RU2219205C2 - Aqueous coating composition containing polymer and modifying agent of rheological property prepared by polyaddition - Google Patents

Aqueous coating composition containing polymer and modifying agent of rheological property prepared by polyaddition Download PDF

Info

Publication number
RU2219205C2
RU2219205C2 RU2001101935/04A RU2001101935A RU2219205C2 RU 2219205 C2 RU2219205 C2 RU 2219205C2 RU 2001101935/04 A RU2001101935/04 A RU 2001101935/04A RU 2001101935 A RU2001101935 A RU 2001101935A RU 2219205 C2 RU2219205 C2 RU 2219205C2
Authority
RU
Russia
Prior art keywords
mol
meth
polymer
polyaddition
composition according
Prior art date
Application number
RU2001101935/04A
Other languages
Russian (ru)
Other versions
RU2001101935A (en
Inventor
Рулоф БУТЕР (NL)
Рулоф БУТЕР
Андреас Хенрикус Йоханнес РУЛОФС (NL)
Андреас Хенрикус Йоханнес РУЛОФС
Original Assignee
Акцо Нобель Н.В.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Акцо Нобель Н.В. filed Critical Акцо Нобель Н.В.
Publication of RU2001101935A publication Critical patent/RU2001101935A/en
Application granted granted Critical
Publication of RU2219205C2 publication Critical patent/RU2219205C2/en

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
    • C09D151/003—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78—Nitrogen
    • C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
    • C08G18/791—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups
    • C08G18/792—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups formed by oligomerisation of aliphatic and/or cycloaliphatic isocyanates or isothiocyanates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/02—Homopolymers or copolymers of hydrocarbons
    • C08L25/04—Homopolymers or copolymers of styrene
    • C08L25/08—Copolymers of styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/062—Copolymers with monomers not covered by C08L33/06
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
    • C09D125/02—Homopolymers or copolymers of hydrocarbons
    • C09D125/04—Homopolymers or copolymers of styrene
    • C09D125/08—Copolymers of styrene
    • C09D125/14—Copolymers of styrene with unsaturated esters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09D133/062—Copolymers with monomers not covered by C09D133/06
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/004—Reflecting paints; Signal paints
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S525/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S525/902—Core-shell

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Paints Or Removers (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

FIELD: building materials. SUBSTANCE: invention relates to an aqueous coating composition containing mixture of from 90 to 99 wt.-% of composition of film- -forming binding agent containing alkaline non-swelling dispersion of type core-envelope obtained by polyaddition of polymer (I), 1-10 wt.-% of dispersion modifying rheological properties prepared by polyaddition of polymer (II). It is required that the total content of (meth)acrylic acid in 100 parts of polymer (I) prepared by polyaddition was less 1.75 wt.-%. An aqueous composition can be used as a basic layer/transparent layer. Such application is characterized by reducing effect of penetration inward as compared with the known system of basic layer/transparent layer. EFFECT: enhanced and valuable properties of composition. 13 cl, 5 tbl, 22 ex

Description

Текст описания в факсимильном виде (см. графическую часть) То Description text in facsimile form (see graphic part)

Claims (13)

1. Водная композиция покрытия, содержащая смесь 90-99 мас.% композиции пленкообразующего связующего, включающей щелочную ненабухаемую дисперсию типа ядро-оболочка полученного полиприсоединением полимера (I), и 1-10 мас.% модифицирующей реологические свойства дисперсии полученного полиприсоединением полимера (II), причем сумма массовых процентов, приведенных для композиции пленкообразующего связующего и дисперсии (II), всегда равна 100 мас.%, где дисперсию (I) полимера получают в две или более стадии эмульсионной полимеризацией, и ее получают в результате сополимеризации на первой стадии (1) 60-95 мас.ч. (рассчитанных на 100 мас.ч. общего количества полученного полиприсоединением полимера (I) смеси мономеров А, состоящей из (i) 65-100 мол.% смеси, (a) 10-98 мол.% (цикло)алкил(мет)акрилата, у которого (цикло)алкильная группа содержит 4-12 углеродных атомов, (b) 0-55 мол.% стирола, (c) 2-15 мол.% гидроксиалкил(мет)акрилата и (d) 0-20 мол.% ди(цикло)алкилмалеата и/или фумарата, у которого (цикло)алкильные группы содержат 4-12 углеродных атомов, причем сумма мол.%, приведенных для мономеров (а), (b), (с) и (d), всегда равна 100 мол.% и (ii) 0-35 мол.% другого сополимеризуемого мономера с одной ненасыщенностью этиленового типа, причем сумма мольных процентов, приведенных для компонентов (i) и (ii), всегда равна 100 мол.%, и в результате сополимеризации на последующей стадии (2) 5-40 мас.ч., рассчитанных на 100 мас.ч. общего количества полученного полиприсоединением полимера (I) смеси мономеров В, состоящей из (e) 1-10 мол.% (мет)акриловой кислоты, (f) 2-20 мол.% гидроксиалкил (мет)акрилата, (g) 0-55 мол.% стирола и (h) 15-97 мол.% другого сополимеризуемого мономера с одной ненасыщенностью этиленового типа, причем сумма мольных процентов, приведенных для мономеров (е), (f), (g) и (h), всегда равна 100 мол.%, причем группы карбоновой кислоты, источником которых служит (мет)акриловая кислота, по меньшей мере частично нейтрализованы, с получением несшитого полученного полиприсоединением полимера I, в результате чего общее содержание (мет)акриловой кислоты в 100 ч. общего количества полученного полиприсоединением полимера (I) будет меньше 1,75 мас.% и где дисперсию полимера (II) получают эмульсионной полимеризацией, и ее получают в результате сополимеризации (iii) 99,5-99,99 мас.ч., рассчитанных на 100 мас.ч. общего количества полученного полиприсоединением полимера (II) смеси мономеров С, состоящей из (j) 10-80 мас.% (цикло)алкил(мет)акрилата, (k) 20-50 мас.% (мет)акриловой кислоты, (m) 0-20 мас.% гидроксиалкил(мет)акрилата и (n) 0-20 мас.% другого сополимеризуемого мономера с одной ненасыщенностью этиленового типа, причем сумма массовых процентов, приведенных для мономеров (j), (k), (m) и (n), всегда равна 100 мас.% и (iv) 0,01-0,5 мас.ч., рассчитанных на 100 мас.ч. общего количества полученного полиприсоединением полимера (II) соединения по меньшей мере с двумя ненасыщенными группами, причем группы карбоновой кислоты, источником которых служит (мет)акриловая кислота, по меньшей мере частично нейтрализованы.1. An aqueous coating composition containing a mixture of 90-99 wt.% A film-forming binder composition comprising an alkaline, non-swellable core-shell dispersion obtained by polyaddition polymer (I), and 1-10 wt.% Modifying the rheological properties of the dispersion obtained by polyaddition polymer (II) moreover, the sum of the weight percent given for the composition of the film-forming binder and dispersion (II) is always equal to 100 wt.%, where the polymer dispersion (I) is obtained in two or more stages by emulsion polymerization, and it is obtained by cutting ltate copolymerization in a first step (1) 60-95 parts by weight (calculated on 100 parts by weight of the total amount obtained by polyaddition of the polymer (I) of the mixture of monomers A, consisting of (i) 65-100 mol.% of the mixture, (a) 10-98 mol.% (cyclo) alkyl (meth) acrylate in which the (cyclo) alkyl group contains 4-12 carbon atoms, (b) 0-55 mol.% styrene, (c) 2-15 mol.% hydroxyalkyl (meth) acrylate and (d) 0-20 mol.% di (cyclo) alkyl maleate and / or fumarate, in which (cyclo) alkyl groups contain 4-12 carbon atoms, and the sum of mol.% given for monomers (a), (b), (c) and (d) is always equal to 100 mol.% and (ii) 0-35 mol.% of another copolymerizable monomer with one unsaturation of the ethylene type, and the sum of the molar percentages given for components (i) and (ii) is always equal to 100 mol.%, and as a result of copolymerization in the next step (2), 5-40 wt.h., calculated on 100 wt. including the total amount obtained by polyaddition of polymer (I) of the mixture of monomers B, consisting of (e) 1-10 mol.% (meth) acrylic acid, (f) 2-20 mol.% hydroxyalkyl (meth) acrylate, (g) 0 -55 mol% of styrene and (h) 15-97 mol% of another copolymerizable monomer with one ethylene type unsaturation, the sum of the molar percent given for the monomer s (e), (f), (g) and (h) is always equal to 100 mol%, and the carboxylic acid groups, the source of which is (meth) acrylic acid, are at least partially neutralized, to obtain an uncrosslinked polymer obtained by polyaddition I, as a result of which the total content of (meth) acrylic acid in 100 parts of the total amount of polymer (I) obtained by polyaddition is less than 1.75 wt.% And where the polymer dispersion (II) is obtained by emulsion polymerization, and it is obtained by copolymerization ( iii) 99.5-99.99 parts by weight calculated on 100 parts by weight the total amount obtained by polyaddition of polymer (II) of the mixture of monomers C, consisting of (j) 10-80 wt.% (cyclo) alkyl (meth) acrylate, (k) 20-50 wt.% (meth) acrylic acid, (m) 0-20 wt.% Hydroxyalkyl (meth) acrylate and (n) 0-20 wt.% Another copolymerizable monomer with one ethylene type unsaturation, the sum of the weight percent given for monomers (j), (k), (m) and (n) is always equal to 100 wt.% and (iv) 0.01-0.5 parts by weight, calculated on 100 parts by weight. the total amount of the compound obtained by polyaddition of polymer (II) with at least two unsaturated groups, the carboxylic acid groups, the source of which is (meth) acrylic acid, are at least partially neutralized. 2. Композиция по п.1, отличающая тем, что смесь мономеров А состоит из (i) 80-100 мол.% смеси, (a) 30-95 мол.% (цикло)алкил(мет)акрилата, у которого (цикло)алкильная группа содержит 4-12 углеродных атомов, (b) 0-50 мол.% стирола, (c) 5-12 мол.% гидроксиалкил(мет)акрилата и (d) 0-8 мол.% ди(цикло)алкилмалеата и/или - фумарата, у которого (цикло)алкильные группы содержат 4-12 углеродных атомов, и (ii) 0-20 мол.% другого сополимеризуемого мономера с одной ненасыщенностью этиленового типа.2. The composition according to claim 1, characterized in that the mixture of monomers A consists of (i) 80-100 mol.% Of the mixture, (a) 30-95 mol.% (Cyclo) alkyl (meth) acrylate, in which (cyclo ) the alkyl group contains 4-12 carbon atoms, (b) 0-50 mol% of styrene, (c) 5-12 mol% of hydroxyalkyl (meth) acrylate and (d) 0-8 mol% of di (cyclo) alkyl maleate and / or a fumarate in which (cyclo) alkyl groups contain 4-12 carbon atoms, and (ii) 0-20 mol% of another copolymerizable monomer with one ethylene type unsaturation. 3. Композиция по п.1 или 2, отличающаяся тем, что смесь мономеров В состоит из (e) 5-8 мол.% (мет)акриловой кислоты, (f) 5-12 мол.% гидроксиалкил (мет)акрилата, (g) 0-30 мол.% стирола и (h) 50-90 мол.% другого сополимеризуемого мономера с одной ненасыщенностью этиленового типа.3. The composition according to claim 1 or 2, characterized in that the mixture of monomers B consists of (e) 5-8 mol.% (Meth) acrylic acid, (f) 5-12 mol.% Hydroxyalkyl (meth) acrylate, ( g) 0-30 mol% of styrene; and (h) 50-90 mol% of another copolymerizable monomer with one ethylene type unsaturation. 4. Композиция по любому из пп.1-3, отличающаяся тем, что общее содержание (мет)акриловой кислоты в 100 ч. общего количества полученного полиприсоединением полимера (I) находится в диапазоне 0,5-1,4 мас.%.4. The composition according to any one of claims 1 to 3, characterized in that the total content of (meth) acrylic acid in 100 parts by weight of the total amount of polymer (I) obtained by polyaddition is in the range of 0.5-1.4 wt.%. 5. Композиция по любому из пп.1-4, отличающаяся тем, что смесь мономеров С состоит из (j) 50-70 мас.% (цикло)алкил(мет)акрилата, (k) 30-40 мас.% (мет)акриловой кислоты, (m) 0-5 мас.% гидроксиалкил(мет)акрилата и (n) 0-5 мас.% другого сополимеризуемого мономера с одной ненасыщенностью этиленового типа.5. The composition according to any one of claims 1 to 4, characterized in that the mixture of monomers C consists of (j) 50-70 wt.% (Cyclo) alkyl (meth) acrylate, (k) 30-40 wt.% (Meth ) acrylic acid, (m) 0-5 wt.% hydroxyalkyl (meth) acrylate and (n) 0-5 wt.% another copolymerizable monomer with one ethylene type unsaturation. 6. Композиция по любому из пп.1-5, отличающаяся тем, что дисперсию полимера (II) получают эмульсионной полимеризацией (iii) 99,85-99,95 мас.ч. смеси мономеров С и (iv) 0,05-0,15 мас.ч. соединения, имеющего по меньшей мере две ненасыщенные группы.6. The composition according to any one of claims 1 to 5, characterized in that the dispersion of the polymer (II) is obtained by emulsion polymerization (iii) of 99.85-99.95 wt.h. a mixture of monomers C and (iv) 0.05-0.15 wt.h. a compound having at least two unsaturated groups. 7. Композиция по любому из пп.1-6, отличающаяся тем, что соединение, имеющее по меньшей мере две ненасыщенные группы, имеет по меньшей мере одну аллильную группу.7. The composition according to any one of claims 1 to 6, characterized in that the compound having at least two unsaturated groups has at least one allyl group. 8. Композиция по п.7, отличающаяся тем, что соединение, имеющее по меньшей мере две ненасыщенные группы, выбирают из диаллилфталата, аллилметакрилата и триаллилизоцианурата.8. The composition according to claim 7, characterized in that the compound having at least two unsaturated groups is selected from diallyl phthalate, allyl methacrylate and triallyl isocyanurate. 9. Композиция по любому из пп.1-8, отличающаяся тем, что композиция пленкообразующего связующего содержит в дополнение к щелочной ненабухаемой дисперсии типа ядро-оболочка полученного полиприсоединением полимера (I) по меньшей мере один разбавляемый водой материал.9. The composition according to any one of claims 1 to 8, characterized in that the film-forming binder composition contains, in addition to an alkaline, non-swellable core-shell dispersion obtained by polyaddition polymer (I), at least one water-dilutable material. 10. Композиция по п.9, отличающаяся тем, что композиция пленкообразующего связующего может содержать от 0,1 до 99,9 мас.% щелочной ненабухаемой дисперсии типа ядро-оболочка полученного полиприсоединением полимера (I) и от 99,9 до 0,1 мас.% по меньшей мере одного разбавляемого водой материала, где сумма массовых процентов, приведенных для дисперсии (I) и разбавляемого водой материала (материалов), всегда равна 100 мас.%.10. The composition according to claim 9, characterized in that the film-forming binder composition may contain from 0.1 to 99.9 wt.% Alkaline non-swellable dispersion of the core-shell type obtained by polyaddition polymer (I) and from 99.9 to 0.1 wt.% at least one water-dilutable material, where the sum of the weight percent given for dispersion (I) and water-dilutable material (s) is always 100% by weight. 11. Композиция по п.9 или 10, отличающаяся тем, что разбавляемый водой материал выбирают из алкидных смол, сложных полиэфиров, полиуретанов и их смесей.11. The composition according to claim 9 or 10, characterized in that the material diluted with water is selected from alkyd resins, polyesters, polyurethanes and mixtures thereof. 12. Композиция по п.11, отличающаяся тем, что разбавляемым водой материалом является полиуретан.12. The composition according to claim 11, characterized in that the material diluted with water is polyurethane. 13. Композиция основного слоя, содержащая водную композицию покрытия по любому из пп.1-12.13. The composition of the main layer containing the aqueous coating composition according to any one of claims 1 to 12.
RU2001101935/04A 1998-06-23 1999-06-22 Aqueous coating composition containing polymer and modifying agent of rheological property prepared by polyaddition RU2219205C2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP98111529.8 1998-06-23
EP98111529 1998-06-23

Publications (2)

Publication Number Publication Date
RU2001101935A RU2001101935A (en) 2003-12-10
RU2219205C2 true RU2219205C2 (en) 2003-12-20

Family

ID=8232160

Family Applications (1)

Application Number Title Priority Date Filing Date
RU2001101935/04A RU2219205C2 (en) 1998-06-23 1999-06-22 Aqueous coating composition containing polymer and modifying agent of rheological property prepared by polyaddition

Country Status (14)

Country Link
US (1) US6376575B2 (en)
EP (1) EP1093496B1 (en)
JP (1) JP4759136B2 (en)
KR (1) KR20010053116A (en)
CN (1) CN1306559A (en)
AT (1) ATE258212T1 (en)
AU (1) AU752913B2 (en)
BR (1) BR9911481A (en)
CA (1) CA2335757A1 (en)
DE (1) DE69914333T2 (en)
ES (1) ES2215391T3 (en)
RU (1) RU2219205C2 (en)
TW (1) TW500780B (en)
WO (1) WO1999067339A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2738180C1 (en) * 2017-06-29 2020-12-09 Ппг Индастриз Огайо, Инк. Aqueous dispersions, coating compositions formed by aqueous dispersions, and multilayer coatings

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19903391A1 (en) 1999-01-29 2000-08-03 Bayer Ag Aqueous coating agent, process for its preparation and its use
WO2001038448A1 (en) * 1999-11-22 2001-05-31 3M Innovative Properties Company Water-based coating composition
US6822040B2 (en) * 2001-09-25 2004-11-23 Basf Corporation Basecoat composition with improved repair properties
JP2003286324A (en) * 2002-01-25 2003-10-10 Daicel Chem Ind Ltd Aqueous resin dispersion and its production method
EP1439198A1 (en) * 2003-01-20 2004-07-21 Akzo Nobel N.V. Resin composition
DE102004016647A1 (en) * 2004-03-31 2005-10-20 Basf Ag Coating materials based on low-emission binders
DE102004029073A1 (en) * 2004-06-16 2005-12-29 Degussa Ag Paint formulation with improved rheological properties
JP5116486B2 (en) * 2005-06-09 2013-01-09 関西ペイント株式会社 Method for forming glittering multilayer coating film
CN101302264B (en) * 2007-05-11 2010-11-17 北京化工大学 Polymer emulsion having unsaturated double bond and preparation thereof
US7449287B1 (en) * 2008-01-30 2008-11-11 Eastman Kodak Company Pearlescent textured imaging supports
EP2143743A1 (en) 2008-07-08 2010-01-13 Akzo Nobel Coatings International B.V. Use of derivatives of dianhydrohexitol in the preparation of resins
CA2734391A1 (en) * 2008-09-04 2010-03-11 E. I. Dupont De Nemours And Company Aqueous coating composition
CN104893527B (en) * 2015-06-09 2017-11-03 浩力森涂料（上海）有限公司 A kind of aqueous polyurethane coating for improving limiting film thickness and preparation method thereof
TWI705114B (en) 2015-08-31 2020-09-21 美商羅門哈斯公司 Aqueous multi-stage copolymer compositions for use in leather topcoats
US20190040172A1 (en) * 2016-02-04 2019-02-07 Isp Investments Llc Aqueous emulsion polymers as rheology modifiers, compositions thereof, and method of use
KR20220007138A (en) * 2019-05-13 2022-01-18 피피지 인더스트리즈 오하이오 인코포레이티드 Coating compositions and systems and methods for applying such coating compositions
BR112023025037A2 (en) * 2021-06-15 2024-02-27 Allnex Netherlands Bv AQUEOUS POLYACRYLATE DISPERSION, AQUEOUS COATING COMPOSITION, METHOD FOR MANUFACTURING A COATING COMPOSITION, USE OF THE AQUEOUS COATING COMPOSITION, AND, METAL OR PLASTIC SUBSTRATE

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT580324A (en) * 1956-11-21
US3821145A (en) * 1972-12-22 1974-06-28 Du Pont Aqueous coating composition of an acrylic graft copolymer,a linear acrylic polymer and a cross-linking agent
JPS5649760A (en) * 1979-09-29 1981-05-06 Kansai Paint Co Ltd Water-dispersed coating composition
EP0038127B1 (en) 1980-04-14 1984-10-17 Imperial Chemical Industries Plc Multi-layer coating process involving use of aqueous basecoat composition containing crosslinked polymer microparticles and having a pseudoplastic or thixotropic character
JPS5763318A (en) * 1980-10-04 1982-04-16 Japan Atom Energy Res Inst Polymer emulsion and its production
JPS59210918A (en) * 1983-05-17 1984-11-29 Nippon Paint Co Ltd Thermosetting polymer emulsion
US4973621A (en) 1987-04-07 1990-11-27 Akzo N.V. Aqueous coating composition based on a dispersion of an addition polymer, especially suited to be used in an aqueous base coat
JP2634167B2 (en) * 1987-05-20 1997-07-23 日本ペイント株式会社 Aqueous paint composition
JP2680227B2 (en) * 1992-07-16 1997-11-19 フジケミ東京株式会社 Tile wall repair method
WO1994004581A1 (en) * 1992-08-13 1994-03-03 Ppg Industries, Inc. Waterborne latices adapted for spray application
JPH1072510A (en) * 1995-07-17 1998-03-17 Daiso Co Ltd Aqueous emulsion containing fine particles of cross-linked ally copolymer

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2738180C1 (en) * 2017-06-29 2020-12-09 Ппг Индастриз Огайо, Инк. Aqueous dispersions, coating compositions formed by aqueous dispersions, and multilayer coatings

Also Published As

Publication number Publication date
ATE258212T1 (en) 2004-02-15
US6376575B2 (en) 2002-04-23
JP2002518575A (en) 2002-06-25
DE69914333T2 (en) 2004-11-18
AU4775999A (en) 2000-01-10
AU752913B2 (en) 2002-10-03
EP1093496B1 (en) 2004-01-21
EP1093496A1 (en) 2001-04-25
DE69914333D1 (en) 2004-02-26
CA2335757A1 (en) 1999-12-29
ES2215391T3 (en) 2004-10-01
WO1999067339A1 (en) 1999-12-29
JP4759136B2 (en) 2011-08-31
BR9911481A (en) 2001-03-20
CN1306559A (en) 2001-08-01
TW500780B (en) 2002-09-01
US20010005732A1 (en) 2001-06-28
KR20010053116A (en) 2001-06-25

Similar Documents

Publication Publication Date Title
RU2219205C2 (en) Aqueous coating composition containing polymer and modifying agent of rheological property prepared by polyaddition
RU2001101935A (en) AQUEOUS COATING COMPOSITION CONTAINING A POLYMER RECEIVED BY A POLYJOINT AND A MODULATOR OF RHEOLOGICAL PROPERTIES
AU2000273682A1 (en) Copolymers and oil- and water-repellent compositions containing them
CZ20024179A3 (en) Dispersed coating compositions free of preservative formulations
DK0777712T3 (en) Polymer blends and their use as additives for petroleum intermediate distillates
AU4610801A (en) Thermoplastic polyesters with improved shock-proof properties and impact modifying composition
EA200400190A1 (en) LATEX ACRYLIC POLYMER DISPERSIONS AS ADDITIVES TO INHIBIT PAROFFIN DEPOSITS IN RAW OIL AND CONTAINING THEIR COMPOSITIONS
WO2003099904A3 (en) Fluorochemical composition comprising a fluorinated polyether and treatment of a fibrous substrate therewith
PL1739110T3 (en) Polyethylene composition of improved processability
BR8801631A (en) WATER COATING COMPOSITION, BASIC COVERAGE AND WATER DISPERSION OF AN ADDITION POLYMER
CA2219208A1 (en) Aqueous dispersion of a peelable coating composition
EP0999736B1 (en) Removable protective coating
US5102946A (en) Stabilized chlorinated resin latex
WO2002000800A3 (en) Acrylic adhesive compositions comprising acrylate microspheres
EP0939105A4 (en) Durable water repellent and coated articles
CA2325785A1 (en) Thermoplastic polyester compositions with improved impact strength
EP1125982A3 (en) Thermoplastic fluorinated polymers
CA2325784A1 (en) Thermoplastic polyester compositions with improved impact strength
CA1159987A (en) Alkali-soluble hot melt adhesive compositions
JPS63199258A (en) Low fogging transparent composition and its production
CN108291109B (en) Coating composition
FI109356B (en) Aqueous polymeric dispersions for coating wood
EP1378769A3 (en) Water-absorptive contact lens and method of producing the same
US5691033A (en) Coating compositions containing aluminum pigment and methods of coating
CA2512027A1 (en) Compositions and treated substrates having reversibly adaptable surface energy properties and method for making the same

Legal Events

Date Code Title Description
MM4A The patent is invalid due to non-payment of fees

Effective date: 20040623