RU2111944C1 - Explosive suspension composition - Google Patents
Explosive suspension composition Download PDFInfo
- Publication number
- RU2111944C1 RU2111944C1 RU96118533A RU96118533A RU2111944C1 RU 2111944 C1 RU2111944 C1 RU 2111944C1 RU 96118533 A RU96118533 A RU 96118533A RU 96118533 A RU96118533 A RU 96118533A RU 2111944 C1 RU2111944 C1 RU 2111944C1
- Authority
- RU
- Russia
- Prior art keywords
- explosive
- composition
- composition according
- aqueous solution
- nitrate
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims abstract description 32
- 239000002360 explosive Substances 0.000 title claims abstract description 25
- 239000000725 suspension Substances 0.000 title claims abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000007864 aqueous solution Substances 0.000 claims abstract description 5
- 150000002334 glycols Chemical class 0.000 claims abstract description 5
- 239000000654 additive Substances 0.000 claims abstract description 4
- 239000000843 powder Substances 0.000 claims abstract description 4
- 229910002651 NO3 Inorganic materials 0.000 claims description 6
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 6
- 150000003841 chloride salts Chemical class 0.000 claims description 4
- 239000003292 glue Substances 0.000 claims description 2
- 239000004449 solid propellant Substances 0.000 claims description 2
- ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 abstract description 3
- 230000035945 sensitivity Effects 0.000 abstract description 3
- 239000000853 adhesive Substances 0.000 abstract description 2
- 230000001070 adhesive effect Effects 0.000 abstract description 2
- 238000005422 blasting Methods 0.000 abstract description 2
- 238000005474 detonation Methods 0.000 abstract description 2
- 238000004880 explosion Methods 0.000 abstract description 2
- 238000005065 mining Methods 0.000 abstract description 2
- SPSSULHKWOKEEL-UHFFFAOYSA-N 2,4,6-trinitrotoluene Chemical group CC1=C([N+]([O-])=O)C=C([N+]([O-])=O)C=C1[N+]([O-])=O SPSSULHKWOKEEL-UHFFFAOYSA-N 0.000 abstract 1
- QBWCMBCROVPCKQ-UHFFFAOYSA-N chlorous acid Chemical class OCl=O QBWCMBCROVPCKQ-UHFFFAOYSA-N 0.000 abstract 1
- 230000000694 effects Effects 0.000 abstract 1
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Inorganic materials [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 abstract 1
- 235000010333 potassium nitrate Nutrition 0.000 abstract 1
- 230000035939 shock Effects 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- -1 etc. Chemical class 0.000 description 2
- 230000008014 freezing Effects 0.000 description 2
- 238000007710 freezing Methods 0.000 description 2
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- 239000004375 Dextrin Substances 0.000 description 1
- 229920001353 Dextrin Polymers 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- FJWGYAHXMCUOOM-QHOUIDNNSA-N [(2s,3r,4s,5r,6r)-2-[(2r,3r,4s,5r,6s)-4,5-dinitrooxy-2-(nitrooxymethyl)-6-[(2r,3r,4s,5r,6s)-4,5,6-trinitrooxy-2-(nitrooxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-3,5-dinitrooxy-6-(nitrooxymethyl)oxan-4-yl] nitrate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O)O[C@H]1[C@@H]([C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@@H](CO[N+]([O-])=O)O1)O[N+]([O-])=O)CO[N+](=O)[O-])[C@@H]1[C@@H](CO[N+]([O-])=O)O[C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O FJWGYAHXMCUOOM-QHOUIDNNSA-N 0.000 description 1
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
- 229940037003 alum Drugs 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- GRWVQDDAKZFPFI-UHFFFAOYSA-H chromium(III) sulfate Chemical compound [Cr+3].[Cr+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O GRWVQDDAKZFPFI-UHFFFAOYSA-H 0.000 description 1
- 235000019425 dextrin Nutrition 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- 229940079938 nitrocellulose Drugs 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
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Abstract
Description
Изобретение относится к взрывчатым составам, предназначенным для ведения взрывных работ в горнодобывающей промышленности. The invention relates to explosive compositions intended for blasting in the mining industry.
Известен суспензионный взрывчатый состав, содержащий по массе 58-85% бездымного пороха и 15-42% воды или водного ненасыщенного раствора селитр (патент РФ N 2021239, 5 CO 6 B 25/24, 25/26, 23.07.92). Known suspension explosive composition containing by weight 58-85% smokeless powder and 15-42% water or an aqueous unsaturated solution of nitrate (
Данный состав в качестве прототипа. Состав имеет невысокие взрывчатые характеристики и недостаточную сырьевую базу. This composition as a prototype. The composition has low explosive characteristics and an insufficient raw material base.
Технический результат изобретения - утилизация взрывчатых веществ и взрывчатых составов военного назначения и повышение взрывчатых характеристик. The technical result of the invention is the disposal of explosives and explosive compositions for military purposes and increase explosive characteristics.
Это достигается тем, что во взрывчатом составе, содержащем взрывчатую основу и воду или водный раствор селитр, в качестве взрывчатой основы используют утилизированные ВВ или ВС. This is achieved by the fact that in an explosive composition containing an explosive base and water or an aqueous solution of nitrate, utilized explosives or aircraft are used as the explosive base.
Для утилизации бездымных порохов (пироксилиновых, баллиститных) или твердого топлива состав может дополнительно содержать их в количестве 1-89 мас. %. For disposal of smokeless powders (pyroxylin, ballistic) or solid fuel, the composition may additionally contain them in an amount of 1-89 wt. %
Состав может содержать, мас.%: ненасыщенный водный раствор селитр концентрации 1-64 в количестве 10-50, 1-20 хлористых солей, 1-50 гликолей, 0,3-10 клея и 0,01-0,5 структурообразующей добавки. The composition may contain, wt.%: Unsaturated aqueous solution of nitrate concentration of 1-64 in the amount of 10-50, 1-20 chloride salts, 1-50 glycols, 0.3-10 glue and 0.01-0.5 structure-forming additives.
В суспензионном взрывчатом составе используются взрывчатые вещества и составы, извлекаемые из боеприпасов (A-IX-1, A-IX-2, ТГ-40, ТГ-50 и др.). In suspension explosive composition, explosives and compositions extracted from ammunition (A-IX-1, A-IX-2, TG-40, TG-50, etc.) are used.
Пример. К 700 г взрывчатого состава ТГ-40 (тротил - 40 мас.%, гексоген - 60 мас.%) добавляют 300 г воды. Получают 1000 г взрывчатого состава. Аналогичным образом изготавливают другие образцы взрывчатых составов, свойства которых приведены в таблице. Example. To 700 g of explosive composition TG-40 (TNT - 40 wt.%, RDX - 60 wt.%) Add 300 g of water. Get 1000 g of explosive composition. Other samples of explosive compositions, the properties of which are given in the table, are made in a similar manner.
Текучесть образцов определяют по времени растекания по поверхности образца объемами 250 мл или по времени истечения из трубки. The fluidity of the samples is determined by the spreading time on the surface of the sample with volumes of 250 ml or by the time of outflow from the tube.
Из данных таблицы видно, что составы характеризуются высокой текучестью (свободно льются), обладают высокой теплотой взрыва и скоростью детонации и низкой чувствительностью к механическим воздействиям. При этом составы, содержащие растворы селитр, хлористые соли или гликоли, дополнительно имеют пониженную температуру замерзания. Для растворов аммиачной и кальциевой селитр наименьшую температуру замерзания имеют их 40-45% растворы. From the data of the table it can be seen that the compositions are characterized by high fluidity (freely pour), have a high heat of explosion and detonation speed and low sensitivity to mechanical stress. Moreover, compositions containing solutions of nitrate, chloride salts or glycols, additionally have a low freezing temperature. For solutions of ammonia and calcium nitrate, the lowest freezing point is their 40-45% solutions.
В составе используются гликоли, такие как этиленгликоль, диэтиленгликоль, этилцелозольв и др. , и хлористые соли, такие как хлористый натрий, хлористый кальций и др. The composition uses glycols, such as ethylene glycol, diethylene glycol, ethyl cellosolve, etc., and chloride salts, such as sodium chloride, calcium chloride, etc.
Для уменьшения скорости испарения воды или растворов предлагается использовать их загущение клеями (натрийкарбоксиметилцеллюлоза, декстрин, крахмал и др.) и структурообразующими добавками (сульфат хрома, бура, квасцы и др.). To reduce the rate of evaporation of water or solutions, it is proposed to use their thickening with adhesives (sodium carboxymethyl cellulose, dextrin, starch, etc.) and structure-forming additives (chromium sulfate, borax, alum, etc.).
Суспензионный взрывчатый состав может укупориваться в герметичную тару или в патроны из водонепроницаемой оболочки (полиэтиленовой и др.). Suspension explosive composition can be sealed in airtight containers or in cartridges from a waterproof shell (polyethylene, etc.).
При извлечении ВВ и ВС из боеприпасов вымыванием струей воды или раствора последние могут использоваться в составе суспензионного ВВ. When extracting explosives and aircraft from ammunition by washing with a stream of water or solution, the latter can be used as part of a suspension explosive.
Способ получения предложенного состава состоит в том, что утилизированные тротил и/или взрывчатые составы перемешиваются или заливаются жидкостью. A method of obtaining the proposed composition is that the disposed of TNT and / or explosive compositions are mixed or filled with liquid.
Claims (7)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| RU96118533A RU2111944C1 (en) | 1996-09-17 | 1996-09-17 | Explosive suspension composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| RU96118533A RU2111944C1 (en) | 1996-09-17 | 1996-09-17 | Explosive suspension composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2111944C1 true RU2111944C1 (en) | 1998-05-27 |
| RU96118533A RU96118533A (en) | 1998-12-27 |
Family
ID=20185498
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU96118533A RU2111944C1 (en) | 1996-09-17 | 1996-09-17 | Explosive suspension composition |
Country Status (1)
| Country | Link |
|---|---|
| RU (1) | RU2111944C1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2279419C2 (en) * | 2003-05-15 | 2006-07-10 | Виктор Степанович Прокопенко | Method of preparing water-containing blasting material charge, water-containing liquid (options), and water-containing blasting material |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2021239C1 (en) * | 1992-07-23 | 1994-10-15 | Старокожев Владимир Филиппович | Explosive composition |
-
1996
- 1996-09-17 RU RU96118533A patent/RU2111944C1/en not_active IP Right Cessation
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2021239C1 (en) * | 1992-07-23 | 1994-10-15 | Старокожев Владимир Филиппович | Explosive composition |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2279419C2 (en) * | 2003-05-15 | 2006-07-10 | Виктор Степанович Прокопенко | Method of preparing water-containing blasting material charge, water-containing liquid (options), and water-containing blasting material |
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| Date | Code | Title | Description |
|---|---|---|---|
| MM4A | The patent is invalid due to non-payment of fees |
Effective date: 20080918 |