RU2016123140A - A method of treating produced or return water using a nucleophilic agent for decontaminating a diluent - Google Patents

A method of treating produced or return water using a nucleophilic agent for decontaminating a diluent Download PDF

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RU2016123140A
RU2016123140A RU2016123140A RU2016123140A RU2016123140A RU 2016123140 A RU2016123140 A RU 2016123140A RU 2016123140 A RU2016123140 A RU 2016123140A RU 2016123140 A RU2016123140 A RU 2016123140A RU 2016123140 A RU2016123140 A RU 2016123140A
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sulfur
nucleophilic agent
well
vitamin
phosphorus
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RU2016123140A
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RU2681326C1 (en
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Брэндон Марк ВИТТУР
Чарлз Дейвид АРМСТРОНГ
Маршалл Г. ОЛТ
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Бейкер Хьюз Инкорпорейтед
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    • EFIXED CONSTRUCTIONS
    • E21EARTH OR ROCK DRILLING; MINING
    • E21BEARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B21/00Methods or apparatus for flushing boreholes, e.g. by use of exhaust air from motor
    • E21B21/06Arrangements for treating drilling fluids outside the borehole
    • E21B21/068Arrangements for treating drilling fluids outside the borehole using chemical treatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09CRECLAMATION OF CONTAMINATED SOIL
    • B09C1/00Reclamation of contaminated soil
    • B09C1/002Reclamation of contaminated soil involving in-situ ground water treatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09CRECLAMATION OF CONTAMINATED SOIL
    • B09C1/00Reclamation of contaminated soil
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09CRECLAMATION OF CONTAMINATED SOIL
    • B09C1/00Reclamation of contaminated soil
    • B09C1/08Reclamation of contaminated soil chemically
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/50Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/54Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using organic material
    • C02F1/56Macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K8/00Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
    • C09K8/52Compositions for preventing, limiting or eliminating depositions, e.g. for cleaning
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K8/00Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
    • C09K8/60Compositions for stimulating production by acting on the underground formation
    • C09K8/62Compositions for forming crevices or fractures
    • C09K8/66Compositions based on water or polar solvents
    • C09K8/68Compositions based on water or polar solvents containing organic compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K8/00Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
    • C09K8/60Compositions for stimulating production by acting on the underground formation
    • C09K8/62Compositions for forming crevices or fractures
    • C09K8/66Compositions based on water or polar solvents
    • C09K8/68Compositions based on water or polar solvents containing organic compounds
    • C09K8/685Compositions based on water or polar solvents containing organic compounds containing cross-linking agents
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K8/00Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
    • C09K8/60Compositions for stimulating production by acting on the underground formation
    • C09K8/84Compositions based on water or polar solvents
    • C09K8/86Compositions based on water or polar solvents containing organic compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K8/00Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
    • C09K8/60Compositions for stimulating production by acting on the underground formation
    • C09K8/84Compositions based on water or polar solvents
    • C09K8/86Compositions based on water or polar solvents containing organic compounds
    • C09K8/88Compositions based on water or polar solvents containing organic compounds macromolecular compounds
    • C09K8/885Compositions based on water or polar solvents containing organic compounds macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K8/00Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
    • C09K8/60Compositions for stimulating production by acting on the underground formation
    • C09K8/84Compositions based on water or polar solvents
    • C09K8/86Compositions based on water or polar solvents containing organic compounds
    • C09K8/88Compositions based on water or polar solvents containing organic compounds macromolecular compounds
    • C09K8/887Compositions based on water or polar solvents containing organic compounds macromolecular compounds containing cross-linking agents
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K8/00Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
    • C09K8/60Compositions for stimulating production by acting on the underground formation
    • C09K8/84Compositions based on water or polar solvents
    • C09K8/86Compositions based on water or polar solvents containing organic compounds
    • C09K8/88Compositions based on water or polar solvents containing organic compounds macromolecular compounds
    • C09K8/90Compositions based on water or polar solvents containing organic compounds macromolecular compounds of natural origin, e.g. polysaccharides, cellulose
    • EFIXED CONSTRUCTIONS
    • E21EARTH OR ROCK DRILLING; MINING
    • E21BEARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B43/00Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
    • E21B43/16Enhanced recovery methods for obtaining hydrocarbons
    • EFIXED CONSTRUCTIONS
    • E21EARTH OR ROCK DRILLING; MINING
    • E21BEARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B43/00Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
    • E21B43/25Methods for stimulating production
    • E21B43/26Methods for stimulating production by forming crevices or fractures
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09CRECLAMATION OF CONTAMINATED SOIL
    • B09C2101/00In situ
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/30Organic compounds
    • C02F2101/32Hydrocarbons, e.g. oil
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/06Contaminated groundwater or leachate
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2208/00Aspects relating to compositions of drilling or well treatment fluids
    • C09K2208/26Gel breakers other than bacteria or enzymes

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Environmental & Geological Engineering (AREA)
  • Geology (AREA)
  • Mining & Mineral Resources (AREA)
  • Soil Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Water Supply & Treatment (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Fluid Mechanics (AREA)
  • Physics & Mathematics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Lubricants (AREA)
  • Preventing Corrosion Or Incrustation Of Metals (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Claims (33)

1. Способ, включающий:1. A method comprising: а) смешивание добываемой воды или возвратной воды из подземного резервуара с серо- или фосфорсодержащим нуклеофильным агентом, где добываемая вода или возвратная вода содержит полимерный загуститель или его остаток, а также разжижитель, содержащий витамин В1 и/или илид,a) mixing produced water or return water from an underground reservoir with a sulfur- or phosphorus-containing nucleophilic agent, where the produced water or return water contains a polymer thickener or its residue, as well as a thinner containing vitamin B1 and / or ylide, б) дезактивацию разжижителя, содержащего витамин В1 и/или илид, в присутствии серо- или фосфорсодержащего нуклеофильного агента для получения воды, пригодной для рециркуляции, иb) deactivating a diluent containing vitamin B1 and / or ylide in the presence of a sulfur or phosphorus nucleophilic agent to produce water suitable for recycling, and в) закачивание рециркуляционной воды в подземный резервуар.c) injection of recirculated water into an underground tank. 2. Способ по п. 1, где подземный резервуар представляет собой газоносную скважину, нефтеносную скважину или геотермальную скважину.2. The method according to p. 1, where the underground reservoir is a gas well, oil well or geothermal well. 3. Способ по п. 1, где серо- или фосфорсодержащий нуклеофильный агент содержит по крайней мере одну неподеленную пару электронов.3. The method of claim 1, wherein the sulfur or phosphorus-containing nucleophilic agent comprises at least one lone pair of electrons. 4. Способ по п. 1, где серо- или фосфорсодержащий нуклеофильный агент представляет собой неорганическое соединение.4. The method of claim 1, wherein the sulfur or phosphorus nucleophilic agent is an inorganic compound. 5. Способ по п. 4, где серо- или фосфорсодержащий нуклеофильный агент содержит серу.5. The method of claim 4, wherein the sulfur or phosphorus nucleophilic agent contains sulfur. 6. Способ по п. 5, где серосодержащий нуклеофильный агент представляет собой сульфит или бисульфит.6. The method of claim 5, wherein the sulfur-containing nucleophilic agent is sulfite or bisulfite. 7. Способ по п. 6, где серо- или фосфорсодержащий нуклеофильный агент представляет собой раствор сульфита натрия.7. The method according to p. 6, where the sulfur or phosphorus nucleophilic agent is a solution of sodium sulfite. 8. Способ по п. 1, где полимерный загуститель представляет собой (i) синтетический полимер, выбранный из группы, включающей поливиниловые спирты, полиакрилаты, полипирролидоны и полиакриламиды, или (ii) полисахариды, выбранные из группы, включающей производные целлюлозы, галактоманнан или производное галактоманнана, ксантан, сукциноглюкан и склероглюкан, а также их смеси.8. The method of claim 1, wherein the polymer thickener is (i) a synthetic polymer selected from the group consisting of polyvinyl alcohols, polyacrylates, polypyrrolidones and polyacrylamides, or (ii) polysaccharides selected from the group comprising cellulose derivatives, galactomannan or a derivative galactomannan, xanthan, succinoglucan and scleroglucan, as well as mixtures thereof. 9. Способ по п. 8, где полисахарид выбирают из группы, включающей гуаровую камедь, гидроксипропилгуар, карбоксиметилгуар, карбоксиметилгидроксипропилгуар, ксантановую камедь и склероглюкан.9. The method of claim 8, wherein the polysaccharide is selected from the group consisting of guar gum, hydroxypropyl guar, carboxymethyl guar, carboxymethyl hydroxypropyl guar, xanthan gum, and scleroglucan. 10. Способ по п. 1, где полимерный загуститель является по крайней мере частично сшитым.10. The method of claim 1, wherein the polymer thickener is at least partially crosslinked. 11. Способ обработки флюида после операции гидроразрыва подземного пласта, через который проходит скважина, с использованием флюида для гидроразрыва, содержащего полимерный загуститель и разжижитель, содержащий витамин В1 и/или илид, и указанный способ включает:11. A method of processing a fluid after a fracturing operation of an underground formation through which a well passes using a fracturing fluid containing a polymer thickener and a thinner containing vitamin B1 and / or ylid, and the method includes: (а) снижение вязкости флюида для гидроразрыва за счет по крайней мере частичной деградации полимерного загустителя в присутствии витамина В1 и/или илида, при этом получают флюид с пониженной вязкостью,(a) reducing the viscosity of the fracturing fluid due to at least partial degradation of the polymer thickener in the presence of vitamin B1 and / or ylide, thereby obtaining a fluid with a reduced viscosity, (б) дезактивацию витамина В1 и/или илида в составе флюида с пониженной вязкостью при добавлении во флюид с пониженной вязкостью серо- или фосфорсодержащего нуклеофильного агента.(b) the deactivation of vitamin B1 and / or ylide in the composition of the fluid with a reduced viscosity when a sulfur or phosphorus-containing nucleophilic agent is added to the fluid with a reduced viscosity. 12. Способ по п. 11, где флюидом со сниженной вязкостью является добываемая вода или возвратная вода.12. The method of claim 11, wherein the reduced viscosity fluid is produced water or return water. 13. Способ по п. 12, где добываемую воду или возвратную воду извлекают из скважины до дезактивации витамина В1 и/или илида в присутствии серо- или фосфорсодержащего нуклеофильного агента.13. The method according to p. 12, where the produced water or return water is extracted from the well prior to deactivation of vitamin B1 and / or ylide in the presence of a sulfur or phosphorus-containing nucleophilic agent. 14. Способ по п. 11, где серо- или фосфорсодержащий нуклеофильный агент содержит неподеленную пару электронов.14. The method according to p. 11, where the sulfur or phosphorus nucleophilic agent contains an unshared pair of electrons. 15. Способ по п. 11, где серосодержащий нуклеофильный агент представляет собой сульфит или бисульфит.15. The method according to p. 11, where the sulfur-containing nucleophilic agent is a sulfite or bisulfite. 16. Способ обработки добываемой или возвратной воды, содержащей остаточный полимерный загуститель, который включает:16. A method of treating produced or return water containing residual polymer thickener, which includes: (а) добавление витамина В1 и/или илида в добываемую или возвратную воду и снижение вязкости остаточного полимерного загустителя, а также(a) adding vitamin B1 and / or ylide to the produced or return water and lowering the viscosity of the residual polymer thickener, and (б) добавление серо- или фосфорсодержащего нуклеофильного агента в добываемую или возвратную воду для дезактивации витамина В1 и/или илида.(b) adding a sulfur or phosphorus nucleophilic agent to the produced or return water to deactivate vitamin B1 and / or ylide. 17. Способ по п. 16, где витамин В1 и/или илид, а также нуклеофильный агент добавляют в добываемую или возвратную воду одновременно.17. The method according to p. 16, where vitamin B1 and / or ylide, as well as a nucleophilic agent are added to the produced or return water at the same time. 18. Способ интенсификации подземного пласта, через который проходит скважина, который включает:18. A method of stimulating an underground formation through which a well passes, which includes: (а) закачивание в скважину флюида для обработки скважины, содержащего первый полимерный загуститель и витамин В1 и/или илид, под давлением, достаточным для осуществления или инициации разрыва,(a) injecting into the well a fluid for treating a well containing a first polymer thickener and vitamin B1 and / or ylide under a pressure sufficient to effect or initiate a fracture, (б) снижение вязкости флюида для обработки скважины с использованием витамина В1 и/или илида,(b) reducing the viscosity of the fluid for treating a well using vitamin B1 and / or ylide, (в) извлечение добываемой воды или возвратной воды из скважины,(c) recovering produced water or return water from the well, (г) дезактивацию витамина В1 и/или илида в составе добываемой воды или возвратной воды при добавлении в добываемую воду или возвратную воду серо- или фосфорсодержащего нуклеофильного агента,(d) the deactivation of vitamin B1 and / or ylide in the composition of the produced water or return water when sulfur-containing or phosphorus-containing nucleophilic agent is added to the produced water or return water, (д) добавление второго полимерного загустителя в добываемую воду или возвратную воду для получения второго флюида для обработки и закачивание второго флюида для обработки в скважину под давлением, достаточным для осуществления или инициации разрыва пласта.(e) adding a second polymer thickener to the produced water or return water to produce a second treatment fluid and injecting the second treatment fluid into the well at a pressure sufficient to effect or initiate a fracturing. 19. Способ по п. 18, где второй флюид для обработки дополнительно содержит разжижитель.19. The method of claim 18, wherein the second processing fluid further comprises a diluent. 20. Способ по п. 19, где серо- или фосфорсодержащий нуклеофильный агент содержит неподеленную пару электронов.20. The method according to p. 19, where the sulfur - or phosphorus-containing nucleophilic agent contains an unshared pair of electrons. 21. Способ по п. 18, где серосодержащий нуклеофильный агент представляет собой сульфит.21. The method according to p. 18, where the sulfur-containing nucleophilic agent is a sulfite.
RU2016123140A 2013-11-13 2014-10-27 Method of treating produced or flowback water with nucleophilic agent to deactivate breaker RU2681326C1 (en)

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US201361903828P 2013-11-13 2013-11-13
US61/903,828 2013-11-13
PCT/US2014/062434 WO2015073197A1 (en) 2013-11-13 2014-10-27 Method of treating produced or flowback water with nucleophilic agent to deactivate breaker

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US20150129231A1 (en) 2015-05-14
US9822594B2 (en) 2017-11-21

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