RU2015116523A - METHOD FOR POST-PRODUCTION THERMAL PROCESSING OF ADDITIVELY PRODUCED PRODUCTS FROM STRENGTHENED GAMMA PRIMA PHASE OF SUPER ALLOYS - Google Patents

METHOD FOR POST-PRODUCTION THERMAL PROCESSING OF ADDITIVELY PRODUCED PRODUCTS FROM STRENGTHENED GAMMA PRIMA PHASE OF SUPER ALLOYS Download PDF

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RU2015116523A
RU2015116523A RU2015116523A RU2015116523A RU2015116523A RU 2015116523 A RU2015116523 A RU 2015116523A RU 2015116523 A RU2015116523 A RU 2015116523A RU 2015116523 A RU2015116523 A RU 2015116523A RU 2015116523 A RU2015116523 A RU 2015116523A
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RU2684989C2 (en
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Томас ЭТТЕР
Роман ЭНГЕЛИ
Андреас КЮНЦЛЕР
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ДЖЕНЕРАЛ ЭЛЕКТРИК ТЕКНОЛОДЖИ ГмбХ, СН
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22FCHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/16Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of other metals or alloys based thereon
    • C22F1/18High-melting or refractory metals or alloys based thereon
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F10/00Additive manufacturing of workpieces or articles from metallic powder
    • B22F10/60Treatment of workpieces or articles after build-up
    • B22F10/64Treatment of workpieces or articles after build-up by thermal means
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F3/00Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
    • B22F3/12Both compacting and sintering
    • B22F3/14Both compacting and sintering simultaneously
    • B22F3/15Hot isostatic pressing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F3/00Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
    • B22F3/12Both compacting and sintering
    • B22F3/16Both compacting and sintering in successive or repeated steps
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F3/00Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
    • B22F3/24After-treatment of workpieces or articles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B33ADDITIVE MANUFACTURING TECHNOLOGY
    • B33YADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y40/00Auxiliary operations or equipment, e.g. for material handling
    • B33Y40/20Post-treatment, e.g. curing, coating or polishing
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D6/00Heat treatment of ferrous alloys
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C19/00Alloys based on nickel or cobalt
    • C22C19/03Alloys based on nickel or cobalt based on nickel
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C19/00Alloys based on nickel or cobalt
    • C22C19/07Alloys based on nickel or cobalt based on cobalt
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22FCHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/10Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of nickel or cobalt or alloys based thereon
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F10/00Additive manufacturing of workpieces or articles from metallic powder
    • B22F10/20Direct sintering or melting
    • B22F10/28Powder bed fusion, e.g. selective laser melting [SLM] or electron beam melting [EBM]
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F3/00Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
    • B22F3/24After-treatment of workpieces or articles
    • B22F2003/248Thermal after-treatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F5/00Manufacture of workpieces or articles from metallic powder characterised by the special shape of the product
    • B22F5/009Manufacture of workpieces or articles from metallic powder characterised by the special shape of the product of turbine components other than turbine blades
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/25Process efficiency

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Thermal Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Powder Metallurgy (AREA)
  • Turbine Rotor Nozzle Sealing (AREA)
  • Health & Medical Sciences (AREA)
  • Child & Adolescent Psychology (AREA)
  • Heat Treatment Of Articles (AREA)
  • Laser Beam Processing (AREA)
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Abstract

1. Способ послепроизводственной термической обработки аддитивно изготовленного изделия из упрочненного гамма-прим-фазой (γ′) суперсплава на основе Ni или Со или Fe или их сочетания, состоящий из следующих стадий:a) обеспечение аддитивно изготовленного изделия в послепроизводственном состоянии, затемb) нагревание изделия от комнатной температуры (RT) до температуры T, причем Tявляется на 50-100°С меньшей, чем температура T, при которой начинается падение коэффициента теплового расширения, затемc) выдерживание изделия в течение времени t1 при Tдля достижения равномерной температуры изделия, затемd) нагревание изделия путем применения быстрого нагрева со скоростью нагрева vпо меньшей мере 25°С/мин от Тдо температуры Т≥850°С, чтобы исключить или по меньшей мере уменьшить выделение гамма-прим-фазы, затемe) применение к изделию дополнительных стадий с длительностью/температурой в зависимости от цели термической обработки.2. Способ по п. 1, отличающийся тем, что на стадии (d) скорость нагрева v=25-60°C/мин.3. Способ по п. 1, отличающийся тем, что на стадии (е) осуществляют изотермическую выдержку tв течение 2 часов для уменьшения остаточных напряжений.4. Способ по п. 1, отличающийся тем, что на стадии (е) применяют иные или дополнительные времена выдержки при температурах Т>Тдля дальнейшего уменьшения остаточных напряжений и/или перекристаллизации микроструктуры.5. Способ по п. 1, отличающийся тем, что термическую обработку осуществляют под давлением в течение горячего изостатического прессования (ГИП).6. Способ по любому из пп. 1-5, отличающийся следующими параметрами послепроизводственной термической обработки аддитивно изготовленного изделия, выполненного из IN 738LC:T=400°Cv=5°C/минv=35°C/минT=1050°Ct=2 чT=1120°C/2 ч или 1200°C/4 ч или 1250°C/3 1. A method of post-production heat treatment of an additively manufactured product from a gamma-prim-phase (γ ′) hardened superalloy based on Ni or Co or Fe or a combination thereof, consisting of the following stages: a) providing the additively manufactured product in the post-production state, then b) heating products from room temperature (RT) to temperature T, and T is 50-100 ° C lower than temperature T at which the thermal expansion coefficient begins to fall, then c) keeping the product for a time t1 at T for d achieving a uniform temperature of the product, then d) heating the product by applying rapid heating with a heating rate v of at least 25 ° C / min from Tdo temperature T≥850 ° C to eliminate or at least reduce the emission of gamma-prim phase, then e) application to the product of additional stages with a duration / temperature depending on the purpose of the heat treatment. 2. The method according to claim 1, characterized in that in step (d) the heating rate is v = 25-60 ° C / min. 3. The method according to claim 1, characterized in that at the stage (e) isothermal exposure t for 2 hours is carried out to reduce residual stresses. A method according to claim 1, characterized in that at the stage (e), other or additional holding times are used at temperatures T> T to further reduce the residual stresses and / or recrystallization of the microstructure. The method according to claim 1, characterized in that the heat treatment is carried out under pressure during hot isostatic pressing (GUI) .6. The method according to any one of paragraphs. 1-5, characterized by the following parameters of post-production heat treatment of an additively manufactured product made of IN 738LC: T = 400 ° Cv = 5 ° C / minv = 35 ° C / minT = 1050 ° Ct = 2 hT = 1120 ° C / 2 h or 1200 ° C / 4 h or 1250 ° C / 3

Claims (6)

1. Способ послепроизводственной термической обработки аддитивно изготовленного изделия из упрочненного гамма-прим-фазой (γ′) суперсплава на основе Ni или Со или Fe или их сочетания, состоящий из следующих стадий:1. The method of post-production heat treatment of an additively manufactured product from a gamma-prim-phase (γ ′) hardened superalloy based on Ni or Co or Fe or a combination thereof, consisting of the following stages: a) обеспечение аддитивно изготовленного изделия в послепроизводственном состоянии, затемa) ensuring the additively manufactured product in the post-production state, then b) нагревание изделия от комнатной температуры (RT) до температуры T1, причем T1 является на 50-100°С меньшей, чем температура Ts, при которой начинается падение коэффициента теплового расширения, затемb) heating the product from room temperature (RT) to a temperature T 1 , wherein T 1 is 50-100 ° C lower than the temperature T s at which the thermal expansion coefficient begins to fall, then c) выдерживание изделия в течение времени t1 при T1 для достижения равномерной температуры изделия, затемc) holding the product for a time t1 at T 1 to achieve a uniform temperature of the product, then d) нагревание изделия путем применения быстрого нагрева со скоростью нагрева v2 по меньшей мере 25°С/мин от Т1 до температуры Т2≥850°С, чтобы исключить или по меньшей мере уменьшить выделение гамма-прим-фазы, затемd) heating the product by applying rapid heating at a heating rate v 2 of at least 25 ° C / min from T 1 to a temperature of T 2 ≥850 ° C to eliminate or at least reduce the release of gamma-prim phase, then e) применение к изделию дополнительных стадий с длительностью/температурой в зависимости от цели термической обработки.e) application of additional stages with duration / temperature to the product, depending on the purpose of the heat treatment. 2. Способ по п. 1, отличающийся тем, что на стадии (d) скорость нагрева v2=25-60°C/мин.2. The method according to p. 1, characterized in that in stage (d) the heating rate v 2 = 25-60 ° C / min 3. Способ по п. 1, отличающийся тем, что на стадии (е) осуществляют изотермическую выдержку t2 в течение 2 часов для уменьшения остаточных напряжений.3. The method according to p. 1, characterized in that at the stage (e) carry out isothermal exposure t 2 within 2 hours to reduce residual stresses. 4. Способ по п. 1, отличающийся тем, что на стадии (е) применяют иные или дополнительные времена выдержки при температурах Т32 для дальнейшего уменьшения остаточных напряжений и/или перекристаллизации микроструктуры.4. The method according to p. 1, characterized in that at the stage (e) apply other or additional holding times at temperatures T 3 > T 2 to further reduce residual stresses and / or recrystallization of the microstructure. 5. Способ по п. 1, отличающийся тем, что термическую обработку осуществляют под давлением в течение горячего изостатического прессования (ГИП).5. The method according to p. 1, characterized in that the heat treatment is carried out under pressure during hot isostatic pressing (GUI). 6. Способ по любому из пп. 1-5, отличающийся следующими параметрами послепроизводственной термической обработки аддитивно изготовленного изделия, выполненного из IN 738LC:6. The method according to any one of paragraphs. 1-5, characterized by the following parameters of the post-production heat treatment of additively manufactured products made of IN 738LC: T1=400°CT 1 = 400 ° C v1=5°C/минv 1 = 5 ° C / min v2=35°C/минv 2 = 35 ° C / min T2=1050°CT 2 = 1050 ° C t2=2 чt 2 = 2 h T3=1120°C/2 ч или 1200°C/4 ч или 1250°C/3 ч. T 3 = 1120 ° C / 2 h or 1200 ° C / 4 h or 1250 ° C / 3 h
RU2015116523A 2014-05-12 2015-04-29 Method of following production thermal treatment of additively made articles from super-hardened gamma-type super fell charts RU2684989C2 (en)

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EP14167904.3A EP2944402B1 (en) 2014-05-12 2014-05-12 Method for post-built heat treatment of additively manufactured components made of gamma-prime strengthened superalloys

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CN105088119B (en) 2019-05-10
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KR20150129616A (en) 2015-11-20
JP2015227505A (en) 2015-12-17
US20150322557A1 (en) 2015-11-12
RU2684989C2 (en) 2019-04-16
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EP2944402A1 (en) 2015-11-18
EP2944402B1 (en) 2019-04-03
US9670572B2 (en) 2017-06-06

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