RU97113757A - MULTILAYER SHRINKING FILM - Google Patents

MULTILAYER SHRINKING FILM

Info

Publication number
RU97113757A
RU97113757A RU97113757/04A RU97113757A RU97113757A RU 97113757 A RU97113757 A RU 97113757A RU 97113757/04 A RU97113757/04 A RU 97113757/04A RU 97113757 A RU97113757 A RU 97113757A RU 97113757 A RU97113757 A RU 97113757A
Authority
RU
Russia
Prior art keywords
shrink
film
ethylene
copolymer
temperature
Prior art date
Application number
RU97113757/04A
Other languages
Russian (ru)
Other versions
RU2159186C2 (en
Inventor
Ба Серж
Чокка Паоло
Ли Мампауэр Эдвард
Original Assignee
В.Р.Грейс энд Ко.-Конн
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US08/357,487 external-priority patent/US6150011A/en
Application filed by В.Р.Грейс энд Ко.-Конн filed Critical В.Р.Грейс энд Ко.-Конн
Publication of RU97113757A publication Critical patent/RU97113757A/en
Application granted granted Critical
Publication of RU2159186C2 publication Critical patent/RU2159186C2/en

Links

Claims (12)

1. Термоусадочная пленка, включающая центральный слой, состоящий из сополимера этилена и винилового спирта, двух наружных слоев из смесей, состоящих из этиленвинилацетатного и этилен-альфа-олефинового сополимеров, и двух адгезионных слоев, отличающаяся тем, что указанная пленка имеет свободную усадку не менее 40%, предпочтительно - не менее 45% и наиболее предпочтительно - не менее 50%, в обоих направлениях при 120oС и максимальную свободную усадку в поперечном направлении во всем диапазоне температур усадки, не превышающую 0,5 Н/см.1. Shrink film, comprising a central layer consisting of a copolymer of ethylene and vinyl alcohol, two outer layers of mixtures consisting of ethylene vinyl acetate and ethylene alpha olefin copolymers, and two adhesive layers, characterized in that said film has a free shrink of at least 40%, preferably not less than 45% and most preferably not less than 50%, in both directions at 120 ° C. and the maximum free shrink in the transverse direction over the entire range of shrink temperatures not exceeding 0.5 N / cm. 2. Термоусадочная пленка по п. 1, отличающаяся тем, что центральный слой состоит главным образом из сополимера(ов) этилена и винилового спирта, необязательно смешанного с полиамидом(ами). 2. Shrink film according to claim 1, characterized in that the central layer consists mainly of copolymer (s) of ethylene and vinyl alcohol, optionally mixed with polyamide (s). 3. Термоусадочная пленка по п. 2, отличающаяся тем, что наружные слои состоят главным образом из этиленвинилацетатного сополимера и одного или нескольких этилен-альфа-олефиновых сополимеров. 3. Shrink film according to claim 2, characterized in that the outer layers mainly consist of an ethylene vinyl acetate copolymer and one or more ethylene alpha olefin copolymers. 4. Термоусадочная пленка по п. 3, где центральный слой состоит главным образом из смеси сополимера(ов) этилена и винилового спирта с полиамидом(ами), наружные слои состоят главным образом из смеси этиленвинилацетатного сополимера, этилен-альфа-олефинового сополимера низкой плотности (LLDPE) и этилен-альфа-олефинового сополимера средней плотности (LMDPE), отличающаяся тем, что свободная усадка в обоих направлениях при 120oС составляет не менее 45% и предпочтительно - не менее 50%.4. The shrink film of claim 3, wherein the center layer consists mainly of a mixture of ethylene vinyl alcohol copolymer (s) with polyamide (s), the outer layers mainly consist of a mixture of ethylene vinyl acetate copolymer, low density ethylene alpha olefin copolymer ( LLDPE) and medium density ethylene-alpha-olefin copolymer (LMDPE), characterized in that free shrink in both directions at 120 ° C. is at least 45% and preferably at least 50%. 5. Термоусадочная пленка по п. 4, отличающаяся тем, что центральный слой состоит главным образом из смеси сополимера этилена и винилового спирта с полиамидом в количестве до 20 маc.%, а пленка вулканизована. 5. Shrink film according to claim 4, characterized in that the central layer consists mainly of a mixture of a copolymer of ethylene and vinyl alcohol with polyamide in an amount of up to 20 wt.%, And the film is vulcanized. 6. Термоусадочная пленка по п. 1, отличающаяся тем, что она имеет толщину примерно 15-150 мкм. 6. Shrink film according to claim 1, characterized in that it has a thickness of about 15-150 microns. 7. Термоусадочная пленка по п. 6, отличающаяся тем, что толщина пленки составляет примерно 18-90 мкм, предпочтительно примерно 18-40, наиболее предпочтительно примерно 20-35 мкм. 7. Shrink film according to claim 6, characterized in that the film thickness is about 18-90 microns, preferably about 18-40, most preferably about 20-35 microns. 8. Способ селективного снижения силы усадки в поперечном направлении термоусадочной пленки, включающей центральный слой, состоящий из сополимера этилена и винилового спирта, два наружных слоя из смесей, состоящих из этиленвинилацетатного и этилен-альфа-олефинового сополимеров, и два адгезионных слоя, до величины, не превышающей 0,5 Н/см во всем диапазоне температур усадки, при сохранении практически без изменения % свободной усадки пленки при 120oС, который предусматривает нагревание пленки, полученной известными способами экструзии и ориентирования и имеющей силу усадки в поперечном направлении больше 0,5 Н/см, при температуре примерно 70-100oС в течение времени, достаточного для индуцирования снижения максимального значения силы усадки в поперечном направлении пленки до величины, не превышающей 0,5 Н/см, без значительного снижения % свободной усадки пленки при 120oС, а затем резкое охлаждение ее до температуры ниже комнатной, предпочтительно - ниже примерно 20oС.8. A method for selectively reducing the shrink force in the transverse direction of a shrink film, comprising a central layer consisting of a copolymer of ethylene and vinyl alcohol, two outer layers of mixtures consisting of ethylene-vinyl acetate and ethylene-alpha-olefin copolymers, and two adhesive layers, to a value not exceeding 0.5 N / cm in the entire range of temperature shrinkage, while maintaining virtually unchanged% free shrinkage of the film at 120 o C, which involves heating the film obtained by known methods of extrusion and Orientation and having a shrink force in the transverse direction of more than 0.5 N / cm, at a temperature of about 70-100 o C for a time sufficient to induce a decrease in the maximum value of the shrink force in the transverse direction of the film to a value not exceeding 0.5 N / cm, without a significant reduction in% free shrinkage of the film at 120 o C, and then a sharp cooling to a temperature below room temperature, preferably below about 20 o C. 9. Способ по п. 8, отличающийся тем, что нагревание пленки осуществляют в течение примерно 0,1-7,5 с. 9. The method according to p. 8, characterized in that the heating of the film is carried out for about 0.1-7.5 s. 10. Способ по п. 8, отличающийся тем, что нагревание пленки осуществляют при температуре примерно 70-95oС, и предпочтительно примерно 72-90oС.10. The method according to p. 8, characterized in that the heating of the film is carried out at a temperature of about 70-95 o C, and preferably about 72-90 o C. 11. Способ упаковки деформируемых изделий, таких как подносы, в целях получения плотной упаковки, не вызывающей деформации, который включает обертывание деформируемого изделия в пакет соответствующего размера, изготовленный из пленки по любому из предшествующих пп. 1-7, необязательно в условиях продувки газом, удаление избытка газа из пакета, герметизирование открытого конца пакета и пропускание разрыхленной упаковки через усадочную камеру с горячим воздухом, нагретым до температуры 140-160oС, для обеспечения плотной упаковки.11. A method of packaging deformable products, such as trays, in order to obtain a dense, non-deforming package, which includes wrapping a deformable product in a bag of an appropriate size made of a film according to any one of the preceding claims. 1-7, optionally under gas purging conditions, removing excess gas from the bag, sealing the open end of the bag and passing the loosened package through a shrink chamber with hot air heated to a temperature of 140-160 o C, to ensure tight packaging. 12. Упаковка, полученная способом по п. 10. 12. The packaging obtained by the method according to p. 10.
RU97113757/04A 1994-12-16 1995-12-15 Laminated thermoshrinkage film RU2159186C2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/357,487 US6150011A (en) 1994-12-16 1994-12-16 Multi-layer heat-shrinkage film with reduced shrink force, process for the manufacture thereof and packages comprising it
US357,487 1994-12-16

Publications (2)

Publication Number Publication Date
RU97113757A true RU97113757A (en) 1999-06-10
RU2159186C2 RU2159186C2 (en) 2000-11-20

Family

ID=23405826

Family Applications (1)

Application Number Title Priority Date Filing Date
RU97113757/04A RU2159186C2 (en) 1994-12-16 1995-12-15 Laminated thermoshrinkage film

Country Status (17)

Country Link
US (1) US6150011A (en)
EP (1) EP0797507B1 (en)
JP (1) JPH10512506A (en)
CN (1) CN1190367A (en)
AT (1) ATE181282T1 (en)
BR (1) BR9510093A (en)
CA (1) CA2207718C (en)
DE (1) DE69510373T2 (en)
ES (1) ES2133844T3 (en)
FI (1) FI972512A (en)
MX (1) MX9704389A (en)
MY (1) MY131731A (en)
NZ (1) NZ298960A (en)
RU (1) RU2159186C2 (en)
TW (1) TW296997B (en)
WO (1) WO1996018501A1 (en)
ZA (1) ZA9510748B (en)

Families Citing this family (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5744181A (en) * 1995-03-01 1998-04-28 W. R. Grace & Co.-Conn. Packaging method using thermoplastic materials and package obtained thereby
US6623821B1 (en) * 1995-03-31 2003-09-23 E. I. Du Pont De Nemours And Company Heat-shrinkable, heat-sealable polyester film for packaging
JP4495264B2 (en) 1998-04-24 2010-06-30 株式会社クレハ Heat shrinkable multilayer film
US6436496B1 (en) * 1998-11-06 2002-08-20 Avery Dennison Corporation Halogen-free, printable, multilayered shrink films and articles encapsulated therein
AUPP749398A0 (en) * 1998-12-03 1999-01-07 Sporos Sa Multilayer heat shrinkable film
MXPA04003265A (en) 2001-10-17 2004-07-23 Avery Dennison Corp Multilayered shrink films and articles encapsulated therewith.
US20040175467A1 (en) * 2003-03-07 2004-09-09 Mueller Chad D. Packages made from multilayer structures
US20040173944A1 (en) * 2003-03-07 2004-09-09 Mueller Chad D. Methods of making multilayer barrier structures
US20040173491A1 (en) * 2003-03-07 2004-09-09 Buelow Duane H. Packages made from thermoplastic multilayer barrier structures
US20040175464A1 (en) 2003-03-07 2004-09-09 Blemberg Robert J. Multilayer structures, packages, and methods of making multilayer structures
US20040175465A1 (en) * 2003-03-07 2004-09-09 Buelow Duane H. Thermoplastic multilayer structures
US20040173932A1 (en) * 2003-03-07 2004-09-09 Douglas Michael J. Methods of making multilayer structures
US20040175466A1 (en) * 2003-03-07 2004-09-09 Douglas Michael J. Multilayer barrier structures, methods of making the same and packages made therefrom
US20040175592A1 (en) * 2003-03-07 2004-09-09 Douglas Michael J. Thermoplastic multilayer barrier structures
US20040234797A1 (en) * 2003-05-23 2004-11-25 Cryovac, Inc. Oxygen scavenging film with antifog properties
JP4604025B2 (en) * 2004-05-18 2010-12-22 グンゼ株式会社 Multilayer heat shrinkable film and packaging battery
US20060099436A1 (en) * 2004-11-05 2006-05-11 Cryovac, Inc. Reduced antifog level in oxygen scavenging film with antifog properties
EP1827820B8 (en) * 2004-12-10 2016-10-12 Bemis Company, Inc. Packaging films comprising nylon blend compositions
FR2887801B1 (en) * 2005-07-01 2007-09-07 Bollore Sa FILM WITH SEVERAL LAYERS
CN101318577B (en) * 2008-07-07 2011-08-17 苏州天加新材料有限公司 Thermal contraction sheet film for bone and meat packaging
AU2010294162A1 (en) * 2009-09-14 2012-03-08 Cryovac, Inc. Gas barrier heat-shrinkable film
ES2581296T7 (en) 2013-05-21 2017-07-26 Cryovac, Inc. Heat shrinkable gas barrier film
WO2015181333A1 (en) * 2014-05-28 2015-12-03 Cryovac, Inc. Multilayer heat shrinkable films
CA2957322C (en) * 2014-08-06 2020-07-21 Handy Technology (Zhuhai) Ltd. Self-heating insulating film and face mask and eye mask manufactured therefrom
WO2017207662A1 (en) 2016-06-01 2017-12-07 Cryovac, Inc. Gas-barrier heat-shrinkable film
US10633524B2 (en) 2016-12-01 2020-04-28 Cryovac, Llc Multilayer heat shrinkable films
CA3019433A1 (en) 2017-10-02 2019-04-02 Flexopack S.A. Multilayer cling film
JP7061930B2 (en) * 2018-06-01 2022-05-02 株式会社クレハ Heat shrinkable multilayer film
WO2020176282A1 (en) * 2019-02-25 2020-09-03 Cryovac, Llc Abrasion resistant heat shrinkable multilayer film
CN111572998B (en) * 2020-05-22 2022-01-04 温州市恒生包装有限公司 Multidirectional crack arrest pyrocondensation membrane

Family Cites Families (36)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA849081A (en) * 1967-03-02 1970-08-11 Du Pont Of Canada Limited PRODUCTION OF ETHYLENE/.alpha.-OLEFIN COPOLYMERS OF IMPROVED PHYSICAL PROPERTIES
US3595735A (en) * 1968-05-06 1971-07-27 Nat Distillers Chem Corp Blown tubular films
US3741253A (en) * 1971-03-30 1973-06-26 Grace W R & Co Laminates of ethylene vinyl acetate polymers and polymers of vinylidene chloride
US4064296A (en) * 1975-10-02 1977-12-20 W. R. Grace & Co. Heat shrinkable multi-layer film of hydrolyzed ethylene vinyl acetate and a cross-linked olefin polymer
BG24190A1 (en) * 1976-09-08 1978-01-10 Antonov Method of synthesis of speech and device for effecting same
JPS5382888A (en) * 1976-12-29 1978-07-21 Kureha Chem Ind Co Ltd Co-extruded five-layered drawn cylindrical film and its manufacture
JPS5391890A (en) * 1977-01-24 1978-08-12 Kureha Chemical Ind Co Ltd Method of producing skin package
US4284458A (en) * 1977-07-25 1981-08-18 W. R. Grace & Co. Method for producing laminated film
US4302566A (en) * 1978-03-31 1981-11-24 Union Carbide Corporation Preparation of ethylene copolymers in fluid bed reactor
US4302565A (en) * 1978-03-31 1981-11-24 Union Carbide Corporation Impregnated polymerization catalyst, process for preparing, and use for ethylene copolymerization
US4188443A (en) * 1978-08-30 1980-02-12 W. R. Grace & Co. Multi-layer polyester/polyolefin shrink film
US4194039A (en) * 1978-04-17 1980-03-18 W. R. Grace & Co. Multi-layer polyolefin shrink film
DE2838062C2 (en) * 1978-08-31 1983-01-20 Siemens AG, 1000 Berlin und 8000 München Arrangement with parallel-connected DC converters
US4399180A (en) * 1978-09-15 1983-08-16 Mobil Oil Corporation Coextruded thermoplastic stretch-wrap
US4352849A (en) * 1981-03-26 1982-10-05 W. R. Grace & Co. Coextruded, heat-shrinkable, multi-layer, polyolefin packaging film
US4399173A (en) * 1982-01-04 1983-08-16 Union Carbide Corporation Multilayer films comprising low pressure, low density polyethylene
JPS58142848A (en) * 1982-02-19 1983-08-25 呉羽化学工業株式会社 Laminated film
US4532189A (en) * 1982-02-19 1985-07-30 W. R. Grace & Co., Cryovac Div. Linear polyethylene shrink films
US4457960A (en) * 1982-04-26 1984-07-03 American Can Company Polymeric and film structure for use in shrink bags
US4557780A (en) * 1983-10-14 1985-12-10 American Can Company Method of making an oriented polymeric film
US4590124A (en) * 1984-05-10 1986-05-20 W. R. Grace & Co., Cryovac Div. Storm window film
US4551380A (en) * 1984-05-10 1985-11-05 W. R. Grace & Co., Cryovac Div. Oriented heat-sealable multilayer packaging film
US4514465A (en) * 1984-05-30 1985-04-30 W. R. Grace & Co., Cryovac Div. Storm window film comprising at least five layers
US4726984A (en) * 1985-06-28 1988-02-23 W. R. Grace & Co. Oxygen barrier oriented film
US4724185A (en) * 1985-09-17 1988-02-09 W. R. Grace & Co., Cryovac Div. Oxygen barrier oriented film
CA1308012C (en) * 1986-01-17 1992-09-29 Robert Wayne Thies Multilayered polyolefin high shrinkage, low-shrink force shrink film
US4755419A (en) * 1986-03-21 1988-07-05 W. R. Grace & Co., Cryovac Div. Oxygen barrier oriented shrink film
US5004647A (en) * 1986-03-21 1991-04-02 W. R. Grace & Co.-Conn. Oxygen barrier biaxially oriented film
US4839235A (en) * 1986-06-30 1989-06-13 W. R. Grace & Co. Oxygen barrier film
US4833024A (en) * 1987-04-03 1989-05-23 W. R. Grace & Co. Low shrink energy films
US4837084A (en) * 1987-07-02 1989-06-06 W. R. Grace & Co.-Conn. Thermoplastic multi-layer packaging film and bags made therefrom
US5023143A (en) * 1989-03-14 1991-06-11 W. R. Grace & Co.-Conn. Low shrink force shrink film
US5272236A (en) * 1991-10-15 1993-12-21 The Dow Chemical Company Elastic substantially linear olefin polymers
US5278272A (en) * 1991-10-15 1994-01-11 The Dow Chemical Company Elastic substantialy linear olefin polymers
WO1994007954A1 (en) * 1992-10-02 1994-04-14 E.I. Du Pont De Nemours And Company Improved shrink film and methods relating thereto
US5382470A (en) * 1993-04-09 1995-01-17 Viskase Corporation EVOH oxygen barrier stretched multilayer film

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