RU2017124359A - LUBRICANT COMPOSITION INHIBITING ALPHA-OLEFIN ADSORPTION, METHOD FOR ADSORPTION INHIBITION AND ADSORPTION INHIBITOR - Google Patents

LUBRICANT COMPOSITION INHIBITING ALPHA-OLEFIN ADSORPTION, METHOD FOR ADSORPTION INHIBITION AND ADSORPTION INHIBITOR Download PDF

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RU2017124359A
RU2017124359A RU2017124359A RU2017124359A RU2017124359A RU 2017124359 A RU2017124359 A RU 2017124359A RU 2017124359 A RU2017124359 A RU 2017124359A RU 2017124359 A RU2017124359 A RU 2017124359A RU 2017124359 A RU2017124359 A RU 2017124359A
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acid derivative
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Хироюки ТАДЗАКИ
Мицухиро НАГАКАРИ
Хироси КАНЕКО
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Шелл Интернэшнл Рисерч Маатсхаппий Б.В.
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    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M141/00—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential
    • C—CHEMISTRY; METALLURGY
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    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
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    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
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    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
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    • C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
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    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
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    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
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    • C10M2207/26—Overbased carboxylic acid salts
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    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
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    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C10M2215/064—Di- and triaryl amines
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    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C10M2215/064—Di- and triaryl amines
    • C10M2215/065—Phenyl-Naphthyl amines
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    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/08—Amides
    • C—CHEMISTRY; METALLURGY
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    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/12—Partial amides of polycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/223—Five-membered rings containing nitrogen and carbon only
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    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/046—Overbasedsulfonic acid salts
    • C—CHEMISTRY; METALLURGY
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    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
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Claims (22)

1. Смазочная композиция, содержащая в качестве базового масла любое из масел из группы III, группы IV и полиизобутиленов, отнесенных к группе V в соответствии с классификацией базовых масел по API, или их смесь, и α-олефин, присутствующий в количестве 1 мас.% или менее относительно общей массы композиции, причем к композиции добавлены производное саркозиновой кислоты, производное аспарагиновой кислоты или производное диэтаноламина, или их смеси.1. A lubricating composition containing as a base oil any of the oils from group III, group IV and polyisobutylenes assigned to group V in accordance with the classification of base oils according to API, or a mixture thereof, and α-olefin, present in an amount of 1 wt. % or less relative to the total weight of the composition, wherein a sarcosic acid derivative, an aspartic acid derivative or a diethanolamine derivative, or mixtures thereof are added to the composition. 2. Смазочная композиция по п. 1, отличающаяся тем, что производное саркозиновой кислоты описывается следующей формулой 1:2. The lubricating composition according to claim 1, characterized in that the sarcosinic acid derivative is described by the following formula 1:
Figure 00000001
Figure 00000001
 где функциональная группа R1 представляет собой алкил C16-20;where the functional group R 1 represents an alkyl C 16-20 ; причем производное аспарагиновой кислоты описывается следующей формулой 2:moreover, the aspartic acid derivative is described by the following formula 2:
Figure 00000002
Figure 00000002
 где функциональные группы R2 и R3 обозначают водород или один и тот же или разный алкил C3-6, алкенил, или гидроксиалкил; функциональная группа R4 обозначает алкил C1-30 или алкенил, алкил C1-30, имеющий эфирную связь, или гидроксиалкил; и функциональная группа R5 обозначает насыщенную или ненасыщенную группу C1-30 карбоновой кислоты или алкил C1-30, алкенил, или гидроксиалкил; иwhere the functional groups R 2 and R 3 are hydrogen or the same or different C 3-6 alkyl, alkenyl, or hydroxyalkyl; the R 4 functional group is C 1-30 alkyl or alkenyl, C 1-30 alkyl having an ether bond, or hydroxyalkyl; and the functional group R 5 is a saturated or unsaturated group of C 1-30 carboxylic acid or C 1-30 alkyl, alkenyl, or hydroxyalkyl; and причем производное диэтаноламина описывается следующей формулой 3:moreover, the diethanolamine derivative is described by the following formula 3:
Figure 00000003
Figure 00000003
 где функциональная группа R6 обозначает алкил C16-20;where the functional group R 6 denotes alkyl C 16-20 ; 3. Смазочная композиция по п. 1 или 2, отличающаяся тем, что количество производного саркозиновой кислоты или производного диэтаноламина составляет от 0,001 до 3 мас.% относительно общего количества композиции, или количество производного аспарагиновой кислоты составляет от 0,005 до 3 мас.% относительно общего количества композиции.3. The lubricating composition according to claim 1 or 2, characterized in that the amount of sarcosinic acid derivative or diethanolamine derivative is from 0.001 to 3 wt.% Relative to the total amount of the composition, or the amount of aspartic acid derivative is from 0.005 to 3 wt.% Relative to the total amount of composition. 4. Способ ингибирования адсорбции α-олефина, присутствующего в смазочной композиции, на поверхности металла, когда смазочная композиция содержит в качестве базового масла любое из масел из группы III, группы IV и полиизобутилены, отнесенные к группе V в соответствии с классификацией базовых масел по API, или их смесь, и α-олефин, присутствующий в количестве 1 мас.% или менее относительно общей массы композиции, этот способ включает добавление к смазочной композиции производного саркозиновой кислоты, производного аспарагиновой кислоты или производного диэтаноламина, или их смеси.4. A method of inhibiting the adsorption of α-olefin present in a lubricant composition on a metal surface, when the lubricant composition contains any of the oils from group III, group IV and polyisobutylene classified as group V in accordance with the API base oil classification as a base oil , or a mixture thereof, and an α-olefin present in an amount of 1 wt.% or less relative to the total weight of the composition, this method comprises adding to the lubricating composition a sarcosinic acid derivative, an aspartic acid derivative or aqueous diethanolamine, or mixtures thereof. 5. Способ ингибирования адсорбции α-олефина по п. 4, отличающийся тем, что производное саркозиновой кислоты описывается следующей формулой 1:5. The method of inhibiting the adsorption of α-olefin according to claim 4, characterized in that the sarcosinic acid derivative is described by the following formula 1:
Figure 00000001
Figure 00000001
 где функциональная группа R1 обозначает алкил C16-20;where the functional group R 1 denotes alkyl C 16-20 ; причем производное аспарагиновой кислоты описывается следующей формулой 2:moreover, the aspartic acid derivative is described by the following formula 2:
Figure 00000002
Figure 00000002
 где функциональные группы R2 и R3 обозначают водород или один и тот же или разный алкил C3-6, алкенил или гидроксиалкил; функциональная группа R4 обозначает алкил C1-30 или алкенил, алкил C1-30, имеющий эфирную связь, или гидроксиалкил; и функциональная группа R5 обозначает насыщенную или ненасыщенную группу C1-30 карбоновой кислоты или алкил C1-30, алкенил или гидроксиалкил; иwhere the functional groups R 2 and R 3 are hydrogen or the same or different C 3-6 alkyl, alkenyl or hydroxyalkyl; the R 4 functional group is C 1-30 alkyl or alkenyl, C 1-30 alkyl having an ether bond, or hydroxyalkyl; and the functional group R 5 is a saturated or unsaturated group of C 1-30 carboxylic acid or C 1-30 alkyl, alkenyl or hydroxyalkyl; and причем производное диэтаноламина описывается следующей формулой 3:moreover, the diethanolamine derivative is described by the following formula 3:
Figure 00000003
Figure 00000003
 где функциональная группа R6 обозначает алкил C16-20;where the functional group R 6 denotes alkyl C 16-20 ; 6. Способ ингибирования адсорбции α-олефина по п. 4 или 5, отличающийся тем, что количество добавленного производного саркозиновой кислоты или производного диэтаноламина составляет от 0,001 до 3 мас.% относительно общего количества композиции, или количество добавленного производного аспарагиновой кислоты составляет от 0,005 до 3 мас.% относительно общего количества композиции. 6. The method of inhibiting the adsorption of α-olefin according to claim 4 or 5, characterized in that the amount of added sarcosinic acid derivative or diethanolamine derivative is from 0.001 to 3 wt.% Relative to the total amount of the composition, or the amount of added aspartic acid derivative is from 0.005 to 3 wt.% Relative to the total amount of composition.
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