preformed material 90 and the VTE layer of Fig. 01.

That the preformed material 001 (Fig. 11) has a bonding layer superimposed between the VUE layer

0 and layer NY Preformed material YA (Fig. OY) can have a bond layer superimposed between layer 184 and layer VAY Preformed material can be 090 (Fig.

(OV) has a bonding layer superimposed between layer 194 and layer 199. The preformed material 0" (Fig. VE) has a bonding layer superimposed between layer 7007 and layer YAY | For fig. Cover 907 has a bond layer between layer 06 and outer 3.7 (some unlimited embodiments; outer portion 11 includes one or more of the following: foaming (including foamed PP; PET) foamed; etc.); non-foaming material (Jaa) thermoplastic phenoxy (PP PET) (phenoxy) terminator unions or other suitable materials to form the outer part of a cap. Layer YE includes one or more of the following: PET phenoxy a mixture of polyolefin-phenoxy Leia conjugates or any other suitable material to form part of the covering. Guat phenoxy polyolefin ¢ (polyolefin) 0 conjugates of which Mi) Jill (polyolefin-methoxy) The covers shown in the figures can be vy ( a)- YY (2—) has one or more binders; preferably at least one binder layer is present between a pair of adjacent layers. vo is prepared another feature is a binder layer which includes a phenoxy thermoplastic material such as a mixture of phenoxy “(phenoxy) can help blend 0 (compatibility) of the phenoxy layer Pure and somewhat other class. Phenoxy can work. ....(phenoxy) effectively on the mixture of polypropylene (©000170:007160; polyethylene) and the like. Materials) and the bonding layer(s) to achieve the desired properties of a product 0—Products Involving Laminate The laminated material may form one or more parts of the material layers (eg packaging containing pre-materials (JS) stoppers and containers). Preformed material vo Yo may include laminated material Figure 400 is an enlarged view Gold of the wall segment £Y of the preformed material 0 +©. In the cpu pall embodiment the wall profile includes £ 7 on a laminated material comprising one or more layers.The laminated material is preferably composed of several

7< small layers. anyway; Layers of laminated material can have any suitable size based on the desired properties and desired characteristics of the preformed material; And the resulting container formed from the preformed material. Wall strip seams can generally include ?; materials that are the same or different from each other. Can you make one or more layers © that make up a wall segment?; of materials shown herein or other materials known in art. in the embodiment shown; have a wall strip?; Inner layer 497 Outer layer $0 (and one or more middle layers) £0 between them. in some embodiments; The inner layer of $V is suitable for food contact; Sie polyethylene terephtalate ("PET") or other suitable material that can form the inner cavity of a bottle made of preformed material 0.70:

The £1 wall profile can optionally have at least one layer of material having good Alle gas properties. in some embodiments; Wall section 4 of the preformed Fo has several layers with good gas-insulating properties. Preferably one or more layers of wall strip?; Incorporating an insulating material that inhibits or prevents the entry and/or egress of fluid through the wall of a container made of preformed material VO0*..With this, the wall section may include:

€F on several layers does not have good insulating properties.

Do you have a section of the wall? Preformed material Ve has at least one layer composed of recycled or post-consumer PET (“0011]”). For example JB in an embodiment; a wall profile £F can have several layers composed of 1111. In some embodiments; may

0 - The inner layer 1; shall be formed from raw PET and the other layers of the wall profile ¥£ may be formed from raw PET or 8127. In addition to WL, other materials may be used to obtain the desired characteristics and physical properties of the preformed material +; or the resulting container made of the preformed material Xe Yo may Each of the layers of the wall profile shall generally have the same thickness. In the manner of (dio) the layers of the wall profile £7 may generally have different thicknesses from each other. The required number of layers can be determined by a skilled artisan; the thickness of each layer composition of each

'Yo layer of wall segment?;. In one of the unrestricted embodiments; Previous material can have a £7 wall section incorporating more than two layers. in some preferred incarnations; Ye profile may be for the wall segment?; more than ¥ layers. Can generally align the layers of laminated material forming ce as shown in the figure for preformed material 1 wall?; one of the inner surface 9; Glad 0 outer surface has VE layers The parts of the laminated material that make up the body part can include Te

Fe generally parallel to the longitudinal axis of the preformed material The distance and/or orientation of the wall profile layers £0 can vary or generally remain constant Thickness of one or more Lad layers along the wall profile ?;. In addition to this, the section of wall 47 may differ from what is imagined; or may be substantially fixed along with the preformed material 0 that one or more of the layers have openings; permeable or cast into an adjacent layer. The laminated material may also form other multi-layer or single-layer products. For example an outer layer 50 with reference to the figure ©; The preformed material may include an inner layer; © defines the inner surface of the preformed material 00 preferably not extended OF . -.. . It is also preferable not to have it on the inner surface FY the outer layer. 7* to the neck part ve At least one of the outer layer 0 and Cua 50 of the preformed material OY may include a laminated material. in the embodiment shown; The outer layer of the inner of contains another material. It is preferable that the inner layer of lamellar and the suitable inner layer include 00 ore; So that the inner surface of the preformed PET material is preferable to “PET” over a laminated material of food contact. in another embodiment not shown; Inner layer 0 contains of others. The inner sale layer preferably comprises 0X and the outer layer comprises the materials of which make up the inner surface. However, the inner layer may include 7 etc.). in the form of PP (RPET 5 PET incorporating the other PET described herein (e.g. foaming material; on laminate material. Therefore; oF alternate; includes both inner layer ©4 and outer layer) Many unions can be used to form the material The preforms shown here. YO have multiple layers. May have 7-17 Products shown in Figures JB may include one or more layers of such products on laminated material. For example

Preformed 000 shown in Figure JA on an outer layer OF formed from lamellar material. The outer layer oF covers the lower surface of the support ring YA and extends along the body part NE with reference to Figure 10 One or more of the layers 174 and 11 © may comprise a laminated material. In one embodiment the entire preformed material consists essentially of different laminated layers VY 14 bonded together. In some embodiments it includes at least one of Layers 174 and 11 on laminate material; Bale) Thermoplastic phenoxy type PP (PET ¢ (phenoxy) (including foamed and non-foamed type) etc. May 0 Optionally only one layer of Layers VTE and 11 of a laminate material Ve seals may also comprise a laminate material The laminate material can form an intrinsic part of the seal or only a portion of it In some unconstrained embodiments the laminate material comprises less than about 798 V Weight Gal includes less than about Ave dye (he do (foo 08) dal 285 dal of plug weight. In some embodiments the laminate includes ranges within these percentages of plug weight. wll Is As shown in Figure V4 At least part of Ye Yada contains lamellar material. Layer 106 and/or outer part 9011 may include material (AEE) in an embodiment; The outer part (YY) includes a laminate material and the 706 layer includes a laminate material (eg PET “PP” etc.). Furthermore it; The Jalal part of the seals may contain laminated material. in some embodiments; The outer parts may first include laminated material. The Yes of the plugs of Figures 11 (a) through YY (e) may have the same or different inner and outer layers (or outer parts). Figure YY (c) shows a seal 1 having an intermediate layer 14 composed of materials having the thermal properties of glad; optical and/or buffer. For example; Layer YUE can be formed from laminated material. Yo the laminated material can form at least part of the YEE layer of plug 3406 (Fig. 71(a)); the vou layer of the You plug (Fig. 71(b)); Layer 266 and/or Layer 3164 of the YT Plug (Fig. 71(c)); VE layer of plug 370 (Fig. 1(d)); layer 382

Analogs of FAL (Fig. 1(e)); exemplary. Other parts of the bale may be formed of the same material or a different Bale. In some embodiments most complete seal includes laminated material. 1— Products Incorporating a heat-resistant coating ° Products described herein may comprise one or more heat-resistant materials.As used in the phrase “refractory materials” is an inclusive term used in its usual sense and includes, without limitation, materials which are suitable for hot casting or casting applications For example, a refractory material may include a material with high refractory resistance that has extended stability during the hot casting method. The refractory material may include polypropylene (©00170:0071©60; chy sh “polyester” and the like. In some embodiments, the refractory material has greater thermal dimensional stability than PET Amorphous The refractory material may form part of the products (i) one layer more than one profile; raw material chip; 10 and other products described here). - : in one embodiment; It should be noted that there is a Fully formed and blow molded container with an inner layer; Which in turn includes poly (polyster) sid of thermoplastic; outer layer which includes thermoplastic material (Jia) polymeric material (polymer: heat resistant) has a greater thermal resistance than that of YT thermoplastic polymer (YT) for the inner layer; intermediate bonding layer; Which causes adhesion between the inner layer and the outer layer; The layers are formed by accompanying extrusion prior to the molding procedure. preferably The thermoplastic polyester of the inner layer is PET and may also comprise at least one oxygen scavenger and an inert carrier mixed with a thermoplastic polymer. Preferably TO the inert carrier is a polyamide such as 10006. In light of the present explanation; A person skilled in the art can select from many types of laminate material(s) to achieve the desired properties of the product from which they are made. Products may form

a

described herein by any appropriate means. Products can be shaped for example by molding

Chall blow molding; co-extrusion injection blow molding (BAY); elongation blow molding (had) and other methods are described here. The various methods and techniques described above

Provides several ways to conduct the invention. Of course it is understood that there is no necessity to bring all

© Purposes or Features Described Lida for any particular incarnation described herein. li Those skilled in art realize eg. The possibility of performing methods in a way that achieves or produces a feature

or a set of features optimized as described herein without the need to achieve the other purposes or benefits as referred to or suggested herein.

In addition to the aforementioned; The adept at art is aware of the interchangeability of the many attributes of embodiments

The different lik shown here. likewise; He who is skilled in the art can run roads 0

The principles described here combine and match the many features and steps described above. Other known equivalents for each of these traits and steps additionally do not comply

The methods described and described herein are in the exact order of the procedures described; As can not

A person skilled in the art selects several types of laminated material(s) to achieve desired properties

0 . of the manufactured product. The products described herein may be shaped by any suitable means; Products can, for example, be shaped through injection molding; blow molding, injection blow molding; emanation ... common emanation; blow molding with cial elongation and other methods are shown here. The many methods and techniques described above provide several ways of performing the invention. It is understandable of course

Not necessary to achieve all of the purposes or benefits described under any particular embodiment

Te is described here. So; Those skilled in art realize eg. The possibility of ol ya) methods in a way that optimizes or optimizes one or more features as described

herein without the need to achieve the other purposes or features as indicated or suggested herein.

Although the invention is illustrated in the context of particular embodiments and examples; Only the skilled

In art they understand the extension of invention beyond the embodiments specifically indicated, i.e. into embodiments

Other alternatives and/or obvious uses, modifications, and equivalents of Ye. Accordingly, the invention is not intended to comply with the specific explanation of the preferred embodiments herein. Instead; His aims

The request that the scope of the invention be limited only by reference to the enclosed claims; And that modifications

1 are within the scope of Gill's practice of the methods and materials herein described which are cognizant of those skilled in the applicant's invention. 17 41 |

Claims (1)

0 ideal items (YY) (neck portion) (c+) (preform) sale -1 -1 ("" body portion) is for (YE) body portion and a body part 7 It also includes the body ¢ (£Y) (end cap) and a parietal end cap “(°Y) (second layer) and a second layer (0) ( first layer) on a first layer (body portion) “(expandable material) on stretchable material (©) (second layer) Jam, © microspheres where it is a stretchy material Comprising several microspheres until it forms a foamy construction when heated at a temperature higher than the expansion temperature. al Y where the first layer is 10 of the preform material - 1 and is The second layer (inner layer) is an inner layer (54) (first layer) ¥ and it forms the inner layer “(outer layer) is an outer layer (oY) (second layer) 0 and it forms the outer layer (preform) Inner layer (preform) Outer layer (preform) © 1 *- The preform of Claim 11, where microspheres Y include a thermoplastic material that expands during thermal dalled. : . 1 0 €—preform of claim 1; wherein the heat treatment includes a “preheating cycle” to raise the temperature of the preform to a temperature suitable for blow molding. =o) the preform of claim 0; wherein the secondary layer additionally includes a “carrier” polymer and a foaming agent. 1 +- preform Cua includes microspheres ¥ over mostly completely collapsed microspheres; lb SF expandable microspheres Ua or expandable microspheres ; to fully expand. 1 7#- The preform of the Cuno claim includes microspheres "on about Te to about 770 by weight of the preform. YY where the first layer 1 of the preform is the preformed material + 1 selected from the set of (innermost layer) is the first layer " and unions thereof. (phenoxy) thermoplastics of the type phenoxy (polyester) polyester TF in which the first layer 10 of the protective element (preform) of the preformed material 1-1 is formed by molding and injection. (oY) (second layer) and the second layer (54) (first layer) Y where the neck part 1 of the preform is the preformed material 1-01 with a single layer. (threaded neck end) Threaded Bie is the (YY) (neck portion) Y end of claim 0 wherein the preform includes preform-11 (ethylene vinyl) material selected from the ethylene vinyl group Acetate (microspheres) “polyamides” (PET) (polyethylene terephthalate) acetate) | “(polyethylene terephthalate glycol) polyamides . PET And copolymers (polyethylene 2,6) -7617 polyethylene. (acrylonitrile) acrylonitrile “(1,5- naphthalate PET copolymers) 1 including at least one Cua) of preform SAY 1 on material (oY) (second layer) pil Akl) (o£) (first layer) “from the first layer -: Bala ¥ which additionally includes layer 0 of the preform material - 19 At least one additive 1 comprising a barrier.” Wherein 1 preform includes preform - 1401 to less than approximately 7460 microspheres by weight of the preform. ) Y includes microspheres Cua) of preform -1# 1 by weight of preform. 771 of approximately Jd on (microspheres) Y part comprises at least Cuno) of preform 11-1 on several microspheres (YY) (threaded neck portion) _ of the “microspheres” ¥ where it includes Outer layer 0 of preform Preform-11” 1 selected from carrier and microspheres on microspheres (°Y) (outer layer) Y ¥ The group consisting of polypropylene polyethylene terephthalate and combinations thereof. VA the preform of claim 1 in which the body portion (Y€) ¥ comprises several layers; And prepare at least one of the layers to come into contact with food. 11-1 method for producing a preform (+0) according to any one of the “previous claims” and includes: 1 . Formation of a first layer (o£) (first layer) of the preform material and formation of a second ft layer (©Y) (second layer) of the preform where the second layer includes (second layer) © contains several microspheres and prepares the microspheres 1 to expand when thermally activated. (first layer) where the first layer 09 of claim method —Y 1 ¥ 9,5) is an inner layer of the preform The material (second layer) i (©) is an outer layer of the preform; -.o(preform) and the inner layer forms an inner surface of the preform. Formation: Loe (preform) © while the outer layer forms the outer surface of the preform. .: (preform) Formation 1 includes: (VV) to produce a bottle (method) 71-1 1-“71 according to any one of the claims of (0+) (preform) Provide preformed material Y” to 10- heat this material so that at least part of it expands partially to form a foam; and 1 perform blow molding of the preformed material into a bottle containing foaming material. 1 77- Method (method) of protection (oY) where the preform ¥ includes an inner layer and an outer foam layer; the outer layer includes several microspheres ) in a stretched position. 1 7?- method (method) of claim 17; whereby microspheres "expand from a partially expanded position to an expanded position during heating of the preform" YE) method of claim 17; wherein the bottle contains microspheres . (microspheres) 1" in an expanded position. 1 © 7 ?-method of claim FY where a portion of the preformed material JS (preform) Y heated has an initial density and foam has a density second; the second density is about 7980" lower than the first density. 1 “?-method of claim 17; where the preform includes at least a first layer and a second layer” and the layer is The first (first layer) is a material selected from the group consisting of (PET). ; . thermoplastics of the type phenoxy unions thereof; The second layer includes | © on several microspheres =YY 1 preform of any one of claims 1 to OA Y where at least part of the microspheres is prepared (microspheres) to break at de gia A at high temperature. 1 1