RU99115090A - METHOD FOR PRODUCING HYDROCARBONS - Google Patents

METHOD FOR PRODUCING HYDROCARBONS

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Publication number
RU99115090A
RU99115090A RU99115090/04A RU99115090A RU99115090A RU 99115090 A RU99115090 A RU 99115090A RU 99115090/04 A RU99115090/04 A RU 99115090/04A RU 99115090 A RU99115090 A RU 99115090A RU 99115090 A RU99115090 A RU 99115090A
Authority
RU
Russia
Prior art keywords
catalyst
cobalt
manganese
carrier
impregnating
Prior art date
Application number
RU99115090/04A
Other languages
Russian (ru)
Other versions
RU2187486C2 (en
Inventor
Якобус Йоханнес Корнелис Герлингс
Аренд Хук
Ханс Михил ХЕЙСМАНН
Петер Виллиам ЛЕДНОР
Original Assignee
Шелл Интернэшнл Рисерч Маатсхаппий Б.В.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Шелл Интернэшнл Рисерч Маатсхаппий Б.В. filed Critical Шелл Интернэшнл Рисерч Маатсхаппий Б.В.
Publication of RU99115090A publication Critical patent/RU99115090A/en
Application granted granted Critical
Publication of RU2187486C2 publication Critical patent/RU2187486C2/en

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Claims (10)

1. Способ получения углеводородов путем каталитического взаимодействия моноокиси углерода с водородом, причем в ходе данного взаимодействия подаваемый материал, содержащий водород и моноокись углерода, контактируют при повышенной температуре и давлении с катализатором, включающим в себя кобальт и марганец, причем в данном катализаторе мольное отношение кобальт/марганец составляет 14:1 - 7:1, а ОСГЧ составляет по меньшей мере 1600 Нл/л/ч.1. A method of producing hydrocarbons by the catalytic interaction of carbon monoxide with hydrogen, and during this interaction, the feed material containing hydrogen and carbon monoxide is contacted at an elevated temperature and pressure with a catalyst comprising cobalt and manganese, wherein the molar ratio of cobalt in this catalyst / manganese is 14: 1 - 7: 1, and the GHS is at least 1600 Nl / l / h. 2. Способ по п.1, в котором отношение кобальт/марганец находится в диапазоне 13:1 - 9:1. 2. The method according to claim 1, in which the ratio of cobalt / manganese is in the range of 13: 1 to 9: 1. 3. Способ по пп.1 или 2, в котором ОСГЧ составляет 2100 - 25000 Нл/л/ч, предпочтительно, 2700 - 16000 Нл/л/ч. 3. The method according to claims 1 or 2, in which the TSS is 2100 - 25000 Nl / l / h, preferably 2700 - 16000 Nl / l / h. 4. Способ по любому из пп.1 - 3, в котором катализатор включает в себя пористый носитель, особенно носитель из тугоплавкого оксида. 4. The method according to any one of claims 1 to 3, in which the catalyst includes a porous carrier, especially a carrier of a refractory oxide. 5. Способ по п.4, в котором тугоплавким оксидом является окись алюминия, двуокись циркония, двуокись кремния или двуокись титана, особенно двуокись титана. 5. The method according to claim 4, in which the refractory oxide is alumina, zirconia, silicon dioxide or titanium dioxide, especially titanium dioxide. 6. Способ по п.4 или 5, в котором катализатор получают путем пропитки носителя каталитически активными соединениями, или предшественниками каталитически активных соединений, предпочтительно путем пропитки объема пор. 6. The method according to claim 4 or 5, in which the catalyst is obtained by impregnating the support with catalytically active compounds or precursors of catalytically active compounds, preferably by impregnating the pore volume. 7. Способ по любому из пп.4 - 6, в котором катализатор включает в себя 3 - 60 мас.ч. кобальта на 100 мас.ч. носителя. 7. The method according to any one of claims 4 to 6, in which the catalyst includes 3 to 60 parts by weight of cobalt per 100 parts by weight carrier. 8. Способ по любому из пп.1 - 7, в котором по меньшей мере часть кобальта находится в виде металла. 8. The method according to any one of claims 1 to 7, in which at least part of the cobalt is in the form of a metal. 9. Способ по любому из пп.1 - 8, в котором температура находится в диапазоне 175 - 275oC, а давление 5 - 50 бар авс., причем синтез углеводородов, предпочтительно, осуществляют в фазе катализаторной суспензии.9. The method according to any one of claims 1 to 8, in which the temperature is in the range 175 - 275 o C, and the pressure is 5 - 50 bar abs., And the synthesis of hydrocarbons is preferably carried out in the phase of the catalyst suspension. 10. Способ по любому из пп.1 - 9, в котором селективность C5+ составляет по меньшей мере 85%, предпочтительно, по меньшей мере 88%.10. The method according to any one of claims 1 to 9, in which the selectivity of C 5+ is at least 85%, preferably at least 88%.
RU99115090/04A 1996-12-13 1997-12-11 Hydrocarbons production process RU2187486C2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP96203538 1996-12-13
EP96203538.2 1996-12-13

Publications (2)

Publication Number Publication Date
RU99115090A true RU99115090A (en) 2001-05-27
RU2187486C2 RU2187486C2 (en) 2002-08-20

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
RU99115090/04A RU2187486C2 (en) 1996-12-13 1997-12-11 Hydrocarbons production process

Country Status (15)

Country Link
US (1) US5958985A (en)
EP (1) EP0966415B1 (en)
AU (1) AU718101B2 (en)
CA (1) CA2274688C (en)
DE (1) DE69711714T2 (en)
DZ (1) DZ2370A1 (en)
ES (1) ES2175521T3 (en)
ID (1) ID21757A (en)
MY (1) MY118696A (en)
NO (1) NO329313B1 (en)
NZ (1) NZ335515A (en)
RU (1) RU2187486C2 (en)
SA (1) SA97180722B1 (en)
WO (1) WO1998025870A1 (en)
ZA (1) ZA9711090B (en)

Families Citing this family (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6475943B1 (en) * 1995-11-08 2002-11-05 Shell Oil Company Catalyst activation process
ES2221235T3 (en) * 1997-12-30 2004-12-16 Shell Internationale Research Maatschappij B.V. COBALT FISCHER-TROSCH CATALYST.
US6191066B1 (en) * 1998-05-27 2001-02-20 Energy International Corporation Fischer-Tropsch activity for non-promoted cobalt-on-alumina catalysts
MXPA02012731A (en) * 2000-07-03 2003-05-14 Shell Int Research Catalyst and process for the preparation of hydrocarbons.
CA2458028A1 (en) * 2001-08-22 2003-03-06 Shell Internationale Research Maatschappij B.V. Purification of titania
FR2830858B1 (en) * 2001-10-11 2003-12-12 Inst Francais Du Petrole PROCESS FOR THE SYNTHESIS OF HYDROCARBONS IN A THREE-PHASE REACTOR IN THE PRESENCE OF A CATALYST COMPRISING A GROUP VIII METAL SUPPORTED ON ZIRCONIA OR ON MIXED ZIRCONIUM-ALUMINA OXIDE
US6956063B2 (en) * 2001-12-28 2005-10-18 Conocophillips Company Method for reducing water concentration in a multi-phase column reactor
US7001927B2 (en) * 2001-12-28 2006-02-21 Conocophillips Company Water removal in Fischer-Tropsch processes
US6809122B2 (en) * 2001-12-28 2004-10-26 Conocophillips Company Method for reducing the maximum water concentration in a multi-phase column reactor
MY134279A (en) * 2002-06-05 2007-11-30 Shell Int Research Process for the production of hydrocarbons from gaseous hydrocarbonaceous feed
KR101054604B1 (en) * 2003-04-07 2011-08-04 도꾸리쯔 교세이 호진 세끼유 덴넨 가스·긴조꾸 고부쯔 시겐 기꼬 Catalysts for preparing hydrocarbons from synthesis gas and methods for preparing catalysts
JP5619356B2 (en) * 2005-08-22 2014-11-05 シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイＳｈｅｌｌ Ｉｎｔｅｒｎａｔｉｏｎａｌｅ Ｒｅｓｅａｒｃｈ Ｍａａｔｓｃｈａｐｐｉｊ Ｂｅｓｌｏｔｅｎｖｅｎｎｏｏｔｓｈａｐ Operation method of diesel fuel and diesel engine
WO2008090105A2 (en) * 2007-01-23 2008-07-31 Shell Internationale Research Maatschappij B.V. Process for preparing a catalyst
EP2379676A4 (en) * 2008-12-22 2012-06-20 Wm Gtl Inc Low-pressure fischer-tropsch process
US8148295B2 (en) 2009-02-16 2012-04-03 Millennium Inorganic Chemicals, Inc. Catalyst promoters in vanadium-free mobile catalyst
TWI399241B (en) * 2009-10-30 2013-06-21 Univ Nat Defense A modified catalyst for reforming ethanol to produce hydrogen and the manufacturing method thereof
JP5730495B2 (en) * 2010-03-30 2015-06-10 独立行政法人石油天然ガス・金属鉱物資源機構 Method for producing activated catalyst for Fischer-Tropsch synthesis reaction, method for producing catalyst slurry, and method for supplying catalyst slurry to Fischer-Tropsch synthesis reactor
EP2655553A1 (en) 2010-12-22 2013-10-30 Saudi Basic Industries Corporation Catalyst useful in fisher-tropsch synthesis
EP2679568A1 (en) 2012-06-25 2014-01-01 Saudi Basic Industries Corporation Process for production ethylene and propylene from syngas
EA029026B1 (en) 2012-06-27 2018-01-31 Сауди Бейсик Индастриз Корпорейшн Catalyst and process for the selective production of lower hydrocarbons c1-c5 from syngass with low methane and coproduction
GB201214122D0 (en) * 2012-08-07 2012-09-19 Oxford Catalysts Ltd Treating of catalyst support
WO2015015316A2 (en) 2013-07-31 2015-02-05 Saudi Basic Industies Corporation Catalyst for conversion of synthesis gas
EA033748B1 (en) * 2015-02-25 2019-11-21 Sasol Tech Pty Ltd Hydrocarbon synthesis process
CN109562370B (en) * 2016-08-11 2021-12-24 南非沙索有限公司 Cobalt-containing catalyst composition
GB201614363D0 (en) * 2016-08-23 2016-10-05 Bp Plc Fischer-tropsch catalyst performance enhancement process
WO2018100512A1 (en) * 2016-11-30 2018-06-07 Sabic Global Technologies B.V. Apparatus and method related to carbon dioxide removal
AU2019219056B2 (en) 2018-02-09 2024-04-18 Bp P.L.C. Fischer-Tropsch process, supported Fischer-Tropsch synthesis catalyst and uses thereof
EP3628400A1 (en) 2018-09-26 2020-04-01 Bp P.L.C. Fischer-tropsch process, supported fischer-tropsch synthesis catalyst and uses thereof
EP3549996A1 (en) * 2018-04-03 2019-10-09 Evonik Degussa GmbH Olefins based on fischer-tropsch synthesis
US12043591B2 (en) 2018-09-28 2024-07-23 Bp P.L.C. Fischer-tropsch process
RU2732328C1 (en) * 2020-03-02 2020-09-15 Роман Евгеньевич Яковенко Method for obtaining hydrocarbons c5-c18 of carbon monoxide and hydrogen

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4463101A (en) * 1980-12-29 1984-07-31 Mobil Oil Corporation Catalyst for converting synthesis gas to high octane predominantly olefinic naphtha
DE3130988A1 (en) * 1981-08-05 1983-02-24 Schering Ag, 1000 Berlin Und 4619 Bergkamen CATALYST AND METHOD FOR PRODUCING OLEFINES - PARTICULARLY LINEAR (ALPHA) -OLEFINS - FROM SYNTHESIS GAS
US4874732A (en) * 1987-07-13 1989-10-17 Uop Cobalt Fischer-Tropsch catalysts having improved selectivity
US5162284A (en) * 1991-08-05 1992-11-10 Exxon Research And Engineering Co. Copper promoted cobalt-manganese spinel catalyst and method for making the catalyst for Fischer-Tropsch synthesis
EP0833807B1 (en) * 1995-06-16 2004-04-14 Shell Internationale Researchmaatschappij B.V. Catalyst and process for the preparation of hydrocarbons

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