RU97113493A - QUICK CURING WATER COMPOSITION FOR COATING AND PAINT - Google Patents

QUICK CURING WATER COMPOSITION FOR COATING AND PAINT

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Publication number
RU97113493A
RU97113493A RU97113493/04A RU97113493A RU97113493A RU 97113493 A RU97113493 A RU 97113493A RU 97113493/04 A RU97113493/04 A RU 97113493/04A RU 97113493 A RU97113493 A RU 97113493A RU 97113493 A RU97113493 A RU 97113493A
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RU
Russia
Prior art keywords
monomers
weight
aqueous coating
fast
coating composition
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RU97113493/04A
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Russian (ru)
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RU2158744C2 (en
Inventor
Дж.Хелмер Брэдли
В.Янг Джеймс (младший)
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Дзе Дау Кемикал Компани
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Publication of RU97113493A publication Critical patent/RU97113493A/en
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Publication of RU2158744C2 publication Critical patent/RU2158744C2/en

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Claims (14)

1. Быстроотверждающаяся водная композиция для покрытия, отличающаяся тем, что включает а) от 90 до 99,6 вес.%, в расчете на вес сухих материалов в композиции, анионостабилизированной водной эмульсии полимера, имеющего Tg от -10oС до 50oС, при этом полимер включает в полимеризованной форме по меньшей мере один этиленоненасыщенный мономер, где в расчете на общий вес всех этиленоненасыщенных мономеров в полимере от 0 до 5 вес.% мономеров являются мономерами α, β-этиленоненасыщенной алифатической карбоновой кислоты; (в) от 0,2 до 5 вес.% полиимина, имеющего среднечисленную молекулярную массу от 250 до 2000; и (с) от 0,2 до 5 вес.% летучего основания; при этом композиция имеет рН от 8 до 11, и пленка, отлитая из композиции, имеет скорость отверждения, равную по меньшей мере в пределах от 5 до 20 минут после отливки при окружающих условиях; температуре до 30oС и относительной влажности не менее 50%.1. Fast-curing aqueous coating composition, characterized in that it comprises a) from 90 to 99.6 wt.%, Calculated on the weight of dry materials in the composition, an anionically stabilized aqueous emulsion of a polymer having a Tg from -10 o C to 50 o C wherein the polymer comprises in polymerized form at least one ethylenically unsaturated monomer, where, based on the total weight of all ethylenically unsaturated monomers in the polymer, from 0 to 5 wt.% of the monomers are monomers of α, β-ethylenically unsaturated aliphatic carboxylic acid; (C) from 0.2 to 5 wt.% polyimine having a number average molecular weight of from 250 to 2000; and (c) from 0.2 to 5% by weight of a volatile base; wherein the composition has a pH of from 8 to 11, and the film cast from the composition has a curing rate of at least 5 to 20 minutes after casting under ambient conditions; temperature up to 30 o С and relative humidity not less than 50%. 2. Быстроотверждающаяся водная композиция для покрытия по п.1, отличающаяся тем, что пленка, отлитая из композиции, имеет скорость отверждения, равную по меньшей мере в пределах от 6 до 20 мин. 2. The fast-curing aqueous coating composition according to claim 1, characterized in that the film cast from the composition has a curing rate equal to at least 6 to 20 minutes. 3. Быстроотверждающаяся водная композиция для покрытия по любому из предшествующих пунктов, отличающаяся тем, что полимеризационная смесь включает от 0,3 до 2 вес.% одного или более мономеров α, β-этиленоненасыщенной алифатической карбоновой кислоты. 3. Fast-curing aqueous coating composition according to any one of the preceding paragraphs, characterized in that the polymerization mixture comprises from 0.3 to 2 wt.% One or more monomers of α, β-ethylenically unsaturated aliphatic carboxylic acid. 4. Быстроотверждающаяся водная композиция для покрытия по любому из предшествующих пунктов, отличающаяся тем, что рН композиции составляет от 9,5 до 11. 4. Quick-setting aqueous coating composition according to any one of the preceding paragraphs, characterized in that the pH of the composition is from 9.5 to 11. 5. Быстроотверждающаяся водная композиция для покрытия по любому из предшествующих пунктов, отличающаяся тем, что композиция включает от 0,3 до 2 вес.% полиимина. 5. Fast-curing aqueous coating composition according to any one of the preceding paragraphs, characterized in that the composition comprises from 0.3 to 2 wt.% Polyimine. 6. Быстроотверждающаяся водная композиция для покрытия по любому из предшествующих пунктов, отличающаяся тем, что молекулярная масса полиэтиленимина составляет от 400 до 2000. 6. Fast-curing aqueous coating composition according to any one of the preceding paragraphs, characterized in that the molecular weight of polyethyleneimine is from 400 to 2000. 7. Быстроотверждающаяся водная композиция для покрытия по любому из предшествующих пунктов, отличающаяся тем, что мономеры полимеризационной смеси включают от 40 до 60 вес.% метилметакрилата и от 60 до 40 вес.% бутилакрилата и от 0 до 3 вес.% акриловой кислоты, метакриловой кислоты или их смеси. 7. Fast-curing aqueous coating composition according to any one of the preceding paragraphs, characterized in that the monomers of the polymerization mixture include from 40 to 60 wt.% Methyl methacrylate and from 60 to 40 wt.% Butyl acrylate and from 0 to 3 wt.% Acrylic acid, methacrylic acids or mixtures thereof. 8. Быстроотверждающаяся водная композиция для покрытия по любому из предшествующих пунктов, отличающаяся тем, что мономеры полимеризационной смеси включают от 1 до 70 вес.% одного или более винилароматических мономеров. 8. Fast-curing aqueous coating composition according to any one of the preceding paragraphs, characterized in that the monomers of the polymerization mixture include from 1 to 70 wt.% One or more vinyl aromatic monomers. 9. Быстроотверждающаяся водная композиция для покрытия по любому из предшествующих пунктов, отличающаяся тем, что мономеры полимеризационной смеси включают от 2 до 99 вес.% стирола и бутадиена. 9. Fast-curing aqueous coating composition according to any one of the preceding paragraphs, characterized in that the monomers of the polymerization mixture include from 2 to 99 wt.% Styrene and butadiene. 10. Быстроотверждающаяся водная дорожно-маркировочная краска, отличающаяся тем, что включает быстроотверждающуюся водную композицию для покрытия по п.1; и органический или неорганический пимент, где краска в соответствии с ASTM D 711-84 имеет время высыхания пленки до исчезнования следов 20 мин или менее. 10. Fast-curing aqueous road marking paint, characterized in that it includes a quick-curing aqueous coating composition according to claim 1; and organic or inorganic pimento, where the paint in accordance with ASTM D 711-84 has a film drying time until traces of 20 minutes or less disappear. 11. Быстроотверждающаяся водная композиция связующего, обладающего миграционной устойчивостью, отличающаяся тем, что быстроотверждающуюся водную композицию для покрытия по п.1; и органический наполнитель, неорганический наполнитель, органическое волокно, минеральное волокно или их смесь. 11. Fast-curing aqueous binder composition having migration stability, characterized in that the fast-curing aqueous coating composition according to claim 1; and organic filler, inorganic filler, organic fiber, mineral fiber, or a mixture thereof. 12. Водная композиция для покрытия, отличающаяся тем, что (а) от 90 до 99,6 вес. %, в расчете на вес сухих материалов в композиции, анионостабилизированной водной эмульсии сополимера, имеющего Tg от -10oС до 50oС, при этом сополимер включает в полимеризованной форме полимеризационную смесь, содержащую два или более этиленоненасыщенных мономеров, где, в расчете на общий вес всех этиленоненасыщенных мономеров в полимеризационной смеси, от 0 до 5 вес.% мономеров являются мономерами α, β-этиленоненасыщенной алифатической карбоновой кислоты; (в) от 0,2 до 5 вес.% полиимина, имеющего молекулярную массу от 250 до 2000; с) от 0,2 до 5 вес.% летучего основания; где композиция имеет рН от 8 до 11 и где пигментосодержащий состав, полученный из композиции, в соответствии с ASTM D 711-84 имеет время высыхания пленки до исчезновения следов 20 минут или менее.12. Aqueous coating composition, characterized in that (a) from 90 to 99.6 weight. %, based on the weight of dry materials in the composition, an anionically stabilized aqueous emulsion of a copolymer having a Tg from -10 ° C to 50 ° C, the copolymer comprising in a polymerized form a polymerization mixture containing two or more ethylenically unsaturated monomers, where, based on the total weight of all ethylenically unsaturated monomers in the polymerization mixture, from 0 to 5 wt.% of the monomers are monomers of α, β-ethylenically unsaturated aliphatic carboxylic acid; (C) from 0.2 to 5 wt.% polyimine having a molecular weight of from 250 to 2000; c) from 0.2 to 5% by weight of volatile base; where the composition has a pH of from 8 to 11 and where the pigment-containing composition obtained from the composition, in accordance with ASTM D 711-84 has a drying time of the film until the disappearance of traces of 20 minutes or less. 13. Водная композиция для покрытия, отличающаяся тем, что а) анионостабилизированную водную эмульсию полимера, имеющего Тg от -10oС до 50oС, при этом полимер включает в полимеризованной форме, по меньшей мере, один этиленоненасыщенный мономер, где в расчете на общий вес всех этиленоненасыщенных мономеров в полимере, от О до 5 вес. % мономеров являются мономерами α, β-этиленоненасыщенной алифатической карбоновой кислоты; в) полиимин, имеющий среднечисленную молекулярную массу от 250 до 2000; и с) летучее основание, где композиция имеет рН от 8 до 11, и где количества компонентов (в) и (с) являются такими, что пигментосодержащий состав, полученный из композиции, в соответствии с ASTM D 711-84 имеет время высыхания пленки до исчезновения следов 20 мин или менее.13. An aqueous coating composition, characterized in that a) an anionically stabilized aqueous emulsion of a polymer having a Tg of from -10 ° C. to 50 ° C. , wherein the polymer comprises in the polymerized form at least one ethylenically unsaturated monomer, where based on the total weight of all ethylenically unsaturated monomers in the polymer, from O to 5 weight. % of the monomers are monomers of α, β-ethylenically unsaturated aliphatic carboxylic acid; c) a polyimine having a number average molecular weight of from 250 to 2000; and c) a volatile base, where the composition has a pH of from 8 to 11, and where the amounts of components (c) and (c) are such that the pigment-containing composition obtained from the composition according to ASTM D 711-84 has a film drying time to disappearance of traces of 20 minutes or less. 14. Композиция по п. 13, отличающаяся тем, что количество полиимина составляет от 0,2 до 5 вес. частей, количество летучего основания составляет от 0,2 до 5 вес.частей и количества компонентов (в) и (с) представлены в расчете на 100 вес. частей компонента (а), при этом количества компонентов (а), (в) и (с) выражены в расчете на вес сухих материалов в этих компонентах. 14. The composition according to p. 13, characterized in that the amount of polyimine is from 0.2 to 5 weight. parts, the amount of volatile base is from 0.2 to 5 parts by weight and the amounts of components (c) and (c) are presented per 100 weight. parts of component (a), while the amounts of components (a), (c) and (c) are expressed based on the weight of dry materials in these components.
RU97113493/04A 1995-01-18 1996-01-18 Fast-hardening aqueous composition for coating, and paint RU2158744C2 (en)

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US37532595A 1995-01-18 1995-01-18
US08/375,325 1995-01-18

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EP (1) EP0804514B1 (en)
JP (1) JPH10512611A (en)
KR (1) KR19987001476A (en)
CN (1) CN1132886C (en)
AR (1) AR000747A1 (en)
AT (1) ATE176919T1 (en)
AU (1) AU693002B2 (en)
BR (1) BR9606771A (en)
CA (1) CA2210807A1 (en)
CZ (1) CZ223497A3 (en)
DE (1) DE69601572T2 (en)
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FI (1) FI119937B (en)
MX (1) MX198306B (en)
NZ (1) NZ302505A (en)
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