RU96110768A - METHOD OF OBTAINING 1-ETHYL-2-PHENYL-ALYUMYCLOPROPANE - Google Patents

METHOD OF OBTAINING 1-ETHYL-2-PHENYL-ALYUMYCLOPROPANE

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Publication number
RU96110768A
RU96110768A RU96110768/04A RU96110768A RU96110768A RU 96110768 A RU96110768 A RU 96110768A RU 96110768/04 A RU96110768/04 A RU 96110768/04A RU 96110768 A RU96110768 A RU 96110768A RU 96110768 A RU96110768 A RU 96110768A
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RU
Russia
Prior art keywords
ethyl
obtaining
alyumyclopropane
phenyl
styrene
Prior art date
Application number
RU96110768/04A
Other languages
Russian (ru)
Other versions
RU2152395C1 (en
Inventor
У.М. Джемилев
А.Г. Ибрагимов
Р.М. Султанов
Л.О. Хафизова
Л.М. Халилов
С.В. Русаков
Original Assignee
Институт нефтехимии и катализа с опытным заводом АН РБ
Filing date
Publication date
Application filed by Институт нефтехимии и катализа с опытным заводом АН РБ filed Critical Институт нефтехимии и катализа с опытным заводом АН РБ
Priority to RU96110768A priority Critical patent/RU2152395C1/en
Priority claimed from RU96110768A external-priority patent/RU2152395C1/en
Publication of RU96110768A publication Critical patent/RU96110768A/en
Application granted granted Critical
Publication of RU2152395C1 publication Critical patent/RU2152395C1/en

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Claims (1)

Способ получения 1-этил-2-фенилалюмациклопропана, отличающийся тем, что стирол
Figure 00000001
взаимодействует с алюминийдихлоридом Et-AlCl2 и металлическим магнием в мольном соотношении
Figure 00000002

в присутствии двухкомпонентного катализатора, состоящего из двухлористого кобальта (CoCl2) в количестве 3 - 5 мол.% по отношению к стиролу и трифенилфосфина (Ph3P) в мольном соотношении 1 : (1 oC 3), реакцию проводят в атмосфере аргона при нормальных условиях в среде тетрагидрофурана в течение 8 - 12 ч.The method of obtaining 1-ethyl-2-phenylalumocyclopropane, characterized in that styrene
Figure 00000001
interacts with aluminum dichloride Et-AlCl 2 and metallic magnesium in a molar ratio
Figure 00000002

in the presence of a two-component catalyst consisting of cobalt dichloride (CoCl 2 ) in an amount of 3 to 5 mol.% relative to styrene and triphenylphosphine (Ph 3 P) in a molar ratio of 1: (1 o C 3), the reaction is carried out in argon atmosphere at normal conditions in tetrahydrofuran medium for 8 to 12 hours.
RU96110768A 1996-05-28 1996-05-28 Method of synthesis of 1-ethyl-2-phenylalumacyclopropane RU2152395C1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
RU96110768A RU2152395C1 (en) 1996-05-28 1996-05-28 Method of synthesis of 1-ethyl-2-phenylalumacyclopropane

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
RU96110768A RU2152395C1 (en) 1996-05-28 1996-05-28 Method of synthesis of 1-ethyl-2-phenylalumacyclopropane

Publications (2)

Publication Number Publication Date
RU96110768A true RU96110768A (en) 1998-08-20
RU2152395C1 RU2152395C1 (en) 2000-07-10

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Country Status (1)

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RU (1) RU2152395C1 (en)

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