RU2015122358A - METHOD FOR PRODUCING POLYANANINE DOPED BY METAL - Google Patents

METHOD FOR PRODUCING POLYANANINE DOPED BY METAL Download PDF

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Publication number
RU2015122358A
RU2015122358A RU2015122358A RU2015122358A RU2015122358A RU 2015122358 A RU2015122358 A RU 2015122358A RU 2015122358 A RU2015122358 A RU 2015122358A RU 2015122358 A RU2015122358 A RU 2015122358A RU 2015122358 A RU2015122358 A RU 2015122358A
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RU
Russia
Prior art keywords
dopant
producing
polyaniline
metal
doped
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RU2015122358A
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Russian (ru)
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RU2606231C1 (en
Inventor
Татьяна Анатольевна Моисеева
Татьяна Николаевна Мясоедова
Виктор Владимирович Петров
Original Assignee
федеральное государственное автономное образовательное учреждение высшего образования "Южный федеральный университет" (Южный федеральный университет)
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Application filed by федеральное государственное автономное образовательное учреждение высшего образования "Южный федеральный университет" (Южный федеральный университет) filed Critical федеральное государственное автономное образовательное учреждение высшего образования "Южный федеральный университет" (Южный федеральный университет)
Priority to RU2015122358A priority Critical patent/RU2606231C1/en
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Publication of RU2606231C1 publication Critical patent/RU2606231C1/en
Publication of RU2015122358A publication Critical patent/RU2015122358A/en

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/02—Polyamines
    • C08G73/026—Wholly aromatic polyamines
    • C08G73/0266—Polyanilines or derivatives thereof
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
    • H01B1/06—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances
    • H01B1/12—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances organic substances
    • H01B1/124—Intrinsically conductive polymers
    • H01B1/128—Intrinsically conductive polymers comprising six-membered aromatic rings in the main chain, e.g. polyanilines, polyphenylenes

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)

Claims (1)

Способ получения полианилина допированного металлом, включающий растворение окислителя в чистом растворителе, добавление анилинового мономера по каплям при перемешивании и выдерживание реакционной смеси при температуре 30°С., отличающийся тем, что используют допант, причем допант выбран из группы, включающей соли металлов хлорид меди (II), оксихлорид циркония (IV), хлорид олова (II), кроме того допант используют с концентрацией 0,1 - 0,5 моль/дм3, осаждение полианилина на подложку происходит в процессе полимеризации, время протекания полимеризации и осаждения полианилина на подложке 40-60 часов.A method for producing metal doped polyaniline, including dissolving an oxidizing agent in a pure solvent, adding an aniline monomer dropwise with stirring, and maintaining the reaction mixture at a temperature of 30 ° C., Characterized in that a dopant is used, and the dopant is selected from the group consisting of metal salts of copper chloride ( II), zirconium (IV) oxychloride, tin (II) chloride, in addition, a dopant is used with a concentration of 0.1 - 0.5 mol / dm 3 , the deposition of polyaniline on a substrate occurs during polymerization, the polymerization time tion and deposition of polyaniline on a substrate for 40-60 hours.
RU2015122358A 2015-06-10 2015-06-10 Method of producing metal-doped polyaniline RU2606231C1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
RU2015122358A RU2606231C1 (en) 2015-06-10 2015-06-10 Method of producing metal-doped polyaniline

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
RU2015122358A RU2606231C1 (en) 2015-06-10 2015-06-10 Method of producing metal-doped polyaniline

Publications (2)

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RU2606231C1 RU2606231C1 (en) 2017-01-10
RU2015122358A true RU2015122358A (en) 2017-01-10

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RU2015122358A RU2606231C1 (en) 2015-06-10 2015-06-10 Method of producing metal-doped polyaniline

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114577864A (en) * 2022-05-09 2022-06-03 成都晟铎传感技术有限公司 MEMS hydrogen sulfide sensor for improving metal salt poisoning effect and preparation method thereof

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6772948B2 (en) * 2017-04-28 2020-10-21 富士通株式会社 Gas sensor devices, gas sensor systems, and methods for manufacturing gas sensor devices

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2323228C1 (en) * 2003-12-31 2008-04-27 Каунсил Оф Сайентифик Энд Индастриал Рисерч Method for preparing conducting polyaniline
US20060163540A1 (en) * 2005-01-27 2006-07-27 Chien-Hsin Yang Solid status electro-chromic device process using conductive polymer nano material
RU2505558C1 (en) * 2012-12-19 2014-01-27 Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Ярославский государственный технический университет" Electrochemical method for synthesis of metal-doped polyaniline

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114577864A (en) * 2022-05-09 2022-06-03 成都晟铎传感技术有限公司 MEMS hydrogen sulfide sensor for improving metal salt poisoning effect and preparation method thereof
CN114577864B (en) * 2022-05-09 2022-07-12 成都晟铎传感技术有限公司 MEMS hydrogen sulfide sensor for improving metal salt poisoning effect and preparation method thereof

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Publication number Publication date
RU2606231C1 (en) 2017-01-10

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