RU2385002C2 - Insecticide compositions from thiacloprid and pyrethroids - Google Patents

Abstract

FIELD: agriculture.

SUBSTANCE: substances are described to fight insects, which contain thiacloprid and one of further listed compounds in the ratio that provides for synergism effect: acrinatrin, alpha-cypermethrin, betaciflutrin, cyhalothrin, cypermethrin, deltametrin, lambda-cyhalothrin, permethrin, zeta-cypermethrin, ciflutrin, biphenthrin, gamma-cyhalothrin.

EFFECT: agents have very good insecticide properties.

1 cl, 8 tbl, 8 ex

Description

The present invention relates to new compositions of active substances, which consist, on the one hand, of thiacloprid and, on the other hand, of other known insecticidal active substances and which are very effective in controlling animal pests.

It is already known that thiacloprid formula

exhibits insecticidal properties (European patent No. 0235725). In addition, it is known that pyrethroids have insecticidal properties (international patent application No. 93-22297, No. 93-10083, German patent application No. A 2641343, international patent application No. A 347488, No. A-210487, US patent No. 3264177 and international patent application No. A 234045). However, the action of these substances does not always meet the requirements.

It was found that thiacloprid and not less than one pyrethroid mixtures have very good insecticidal properties, preferably mixtures containing thiacloprid and:

1. Acrinatrin

,

,

known by the application for European patent No. A-048186, and / or

2. Alpha cypermethrin

,

,

known for European patent application No. A-067461, and / or

3. Beta cyfluthrin

,

,

known by the application for European patent No. A-206149, and / or

4. Cigalotrin

,

,

known from the patent application of Germany No. A-2802962, and / or

5. Cypermethrin

,

,

known for the patent application of Germany No. 2326077, and / or

6. Deltamethrin

,

,

known for the patent application of Germany No. 2326077, and / or

7. Esfenvalerate

,

,

known for the patent application of Germany No. A-2737297, and / or

8. Etofenprox

,

,

known for the patent application of Germany No. A-3117510, and / or

9. Fenpropatrin

,

,

known from the patent application of Germany No. A-2231312, and / or

10. Fenvalerate

,

,

known from the patent application of Germany No. A-2335347, and / or

11. Flucytrinate

,

,

known from the patent application of Germany No. A-2757066, and / or

12. Lambda-cygalotrin

,

,

known for European patent application No. A-106469, and / or

13. Permethrin

,

,

known from the patent application of Germany No. A-2326077, and / or

14. Taufluvalinate

,

,

known by the application for European patent No. A-038617, and / or

15. Thralomethrin

,

,

known from the patent application of Germany No. A-2742546, and / or

16. Zeta cypermethrin

,

,

known for the application for European patent No. A-026542, and / or

17. Tsiflutrin

,

,

known from the patent application of Germany No. A-2709264, and / or

18. Bifentrin

,

,

known by European patent application No. A-049977, and / or

19. Cycloprotrin

,

,

known from the patent application of Germany No. A-2653189, and / or

20. Eflusilanate

,

,

known for the patent application of Germany No. A-3604781, and / or

21. Fubfenprox

,

,

known from the patent application of Germany No. A-3708231, and / or

22. Pyrethrin

,

,

known from The Pesticide manual, 1997, 11th Edition, p.1056, and / or

23. Resmetrin

,

,

known from British Patent Application No. A-1168797, and / or

24. Gamma-cygalotrin

,

,

known by The Pesticide Manual, 13th edition, 2003, article 197 on page 232, The British Crop Protection Council.

Unexpectedly, it turned out that the action, in particular the insecticidal effect, of the compositions of the active substances according to the invention significantly exceeds the total effect of the individual active substances. There is a real synergy effect, and not just the addition of activity, which could not have been foreseen.

The active substance compositions according to the invention contain, along with thiacloprid, at least one active substance from compounds 1 to 24. In addition, the active substance compositions may also contain other components with fungicidal, acaricidal or insecticidal activity in a mixture.

When the active substances are contained in the compositions of the active substances in accordance with the invention in certain mass ratios, the synergistic effect is most pronounced. However, the mass ratios of active substances in compositions of active substances can vary within a relatively wide range. In the General case, the compositions of the active substances corresponding to the invention contain thiacloprid and another component of the mixture in the preferred and particularly preferred mass ratios given in the table below. Ratios in mixtures are based on mass ratios. The ratio should be understood as the ratio of thiacloprid to another component of the mixture.

The other component of the mixture Preferred Mass Ratio Particularly preferred mass ratio Acrinatrin 125: 1 to 1:25 from 1: 1 to 1:25 Alpha cypermethrin 125: 1 to 1:25 from 1: 1 to 1:25 Beta-cyfluthrin 125: 1 to 1:25 from 1: 1 to 1:25 Cigalotrin 125: 1 to 1:25 from 1: 1 to 1:25 Cypermethrin 125: 1 to 1:25 from 1: 1 to 1:25 Deltamethrin 125: 1 to 1:25 from 1: 1 to 1:25 Esfenvalerate 125: 1 to 1:25 from 1: 1 to 1:25 Etofenprox 125: 1 to 1:25 from 1: 1 to 1:25 Fenpropatrine 125: 1 to 1:25 from 1: 1 to 1:25 Fenvalerate 125: 1 to 1:25 from 1: 1 to 1:25 Flucytrinate 125: 1 to 1:25 from 1: 1 to 1:25 Lambda cygalothrin 125: 1 to 1:25 from 1: 1 to 1:25 Permethrin 125: 1 to 1:25 from 1: 1 to 1:25 Tau fluvalinate 125: 1 to 1:25 from 1: 1 to 1:25 Tralomethrin 125: 1 to 1:25 from 1: 1 to 1:25 Zeta cypermethrin 125: 1 to 1:25 from 1: 1 to 1:25 Tsiflutrin 125: 1 to 1:25 from 1: 1 to 1:25 Bifenthrin 125: 1 to 1:25 from 1: 1 to 1:25 Cycloprotrin 125: 1 to 1:25 from 1: 1 to 1:25 Eflusilanate 125: 1 to 1:25 from 1: 1 to 1:25 Fubfenprox 125: 1 to 1:25 from 1: 1 to 1:25 Pyrethrin 125: 1 to 1:25 from 1: 1 to 1:25 Resmetrin 125: 1 to 1:25 from 1: 1 to 1:25 Gamma cygalothrin 125: 1 to 1:25 from 1: 1 to 1:25

Compositions of active substances corresponding to the invention with good tolerance by plants, reduced toxicity to warm-blooded and favorable environmental conditions are suitable for protecting plants and plant organs, for increasing yields, improving the quality of harvested crops and for controlling animal pests, in particular insects, arachnids and nematodes that are found in agriculture, forestry, horticulture and recreation, in the field of stockpiling and mother protection fishing and which are of importance in the field of hygienic measures. In a preferred case, they can be used as plant protection products. They are active in relation to species with normal sensitivity, as well as to resistant species, as well as at all and at each individual stage of development. The pests mentioned above include the following representatives.

From the order Isopoda, for example, Oniscus aselus, Armadillidium vulgare, Porcellio scaber.

From the order of Diplopoda, for example Blaniulus guttulatus.

From the order Chilopoda, for example, Qeophilus carpophagus, Scutigera spp.

From the Symphyla order, for example Scutigererella immaculata.

From the Thysanura order, for example, Lepisma saccharina.

From the order Collembola, for example Onychiurus armatus.

From the order Orthoptera, for example, Acheta domesticus, Gryllotalpa spp., Locusta migratoria migratorioides, Melanoplus spp., Schistocerca gregaria.

From the order Blattaria, for example Blatta orientalis, Periplaneta americana, Leucophaea maderae, Blattella germanica.

From the order Dermaptera, for example Forficula auricularia.

From the order Isoptera, for example Reticulitermes spp.

From the order Phthiraptera, e.g. Pediculus humanus corporis, Haematopinus spp., Linognathus spp., Trichodectes spp., Damalinia spp.

From the order Thysanoptera, for example, Hercinothrips femoralis, Thrips tabaci, Thrips palmi, Frankliniella accidentalis.

From the order Heteroptera, e.g. Eurygaster spp., Dysdercus intermedius, Piesma quadrata, Cimex lectularius, Rhodnius prolixus, Triatoma spp.

From the order Homoptera, for example, Aleurodes brassicae, Bemisia tabaci, Trialeurodes vaporariorum, Aphis gossypii, Brevicoryne brassicae, Cryptomyzus ribis, Aphis fabae, Aphis pomi, Eriosoma lanigerum, Hyalopterus arundinephphipploephius phylloephius phylloemis phylloephius phylloemus phylloephius phylloemis phylloidis humuli, Rhopalosiphum padi, Empoasca spp., Euscelis bilobatus, Nephotettix cincticeps, Lecanium corni, Saissetia oleae, Laodelphax striatellus, Nilaparvata lugens, Aonidiella aurantii, Aspidiotus hederacus sppud.

From the order Lepidoptera, for example, Pectinophora gossypiella, Bupalus piniarius, Cheimatobia brumata, Lithocolletis blancardella, Hyponomeuta padella, Plutella xylostella, Malacosoma neustria, Euproctis chrysorrhoea, Lymantria srixpppppppppp, Bupp. , Earias insulana, Heliothis spp., Mamestra brassicae, Panolis flammea, Spodoptera spp., Trichoplusia ni, Carpocapsa pomonella, Pieris spp., Chilo spp., Pyrausta nubilalis, Epellia kuehniella, Gellella phella pella tella pella Cacoecia podana, Capua reticulana, Choristoneura fumiferana, Clysia ambiguella, Homona magnanima, Tortrix viridana, Cnaphalocerus spp., Oulema oryzae.

From the order Coleoptera, for example, Anobium punctatum, Rhizopertha dominica, Bruchidius obtectus, Acanthoscelides obtectus, Hylotrupes bajulus, Agelastica aini, Leptinotarsa decemlineata, Phaedon cochleariae, Diabrotica sphispppsppsa psyplsompsyppsyppsyppsa psyppsa psyppsyppsa psyppsyppsyppsyppsyppsyppsyppsa pspi spi psyppsa psyppsa psyppsa psyppsa psyppsa psyppsa psypprysoppsa psypprypp Sitophilus spp., Otiorrhynchus sulcatus, Cosmopolites sordidus, Ceuthorrhynchus assimilis, Hypera postica, Dermestes spp., Trogoderma spp., Anthrenus spp., Attagenus spp., Lyctus spp., Meligethes aeneus, Ptolus plibus, Poltolus pylinus, Poltibus pylibius spp., Tenebrio molitor, Agriotes spp., Conoderus spp., Melolontha melolontha, Amphimallon solstitialis, Costelytra zealandica, Lissorhoptrus oryzophilus.

From the Hymenoptera order, for example, Diprion spp., Hoplocampa spp., Lasius spp., Monomorium pharaonis, Vespa spp.

From the order Diptera, e.g. Aedes spp., Anopheles spp., Culex spp., Drosophila melanogaster, Musca spp., Fannia spp., Calliphora erythrocephala, Lucilia spp., Chrysomyia spp., Cuterebra spp., Gastrophilus sppa., Hypp. , Stomoxys spp., Oestrus spp., Hypoderma spp., Tabanus spp., Tannia spp., Bibio hortulanus, Oscinella frit, Phorbia spp., Pegomyia hyoscyami, Ceratitis capitata, Dacus oleae, Tipula paludosa, Hylemyiomypp.

From the order Siphonaptera, for example Xenopsylla cheopis, Ceratophyllus spp.

From the Arachnida class, for example, Scorpio maurus, Latrodectus mactans, Acarus siro, Argas spp., Omithodoros spp., Dermanyssus gallinae, Eriophyes ribis, Phyllocoptruta oleivora, Boophilus spp., Rhipicephalus sppma., Mply. Ambly. , Psoroptes spp., Chorioptes spp., Sarcoptes spp., Tarsonemus spp., Bryobia praetiosa, Panonychus spp., Tetranychus spp., Hemitarsonemus spp., Brevipalpus spp.

Nematode parasites on plants include, for example, Pratylenchus spp., Radopholus similis, Ditylenchus dipsaci, Tyienchulus semipenetrans, Heterodera spp., Globodera spp., Meloidogyne spp., Aphelenchoides spp., Longidorus spp., Xipp. Bursaphelenchus spp.

In accordance with the invention, all plants and parts of plants can be treated. Moreover, the concept of plants refers to all plants and plant populations, for example, to desirable and undesirable wild plants or to cultivated plants (including naturally occurring crop plants). Among cultivated plants, cereals (wheat, oats, barley, rye, rice), corn, soybeans, potatoes, cotton, tobacco, rape, and fruit crops (with fruits such as apples, pears, citrus fruits, and grapes) should be mentioned. Cultivated plants can be plants that are obtained by conventional breeding and optimizing techniques, or that are obtained by biotechnological and genetic engineering methods, or as a result of a combination of these methods, including the production of transgenic plants and plants protected by rights to protect the variety or not being protected. The concept of plant parts should be applied to all above-ground and underground parts and organs of plants, for example, to shoot, leaf, flower, and root, for example, leaves, needles, stems, trunks, flowers, fruiting bodies, fruits, and seeds as well as roots, tubers and rhizomes. Parts of plants also include crops, as well as vegetative and generative planting material, such as cuttings, tubers, rhizomes, branches and seeds.

The treatment of plants and plant parts according to the invention with compositions of active substances is carried out directly or by exposure to their environment, habitat or storage area using conventional processing methods, for example by dipping, spraying, evaporation, aerosol exposure, spraying, brushing, injection, and in the case of planting material, in particular seeds, also by applying a single or multilayer coating.

Compositions of active substances can be converted into such conventional formulations as solutions, emulsions, wettable powders, suspensions, dusts, dusting agents, pastes, soluble powders, granules, aerosols, suspension-emulsion concentrates, natural or artificial materials impregnated with the active substances origin, as well as microencapsulated forms in polymeric substances.

These formulations can be prepared by known methods, for example by mixing the active substances with diluents, i.e. with liquid solvents and / or with solid substances carriers using, as appropriate, surface-active agents, i.e. emulsifying and / or dispersing agents, and / or blowing agents.

If water is used as a diluent, for example, organic solvents can also be used as solubilizers. Aromatic compounds such as xylene, toluene or alkylnaphthalenes, such as chlorinated aromatic compounds and chlorinated aliphatic hydrocarbons such as chlorobenzenes, chloroethenes or methylene chloride, such aliphatic hydrocarbons as cyclohexane or paraffins, for example oil distillation products, can mainly serve as liquid solvents. mineral and vegetable oils, alcohols such as butanol or glycol, and their ethers and esters, such as ketones, such as acetone, methyl ethyl ketone, methyl isobutyl ketone or iklogeksanon, strongly polar solvents such as dimethylformamide and dimethyl sulphoxide, and also water.

As carrier solids, for example, ammonium salts and crushed rocks such as kaolin, alumina, talc, chalk, quartz, attapulgite, montmorillonite or infusor earth, and milled synthetic minerals such as finely divided silicic acid, alumina and silicates; as carrier substances for granular formulations, for example, crushed and fractionated natural minerals such as calcite, marble, pumice, sepiolite, dolomite, as well as synthetic granules based on inorganic and organic ground materials and granules from such organic materials, like sawdust, coconut shell, corn cobs and tobacco stalks; emulsifying and / or foaming agents can be, for example, nonionic and anionic emulsifiers such as polyethylene oxide esters of fatty acids, polyethylene oxide ethers of fatty alcohols, for example alkylaryl-polyglycol ethers, alkyl sulfonates, alkyl sulfates, arylsulfonates, as well as protein hydrolysates; dispersing agents may be, for example, lignin sulphite liquor and methyl cellulose.

In the formulations, adhesives such as carboxymethyl cellulose, natural and synthetic powdered, granular or latex polymers, for example gum arabic, polyvinyl alcohol, polyvinyl acetate, as well as natural phospholipids such as cephalins and lecithins, and synthetic phospholipids can be used. Other additives may include mineral and vegetable oils.

Dyes such as inorganic pigments such as iron oxide, titanium oxide, blue ferrocyanides, and organic dyes such as alizarin and metallophthalocyanine dyes, azo dyes, and trace elements such as salts of iron, manganese, boron, copper, cobalt, can be used. molybdenum and zinc.

The content of active substances in the preparative forms in the General case may be from 0.1 to 95 wt.%, In the preferred case, from 0.5 to 90 wt.%.

Compositions of active substances corresponding to the invention may be present in preparations for sale and in ready-to-use formulations prepared from these preparations in a mixture with other active substances such as insecticides, attractants, sterilizers, bactericides, acaricides, nematicides, fungicides, growth regulators or herbicides. Insecticides include, for example, phosphorus acid esters, carbamates, carboxylic acid esters, chlorinated hydrocarbons, phenylureas, substances produced by microorganisms, and others.

Particularly advantageous components of the mixtures are, for example, the following classes of active substances.

Fungicides

2-phenylphenol sulfate, 8-hydroxyquinoline, acibenzolar-S-methyl, aldimorph, amidoflumet, ampropilfos, ampropilfoskaly, andoprim, anilazine, azaconazole, azoxystrobin, benalaxyl, benodanil, benomyl, bentiavalikarbizopropil, benzamakril, benzamakril-isobutyl, bilanafos, binapacryl, biphenyl , bitertanol, blasticidin-S, bromukonazole, bupirimat, butiobate, butylamine, calcium polysulfide, capsimycin, captafol, captan, carbendazim, carboxin, carpropamide, carvone, quinomethionate, chlobentiazone, chlorphenazole, chloronebol, chloronol, chloronol, chloronol, chloronol iazofamide, cyflufenamide, cymoxanil, ciproconazole, cyprodinil, ciprofuram, dagger-G, debacarb, diclofluanide, dichlon, dichlorofen, diclocimet, diclomezine, dicloran, dietofenocarbiminofinimetol, dietofenocinazole dimenocinazole dimenocinazole dimenocinazole dimenocinazin dimenocinazin dimenocinazin dimer diphenylamine, dipirition, ditalimfos, dithianon, dodine, drazoksolon, edifenphos, epoxiconazole, ethaboxam, ethirimol, etridiazole, famoxadone, fenamidone, fenapanil, fenarimol, fenbuconazole, fenfuram, fenhexamid, fenitropan, fenoxanil, fenpiclonil, fenpropidin, fenp opimorph, ferbam, fluazinam, flubenzimine, fludioxonil, flumetover, flumorph, fluoromide, fluoxastrobin, flukinonazole, flurprimidol, fluzilazole, flusulfamide, flutolanil, flutetilfuryl-aluminum, fluethylfiluryl-aluminum, aluminum sulfate, aluminum sulfate, aluminum chloride guazatin, hexachlorobenzene, hexaconazole, gimexazole, imazalil, imibenconazole, iminoktadin triacetate, iminoktadinris (albesilate), iodocarb, ipconazole, iprobenfos, iprodione, iprovalicin, isovamycinocin, isovamycinocin, isovamycinocin, isovamycinocin, isovamycinocin, iromediocinocin, isovamycinocin, isovamycinocin, isuramiocinocin, isuramiocinocin, isuramiocinocin, isuramiocinocin, isovamycinocin, iromediocyanocin, iromediocyanocin, iromediocinocin, iromediocinocin, iromediocinocin, iromediocinocin, isovamycinocin, iromediocinocin, , mancozeb, maneb, meperimzone, mepanipyrim, mepronil, metalaxyl, metalaxyl-M, metconazole, metasulfocarb, metfuroxam, metiram, metominostrobin, metsulfovax, mildiomycin, micobutaniforumnuriforuminoformufinurofinuraminurinofinuraminurinoformu nifrobol, nirominoliprobenol, nikrominoformu nifrobenol, , oxadixyl, oxolinic acid, oxpoconazole, oxycarboxy, oxyfentin, paclobutrazole, pefurazoate, penconazole, pencicuron, fosdifen, phthalide, picoxystrobin, piperaline, polyoxin, polyoxorim, probenazole, prochloraz, propanozamid atrium, propiconazole, propineb, prokvinazid, prothioconazole, pyraclostrobin, pyrazophos, pyrifenox, pyrimethanil, pirokvilon, piroksifur, pyrrolnitrin, kvinkonazol, quinoxyfen, kvintotsen, simeconazole, spiroxamine, sulfur, tebuconazole, tecloftalam, teknazen, tettsiklatsis, tetraconazole, thiabendazole, titsiofen, tiflusamide, thiofanate methyl, thiram, thioximide, toclofos-methyl, tolylfluanide, triadimefon, triadimenol, triazbutyl, triazoxide, tricyclamide, tricyclazole, tridemorph, trifloxystrobin, triflumisole, triforin, trinitiazole in A, vinclozolin, cineb, ziram, zoxamide, (2S) -N- [2- [4 - [[3- (4-chlorophenyl) -2-propynyl] oxy] -3-methoxyphenyl] ethyl] -3-methyl -2 - [(methylsulfonyl) amino] butanamide, 1- (1-naphthalenyl) -1H-pyrrole-2,5-dione, 2,3,5,6-tetrachloro-4- (methylsulfonyl) pyridine, 2-amino -4-methyl-N-phenyl-5-thiosole-carboxamide, 2-chloro-N- (2,3-dihydro-1,1,3-trimethyl-1H-inden-4-yl) -3-pyridinecarboxamide, 3 , 4,5-trichloro-2,6-pyridinedicarbonitrile, actinovate, cis-1- (4-chlorophenyl) -2- (1H-1,2,4-triazol-1-yl) cycloheptanol, methyl ester 1- (2 , 3-dihydro-2,2-dimethyl-1H-inden-1-yl) -1H-imidazole-5-carboxylic acid, potassium hydrogen carbonate, N- (6-methoxy-3-pyridi nyl) -cyclopropanecarboxamide, N-butyl-8- (1,1-dimethylethyl) -1-oxaspiro [4.5] decan-3-amine, sodium tetratiocarbonate, as well as copper salts and such copper-containing preparations as Bordeaux mixture, copper hydroxide, copper naphthenate, copper oxychloride, copper sulfate, kufraneb, copper oxide, mankopper, oksinkopper.

Bactericides

Bronopol, dichlorophene, nitrapirine, nickel dimethyldithiocarbamate, casugamycin, octilinone, furancarboxylic acid, oxytetracycline, probenazole, streptomycin, teclofthalam, copper sulfate and other copper-based preparations.

Insecticides, Acaricides, Nematicides

1. Inhibitors of acetylcholinesterase.

1.1. Carbamates, for example, alanicarb, aldicarb, aldoxycarb, allixicarb, aminocarb, bendiocarb, benfuracarb, bufencarb, butacarb, butocarboxyme, butoxycarboxyme, carbaryl, carbofuran, carbosulfan, cloethocarbofarbocarbocarbam carbamide, dimethylcarbam , methiocarb, methomyl, metolcarb, oxamyl, pyrimicarb, promecarb, propoxur, thiodicarb, thiofanox, trimethacarb, HMS, xylylcarb; triazamates.

1.2. Organic derivatives of phosphorus acids, such as acephate, azamethiphos, azinphos (methyl or ethyl), bromophos ethyl, bromphenvinphos (methyl), butathiophos, caduzafos, carbofenothion, chloroethoxyphos, chlorphenvinphos, chlormephos, chlorpyrilethyl (-meth) coumaphos, cyanofenphos, cyanophos, chlorfenvinphos, demeton-S-methyl, demeton-S-methylsulfone, dialiphos, diazinon, dichlorofention, dichlorvos (DDVF), dicrothophos, dimethoate, dimethylvinphos, dioxabenzofosfof, etulfonfosfofof, diulfabenfosfofof, diofenfosfofof, diofenfosfofof, diofenfosfofof, diofabenfosfofof, diofenfosfofof, diofenfosfofof, etof , fenamifos, fenitrotion, fensulfotion, fenthion, flupirazofo , phonophos, formotion, phosmethylan, fostiazate, heptenophos, iodophenphos, iprobenfos, isazophos, isofenfos, isopropyl-O-salicylate, isoxathion, malathion, mekarbam, methacryphos, metamidophos, methonefonethos, mono-methonethos, mono-methonophosphate, medone methonethos, (-methyl or -ethyl), fentoate, forate, fosalon, phosphate, phosphamidone, phosphocarb, foxime, pyrimiphos (-methyl or-ethyl), profenofos, propaphos, propetamphos, prothiophos, protoate, pyraclofos, pyridafention, quinosulfate, pyridos , sulfotep, sulphrophos, tebupirimfos, temefos, terboufos, tetrachl rvinfos, tiometon, triazophos, triklorfon, vamidothion.

2. Modules of sodium channels (voltage-dependent sodium channel blockers).

2.1. Pyrethroids, for example

acrinatrin, allethrin, (d-cis-trans- or d-trans-), beta-cyfluthrin, bifentrin, bioallethrin, S-cyclopentyl isomer of bioallethrin, bioethanometrin, biopermetrin, bioresmetrin, chloaportrin, cis-cypermethrin, cis-resmetrin permethrin klotsitrin, cycloprothrin, cyfluthrin, cyhalothrin, cypermethrin (alpha-, beta-, theta-, zeta), cyphenothrin, deltamethrin, empenthrin (1R-isomer), esfenvalerate, etofenprox, fenfluthrin, fenpropathrin, fenpiritrin, fenvalerate, flubrotsitrinat, flucythrinate, flufenprox, flumetrin, fluvalinate, fubfenprox, gamma-cygalotrin, imipro rin, cadetrin, lambda-cygalotrin, metoflutrin, permethrin (cis-, trans-), phenotrin (1R-trans-isomer), pralletrin, proflutrin, protrifenbut, pyresmethrin, resmethrin, RU 15525, silafluofen, tau-fluvalinate, teflutrin, teflutrin tetramethrin (1R-isomer), tralomethrin, transfluthrin, ZXI 8901, pyrethrins (pyrethrum);

DDT.

2.2. Oxadiazines, e.g. indoxacarb.

3. Agonists / antagonists of acetylcholine receptors.

3.1. Chloronicotinyls, e.g.

acetamipride, clothianidin, dinotefuran, imidacloprid, nitenpyram, nithiazine, thiacloprid, thiamethoxam.

3.2. Nicotine, bensultap, cartap.

4. Modulators of acetylcholine receptors.

4.1. Spinosins, for example spinosad.

5. Antagonists of GABA-dependent chlorine channels.

5.1. Organochlorine cyclic compounds, e.g.

camfechlor, chlordane, endosulfan, gamma-hexachlorocyclohexane, hexachlorocyclohexane, heptachlor, lindane, methoxychlor.

5.2. Fiproles, for example

acetoprol, etiprol, fipronil, vanilliprol.

6. Activators of chlorine channels.

6.1. Mectins for example

avermectin, emamectin, emamectin-benzoate, ivermectin, milbemycin.

7. Juvenile hormone mimetics, for example

diophenolane, epofenonan, phenoxycarb, hydroprene, kinoprene, metoprene, pyriproxifene, triprene.

8. Agonists / disruptors of ecdysone.

8.1. Diacylhydrazines, e.g.

chromafenoside, halofenoside, methoxyphenoside, tebufenoside.

9. Inhibitors of chitin biosynthesis.

9.1. Benzoylureas, for example

bistrifluron, chlorofluazuron, diflubenzuron, fluazuron, flucycloxuron, flufenoxuron, hexaflumuron, lufenuron, novaluron, noviflumuron, penfluron, teflubenzuron, triflumuron.

9.2. Buprofetzin.

9.3. Cyromazine.

10. Inhibitors of oxidative phosphorylation, ATP biosynthesis breakers.

10.1. Diafentyuron.

10.2. Organotin compounds, for example, azocyclotin, cyhexatin, fenbutatin oxide.

11. Disconnectors of oxidative phosphorylation as a result of violation of the proton gradient.

11.1. Pyrroles, e.g. chlorfenapyr.

11.2. Dinitrophenols, e.g. binapacryl, dinobuton, dinocap, DNOC.

12. Inhibitors of electron transport in site I.

12.1. METI, e.g. phenazaquin, fenproximate, pyrimidiphene, pyridaben, tebufenpyrad, tolfenpyrad.

12.2. Hydramethylnon.

12.3. Dicofol.

13. Inhibitors of electron transport at site II.

Rotenone

14. Inhibitors of electron transport at site III.

Acequinocil, fluacripyrim.

15. Means of microbial origin, disrupting the membrane of the digestive tract.

Strains of Bacillus thuringiensis.

16. Inhibitors of biosynthesis of fats.

Tetronic acids, for example spirodiclofen, spiromesifen.

Tetric acids, for example

3- (2,5-dimethylphenyl) -8-methoxy-2-oxo-1-azaspiro [4.5] dec-3-en-4-yl-ethyl carbonate (formerly known as: carboxylic acid, 3- (2,5- dimethylphenyl) -8-methoxy-2-oxo-1-azaspiro [4.5] dec-3-en-4-yl-ethyl ether, CAS register. No. 382608-10-8) and carboxylic acid, cis-3- (2 , 5-dimethylphenyl) -8-methoxy-2-oxo-1-azazpiro [4.5] dec-3-en-4-yl-ethyl ether (CAS register. No. 203313-25-1).

17. Carboxamides, for example flonicamide.

18. Octopaminergic agonists, for example amitraz.

19. Inhibitors of magnesium-stimulated ATPase, for example propargite.

20. Preparations of the BDCA group, for example N2- [1,1-dimethyl-2- (methylsulfonyl) ethyl] -3-iodo-1N- [2-methyl-4- [1,2,2,2-tetrafluoro-1- (trifluoromethyl) ethyl] phenyl] -1,2-benzene-dicarboxamide (CAS register. No. 272451-65-7).

21. Analogues of nereistoxin, for example thiocyclamic acid oxalate, thiosultap sodium.

22. Biological products, hormones, or pheromones, for example, azadirachtin, Bacillus spec., Beauveria spec., Codlemon, Metarrhizium spec., Paecilomyces spec., Turringienzine, Verticillium spec.

23. Active substances with unknown or nonspecific mechanisms of action.

23.1. Fumigants, for example

aluminum phosphide, methyl bromide, sulfuryl fluoride.

23.2. Selective antifidants, e.g. cryolite, flonicamide, pimetrosine.

23.3. Tick growth inhibitors, e.g. clofentisine, ethoxazole, hexithiazox.

23.4. Amidoflumet, benklotiaz, benzoximate, bifenazate, bromopropylate, buprofetsin, chinomethionat, chlordimeform, chlorobenzilate, chloropicrin, klotiazoben, tsiklopren, ditsiklanil, fenoksakrim, fentrifanil, flubenzimine, flufenirim, flutenzin, gossiplur, hydramethylnon, yaponilur, metoxadiazone, petroleum, piperonyl butoxide, potassium oleate , pyridinyl, sulfuramide, tetradiphon, tetrasul, triaraten, verbutin, Verticillium lecanii,

WL-108477, WL-40027,

YI-5201, YI-5301, YI-5302,

XMC, Xylylcarb,

ZA-3274, zeta cypermethrin, zolaprofos, ZXI-8901,

compound 3-methyl-phenyl-propylcarbamate (tsumacid Z),

compound 3- (5-chloro-3-pyridinyl) -8- (2,2,2-trifluoroethyl) -8-azabicyclo- [3.2.1] octane-3-carbonitrile (CAS register. No. 185982-80-3) and the corresponding 3-endo-isomer (CAS register. No. 185984-60-5) (see, for example, applications for international patent No. 96/37494 and No. 98/25923).

as well as preparations that contain extracts from plants with insecticidal activity, nematodes, fungi or viruses.

The formation of mixtures with other well-known active substances such as herbicides, fertilizers, growth regulators, antidotes or special chemicals is also possible.

Compositions of active substances corresponding to the invention, when used as insecticides, can also be in commercial formulations and ready-to-use formulations prepared in these formulations in the form of mixtures with synergists. Synergists are compounds that increase the effectiveness of active substances, while the added synergist may not have its own activity.

Compositions of active substances corresponding to the invention, when used as insecticides, can also be present in commercial formulations and in ready-to-use formulations prepared from these preparative forms in the form of mixtures with stabilizers that, after application, prevent the decomposition of the active substance in the surrounding plant environment, on the surface of plant parts or in plant tissues.

The content of the active substance in ready-to-use formulations prepared from commercial formulations may vary widely. The concentration of the active substance in the ready-to-use formulations can range from 0.0000001 to 95% by weight of the active substance, preferably from 0.0001 to 1% by weight.

The use of ready-to-use formulations occurs in the usual ways that correspond to these formulations.

When used against pests that violate hygienic requirements, and against pests stocks, the active substance is characterized by excellent residual effect on wood and clay materials, as well as good resistance to alkali on lime bases.

As mentioned above, in accordance with the invention, it is possible to process all plants and their parts. In a preferred embodiment, wild-growing or obtained by such conventional biological breeding methods as crossing or fusion of protoplasts, plant species and plant varieties, as well as parts thereof, are to be processed. In yet another preferred embodiment, it is possible to process transgenic plants and plant varieties (genetically modified organisms) obtained by genetic engineering methods, which, if appropriate, can be combined with conventional techniques, as well as parts of plants.

The concept of “parts” or, respectively, “parts of plants” or “plant parts” was discussed above.

In a particularly preferred case, in accordance with the invention, plant varieties that are commercially available or are widely used are treated. When talking about plant varieties, they mean plants with new properties (“distinctive features”) that are grown both by conventional breeding methods, and by means of mutagenesis or techniques involving recombinant DNA. These may be varieties, biotypes and genotypes.

Depending on the type of plant or plant variety, its place of growth and growing conditions (soil, climate, growing season, top dressing), super-additive (“synergistic”) effects may also occur as a result of processing according to the invention. For example, the result of this may be reduced consumption rates and / or expansion of the activity spectrum, and / or increased action of the substances and means used in accordance with the invention, improved plant growth, improved resistance to elevated or reduced temperatures, improved resistance to lack of moisture or salt content in water and soil, improved flowering, easier harvesting, faster ripening, higher yields, improved quality and / or increased nutritional value of the products obtained, improved ix storage stability and / or processability of the products obtained, which exceed the effects expected.

In a preferred case, the transgenic (genetically engineered) plants or plant varieties that are processed according to the invention include all plants that were obtained as a result of genetic engineering modification of the genetic material, which gave these plants particularly outstanding valuable properties ("distinguishing features "), Examples of such properties are improved plant growth, improved resistance to high or low temperatures, improved resistance to under moisture content or salt content in water or soil, improved flowering, easier harvesting, faster ripening, higher yields, improved quality and / or nutritional value of the resulting products, improved storage stability and / or processability of the resulting products. Other properties that are emphasized are the increased resistance of plants to animal pests and microorganisms, for example to insects, ticks, phytopathogenic fungi, bacteria and / or viruses, as well as the increased resistance of plants to certain herbicidal active substances. As examples of transgenic plants, important cultural plants such as cereals (wheat, rice), corn, soybeans, potatoes, cotton, tobacco, rape, and fruit plants (with fruits such as apples, pears, citrus fruits, and grapes), especially corn, soy, potatoes, cotton, tobacco and rapeseed. Among the properties ("distinctive features") acquired in this case, the increased resistance of plants to insects, arachnids, nematodes and mollusks due to toxins formed in plants, in particular those that are formed in plants based on genetic material from Bacillus Thuringiensis ( for example, based on the genes CryIA (a), CryIA (b), CryIA (c), CryIIA, CryIIIA, CryIIIB2, Cry9c Cry2Ab, Cry3Bb and CryIF, as well as their combinations) (such plants are referred to as Bt plants). Such particularly distinguished properties (“distinguishing features”) include increased plant resistance to fungi, bacteria and viruses as a result of acquired systemic resistance, the presence of systemin, phytoalexins, elicitors and resistance genes and, accordingly, the proteins and toxins they express. Of these properties (“distinguishing features”), it is worth highlighting the increased resistance of plants to certain herbicidal active substances, for example, imidazolinones, sulfonylureas, glyphosate or phosphinotricin (for example, this is the “PAT” gene). In each individual case, genes providing these beneficial properties (“distinctive features”) may be present in transgenic plants and in combination with each other. Examples of “Bt plants” include corn, cotton, soy, and potato varieties that are marketed under the trademarks YIELD GARD® (eg, corn, cotton, soy), KnockOut® (eg, corn), StarLink® ( e.g. corn), Bollgard® (cotton), Nucotn® (cotton) and NewLeaf® (potato). Examples of herbicide-resistant plants are maize, cotton and soybean varieties that are marketed under the trademarks Roundup Ready® (glyphosate resistance, for example, corn, cotton, soybean), Liberty Link® (phosphinotricin resistance, for example, for rapeseed), IMI® (resistance to imidazolinones) and STS® (resistance to sulfonylureas, for example, in corn). Among herbicide-resistant plants (their resistance to herbicides was obtained by conventional breeding methods), the varieties (for example, corn) sold under the Clearfield® trademark should also be mentioned. It goes without saying that all these provisions are also valid in relation to plant varieties that will be obtained in the future or which will accordingly be available for sale in the future and which will have the genetic properties listed above or obtained in the future (“distinguishing features”).

In accordance with the invention, the listed plants can be successfully treated with the active substance compositions according to the invention. The above preferred ratios in the mixtures are valid for the treatment of these plants. When processing plants, special attention should be paid to the compounds or mixtures specially listed in this text.

Compositions of active substances corresponding to the invention not only affect plant pests, carriers of infections and stock pests, they are also active in the veterinary and medical sector in relation to such parasites on animals (ectoparasites) as armor mites, ixodid ticks, scabies mites, redskins , flies (with a stitching and licking mouth apparatus), parasitic larvae of flies, lice, lice beetles, peroids and fleas. These parasites include the following members of the squad.

From the order Anoplurida, e.g. Haematopinus spp., Linognathus spp., Pediculus spp., Phtirus spp., Solenopotes spp ..

From the order Mallophagida and suborders Amblycerina, as well as Ischnocerina, e.g. Trimenopon spp., Menopon spp., Trinoton spp., Bovicola spp., Werneckiella spp., Lepikentron spp., Damalina spp., Trichodectes spp., Felicola

From the order Diptera and suborders Nematocerina, as well as Brachycerina, e.g. Aedes spp., Anopheles spp., Culex spp., Simulium spp., Eusimulium spp., Phlebotomus spp., Lutzomyia spp., Culicoides spp., Chrysops spp., Hyppom spp. ., Atylotus spp., Tabanus spp., Haematopota spp., Philipomyia spp., Braula spp., Musca spp., Hydrotaea spp., Stomoxys spp., Haematobia spp., Morellia spp., Fannia spp., Glossina spp., Calliphora spp., Lucilia spp., Chrysomyia spp., Wohlfahrtia spp., Sarcophaga spp., Oestrus spp., Hypoderma spp., Gasterophilus spp., Hippobosca spp., Lipoptena spp., Melophagus spp ..

From the order Siphonapterida, for example, Pulex spp., Ctenocephalides spp., Xenopsylla spp., Ceratophyllus spp.

From the order Heteropterida, e.g., Cimex spp., Triatoma spp., Rhodnius spp., Panstrongylus spp.

From the order Blattarida, e.g. Blatta orientalis, Periplaneta americana, Blattela germanica, Supella spp.

From the subclass Acari (Acarina) and the Meta- and Mesostigmata orders, e.g. Argas spp., Ornithodorus spp., Otobius spp., Ixodes spp., Amblyomma spp., Boophilus spp., Dermacentor spp., Haemophysalis spp., Hyalma ., Rhipicephalus spp., Dermanyssus spp., Raillietia spp., Pneumonyssus spp., Stemostoma spp., Varroa spp.

From the order Actinedida (Prostigmata) and Acaridida (Astigmata), e.g. Acarapis spp., Cheyletiella spp., Ornithocheyletia spp., Myobia spp., Psorergates spp., Demodex spp., Trombicula spp., Listrophorus spp., Acarus spp., spp., Caloglyphus spp., Hypodectes spp., Pterolichus spp., Psoroptes spp., Chorioptes spp., Otodectes spp., Sarcoptes spp., Notoedres spp., Knemidocoptes spp., Cytodites spp., Laminosioptes

Compositions of active substances according to the invention are also suitable for combating arthropods that attack agricultural useful animals such as cattle, sheep, goats, horses, pigs, donkeys, camels, buffalos, rabbits, chickens, turkeys, ducks , geese, bees, and other domestic animals such as dogs, cats, songbirds, aquarium fish, as well as so-called experimental animals, such as hamsters, guinea pigs, rats and mice. As a result of the fight against these arthropods, mortality among animals is reduced and losses in the productivity of domestic animals are reduced (this applies to meat, milk, wool, skins, eggs, honey, etc.), that is, as a result of using the active substances corresponding to the invention, it becomes possible simplification of the keeping of animals and increase of profitability. The use of the compositions of the active substances according to the invention in the veterinary sector is carried out by known methods by enteral administration, for example, in the form of tablets, capsules, by water, infusion, administration in the form of granules, pastes, balls, by the method of addition to feed, through the tongue, by parenteral administration, for example, by injection (intramuscular, subcutaneous, intravenous, intraperitoneal, etc.), by means of implants, through the nose, by cutaneous use, for example, when bathing or dipping, spraying ( spray), watering (Pour-on and Spot-on), when washing, when dusting, and also using accessories containing active substances such as collars, ear tags, tail tags, bandages on limbs, harnesses, marking devices and etc.

In case of use on livestock, birds, pets, etc. compositions of active substances in the form of formulations (for example, dusts, emulsions, liquid agents), which contain active substances in an amount of from 1 to 80 wt.%, can be used directly or after dilution with a multiplicity of from 100 to 10000, or they can be used as a chemical bath.

In addition, it was found that the active substance compositions of the invention exhibit high insecticidal activity against insects damaging technical materials.

As examples and in the preferred case, but not limiting the scope of the claims, the following insects can be mentioned.

Beetles such as Hylotrupes bajulus, Chlorophorus pilosis, Anobium punctatum, Xestobium rufovillosum, Ptilinus pecticornis, Dendrobium pertinex, Ernobius mollis, Priobium carpini, Lyctus brunneus, Lyctus africis colicollis, Lyctus planus collicollis, Lyctus planicollesollis colis cholecollis, Lyctus planicollis colis lecollis colicollis, Lyctus planicollis colis cholecollis, spec., Tryptodendron spec., Apate monachus, Bostrychus capucins, Heterobostrychus brunneus, Sinoxylon spec., Dinoderus minutus.

Skins such as Sirex juvencus, Urocerus gigas, Urocerus gigas taignus, Urocerus augur.

Termites such as Kalotermes flavicollis, Cryptotermes brevis, Heterotermes indicola, Reticulitermes flavipes, Reticulitermes santonensis, Reticulitermes lucifugus, Mastotermes darwiniensis, Zootermopsis nevadensis, Coptotermes formosanus. Bristles such as Lepisma saccharina.

The concept of technical materials in this regard refers to such non-living materials as, in the preferred case, plastics, adhesives, adhesives, paper and cardboard, leather, wood, wood processing products and coatings.

In a particularly preferred case, the material to be protected from damage by insects is wood or wood processing products.

The term “wood or wood processing products”, which can be protected by means corresponding to the invention or mixtures containing these means respectively, refers, for example, to building wood, wooden beams, railway sleepers, parts of bridges, berths for ships, wooden vehicles, crates, pallets, containers, telegraph poles, wood paneling, wooden windows and doors, plywood, wood panels, joinery or wood products, which in general rayche finds application in home construction or in carpentry.

The active substances can be used as such, in the form of concentrates, or in such conventional formulations as dusts, granules, solutions, suspensions, emulsions or pastes.

The formulations mentioned can be prepared by well-known methods, for example, by mixing the active substances with at least one solvent or, respectively, a diluent, emulsifier, dispersing agent and / or a binding or fixing agent, with a water-repellent agent, and if appropriate, desiccants and UV- can be added. stabilizers, and in some cases also dyes and pigments, as well as other processing aids.

The insecticides or concentrates used to protect wood and wood building materials contain the active substance according to the invention in a concentration of from 0.0001 to 95 wt.%, In particular from 0.001 to 60 wt.%.

The amount of used funds or concentrates, respectively, is determined by the type and place of habitat, as well as the habitat of insects. The optimal amount of agent used can be determined using a series of experiments. However, in the General case, it is sufficient to use from 0.0001 to 20 wt.%, In the preferred case from 0.001 to 10 wt.% Of the active substance based on the protected material.

The solvent and / or diluent is a chemical organic solvent or mixture of solvents and / or an oily or oily non-volatile chemical organic solvent or mixture of solvents and / or a polar chemical organic solvent or mixture of solvents and / or water and, as appropriate, an emulsifier and / or a wetting agent.

As chemical organic solvents, it is preferable to use oily or oily solvents with an evaporation number of more than 35 and with a flash point of more than 30 ° C, preferably of more than 45 ° C. As such non-volatile water-insoluble oily or oily solvents, appropriate mineral oils or aromatic fractions thereof or solvent mixtures containing mineral oils are used, preferably white spirit, kerosene and / or alkyl benzene.

In the preferred case, mineral oils with a boiling point in the range from 170 to 220 ° C are used, white spirit with a boiling point in the range from 170 to 220 ° C, spindle oil with a boiling point in the range from 250 to 350 ° C, kerosene or, respectively aromatic compounds with a boiling point ranging from 160 to 280 ° C, turpentine and the like.

In a preferred embodiment, liquid aliphatic hydrocarbons with a boiling point in the range of 180 to 210 ° C or high boiling mixtures of aromatic and aliphatic hydrocarbons with a boiling point in the range of 180 to 220 ° C and / or spindle oil and / or monochloronaphthalene are used, in a preferred case of α-monochloronaphthalene.

Organic non-volatile oily or oily solvents with an evaporation number of more than 35 and with a flash point of more than 30 ° C, preferably more than 45 ° C, can be partially replaced by organic chemical solvents with high and medium volatility, provided that the solvent mixture also has a number evaporation of more than 35 and a flash point of more than 30 ° C, preferably more than 45 ° C, and the insecticidal-fungicidal mixture in this mixture of solvents is soluble or emulsifiable.

In a preferred embodiment, a portion of the chemical organic solvent or mixture of solvents is replaced with an aliphatic polar chemical organic solvent or mixture of solvents. In the preferred case, chemical organic solvents containing hydroxyl groups and / or ester groups and / or ether functional groups, for example, such as glycol ethers, esters and the like, are used for this.

In the framework of the present invention, known chemical diluents and / or soluble in the used chemical organic solvents or dispersible or emulsifiable artificial resins and / or binding drying oils, in particular binding agents which consist of a corresponding resin or contain it, and these resins are acrylate resin, vinyl resin, for example polyvinyl acetate, polyester resin, polycondensation resin by addition or polyaddition, polyurethane resin, alkyd resin or a modified alkyd resin, phenolic resin, hydrocarbon resin such as indene-coumarone resin, silicone resin, drying vegetable oils and / or drying oils and / or physically drying binders based on natural and / or artificial resin.

The artificial resin used as a binder may be in the form of an emulsion, dispersion or solution. As binders can also be used bitumen or bitumen compositions in an amount up to 10 wt.%. In addition to this, known coloring agents, pigments, water repellents, perfumes and corrosion inhibitors, or corrosion protection agents and the like, can be used.

In a preferred case, according to the invention, at least one alkyd resin or a suitably modified alkyd resin and / or a drying vegetable oil is used as a chemical organic binding agent in the agent or in the concentrate. In the preferred case, in accordance with the invention, alkyd resins with an oil content of more than 45 wt.%, Preferably from 50 to 68 wt.%, Are used.

A part of the said binding agent can be partially or completely replaced with a fixing agent (mixture thereof) or a plasticizer (mixture of plasticizers). These additives are intended to prevent the entrainment of vapors of active substances and their crystallization or, accordingly, deposition. In the preferred case, they replace from 0.01 to 30% of the binding agent (based on 100% of the binding agent used).

Plasticizers belong to the chemical classes of phthalic acid esters such as dibutyl, dioctyl or benzyl butyl phthalate, phosphoric acid esters such as tributyl phosphate, adipic acid esters such as di (2-ethylhexyl) adipate, stearates such as butyl steylate oleates such as butyl oleate; they are glycerol ethers or high molecular weight glycol ethers, glycerol esters and p-toluenesulfonic acid esters.

Chemically, fixing agents are based on polyvinylalkyl ethers such as, for example, polyvinyl methyl ether, or on ketones such as benzophenone, ethylene benzophenone.

In particular, water can also be used as a solvent or diluent, which in such cases is mixed with one or more of the above chemical organic solvents or, respectively, diluents, emulsifiers and dispersants.

The most effective wood protection is achieved with industrial impregnation methods, for example using vacuum, double vacuum, or methods using pressure.

Ready-to-use products may, as appropriate, contain other insecticides and, as appropriate, another fungicide or several fungicides.

In the preferred case, as additional components of the mixtures, insecticides and fungicides mentioned in international patent application No. 94/29268 can be used. The compounds named in this publication are an important component of this application.

The most preferred components of the mixtures may include insecticides such as chlorpyrifos, foxime, silafluofin, alfamethrin, cyfluthrin, cypermethrin, deltamethrin, permethrin, imidacloprid, NI-25, flufenoxuron, hexaflumuron, transflutrin, triaclofenuride, thioclofedin, triflofenuride, thiclofenuride, thiclofenuride teflutrin, as well as fungicides such as epoxiconazole, hexaconazole, azaconazole, propiconazole, tebuconazole, ciproconazole, metconazole, imazalil, dichlorofluanide, tolylfluanide, 3-iodo-2-propynyl-butylcarbamate-3-N-octyl butylcarbamate-3-N-octyl butylcarbamate-3 and 4,5-dichloro-N-octyl-isothiazolin-3-one.

Compounds according to the invention can also be used to protect against fouling of objects, in particular ship hulls, protective gratings, networks, building structures, port facilities and signal structures that are washed by sea or salt water.

Fouling with attached oligochaetes such as worms living in calcareous tubes, as well as shells and representatives of species from the Ledamorpha group (sea ducks), such various representatives of the Lepas and Scalpellum species or species from the Balanomorpha group (marine acorns), such as Balanus or Pollicipes species, increases resistance to movement due to friction and, as a result, leads to increased energy consumption and, in addition, leads to a noticeable increase in production costs due to frequent stay in dry docks.

Along with algae fouling, for example, Ectocarpus sp. and Ceramium sp., of particular importance, in particular, is the overgrowth of the attached organisms from the Entomostraken group, which are united by the name Cirripedia (mustache crayfish).

It has been unexpectedly discovered that the compounds of the invention per se or as a composition with other active substances very effectively inhibit fouling (Antifouling effect).

By using the compounds of the invention both as the sole active substances and in composition with other active substances, the use of heavy metals, for example, in the form of bis (trialkyltin) sulfides, tri-n-butyltin laurate, tri-n- chloride, can be avoided. butyltin, copper (I) oxide, triethyltin chloride, tri-n-butyl- (2-phenyl-4-chlorophenoxy) tin, tributyltin oxide, molybdenum disulfide, antimony oxide, polymer butyl titanate, phenyl (bispyridine) -bismuth chloride, n-butyltin, ethylene bis manganese iocarbamate, zinc dimethyldithiocarbamate, zinc ethylene bistiocarbamate, zinc and copper salts of 2-pyridinethiol-1-oxide, bisdimethyldithiocarbamoyl zinc ethylene bistiocarbamate, zinc oxide, ethylene bis triethobenzoate, copper triethobenzoate, compounds.

Ready-to-use anti-fouling paints may also contain other active substances, as appropriate, preferably algaecides, fungicides, herbicides, molluscicides or, accordingly, other anti-fouling active substances.

In the preferred case, algaecides such as 2-tert-butylamino-4-cyclopropylamino-6-methylthio-1,3,5-triazine, dichlorophene, diuron, endotal, fertinacetate, isoproturon are suitable as components of the compositions for the anti-fouling agents , metabenzothiazuron, oxyfluorophene, quinoclamine and terbutrin, fungicides such as benzo [b] thiophen-S, S-dioxocarboxylic acid cyclohexylamide, dichlorofluanide, fluorofolpet, 3-iodo-2-propynyl-butylcarbamate such as azone-toluazole , cyproconazole, epoxiconase ol, hexaconazole, metconazole, propiconazole and tebuconazole, molluscicides such as fentin acetate, metaldehyde, methiocarb, niclosamide, thiodicarb and trimethacarb, iron chelates,

or conventional anti-fouling active substances such as 4,5-di-chloro-2-octyl-4-isothiazolin-3-one, diiodomethyl paratrylsulfone, 2- (N, N-dimethylthio-carbamoylthio) -5-nitrothiazyl, potassium, copper, sodium and zinc salts of 2-pyridinethiol-1-oxide, pyridinitripenylborane, tetrabutyldistannoxane, 2,3,5,6-tetrachloro-4- (methylsulfonyl) pyridine, 2,4,5,6-tetrachloroisophthalonitrile, tetramethylthiuramdisulfide and 2, 4,6-trichlorophenyl maleinimide.

The antifouling agents used contain the active substance according to the invention in the form of compounds corresponding to the invention in a concentration of from 0.001 to 50 wt.%, In particular from 0.01 to 20 wt.%.

Anti-fouling agents also contain such conventional components as, for example, those described by Ungerer, Chem. Ind. 1985, 37, 730-732, and Williams, Antifouling Marine Coatings, Noyes, Park Ridge, 1973.

In particular, anti-fouling agents contain, along with the algicidal, fungicidal, molluscicidal and insecticidal substances of the invention, binders.

Examples of commonly recognized binders are polyvinyl chloride in a solvent system, chlorinated rubber in a solvent system, acrylic resins in a solvent system, in particular in an aqueous system, vinyl chloride-vinyl acetate copolymer systems in the form of aqueous dispersions or in organic solvent systems, butadiene / styrene / acrylonitrile rubbers, drying oils such as linseed oil, ester resins or modified solid resins combined with resin or bitumen, asphalt, and epoxy Compounds, minor amounts of chlorinated rubber, chlorinated polypropylene and vinyl resins.

Coating agents, if appropriate, also contain inorganic pigments, organic pigments or dyes, which are preferably insoluble in sea water. In addition, the coating agent may contain materials such as rosin in order to enable the controlled release of active substances. Coatings may also contain plasticizers, modifying agents for the regulation of rheological characteristics, as well as other conventional constituents. Corresponding to the invention compounds or the above mixtures can also be introduced into the anti-fouling system "self-shine".

Compositions of active substances are also suitable for controlling animal pests, in particular insects, arachnids and ticks that are found in enclosed spaces, for example, in residential premises, factory buildings, in offices, in car interiors, etc. To combat such pests, they can be used as part of household insecticidal products as the only active substances or in combination with other active and auxiliary substances. They are effective against sensitive and resistant species, as well as at all stages of development. Such pests include the following representatives.

From the order Scorpionidea, for example Buthus occitanus.

From the order Acarina, e.g. Argas persicus, Argas reflexus, Bryobia ssp., Dermanyssus gallinae, Glyciphagus domesticus, Ornithodorus moubat, Rhipicephalus sanguineus, Trombicula alfreddugesi, Neutrombicula autumnalis, Dermatophagoides.

From the order Araneae, for example Aviculariidae, Araneidae.

From the order Opiliones, e.g. Pseudoscorpiones chelifer, Pseudoscorpiones cheiridium, Opiliones phalangium.

From the order Isopoda, for example, Oniscus asellus, Porcellio scaber.

From the order of Diplopoda, for example Blaniulus guttulatus, Polydesmus spp ..

From the order Chilopoda, for example Geophilus spp.

From the order Zygentoma, for example Ctenolepisma spp., Lepisma saccharina, Lepismodes inquilinus.

From the order Blattaria, e.g. Blatta orientalies, Blattella germanica, Blattella asahinai, Leucophaea maderae, Panchlora spp., Parcoblatta spp., Periplaneta australasiae, Periplaneta americana, Periplaneta brunnea, Periplaneta fuligalpa,

From the order Sanatoria, for example, Acheta domesticus.

From the order Dermaptera, for example, Forficula auricularia.

From the order Isoptera, for example, Kalotermes spp., Reticulitermes spp ..

From the order Psocoptera, for example, Lepinatus spp., Liposcelis spp ..

From the order Coleoptera, for example, Anthrenus spp., Attagenus spp., Dermestes spp., Latheticus oryzae, Necrobia spp., Ptinus spp., Rhizopertha dominica, Sitophilus granarius, Sitophilus oryzae, Sitophilus zeamais, Stegobis.

From the order Diptera, for example, Aedes aegypti, Aedes albopictus, Aedes ta Seniorhynchus, Anopheles spp., Calliphora erythrocephala, Chrysozona pluvialis, Culex quinquefasciatus, Culex pipiens, Culex tarsalis, Drosophia colpomica spp. , Simulium spp., Stomoxys calcitrans, Tipula paludosa.

From the order Lepidoptera, for example, Achroia grisella, Galleria mellonella, Plodia interpunctella, Tinea cloacella, Tinea pellionella, Tineola bisselliella.

From the order Siphonaptera, for example, Ctenocephalides canis, Ctenocephalides felis, Pulex irritans, Tunga penetrans, Xenopsylla cheopis.

From the order Hymenoptera, for example, Camponotus herculeanus, Lasius fuliginosus, Lasius niger, Lasius umbratus, Monomorium pharaonis, Paravespula spp., Tetramorium caespitum.

From the order Anoplura, for example, Pediculus humanus capitis, Pediculus humanus corporis, Phthirus pubis.

From the order Heteroptera, for example, Cimex hemipterus, Cimex lectularius, Rhodinus prolixus, Triatoma infestans.

For use in domestic insecticides, the compositions according to the invention are taken as such or they are taken in combination with other suitable active substances such as phosphorus acid esters, carbamates, pyrethroids, neonicotinoids, growth regulators or active substances from other known classes of insecticides.

The compositions are used in the form of aerosols, using spray guns that are not pressurized, for example, using vials with pumps or spray heads, automatic aerosol generators, fog generators, in the form of foams, gels, evaporation products from plates for thermal generators made of cellulose or plastic, liquid evaporators, gel and membrane evaporators, evaporators with a fan device that do not require energy supply or, accordingly, passive evaporating systems, paper products for more shots with moths, pouches or gels for fighting moths, in the form of granules or dusts in sprayed baits or in stationary baits.

The high efficacy of the active substance compositions of the invention is demonstrated by the following examples and tables A-3. While the individual active substances in some cases are not active enough, the compositions show efficacy that is superior to simple overall effectiveness. The synergistic effect of insecticides and acaricides occurs in all cases when the effectiveness of the compositions of the active substances exceeds the sum of the efficiencies of the individual applied active substances.

The expected effectiveness of each individual combination of the two active substances can be calculated using the following formula (S.R. Colby, "Calculating Synergistic and Antagonistic Responses of Herbicide Combinations", Weeds 15, pp. 20-22, 1967).

If

X means the percentage of death, expressed in% of the untreated control, when using active substance A at a rate of consumption of m g / ha or in a concentration of m parts per million,

Y means the percentage of death, expressed in% of the untreated control, when using active substance B at a rate of consumption of n g / ha or at a concentration of n parts per million and

E means the percentage of death, expressed in% of the untreated control, when using active substances A and B at consumption rates of m and n g / ha or at a concentration of m and n parts per million,

so then

.

.

When the experimentally determined percentage of insect deaths exceeds the calculated value, this means that the toxic activity of the combination is super-additive, that is, it means that we are dealing with the synergistic effect. In this case, the percentage of death observed in the experiment should be higher than the value of the expected percentage of death (E) calculated by the above formula.

Example A

Experience at Aphis gossypii

Solvent: 7 parts by weight of dimethylformamide

Emulsifier: 2 parts by weight of alkylaryl polyglycol ether

To obtain a suitable form of the composition with active substances, 1 part of the mass of active substances with the indicated amounts of solvent and emulsifier is mixed and the concentrate containing emulsifier water is diluted to the desired concentration.

The leaves of cotton (Gossypium hirsutum}, which are affected by a large number of cotton aphids (Aphis gossypii), are treated by immersion in a composition with active substances in the desired concentration.

After a certain time, the death of insects in percent is determined. At the same time, 100% means that all leaf aphids died, 0% means that not one leaf aphid died. The obtained values of insect death as a percentage are calculated according to the Colby formula.

In this experiment, it was shown, for example, that the following composition of the active substances corresponding to the invention demonstrates a synergistic increase in effectiveness compared to the separate use of active substances.

Table a Insect Plant Pests Experience on Aphis gossvpii Active substance Ppm Concentration % Death Beta-cyfluthrin 0.12 5 Thiacloprid 0.6 35 Beta-cyfluthrin + thiacloprid (1: 5), in accordance with the invention 0.12 + 0.6 Found 95 * Calculated 38.25 ** * "Found" corresponds to the experimentally determined effectiveness. ** "Calculated" corresponds to the efficiency determined by the Colby formula.

Example B

Experience at Heliothis armigera

Solvent: 7 parts by weight of dimethylformamide

Emulsifier: 2 parts by weight of alkylaryl polyglycol ether

To obtain a suitable form of the composition with active substances, 1 part of the mass of active substances with the indicated amounts of solvent and emulsifier is mixed and the concentrate containing emulsifier water is diluted to the desired concentration.

The leaves of cotton (Gossypium hirsutum) are treated by immersion in the composition with the active substances in the desired concentration, and caterpillars of the cotton scoop (Heliothis armigera) are placed on wet leaves.

After a certain time, the death of insects in percent is determined. At the same time, 100% means that all the tracks were dead, 0% means that not one track was dead. The obtained values of the death of the tracks in percent calculated according to the Colby formula.

In this experiment, it was shown that the following composition of the active substances corresponding to the invention demonstrates a synergistic increase in effectiveness compared to the separate use of active substances.

Table B Insect Plant Pests Experience at Heliothis armigera Active substance Ppm Concentration % Death Beta-cyfluthrin 0.12 0 Thiacloprid 0.6 0 Beta-cyfluthrin + thiacloprid (1: 5), in accordance with the invention 0.12 + 0.6 Found 100 * Calculated 0 ** Lambda cygalothrin 0.12 55 Thiacloprid 0.12 0 Lambda-cygalotrin + thiacloprid (1: 1), in accordance with the invention 0.12 + 0.12 Found 100 * Calculated 55 ** * "Found" corresponds to the experimentally determined effectiveness. ** "Calculated" corresponds to the efficiency determined by the Colby formula.

Example B

Experience at Myzus persicae

Solvent: 7 parts by weight of dimethylformamide

Emulsifier: 2 parts by weight of alkylaryl polyglycol ether

To obtain a suitable form of the composition with active substances, 1 part of the mass of active substances with the indicated amounts of solvent and emulsifier is mixed and the concentrate containing emulsifier water is diluted to the desired concentration.

Leaves of cabbage (Brassica oleracea), which are strongly affected by green peach aphids (Myzus persicae), are treated by immersion in the composition with the active substances in the desired concentration.

After a certain time, the death of insects in percent is determined. At the same time, 100% means that all leaf aphids died, 0% means that not one leaf aphid died. The obtained percentages of aphid death as a percentage are calculated using the Colby formula.

In this experiment, it was shown, for example, that the following composition of the active substances corresponding to the invention demonstrates a synergistic increase in effectiveness compared to the separate use of active substances.

Table B Insect Plant Pests Experience at Myzus persicae Active substance Ppm Concentration % Death Beta-cyfluthrin 0.12 0 Thiacloprid 0.6 35 Beta-cyfluthrin + thiacloprid (1: 5), in accordance with the invention 0.12 + 0.6 Found 95 * Calculated 35 ** * "Found" corresponds to the experimentally determined effectiveness. ** "Calculated" corresponds to the efficiency determined by the Colby formula.

Table B Insect Plant Pests Experience at Myzus persicae Active substance Ppm Concentration % Death Bifenthrin 0.16 0 Thiacloprid Bifentrin + thiacloprid (1: 5), in accordance with the invention 0.8 0 0.16 + 0.8 Found 40 * Calculated 0 ** * "Found" corresponds to the experimentally determined effectiveness. ** "Calculated" corresponds to the efficiency determined by the Colby formula.

Table B Insect Plant Pests Experience at Myzus persicae Active substance Ppm Concentration % Death Gamma cygalothrin 0,032 0 Thiacoprid 0.8 10 Gamma-cygalotrin + thiacloprid (1:25), in accordance with the invention 0.032 + 0.8 Found 35 * Calculated 10 ** * "Found" corresponds to the experimentally determined effectiveness. ** "Calculated" corresponds to the efficiency determined by the Colby formula.

Example D

The experiment on the larvae of Phaedon cochleariae

Solvent: 7 parts by weight of dimethylformamide

Emulsifier: 2 parts by weight of alkylaryl polyglycol ether

To obtain a suitable form of the composition with active substances, 1 part of the mass of active substances with the indicated amounts of solvent and emulsifier is mixed and the concentrate containing emulsifier water is diluted to the desired concentration.

Cabbage leaves (Brassica oleracea) are treated by immersion in a composition with active substances in the desired concentration and larvae of rapeseed leaf beetle (Phaedon cochleariae) are placed on still wet leaves.

After a certain time, the percentage of larvae is determined. At the same time, 100% means that all beetle larvae died, 0% means that not a single beetle larva died. The obtained values of insect death as a percentage are calculated according to the Colby formula.

In this experiment, it was shown that the following composition of the active substances corresponding to the invention demonstrates a synergistic increase in effectiveness compared to the separate use of active substances.

Table g Insect Plant Pests The experiment on the larvae of Phaedon cochleariae Active substance Ppm Concentration % Death Beta-cyfluthrin 0.12 fifteen Thiacloprid 3 fifteen Beta-cyfluthrin + thiacloprid (1:25), in accordance with the invention 0.12 + 3 Found 100 * Calculated 27.75 ** * "Found" corresponds to the experimentally determined effectiveness. ** "Calculated" corresponds to the efficiency determined by the Colby formula.

Table g Insect Plant Pests The experiment on the larvae of Phaedon cochleariae Active substance Ppm Concentration % Death Alpha cypermethrin 0.16 5 Thiacloprid four 5 Alpha cypermethrin + thiacloprid (1:25), in accordance with the invention 0.16 + 4 Found 55 * Calculated 9.75 ** * "Found" corresponds to the experimentally determined effectiveness. ** "Calculated" corresponds to the efficiency determined by the Colby formula. Table g Insect Plant Pests The experiment on the larvae of Phaedon cochleariae

Active substance Ppm Concentration % Death Bifenthrin 0.8 35 Thiacloprid four thirty Bifentrin + thiacloprid (1: 5), in accordance with the invention 0.8 + 4 Found 100 * Calculated 54.5 ** * "Found" corresponds to the experimentally determined effectiveness. ** "Calculated" corresponds to the efficiency determined by the Colby formula.

Table g Insect Plant Pests The experiment on the larvae of Phaedon cochleariae Active substance Ppm Concentration % Death Deltamethrin 0.16 thirty Thiacloprid twenty 40 Deltamethrin + thiacloprid (1: 125), in accordance with the invention 0.16 + 20 Found 90 * Calculated 58 ** * "Found" corresponds to the experimentally determined effectiveness. ** "Calculated" corresponds to the efficiency determined by the Colby formula.

Example D

Experience on Plutella xylostella (strain of normal sensitivity)

Solvent: 7 parts by weight of dimethylformamide

Emulsifier: 2 parts by weight of alkylaryl polyglycol ether

To obtain a suitable form of the composition with active substances, 1 part of the mass of active substances with the indicated amounts of solvent and emulsifier is mixed and the concentrate containing emulsifier water is diluted to the desired concentration.

Cabbage leaves (Brassica oleracea) are treated by immersion in a composition with active substances in the desired concentration and cabbage moth caterpillars (Plutella xylostella, strain of normal sensitivity) are placed on wet leaves.

After a certain time, the caterpillar loss in percent is determined. At the same time, 100% means that all the tracks were dead, 0% means that not one track was dead. The obtained values of insect death as a percentage are calculated according to the Colby formula.

In this experiment, it was shown that the following composition of the active substances corresponding to the invention demonstrates a synergistic increase in effectiveness compared to the separate use of active substances.

Table e Insect Plant Pests Experience on Plutella xylostella (normal sensitivity) Active substance Ppm Concentration % Death Beta-cyfluthrin 0.024 10 Thiacloprid 0.6 0 Beta-cyfluthrin + thiacloprid (1:25), in accordance with the invention 0.024 + 0.6 Found 40 * Calculated 10 ** Lambda cygalothrin 0.024 40 Thiacloprid 0.6 0 Lambda-cygalotrin + thiacloprid (1:25), in accordance with the invention 0.024 + 0.6 Found 80 * Calculated 40 ** * "Found" corresponds to the experimentally determined effectiveness. ** "Calculated" corresponds to the efficiency determined by the Colby formula.

Example E

Experience on Plutella xylostella (resistant strain)

Solvent: 7 parts by weight of dimethylformamide

Emulsifier: 2 parts by weight of alkylaryl polyglycol ether

To obtain a suitable form of the composition with active substances, 1 part of the mass of active substances with the indicated amounts of solvent and emulsifier is mixed and the concentrate containing emulsifier water is diluted to the desired concentration.

Cabbage leaves (Brassica oleracea) are treated by immersion in a composition with active substances in the desired concentration and cabbage moth caterpillars (Plutella xylostella, resistant strain) are placed on the still moist leaves.

After a certain time, the caterpillar loss in percent is determined. At the same time, 100% means that all the tracks were dead, 0% means that not one track was dead. The obtained values of insect death as a percentage are calculated according to the Colby formula.

In this experiment, it was shown that the following composition of the active substances corresponding to the invention demonstrates a synergistic increase in effectiveness compared to the separate use of active substances.

Table E Insect Plant Pests Experience on Plutella xylostella (resistant strain) Active substance Ppm Concentration % Death Beta-cyfluthrin 0.6 35 Thiacloprid 3 0 Beta-cyfluthrin + thiacloprid (1: 5), in accordance with the invention 0.6 + 3 Found 85 * Calculated 35 ** Lambda cygalothrin 0.6 40 Thiacloprid fifteen 10 Lambda-cygalotrin + thiacloprid (1:25), in accordance with the invention 0.6 + 15 Found 85 * Calculated 46 ** * "Found" corresponds to the experimentally determined effectiveness. ** "Calculated" corresponds to the efficiency determined by the Colby formula.

Example G

Experience at Spodoptera exigua

Solvent: 7 parts by weight of dimethylformamide

Emulsifier: 2 parts by weight of alkylaryl polyglycol ether

To obtain a suitable form of the composition with active substances, 1 part of the mass of active substances with the indicated amounts of solvent and emulsifier is mixed and the concentrate containing emulsifier water is diluted to the desired concentration.

The leaves of cabbage (Brassica oleracea) are treated by immersion in the composition with the active substances in the desired concentration, and beet caterpillars (Spodoptera exigua) are placed on the still moist leaves.

After a certain time, the caterpillar loss in percent is determined. At the same time, 100% means that all the tracks were dead, 0% means that not one track was dead. The obtained values of insect death as a percentage are calculated according to the Colby formula.

In this experiment, it was shown that the following composition of the active substances corresponding to the invention demonstrates a synergistic increase in effectiveness compared to the separate use of active substances.

Table g Insect Plant Pests Experience at Spodoptera exigua Active substance Ppm Concentration % Death Beta-cyfluthrin 0.6 25 Thiacloprid fifteen 0 Beta-cyfluthrin + thiacloprid (1:25), in accordance with the invention 0.6 + 15 Found 100 * Calculated 25 ** * "Found" corresponds to the experimentally determined effectiveness. ** "Calculated" corresponds to the efficiency determined by the Colby formula.

Example 3

Experience at Spodoptera fruqiperda

Solvent: 7 parts by weight of dimethylformamide

Emulsifier: 2 parts by weight of alkylaryl polyglycol ether

To obtain a suitable form of the composition with active substances, 1 part of the mass of active substances with the indicated amounts of solvent and emulsifier is mixed and the concentrate containing emulsifier water is diluted to the desired concentration.

Cabbage leaves (Brassica oleracea) are treated by immersion in a composition with active substances in the desired concentration and the caterpillars of the butterfly of the scoop Spodoptera frugiperda are placed on wet leaves.

After a certain time, the caterpillar loss in percent is determined. At the same time, 100% means that all the tracks were dead, 0% means that not one track was dead. The obtained values of the death of the tracks in percent calculated according to the Colby formula.

In this experiment, it was shown that the following composition of the active substances corresponding to the invention demonstrates a synergistic increase in effectiveness compared to the separate use of active substances.

Table h Insect Plant Pests Experience on Spodoptera frugiperda Active substance Ppm Concentration % Death Beta-cyfluthrin 0.12 5 Thiacloprid 0.6 0 Beta-cyfluthrin + thiacloprid (1: 5), in accordance with the invention 0.12 + 0.6 Found 100 * Calculated 5 ** * "Found" corresponds to the experimentally determined effectiveness. ** "Calculated" corresponds to the efficiency determined by the Colby formula.

Claims (1)

Insecticides containing thiacloprid and one of the following compounds in a ratio providing a synergistic effect:
acrinatrin,
alpha cypermethrin,
beta cyfluthrin,
cygalotrin
cypermethrin,
deltamethrin,
lambda cygalotrin,
permethrin
zeta cypermethrin,
cyfluthrin,
bifentrin
gamma-cygalotrin.