RU97121884A - COSMETIC COMPOSITION CONTAINING AT LEAST MEASURES ONE PRIVATE SILICONE POLYMER AND AT LEAST MEASURES ONE LINEAR POLYLICOX AND POLYOXYALKYLENE UNIT - Google Patents
COSMETIC COMPOSITION CONTAINING AT LEAST MEASURES ONE PRIVATE SILICONE POLYMER AND AT LEAST MEASURES ONE LINEAR POLYLICOX AND POLYOXYALKYLENE UNITInfo
- Publication number
- RU97121884A RU97121884A RU97121884/14A RU97121884A RU97121884A RU 97121884 A RU97121884 A RU 97121884A RU 97121884/14 A RU97121884/14 A RU 97121884/14A RU 97121884 A RU97121884 A RU 97121884A RU 97121884 A RU97121884 A RU 97121884A
- Authority
- RU
- Russia
- Prior art keywords
- composition according
- monomers
- group
- polysiloxane
- meth
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims 67
- 229920001296 polysiloxane Polymers 0.000 title claims 35
- 229920000642 polymer Polymers 0.000 title claims 27
- 239000002537 cosmetic Substances 0.000 title claims 3
- -1 polysiloxane part Polymers 0.000 claims 43
- 239000005977 Ethylene Substances 0.000 claims 14
- VGGSQFUCUMXWEO-UHFFFAOYSA-N ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims 14
- 239000000178 monomer Substances 0.000 claims 14
- 150000003254 radicals Chemical class 0.000 claims 14
- NIXOWILDQLNWCW-UHFFFAOYSA-M acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims 13
- 238000006116 polymerization reaction Methods 0.000 claims 9
- 229920001400 block copolymer Polymers 0.000 claims 8
- 125000000524 functional group Chemical group 0.000 claims 8
- 125000000129 anionic group Chemical group 0.000 claims 7
- JKNCOURZONDCGV-UHFFFAOYSA-N 2-(dimethylamino)ethyl 2-methylprop-2-enoate Chemical compound CN(C)CCOC(=O)C(C)=C JKNCOURZONDCGV-UHFFFAOYSA-N 0.000 claims 6
- HRPVXLWXLXDGHG-UHFFFAOYSA-N acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims 6
- 150000001298 alcohols Chemical class 0.000 claims 6
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims 6
- 229910052710 silicon Inorganic materials 0.000 claims 6
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Inorganic materials [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 claims 6
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims 5
- 125000005396 acrylic acid ester group Chemical group 0.000 claims 5
- 150000002148 esters Chemical class 0.000 claims 5
- 229910052739 hydrogen Inorganic materials 0.000 claims 5
- 239000001257 hydrogen Substances 0.000 claims 5
- 125000005397 methacrylic acid ester group Chemical group 0.000 claims 5
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 5
- 239000010703 silicon Substances 0.000 claims 5
- 210000002356 Skeleton Anatomy 0.000 claims 4
- 229920001577 copolymer Polymers 0.000 claims 4
- 230000002209 hydrophobic Effects 0.000 claims 4
- CERQOIWHTDAKMF-UHFFFAOYSA-N methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims 4
- 229920000098 polyolefin Polymers 0.000 claims 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims 4
- 102000011782 Keratins Human genes 0.000 claims 3
- 108010076876 Keratins Proteins 0.000 claims 3
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims 3
- 235000014113 dietary fatty acids Nutrition 0.000 claims 3
- 239000000194 fatty acid Substances 0.000 claims 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 3
- 239000000463 material Substances 0.000 claims 3
- 125000000962 organic group Chemical group 0.000 claims 3
- 239000007921 spray Substances 0.000 claims 3
- ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 claims 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 3
- 125000004890 (C1-C6) alkylamino group Chemical group 0.000 claims 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N (E)-but-2-enedioate;hydron Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims 2
- DEGZUQBZHACZKW-UHFFFAOYSA-N 2-(methylamino)ethyl 2-methylprop-2-enoate Chemical compound CNCCOC(=O)C(C)=C DEGZUQBZHACZKW-UHFFFAOYSA-N 0.000 claims 2
- 241000195940 Bryophyta Species 0.000 claims 2
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims 2
- FPYJFEHAWHCUMM-UHFFFAOYSA-N Maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims 2
- 229940088644 N,N-dimethylacrylamide Drugs 0.000 claims 2
- YLGYACDQVQQZSW-UHFFFAOYSA-N N,N-dimethylprop-2-enamide Chemical compound CN(C)C(=O)C=C YLGYACDQVQQZSW-UHFFFAOYSA-N 0.000 claims 2
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinylpyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 claims 2
- 239000000654 additive Substances 0.000 claims 2
- 125000000033 alkoxyamino group Chemical group 0.000 claims 2
- 125000003282 alkyl amino group Chemical group 0.000 claims 2
- 125000004104 aryloxy group Chemical group 0.000 claims 2
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims 2
- 150000001875 compounds Chemical class 0.000 claims 2
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims 2
- 125000003700 epoxy group Chemical group 0.000 claims 2
- 150000004665 fatty acids Chemical class 0.000 claims 2
- 150000002431 hydrogen Chemical group 0.000 claims 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 2
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 claims 2
- 235000011929 mousse Nutrition 0.000 claims 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 2
- 238000010526 radical polymerization reaction Methods 0.000 claims 2
- 125000005373 siloxane group Chemical group [SiH2](O*)* 0.000 claims 2
- 239000002904 solvent Substances 0.000 claims 2
- 125000006832 (C1-C10) alkylene group Chemical group 0.000 claims 1
- MGNZXYYWBUKAII-UHFFFAOYSA-N 1,3-Cyclohexadiene Chemical compound C1CC=CC=C1 MGNZXYYWBUKAII-UHFFFAOYSA-N 0.000 claims 1
- 150000003923 2,5-pyrrolediones Chemical class 0.000 claims 1
- KGIGUEBEKRSTEW-UHFFFAOYSA-N 2-Vinylpyridine Chemical compound C=CC1=CC=CC=N1 KGIGUEBEKRSTEW-UHFFFAOYSA-N 0.000 claims 1
- MLMGJTAJUDSUKA-UHFFFAOYSA-N 2-ethenyl-1H-imidazole Chemical compound C=CC1=NC=CN1 MLMGJTAJUDSUKA-UHFFFAOYSA-N 0.000 claims 1
- WDQMWEYDKDCEHT-UHFFFAOYSA-N 2-ethylhexyl 2-methylprop-2-enoate Chemical compound CCCCC(CC)COC(=O)C(C)=C WDQMWEYDKDCEHT-UHFFFAOYSA-N 0.000 claims 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N 2-methyl-2-propenoic acid methyl ester Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims 1
- RUMACXVDVNRZJZ-UHFFFAOYSA-N 2-methylpropyl 2-methylprop-2-enoate Chemical compound CC(C)COC(=O)C(C)=C RUMACXVDVNRZJZ-UHFFFAOYSA-N 0.000 claims 1
- DXIJHCSGLOHNES-UHFFFAOYSA-N 3,3-dimethylbut-1-enylbenzene Chemical compound CC(C)(C)C=CC1=CC=CC=C1 DXIJHCSGLOHNES-UHFFFAOYSA-N 0.000 claims 1
- MXRGSJAOLKBZLU-UHFFFAOYSA-N 3-ethenylazepan-2-one Chemical compound C=CC1CCCCNC1=O MXRGSJAOLKBZLU-UHFFFAOYSA-N 0.000 claims 1
- 239000004215 Carbon black (E152) Substances 0.000 claims 1
- LDHQCZJRKDOVOX-NSCUHMNNSA-N Crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 claims 1
- 239000004593 Epoxy Substances 0.000 claims 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N Itaconic acid Chemical compound OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 claims 1
- WCYWZMWISLQXQU-UHFFFAOYSA-N Methyl radical Chemical compound [CH3] WCYWZMWISLQXQU-UHFFFAOYSA-N 0.000 claims 1
- 210000004080 Milk Anatomy 0.000 claims 1
- 229920001774 Perfluoroether Polymers 0.000 claims 1
- 239000004698 Polyethylene (PE) Substances 0.000 claims 1
- 239000004793 Polystyrene Substances 0.000 claims 1
- 229940029983 VITAMINS Drugs 0.000 claims 1
- 229940021016 Vitamin IV solution additives Drugs 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- 150000008065 acid anhydrides Chemical class 0.000 claims 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 claims 1
- 230000000996 additive Effects 0.000 claims 1
- 239000000443 aerosol Substances 0.000 claims 1
- 125000001931 aliphatic group Chemical group 0.000 claims 1
- 229910052783 alkali metal Inorganic materials 0.000 claims 1
- 150000001340 alkali metals Chemical class 0.000 claims 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims 1
- 150000001342 alkaline earth metals Chemical class 0.000 claims 1
- 125000003545 alkoxy group Chemical group 0.000 claims 1
- 125000000217 alkyl group Chemical group 0.000 claims 1
- 150000003863 ammonium salts Chemical class 0.000 claims 1
- 125000003118 aryl group Chemical group 0.000 claims 1
- 125000006367 bivalent amino carbonyl group Chemical group [H]N([*:1])C([*:2])=O 0.000 claims 1
- 238000004061 bleaching Methods 0.000 claims 1
- KAKZBPTYRLMSJV-UHFFFAOYSA-N butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims 1
- SOGAXMICEFXMKE-UHFFFAOYSA-N butyl 2-methylprop-2-enoate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 claims 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims 1
- 150000001735 carboxylic acids Chemical class 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 claims 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M chloride anion Chemical group [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims 1
- 238000007334 copolymerization reaction Methods 0.000 claims 1
- 230000000875 corresponding Effects 0.000 claims 1
- 239000006071 cream Substances 0.000 claims 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims 1
- GQOKIYDTHHZSCJ-UHFFFAOYSA-M dimethyl-bis(prop-2-enyl)azanium;chloride Chemical compound [Cl-].C=CC[N+](C)(C)CC=C GQOKIYDTHHZSCJ-UHFFFAOYSA-M 0.000 claims 1
- 238000004043 dyeing Methods 0.000 claims 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 1
- IMROMDMJAWUWLK-UHFFFAOYSA-N ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 claims 1
- UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 claims 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims 1
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 claims 1
- 238000001125 extrusion Methods 0.000 claims 1
- 239000003205 fragrance Substances 0.000 claims 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N fumaric acid Chemical compound OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims 1
- 239000001530 fumaric acid Substances 0.000 claims 1
- 239000000499 gel Substances 0.000 claims 1
- 239000011521 glass Substances 0.000 claims 1
- 150000002314 glycerols Chemical class 0.000 claims 1
- 229920000578 graft polymer Polymers 0.000 claims 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 claims 1
- 229910052500 inorganic mineral Inorganic materials 0.000 claims 1
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 claims 1
- 125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 claims 1
- 125000005647 linker group Chemical group 0.000 claims 1
- 239000006210 lotion Substances 0.000 claims 1
- 239000011976 maleic acid Substances 0.000 claims 1
- 238000002844 melting Methods 0.000 claims 1
- 235000013336 milk Nutrition 0.000 claims 1
- 239000008267 milk Substances 0.000 claims 1
- 239000011707 mineral Substances 0.000 claims 1
- 125000000896 monocarboxylic acid group Chemical group 0.000 claims 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims 1
- 125000001624 naphthyl group Chemical group 0.000 claims 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims 1
- 239000003921 oil Substances 0.000 claims 1
- 125000004430 oxygen atoms Chemical group O* 0.000 claims 1
- 239000002245 particle Substances 0.000 claims 1
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 claims 1
- 125000000286 phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])* 0.000 claims 1
- 238000006068 polycondensation reaction Methods 0.000 claims 1
- 229920000573 polyethylene Polymers 0.000 claims 1
- 229920002223 polystyrene Polymers 0.000 claims 1
- 230000002335 preservative Effects 0.000 claims 1
- 239000003755 preservative agent Substances 0.000 claims 1
- 150000003141 primary amines Chemical class 0.000 claims 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 claims 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims 1
- 102000004169 proteins and genes Human genes 0.000 claims 1
- 108090000623 proteins and genes Proteins 0.000 claims 1
- 238000007142 ring opening reaction Methods 0.000 claims 1
- 150000003839 salts Chemical group 0.000 claims 1
- 150000003335 secondary amines Chemical class 0.000 claims 1
- 239000002453 shampoo Substances 0.000 claims 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims 1
- 230000000475 sunscreen Effects 0.000 claims 1
- 239000000516 sunscreening agent Substances 0.000 claims 1
- 239000004094 surface-active agent Substances 0.000 claims 1
- SJMYWORNLPSJQO-UHFFFAOYSA-N tert-butyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC(C)(C)C SJMYWORNLPSJQO-UHFFFAOYSA-N 0.000 claims 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims 1
- 238000002560 therapeutic procedure Methods 0.000 claims 1
- 239000002562 thickening agent Substances 0.000 claims 1
- 150000003573 thiols Chemical class 0.000 claims 1
- 125000003944 tolyl group Chemical group 0.000 claims 1
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims 1
- 239000002966 varnish Substances 0.000 claims 1
- 235000013311 vegetables Nutrition 0.000 claims 1
- XTXRWKRVRITETP-UHFFFAOYSA-N vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 claims 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims 1
- 239000011782 vitamin Substances 0.000 claims 1
- 235000013343 vitamin Nutrition 0.000 claims 1
- 229930003231 vitamins Natural products 0.000 claims 1
- 238000005406 washing Methods 0.000 claims 1
- 125000005023 xylyl group Chemical group 0.000 claims 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N α-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 claims 1
Claims (1)
X(Y)nSi(R)3-m Zm (I),
где X означает винильную группу, которая может сополимеризоваться с мономерами (А) и (В);
Y означает двухвалентную связующую группу;
R означает водород, С1-С6-алкил или алкокси, или С6-С12-арил;
Z обозначает одновалентное полисилоксановое звено со средне-числовой молекулярной массой по крайней мере 500;
n равен 0 или 1, и m представляет целое число от 1 до 3; причем процентное соотношение вычисляют относительно общей массы мономеров (А), (В) и (С).5. Composition according to any one of paragraphs. 1 to 4, characterized in that it contains at least one silicone graft copolymer containing a) from 0 to 98 wt. % of at least one low-polarity lipophilic monomer (A) containing low-polarity ethylenic unsaturation that is capable of polymerization by a radical mechanism; b) from 0 to 98 wt. % of at least one polar hydrophilic monomer (B) containing ethylene unsaturation, which is capable of copolymerizing with monomer (s) of type (A); C) from 0.01 to 50 wt. % of at least one polysiloxane macromer (C) of the general formula
X (Y) n Si (R) 3-m Z m (I),
where X denotes a vinyl group which can copolymerize with the monomers (A) and (B);
Y means a divalent linking group;
R is hydrogen, C 1 -C 6 alkyl or alkoxy, or C 6 -C 12 aryl;
Z denotes a monovalent polysiloxane unit with a number average molecular weight of at least 500;
n is 0 or 1, and m is an integer from 1 to 3; moreover, the percentage is calculated relative to the total mass of monomers (A), (B) and (C).
9. Композиция по п. 8, отличающаяся тем, что полярные мономеры (В) выбирают из группы, состоящей из акриловой кислоты, N,N-диметилакриламида, диметиламиноэтилметакрилата, кватернизованного диметиламиноэтилметакрилата и винилпирролидона, и их смесей.8. Composition according to any one of paragraphs. from 5 to 7, characterized in that the polar monomers (B) are selected from the group consisting of acrylic acid, methacrylic acid, N, N-dimethylacrylamide, dimethylaminoethyl methacrylate, quaternized dimethylaminoethylmethacrylate, (meth) acrylamide, N-tert-poly-methylate, methylaminoethyl methacrylate, (meth) acrylamide, N-tert-methylate, methylaminoethylmethacrylate, (meth) acrylamide, N-tert-methyl methylacrylate, (c) dimethylaminoethyl methacrylate, (meth) acrylamide, N-tert-methylate, methylamine methylaminoethyl methacrylate, (meth) acrylamide, N-tert-methyl methylacrylate, (c) dimethylaminoethyl methacrylate, (meth) acrylamide, N. , maleic anhydride and its half esters, hydroxyalkyl (meth) acrylates, diallyldimethylammonium chloride, vinylpyrrolidone, vinyl ethers, maleimides, vinylpyridine, vinylimidazole, heterocyclic vinyl polar compounds, styrene, and lilovogo alcohol, vinyl alcohol and vinylcaprolactam, or mixtures thereof
9. The composition according to p. 8, characterized in that the polar monomers (B) are selected from the group consisting of acrylic acid, N, N-dimethylacrylamide, dimethylaminoethyl methacrylate, quaternized dimethylaminoethyl methacrylate and vinylpyrrolidone, and mixtures thereof.
в которой R1 представляет водород или -СООН; R2 представляет водород, метил или -СН2СООН; R3 представляет С1-С6-алкил, алкокси или алкиламино, С6-С12-арил или гидроксил; R4 представляет С1-С6-алкил, алкокси или алкиламино, С6-С12- арил или гидроксил; q представляет целое число от 2 до 6; р равен 0 или 1; r представляет целое число от 5 до 700; m представляет целое число от 1 до 3.10. Composition according to any one of paragraphs. from 5 to 9, characterized in that the polysiloxane macromer (C) corresponds to the general formula II
in which R 1 represents hydrogen or-COOH; R 2 represents hydrogen, methyl or -CH 2 COOH; R 3 is C 1 -C 6 alkyl, alkoxy or alkylamino, C 6 -C 12 aryl or hydroxyl; R 4 is C 1 -C 6 -alkyl, alkoxy or alkylamino; C 6 -C 12 is aryl or hydroxyl; q represents an integer from 2 to 6; p is 0 or 1; r represents an integer from 5 to 700; m represents an integer from 1 to 3.
причем n является целым числом в интервале от 5 до 700.11. Composition according to any one of paragraphs. 5 to 10, characterized in that the polysiloxane macromer (C) corresponds to the following general formula
moreover, n is an integer in the range from 5 to 700.
где n является целым числом в интервале от 5 до 700; причем процентное содержание вычисляют относительно общей массы мономеров.12. Composition according to any one of paragraphs. 1 to 11, characterized in that it contains at least one copolymer, which can be obtained by radical polymerization, based on a mixture of monomers consisting of: a) 60 wt. % tert-butyl acrylate; b) 20 wt. % acrylic acid; c) 20 wt. % silicone macromer formula
where n is an integer in the range from 5 to 700; moreover, the percentage is calculated relative to the total mass of monomers.
где n является целым числом в интервале от 5 до 700; причем процентное содержание вычисляют по отношению к общей массе мономеров.13. Composition according to any one of paragraphs. 1 to 11, characterized in that it contains at least one copolymer, which can be obtained by radical polymerization, based on a mixture of monomers, consisting of: a) 80 wt. % tert-butyl acrylate; b) 20 wt. % silicone macromer formula
where n is an integer in the range from 5 to 700; moreover, the percentage is calculated with respect to the total mass of monomers.
T-(CH2)s-Si-[O-SiR5R6)t-R7]y
в которой Т выбирают из группы, состоящей из NH2, NHR', эпокси, ОН, или SH-функциональных групп; R5, R6, R7 и R', независимо, обозначают С1-С6-алкил, фенил, бензил, С6-С12- алкилфенил или водород; s представляет число от 2 до 100; t представляет число от 0 до 1000, и у представляет число от 1 до 3.19. Composition according to any one of paragraphs. 15 to 18, characterized in that the polysiloxane macromer is a polysiloxane corresponding to general formula III
T- (CH 2 ) s —Si [O-SiR 5 R 6 ) t —R 7 ] y
in which T is selected from the group consisting of NH 2 , NHR ', epoxy, OH, or SH-functional groups; R 5 , R 6 , R 7 and R ', independently, represent C 1 -C 6 -alkyl, phenyl, benzyl, C 6 -C 12 - alkylphenyl or hydrogen; s represents a number from 2 to 100; t represents a number from 0 to 1000, and y represents a number from 1 to 3.
в которой радикалы G1, которые могут быть одинаковыми или различными, представляют водород или С1-С10-алкильный радикал, или, в другом случае, фенильный радикал; радикалы G2, которые могут быть одинаковыми или различными, представляют С1-С10-алкиленовую группу; G3 представляет полимерный остаток, являющийся результатом (гомо)полимеризации по крайней мере одного анионного мономера, содержащего этиленовую ненасыщенность; G4 представляет полимерный остаток, являющийся результатом (гомо)полимеризации по крайней мере одного гидрофобного мономера, содержащего этиленовую ненасыщенность; m и n равны 0 или 1; а представляет целое число в интервале от 0 до 50; b представляет целое число, которое может составлять от 10 до 350; с представляет целое число в интервале от 0 до 50; при условии, что один из параметров а и с отличен от 0.27. Composition according to any one of p. from 20 to 26, characterized in that the grafted silicone polymer is chosen from silicone polymers containing in its structure the link of formula IV
in which the radicals G 1 , which may be the same or different, are hydrogen or a C 1 -C 10 -alkyl radical, or, in another case, a phenyl radical; G 2 radicals, which may be the same or different, represent a C 1 -C 10 alkylene group; G 3 is a polymer residue resulting from the (homo) polymerization of at least one anionic monomer containing ethylene unsaturation; G 4 is a polymer residue resulting from the (homo) polymerization of at least one hydrophobic monomer containing ethylene unsaturation; m and n are 0 or 1; and represents an integer in the range from 0 to 50; b is an integer which can be from 10 to 350; c is an integer ranging from 0 to 50; provided that one of the parameters a and c is different from 0.
([Y(R2SiO)aR'2iYO][(CnZ2nO)b])2,
в которой R и R', которые могут быть одинаковыми или различными, представляют одновалентный углеводородный радикал, не содержащий алифатической ненасыщенности, n представляет целое число в интервале от 2 до 4, a представляет целое число больше или равное 5, b представляет целое число больше или равное 4, c представляет целое число больше или равное 4, y представляет двухвалентную органическую группу, которая связана с соседним атомом кремния через углерод-кремниевую связь и с полиоксиалкиленовым блоком через атом кислорода, средняя молекулярная масса каждого силоксанового блока находится примерно между 400 и, примерно 10000, причем молекулярная масса каждого полиоксиалкиленового блока составляет от, пример, 300 до, примерно 10000, силоксановые блоки составляют примерно от 10 мас. % до, примерно 95 мас. % блок-сополимера, причем средняя молекулярная масса блок-сополимера составляет по крайней мере 3000.32. Composition according to any one of the preceding paragraphs, characterized in that the linear block copolymer corresponds to the general formula
([Y (R 2 SiO) a R ' 2 iYO] [(C n Z 2n O) b ]) 2 ,
in which R and R ', which may be the same or different, represent a monovalent hydrocarbon radical that does not contain aliphatic unsaturation, n represents an integer in the range from 2 to 4, a represents an integer greater than or equal to 5, b represents an integer greater than or equal to 4, c represents an integer greater than or equal to 4, y represents a divalent organic group that is linked to the neighboring silicon atom through a carbon-silicon bond and to a polyoxyalkylene block through an oxygen atom, the average molecular weight of each siloxane block is between about 400 and about 10,000, wherein the molecular weight of each polyoxyalkylene block ranges from, example, 300 to about 10,000, the siloxane blocks comprise from about 10 wt. % to about 95 wt. % block copolymer, and the average molecular weight of the block copolymer is at least 3000.
[C4H8O(CnH2nO)b -C4H8-SiMe2O(SiMe2O)8SiMe2]c
где Me представляет метил, n является целым числом от 2 до 4, а и b представляют целые числа больше или равные 4, и с представляет число больше или равное 4.35. Composition according to any one of the preceding paragraphs, characterized in that the linear block copolymers of polysiloxane and polyoxyalkylene are chosen among the block copolymers of the formula
[C 4 H 8 O (C n H 2n O) b- C 4 H 8 -SiMe 2 O (SiMe 2 O) 8 SiMe 2 ] c
where Me is methyl, n is an integer from 2 to 4, a and b are integers greater than or equal to 4, and c represents a number greater than or equal to 4.
[-(SiMe2O) x SiMe2-C4H8O-(C2H4O) -(C3H6O)z-C4H8-]
где x представляет число от 5 до 15 включительно, y представляет число от 15 до 30 включительно, и z представляет число от 20 до 40.36. The composition according to p. 35, characterized in that the linear block copolymers of polysiloxane and polyoxyalkylene have a repeating unit, the structure of which
[- (SiMe 2 O) x SiMe 2 -C 4 H 8 O- (C 2 H 4 O) - (C 3 H 6 O) z- C 4 H 8 -]
where x represents a number from 5 to 15 inclusive, y represents a number from 15 to 30 inclusive, and z represents a number from 20 to 40.
[[(CH3)2SiO] 41(СH3)2SiСН2СН(СН3)CH2-O(C2H4O)18- (C3H6O)33CH2CH(CH3)CH2] 16.1
[[(CH3)2SiO] 31(СH3)2SiСН2СН(СН3)CH2-O(C2H4O)20- (C3H6O)29CH2CH(CH3)CH2] 13.3
[[(CH3)2SiO9(СH3)2SiСН2СН(СН3)CH2-O(C2H4O)20- (C3H6O)29CH2CH(CH3)CH2] 26.3
[[(CH3)2SiO] 16(СH3)2SiСН2СН(СН3)CH2-O(C2H4O)18- (C3H6O)20CH2CH(CH3)CH2] 21.5
[[(CH3)2SiO]9(СH3)2SiСН2СН(СН3)CH2-O(C2H4O)5- CH2CH(CH3)CH2] 4.8
38. Композиция по любому из предыдущих пунктов, отличающаяся тем, что линейный блок-сополимер(ы) присутствует (ют) в концентрации в интервале от 0,01 до 20 мас. % по отношению к общей массе композиции, предпочтительно - от 0,1 до 15 мас. %, и предпочтительнее от 0,5 до 10 мас. %.37. The composition according to any one of the claims from 1 to 35, characterized in that the block copolymer is selected from the group consisting of the following compounds
[[(CH 3 ) 2 SiO] 41 (CH 3 ) 2 Si CH 2 CH (CH 3 ) CH 2 -O (C 2 H 4 O) 18 - (C 3 H 6 O) 33 CH 2 CH (CH 3 ) CH 2 ] 16.1
[[(CH 3 ) 2 SiO] 31 (CH 3 ) 2 Si CH 2 CH (CH 3 ) CH 2 -O (C 2 H 4 O) 20 - (C 3 H 6 O) 29 CH 2 CH (CH 3 ) CH 2 ] 13.3
[[(CH 3 ) 2 SiO 9 (CH 3 ) 2 Si CH 2 CH (CH 3 ) CH 2 -O (C 2 H 4 O) 20 - (C 3 H 6 O) 29 CH 2 CH (CH 3 ) CH 2 ] 26.3
[[(CH 3 ) 2 SiO] 16 (CH 3 ) 2 Si CH 2 CH (CH 3 ) CH 2 -O (C 2 H 4 O) 18 - (C 3 H 6 O) 20 CH 2 CH (CH 3 ) CH 2 ] 21.5
[[(CH 3 ) 2 SiO] 9 (CH 3 ) 2 Si CH 2 CH (CH 3 ) CH 2 -O (C 2 H 4 O) 5 - CH 2 CH (CH 3 ) CH 2 ] 4.8
38. Composition according to any one of the preceding paragraphs, characterized in that the linear block copolymer (s) is present (s) in a concentration in the range from 0.01 to 20 wt. % relative to the total weight of the composition, preferably from 0.1 to 15 wt. %, and preferably from 0.5 to 10 wt. %
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9511479A FR2739280B1 (en) | 1995-09-29 | 1995-09-29 | COSMETIC COMPOSITION COMPRISING AT LEAST ONE GRAFT SILICONE POLYMER AND AT LEAST ONE POLYSILOXANE-POLYOXYALKYLENE BLOCK COPOLYMER |
| FR95/11479 | 1995-09-29 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU97121884A true RU97121884A (en) | 1999-08-27 |
| RU2168325C2 RU2168325C2 (en) | 2001-06-10 |
Family
ID=9483069
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU97121884/14A RU2168325C2 (en) | 1995-09-29 | 1996-09-16 | Cosmetic composition containing at least one silicone graft-polymer and at least one linear block-copolymer of polysiloxane and polyoxyalkylene |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US6432418B1 (en) |
| EP (1) | EP0859590B1 (en) |
| JP (1) | JP3322886B2 (en) |
| KR (1) | KR100291819B1 (en) |
| AT (1) | ATE210962T1 (en) |
| BR (1) | BR9610794A (en) |
| CA (1) | CA2223819A1 (en) |
| DE (1) | DE69618230T2 (en) |
| DK (1) | DK0859590T3 (en) |
| ES (1) | ES2170263T3 (en) |
| FR (1) | FR2739280B1 (en) |
| PL (1) | PL186161B1 (en) |
| PT (1) | PT859590E (en) |
| RU (1) | RU2168325C2 (en) |
| WO (1) | WO1997012593A1 (en) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19642623A1 (en) * | 1996-10-16 | 1998-04-23 | Wella Ag | Hair cleanser with setting properties |
| US5965115A (en) * | 1997-11-05 | 1999-10-12 | The Procter & Gamble Company | Personal care compositions |
| US6093410A (en) * | 1997-11-05 | 2000-07-25 | The Procter & Gamble Company | Personal care compositions |
| JP4066497B2 (en) * | 1998-03-23 | 2008-03-26 | ダイキン工業株式会社 | Cosmetics comprising a fluorinated copolymer |
| FR2818901B1 (en) * | 2001-01-02 | 2004-01-23 | Oreal | COSMETIC COMPOSITIONS CONTAINING POLYETHER BLOCK SILICONE AND POLYETHER SILICONE AND USES THEREOF |
| US7959198B2 (en) * | 2002-05-16 | 2011-06-14 | Labor Saving Systems, Ltd. | Magnetic line retrieval system and method |
| WO2004055077A2 (en) * | 2002-12-12 | 2004-07-01 | L'oréal | Cosmetic composition comprising a polymer |
| US7128412B2 (en) * | 2003-10-03 | 2006-10-31 | Xerox Corporation | Printing processes employing intermediate transfer with molten intermediate transfer materials |
| US20050074260A1 (en) * | 2003-10-03 | 2005-04-07 | Xerox Corporation | Printing apparatus and processes employing intermediate transfer with molten intermediate transfer materials |
| KR100641006B1 (en) * | 2004-11-04 | 2006-11-02 | 엘지.필립스 엘시디 주식회사 | Printing Plate |
| US7585922B2 (en) * | 2005-02-15 | 2009-09-08 | L'oreal, S.A. | Polymer particle dispersion, cosmetic compositions comprising it and cosmetic process using it |
| KR101632609B1 (en) | 2008-10-22 | 2016-06-23 | 다우 코닝 코포레이션 | Aminofunctional endblocked silicone polyether copolymers in personal care compositions |
| US8644017B2 (en) | 2011-05-26 | 2014-02-04 | Lsi Corporation | Storage device carriers for adapting a storage device of a first size to a slot for a storage device of a second size |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4532132A (en) * | 1983-04-11 | 1985-07-30 | Dow Corning Corporation | Skin care formulations comprising a water-in-mineral oil emulsion and siloxane compositions therefor |
| DE69006556T2 (en) * | 1989-08-07 | 1994-06-09 | Procter & Gamble | Hair conditioning and styling agents. |
| DE69033073T2 (en) | 1989-08-07 | 1999-11-25 | Procter & Gamble | Hair care and fixative |
| US5472686A (en) * | 1990-12-28 | 1995-12-05 | Nippon Unicar Company Limited | Cosmetic formulations |
| US5468477A (en) * | 1992-05-12 | 1995-11-21 | Minnesota Mining And Manufacturing Company | Vinyl-silicone polymers in cosmetics and personal care products |
| KR100287034B1 (en) * | 1992-05-12 | 2001-04-16 | 스프레이그 로버트 월터 | Cosmetic composition |
| WO1993023446A2 (en) * | 1992-05-15 | 1993-11-25 | The Procter & Gamble Company | Adhesive agent containing polysiloxane-grafted polymer, and cosmetic compositions thereof |
| DE69332875T2 (en) * | 1992-07-28 | 2003-12-04 | Mitsubishi Chem Corp | Hair cosmetic composition |
| FR2707876B1 (en) * | 1993-07-23 | 1995-09-08 | Oreal | Cosmetic compositions for maintaining hairstyles with improved fixing power. |
| FR2709953B1 (en) * | 1993-09-14 | 1995-11-24 | Oreal | Cosmetic composition containing at least one nonionic surfactant of the alkylpolyglycoside and / or polyglycerolated type and at least one polydimethylsiloxane / polyoxalkylene block copolymer. |
| FR2709955B1 (en) * | 1993-09-15 | 1995-10-20 | Oreal | Cosmetic compositions containing a linear polysiloxane-polyoxyalkylene block copolymer and an amphoteric polymer, and their uses. |
-
1995
- 1995-09-29 FR FR9511479A patent/FR2739280B1/en not_active Expired - Fee Related
-
1996
- 1996-09-16 ES ES96931851T patent/ES2170263T3/en not_active Expired - Lifetime
- 1996-09-16 PT PT96931851T patent/PT859590E/en unknown
- 1996-09-16 RU RU97121884/14A patent/RU2168325C2/en not_active IP Right Cessation
- 1996-09-16 AT AT96931851T patent/ATE210962T1/en not_active IP Right Cessation
- 1996-09-16 WO PCT/FR1996/001433 patent/WO1997012593A1/en active IP Right Grant
- 1996-09-16 BR BR9610794A patent/BR9610794A/en not_active IP Right Cessation
- 1996-09-16 KR KR1019970710014A patent/KR100291819B1/en not_active IP Right Cessation
- 1996-09-16 US US08/983,305 patent/US6432418B1/en not_active Expired - Fee Related
- 1996-09-16 JP JP51400597A patent/JP3322886B2/en not_active Expired - Fee Related
- 1996-09-16 EP EP96931851A patent/EP0859590B1/en not_active Revoked
- 1996-09-16 CA CA002223819A patent/CA2223819A1/en not_active Abandoned
- 1996-09-16 DE DE69618230T patent/DE69618230T2/en not_active Expired - Fee Related
- 1996-09-16 DK DK96931851T patent/DK0859590T3/en active
- 1996-09-16 PL PL96324747A patent/PL186161B1/en unknown
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