RU2755115C2 - Пригодное для термообработки изделие, имеющее покрытия на противоположных сторонах стеклянной подложки - Google Patents
Пригодное для термообработки изделие, имеющее покрытия на противоположных сторонах стеклянной подложки Download PDFInfo
- Publication number
- RU2755115C2 RU2755115C2 RU2019127306A RU2019127306A RU2755115C2 RU 2755115 C2 RU2755115 C2 RU 2755115C2 RU 2019127306 A RU2019127306 A RU 2019127306A RU 2019127306 A RU2019127306 A RU 2019127306A RU 2755115 C2 RU2755115 C2 RU 2755115C2
- Authority
- RU
- Russia
- Prior art keywords
- coating
- glass substrate
- dielectric layer
- transparent dielectric
- refractive index
- Prior art date
Links
- 238000000576 coating method Methods 0.000 title claims abstract description 485
- 239000011521 glass Substances 0.000 title claims abstract description 227
- 238000010438 heat treatment Methods 0.000 title claims abstract description 199
- 239000000758 substrate Substances 0.000 title claims abstract description 188
- 239000011248 coating agent Substances 0.000 claims abstract description 353
- 238000000034 method Methods 0.000 claims abstract description 22
- 238000004519 manufacturing process Methods 0.000 claims abstract description 4
- 229910052814 silicon oxide Inorganic materials 0.000 claims description 71
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 70
- 230000003667 anti-reflective effect Effects 0.000 claims description 48
- 239000010955 niobium Substances 0.000 claims description 28
- 239000010936 titanium Substances 0.000 claims description 25
- 238000002834 transmittance Methods 0.000 claims description 23
- 238000010791 quenching Methods 0.000 claims description 14
- 230000000171 quenching effect Effects 0.000 claims description 14
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 13
- 229910000484 niobium oxide Inorganic materials 0.000 claims description 10
- URLJKFSTXLNXLG-UHFFFAOYSA-N niobium(5+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Nb+5].[Nb+5] URLJKFSTXLNXLG-UHFFFAOYSA-N 0.000 claims description 10
- 229910052710 silicon Inorganic materials 0.000 claims description 9
- 229910052758 niobium Inorganic materials 0.000 claims description 5
- 229910052726 zirconium Inorganic materials 0.000 claims description 5
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 3
- 229910052709 silver Inorganic materials 0.000 claims description 3
- 239000004332 silver Substances 0.000 claims description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 2
- 239000000126 substance Substances 0.000 abstract description 5
- 239000010410 layer Substances 0.000 description 190
- 230000007935 neutral effect Effects 0.000 description 46
- 230000003287 optical effect Effects 0.000 description 27
- 239000000463 material Substances 0.000 description 22
- 230000000052 comparative effect Effects 0.000 description 21
- 229910004298 SiO 2 Inorganic materials 0.000 description 18
- 238000005452 bending Methods 0.000 description 11
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 10
- 229910010413 TiO 2 Inorganic materials 0.000 description 8
- 239000003086 colorant Substances 0.000 description 5
- 238000002845 discoloration Methods 0.000 description 5
- 230000001186 cumulative effect Effects 0.000 description 4
- 239000003989 dielectric material Substances 0.000 description 4
- QUPMNPUBXDQPQU-UHFFFAOYSA-N [Nb].[Si]=O Chemical compound [Nb].[Si]=O QUPMNPUBXDQPQU-UHFFFAOYSA-N 0.000 description 3
- 229910052719 titanium Inorganic materials 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 239000011247 coating layer Substances 0.000 description 2
- 238000006073 displacement reaction Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000004544 sputter deposition Methods 0.000 description 2
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 2
- AZUYLZMQTIKGSC-UHFFFAOYSA-N 1-[6-[4-(5-chloro-6-methyl-1H-indazol-4-yl)-5-methyl-3-(1-methylindazol-5-yl)pyrazol-1-yl]-2-azaspiro[3.3]heptan-2-yl]prop-2-en-1-one Chemical compound ClC=1C(=C2C=NNC2=CC=1C)C=1C(=NN(C=1C)C1CC2(CN(C2)C(C=C)=O)C1)C=1C=C2C=NN(C2=CC=1)C AZUYLZMQTIKGSC-UHFFFAOYSA-N 0.000 description 1
- 229910000906 Bronze Inorganic materials 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 229910006501 ZrSiO Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000010974 bronze Substances 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 description 1
- 239000002019 doping agent Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- HEHINIICWNIGNO-UHFFFAOYSA-N oxosilicon;titanium Chemical compound [Ti].[Si]=O HEHINIICWNIGNO-UHFFFAOYSA-N 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B27/00—Tempering or quenching glass products
- C03B27/012—Tempering or quenching glass products by heat treatment, e.g. for crystallisation; Heat treatment of glass products before tempering by cooling
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/3411—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of inorganic materials
- C03C17/3417—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of inorganic materials all coatings being oxide coatings
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/10—Optical coatings produced by application to, or surface treatment of, optical elements
- G02B1/11—Anti-reflection coatings
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/20—Filters
- G02B5/208—Filters for use with infrared or ultraviolet radiation, e.g. for separating visible light from infrared and/or ultraviolet radiation
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/20—Materials for coating a single layer on glass
- C03C2217/21—Oxides
- C03C2217/212—TiO2
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/20—Materials for coating a single layer on glass
- C03C2217/21—Oxides
- C03C2217/218—V2O5, Nb2O5, Ta2O5
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/20—Materials for coating a single layer on glass
- C03C2217/21—Oxides
- C03C2217/22—ZrO2
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/70—Properties of coatings
- C03C2217/73—Anti-reflective coatings with specific characteristics
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/10—Deposition methods
- C03C2218/15—Deposition methods from the vapour phase
- C03C2218/154—Deposition methods from the vapour phase by sputtering
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/30—Aspects of methods for coating glass not covered above
- C03C2218/365—Coating different sides of a glass substrate
Landscapes
- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Life Sciences & Earth Sciences (AREA)
- Optics & Photonics (AREA)
- General Physics & Mathematics (AREA)
- Toxicology (AREA)
- Health & Medical Sciences (AREA)
- Thermal Sciences (AREA)
- Surface Treatment Of Glass (AREA)
- Laminated Bodies (AREA)
- Re-Forming, After-Treatment, Cutting And Transporting Of Glass Products (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US15/422,681 | 2017-02-02 | ||
| US15/422,681 US11112538B2 (en) | 2017-02-02 | 2017-02-02 | Heat treatable coated article having coatings on opposite sides of glass substrate |
| PCT/US2018/016338 WO2018144666A1 (en) | 2017-02-02 | 2018-02-01 | Heat treatable coated article having coatings on opposite sides of glass substrate |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| RU2019127306A RU2019127306A (ru) | 2021-03-02 |
| RU2019127306A3 RU2019127306A3 (enExample) | 2021-04-15 |
| RU2755115C2 true RU2755115C2 (ru) | 2021-09-13 |
Family
ID=61226671
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2019127306A RU2755115C2 (ru) | 2017-02-02 | 2018-02-01 | Пригодное для термообработки изделие, имеющее покрытия на противоположных сторонах стеклянной подложки |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US11112538B2 (enExample) |
| EP (1) | EP3577085B1 (enExample) |
| JP (1) | JP7098637B2 (enExample) |
| KR (1) | KR102563122B1 (enExample) |
| CN (1) | CN110461793B (enExample) |
| MX (1) | MX2019009161A (enExample) |
| MY (1) | MY194544A (enExample) |
| RU (1) | RU2755115C2 (enExample) |
| WO (1) | WO2018144666A1 (enExample) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3759530A1 (en) * | 2018-03-02 | 2021-01-06 | Corning Incorporated | Anti-reflective coatings and articles and methods of forming the same |
| DE102018116993B4 (de) * | 2018-07-13 | 2022-06-02 | Schott Ag | Optische Komponente mit kratzresistenter Anti-Reflexionsbeschichtung und Verfahren zu deren Herstellung |
| EP4126779B1 (en) * | 2020-04-02 | 2025-10-15 | AGC Glass Europe | Coated substrates |
| WO2022229023A1 (en) * | 2021-04-28 | 2022-11-03 | Agc Glass Europe | Greenhouse glass for reduction of overheating during the hot seasons |
| JPWO2023095760A1 (enExample) * | 2021-11-26 | 2023-06-01 | ||
| US12422593B2 (en) | 2022-02-17 | 2025-09-23 | Guardian Glass, LLC | Heat treatable coated article having antireflective coating(s) on substrate |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20060115654A1 (en) * | 2004-11-29 | 2006-06-01 | Guardian Industries Corp | Coated article with color suppression coating including flame pyrolysis deposited layer(s) |
| US20060165963A1 (en) * | 2002-07-03 | 2006-07-27 | Saint-Gobain Glass France | Transparent substrate comprising antiglare coating |
| US20110157703A1 (en) * | 2010-09-03 | 2011-06-30 | Guardian Industries Corp. | Temperable three layer antireflective coating, coated article including temperable three layer antireflective coating, and/or method of making the same |
| RU2439009C2 (ru) * | 2007-06-13 | 2012-01-10 | Ппг Индастриз Огайо, Инк. | Смотровое окно устройств |
| US20130149473A1 (en) * | 2011-12-13 | 2013-06-13 | Marcus Frank | Insulating glass units with low-e and antireflective coatings, and/or methods of making the same |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6514620B1 (en) | 1999-12-06 | 2003-02-04 | Guardian Industries Corp. | Matchable low-E I G units and laminates and methods of making same |
| US6524714B1 (en) * | 2001-05-03 | 2003-02-25 | Guardian Industries Corp. | Heat treatable coated articles with metal nitride layer and methods of making same |
| US7588829B2 (en) | 2002-05-31 | 2009-09-15 | Ppg Industries Ohio, Inc. | Article having an aesthetic coating |
| US6689475B1 (en) | 2002-11-20 | 2004-02-10 | Guardian Industries Corp. | Heat treatable coated articles with boride layer of titanium and/or zirconium and methods of making same |
| FR2858816B1 (fr) * | 2003-08-13 | 2006-11-17 | Saint Gobain | Substrat transparent comportant un revetement antireflet |
| DE102006024524A1 (de) * | 2006-05-23 | 2007-12-06 | Von Ardenne Anlagentechnik Gmbh | Infrarotstrahlung reflektierendes, transparentes Schichtsystem |
| CN101553926B (zh) * | 2007-01-05 | 2011-07-13 | 日本电气硝子株式会社 | 固体成像元件用覆盖玻璃及其制造方法 |
| JP2011168477A (ja) | 2010-01-22 | 2011-09-01 | Nippon Electric Glass Co Ltd | 反射防止膜付き防火保護板ガラス、反射防止膜付き防火保護合わせガラス、および特定防火設備 |
| US9796619B2 (en) * | 2010-09-03 | 2017-10-24 | Guardian Glass, LLC | Temperable three layer antirefrlective coating, coated article including temperable three layer antirefrlective coating, and/or method of making the same |
| US8668990B2 (en) | 2011-01-27 | 2014-03-11 | Guardian Industries Corp. | Heat treatable four layer anti-reflection coating |
| US9221713B2 (en) | 2011-12-21 | 2015-12-29 | Centre Luxembourgeois De Recherches Pour Le Verre Et La Ceramique S.A. (C.R.V.C.) | Coated article with low-E coating having barrier layer system(s) including multiple dielectric layers, and/or methods of making the same |
| PL3013763T3 (pl) * | 2013-06-27 | 2020-08-24 | Agc Glass Europe | Oszklenie przeciwsłoneczne |
| EP3085673B1 (en) * | 2013-12-16 | 2019-05-08 | AGC Inc. | Glass with anti-reflection film and method for manufacturing same |
| EP2886205A1 (en) | 2013-12-19 | 2015-06-24 | Institute of Solid State Physics, University of Latvia | Method for antireflective coating protection with organosilanes |
| US9650290B2 (en) | 2014-05-27 | 2017-05-16 | Centre Luxembourgeois De Recherches Pour Le Verre Et La Ceramique (C.R.V.C.) Sarl | IG window unit for preventing bird collisions |
| WO2017094867A1 (ja) | 2015-12-02 | 2017-06-08 | 旭硝子株式会社 | 波長選択透過性ガラス物品 |
| JP6657872B2 (ja) * | 2015-12-03 | 2020-03-04 | Agc株式会社 | 反射防止膜付きガラス板 |
-
2017
- 2017-02-02 US US15/422,681 patent/US11112538B2/en active Active
-
2018
- 2018-02-01 KR KR1020197024573A patent/KR102563122B1/ko active Active
- 2018-02-01 EP EP18705530.6A patent/EP3577085B1/en active Active
- 2018-02-01 JP JP2019541760A patent/JP7098637B2/ja active Active
- 2018-02-01 CN CN201880010032.6A patent/CN110461793B/zh active Active
- 2018-02-01 WO PCT/US2018/016338 patent/WO2018144666A1/en not_active Ceased
- 2018-02-01 RU RU2019127306A patent/RU2755115C2/ru active
- 2018-02-01 MY MYPI2019004003A patent/MY194544A/en unknown
- 2018-02-01 MX MX2019009161A patent/MX2019009161A/es unknown
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20060165963A1 (en) * | 2002-07-03 | 2006-07-27 | Saint-Gobain Glass France | Transparent substrate comprising antiglare coating |
| US20060115654A1 (en) * | 2004-11-29 | 2006-06-01 | Guardian Industries Corp | Coated article with color suppression coating including flame pyrolysis deposited layer(s) |
| RU2439009C2 (ru) * | 2007-06-13 | 2012-01-10 | Ппг Индастриз Огайо, Инк. | Смотровое окно устройств |
| US20110157703A1 (en) * | 2010-09-03 | 2011-06-30 | Guardian Industries Corp. | Temperable three layer antireflective coating, coated article including temperable three layer antireflective coating, and/or method of making the same |
| US20130149473A1 (en) * | 2011-12-13 | 2013-06-13 | Marcus Frank | Insulating glass units with low-e and antireflective coatings, and/or methods of making the same |
Also Published As
| Publication number | Publication date |
|---|---|
| CN110461793A (zh) | 2019-11-15 |
| JP7098637B2 (ja) | 2022-07-11 |
| WO2018144666A1 (en) | 2018-08-09 |
| KR102563122B1 (ko) | 2023-08-04 |
| RU2019127306A3 (enExample) | 2021-04-15 |
| US11112538B2 (en) | 2021-09-07 |
| EP3577085A1 (en) | 2019-12-11 |
| KR20190126781A (ko) | 2019-11-12 |
| MX2019009161A (es) | 2019-12-09 |
| BR112019016002A2 (pt) | 2020-03-31 |
| RU2019127306A (ru) | 2021-03-02 |
| US20180217296A1 (en) | 2018-08-02 |
| MY194544A (en) | 2022-11-30 |
| EP3577085B1 (en) | 2024-06-05 |
| JP2020511380A (ja) | 2020-04-16 |
| CN110461793B (zh) | 2022-07-22 |
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