RU2315726C1 - Glaze - Google Patents

Glaze Download PDF

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Publication number
RU2315726C1
RU2315726C1 RU2006130063/03A RU2006130063A RU2315726C1 RU 2315726 C1 RU2315726 C1 RU 2315726C1 RU 2006130063/03 A RU2006130063/03 A RU 2006130063/03A RU 2006130063 A RU2006130063 A RU 2006130063A RU 2315726 C1 RU2315726 C1 RU 2315726C1
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RU
Russia
Prior art keywords
glaze
cao
bao
sio
zro
Prior art date
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RU2006130063/03A
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Russian (ru)
Inventor
Юлия Алексеевна Щепочкина
Original Assignee
Юлия Алексеевна Щепочкина
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Юлия Алексеевна Щепочкина filed Critical Юлия Алексеевна Щепочкина
Priority to RU2006130063/03A priority Critical patent/RU2315726C1/en
Application granted granted Critical
Publication of RU2315726C1 publication Critical patent/RU2315726C1/en

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    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00—Glass compositions
    • C03C3/04—Glass compositions containing silica
    • C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
    • C03C3/089—Glass compositions containing silica with 40% to 90% silica, by weight containing boron
    • C03C3/091—Glass compositions containing silica with 40% to 90% silica, by weight containing boron containing aluminium
    • C03C3/093—Glass compositions containing silica with 40% to 90% silica, by weight containing boron containing aluminium containing zinc or zirconium

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Glass Compositions (AREA)

Abstract

FIELD: technology of silicates, composition of unfritted glaze.
SUBSTANCE: the present innovation deals with manufacturing facing plates and articles of household ceramics. The innovation enables to increase thermal resistance and glare of glaze. The glaze in question contains, weight%: SiO2 50.0-56.0; Al2O3 3.0-5.0; B2O3 12.0-16.0; CaO 6.0-8.0; BaO 3.0-5.0; ZrO2 3.0-5.0; K2O 3.0-5.0; ZnO 3.0-5.0; TiO2 5.0-7.0.
EFFECT: higher efficiency.
1 tbl

Description

Изобретение относится к области технологии силикатов, в частности к составам нефриттованных глазурей, используемых в производстве облицовочной плитки, изделий бытовой керамики.The invention relates to the field of technology of silicates, in particular to compositions of non-grit glazes used in the manufacture of facing tiles, household ceramics.

Известна глазурь, содержащая, мас.%: SiO2 51,73-53,17; Al2O3 3,87-6,16; B2O3 8,43-9,08; Fe2O3 1,3-1,43; CaO 22,32-24,03; MgO 1,27-1,38; Na2O 2,89-4,47; K2O 0,15-1,15; BaO 4,13-4,47 [1].Known glaze containing, in wt.%: SiO 2 51.73-53.17; Al 2 O 3 3.87-6.16; B 2 O 3 8.43-9.08; Fe 2 O 3 1.3-1.43; CaO 22.32-24.03; MgO 1.27-1.38; Na 2 O 2.89-4.47; K 2 O 0.15-1.15; BaO 4.13-4.47 [1].

Известна глазурь, содержащая, мас.%: SiO2 31,0-33,0; Al2O3 10,0-12,0; B2O3 25,0-27,0; CaO 6,0-7,0; BaO 3,5-4,5; ZrO2 7,0-9,0; K2O 8,0-4,0; Na2O 3,0-5,0; ZnO 4,5-5,5 [2].Known glaze containing, wt.%: SiO 2 31,0-33,0; Al 2 O 3 10.0-12.0; B 2 O 3 25.0-27.0; CaO 6.0-7.0; BaO 3.5-4.5; ZrO 2 7.0-9.0; K 2 O 8.0-4.0; Na 2 O 3.0-5.0; ZnO 4.5-5.5 [2].

Целью изобретения является повышение термостойкости и блеска глазури.The aim of the invention is to increase the heat resistance and gloss of the glaze.

Цель достигается тем, что в состав глазури дополнительно вводят TiO2, при следующем соотношении компонентов, мас.%: SiO2 50,0-56,0; Al2O3 3,0-5,0; B2O3 12,0-16,0; CaO 6,0-8,0; BaO 3,0-5,0; ZrO2 3,0-5,0; K2O 3,0-5,0; ZnO 3,0-5,0; TiO2 5,0-7,0.The goal is achieved by the fact that TiO 2 is additionally introduced into the glaze composition, in the following ratio of components, wt.%: SiO 2 50.0-56.0; Al 2 O 3 3.0-5.0; B 2 O 3 12.0-16.0; CaO 6.0-8.0; BaO 3.0-5.0; ZrO 2 3.0-5.0; K 2 O 3.0-5.0; ZnO 3.0-5.0; TiO 2 5.0-7.0.

В таблице приведены составы глазури.The table shows the glaze compositions.

ТаблицаTable СоставStructure Компоненты, мас.%:Components, wt.%: Термостойкость, °СHeat resistance, ° С Блеск, %Gloss,% SiO2 SiO 2 Al2O3 Al 2 O 3 B2O3 B 2 O 3 CaOCao BaOBao ZrO2 ZrO 2 K2OK 2 O ZnOZno TiO2 TiO 2 1one 50,050,0 5,05,0 16,016,0 8,08.0 3,03.0 5,05,0 3,03.0 3,03.0 7,07.0 ~300~ 300 ~50~ 50 22 53,053.0 4,04.0 14,014.0 7,07.0 4,04.0 4,04.0 4,04.0 4,04.0 6,06.0 ~250~ 250 ~50~ 50 33 56,056.0 3,03.0 12,012.0 6,06.0 5,05,0 3,03.0 5,05,0 5,05,0 5,05,0 ~250~ 250 ~50~ 50

Компоненты глазури размалывают до остатка 0,1-0,3% на сетке №0056. С добавкой 1-2% глины, 0,1-0,2% электролита (силиката К), 45-50% воды. Полученную суспензию наносят на изделия и обжигают при 1000°С в окислительной среде.The components of the glaze are ground to a residue of 0.1-0.3% on mesh No. 0056. With the addition of 1-2% clay, 0.1-0.2% electrolyte (silicate K), 45-50% water. The resulting suspension is applied to products and fired at 1000 ° C in an oxidizing environment.

Источники информацииInformation sources

1. Авторское свидетельство СССР №1025678, C03C 9/00, 1983.1. USSR Copyright Certificate No. 1025678, C03C 9/00, 1983.

2. Авторское свидетельство CCCР №1544734, С03С 8/04, 1990.2. Copyright certificate of CCCP No. 1544734, С03С 8/04, 1990.

Claims (1)

Глазурь, содержащая SiO2, Al2О3, В2О3, СаО, ВаО, ZrO2, K2O, ZnO, отличающаяся тем, что дополнительно содержит TiO2, при следующем соотношении компонентов, мас.%:Glaze containing SiO 2 , Al 2 O 3 , B 2 O 3 , CaO, BaO, ZrO 2 , K 2 O, ZnO, characterized in that it additionally contains TiO 2 , in the following ratio of components, wt.%: SiO2 SiO 2 50,0-56,050.0-56.0 Al2O3 Al 2 O 3 3,0-5,03.0-5.0 В2О3 B 2 O 3 12,0-16,012.0-16.0 CaOCao 6,0-8,06.0-8.0 BaOBao 3,0-5,03.0-5.0 ZrO2 ZrO 2 3,0-5,03.0-5.0 К2ОK 2 O 3,0-5,03.0-5.0 ZnOZno 3,0-5,03.0-5.0 TiO2 TiO 2 5,0-7,05.0-7.0
RU2006130063/03A 2006-08-21 2006-08-21 Glaze RU2315726C1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
RU2006130063/03A RU2315726C1 (en) 2006-08-21 2006-08-21 Glaze

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
RU2006130063/03A RU2315726C1 (en) 2006-08-21 2006-08-21 Glaze

Publications (1)

Publication Number Publication Date
RU2315726C1 true RU2315726C1 (en) 2008-01-27

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Family Applications (1)

Application Number Title Priority Date Filing Date
RU2006130063/03A RU2315726C1 (en) 2006-08-21 2006-08-21 Glaze

Country Status (1)

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RU (1) RU2315726C1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2498951C1 (en) * 2012-04-04 2013-11-20 Открытое акционерное общество "Тольяттиазот" Glaze

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2498951C1 (en) * 2012-04-04 2013-11-20 Открытое акционерное общество "Тольяттиазот" Glaze

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