RU2015114701A - ORGANIC PEROXIDE WATER EMULSION COMPOSITION - Google Patents

ORGANIC PEROXIDE WATER EMULSION COMPOSITION Download PDF

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RU2015114701A
RU2015114701A RU2015114701A RU2015114701A RU2015114701A RU 2015114701 A RU2015114701 A RU 2015114701A RU 2015114701 A RU2015114701 A RU 2015114701A RU 2015114701 A RU2015114701 A RU 2015114701A RU 2015114701 A RU2015114701 A RU 2015114701A
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composition according
emulsifier
determined
ethoxylated
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RU2015114701A
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RU2674151C2 (en
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Изабелль ТАРТАРЭН
Жак КОШЕ
Альберт БЛУМ
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Аркема Франс
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F114/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F114/02—Monomers containing chlorine
    • C08F114/04—Monomers containing two carbon atoms
    • C08F114/06—Vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/28—Oxygen or compounds releasing free oxygen
    • C08F4/32—Organic compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/28—Oxygen or compounds releasing free oxygen
    • C08F4/32—Organic compounds
    • C08F4/34—Per-compounds with one peroxy-radical
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/02—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/14—Peroxides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06—Homopolymers or copolymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L29/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical; Compositions of hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Compositions of derivatives of such polymers
    • C08L29/02—Homopolymers or copolymers of unsaturated alcohols
    • C08L29/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
    • C08L71/02—Polyalkylene oxides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C407/00—Preparation of peroxy compounds
    • C07C407/003—Separation; Purification; Stabilisation; Use of additives
    • C07C407/006—Stabilisation; Use of additives
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C409/00—Peroxy compounds

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polymerisation Methods In General (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Cosmetics (AREA)
  • Colloid Chemistry (AREA)
  • Polymerization Catalysts (AREA)
  • Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)

Abstract

1. Композиция водной эмульсии органического пероксида, содержащая:- от 10 до 65 мас.% одного или нескольких органических пероксидов;- от 2 до 25 мас.% по меньшей мере одного агента против гелеобразования;- от 0,01 до 10 мас.% по меньшей мере одного эмульгатора;- при необходимости по меньшей мере одну добавку;- воду, количество которой определяют так, чтобы составить остаток общей массы композиции (до 100%);отличающаяся тем, что эмульгатор представляет собой коллоидный агент, представляющий собой поливинилацетат со степенью гидролиза, превышающей 80%, и вязкостью, определенной для водного раствора с концентрацией 4 мас.% при 20˚C, меньшей или равной 5 мПа·с, причем вязкость определяют вискозиметром "Brookfield RVT", шпиндель № 3, 20 об/мин, по стандарту ISO 2555.2. Композиция по п. 1, отличающаяся тем, что вязкость частично гидролизованного поливинилацетата, определенная для водного раствора с концентрацией 4 мас.% при 20˚C, меньше или равна 3 мПа·с.3. Композиция по п. 1 или 2, отличающаяся тем, что частично гидролизованный поливинилацетат модифицирован по ацетатным группам солями металлов, предпочтительно выбранными из карбоксилатов натрия и сульфонатов.4. Композиция по п. 1 или 2, отличающаяся тем, что она содержит второй эмульгатор, представляющий собой неионогенное поверхностно-активное вещество типа этоксилированной жирной кислоты, такой как этоксилированные моно-, ди- или триглицериды жирных кислот, этоксилированных растительных масел, этоксилированного жирного спирта, блок-сополимера, содержащего по меньшей мере один алкиленоксидный блок.5. Композиция по п. 4, отличающаяся тем, что второй эмульгатор представляет собой этоксилированное касторовое масло.6. Композиция по п. 1 или 2, отличающаяся тем, что степень1. The composition of an aqueous emulsion of organic peroxide, containing: - from 10 to 65 wt.% One or more organic peroxides; - from 2 to 25 wt.% At least one anti-gel agent; - from 0.01 to 10 wt.% at least one emulsifier; - if necessary, at least one additive; - water, the amount of which is determined so as to make up the remainder of the total weight of the composition (up to 100%); characterized in that the emulsifier is a colloidal agent representing polyvinyl acetate with a degree hydrolysis in excess of 80% and bone specific to an aqueous solution with a concentration of 4 wt.% at 20˚C, less than or equal to 5 mPa.s, wherein the viscosity is determined viscometer "Brookfield RVT", № 3 spindle, 20 rpm / min at standard ISO 2555.2. The composition according to claim 1, characterized in that the viscosity of the partially hydrolyzed polyvinyl acetate, determined for an aqueous solution with a concentration of 4 wt.% At 20 ° C, is less than or equal to 3 MPa · s. 3. A composition according to claim 1 or 2, characterized in that the partially hydrolyzed polyvinyl acetate is modified by the acetate groups with metal salts, preferably selected from sodium carboxylates and sulfonates. A composition according to claim 1 or 2, characterized in that it contains a second emulsifier, which is a nonionic surfactant such as ethoxylated fatty acids, such as ethoxylated mono-, di- or triglycerides of fatty acids, ethoxylated vegetable oils, ethoxylated fatty alcohol, a block copolymer containing at least one alkylene oxide block. 5. A composition according to claim 4, characterized in that the second emulsifier is ethoxylated castor oil. The composition according to p. 1 or 2, characterized in that the degree

Claims (14)

1. Композиция водной эмульсии органического пероксида, содержащая:1. The composition of the aqueous emulsion of organic peroxide, containing: - от 10 до 65 мас.% одного или нескольких органических пероксидов;- from 10 to 65 wt.% one or more organic peroxides; - от 2 до 25 мас.% по меньшей мере одного агента против гелеобразования;- from 2 to 25 wt.% at least one anti-gelling agent; - от 0,01 до 10 мас.% по меньшей мере одного эмульгатора;- from 0.01 to 10 wt.% at least one emulsifier; - при необходимости по меньшей мере одну добавку;- if necessary, at least one additive; - воду, количество которой определяют так, чтобы составить остаток общей массы композиции (до 100%);- water, the amount of which is determined so as to make up the remainder of the total mass of the composition (up to 100%); отличающаяся тем, что эмульгатор представляет собой коллоидный агент, представляющий собой поливинилацетат со степенью гидролиза, превышающей 80%, и вязкостью, определенной для водного раствора с концентрацией 4 мас.% при 20˚C, меньшей или равной 5 мПа·с, причем вязкость определяют вискозиметром "Brookfield RVT", шпиндель № 3, 20 об/мин, по стандарту ISO 2555.characterized in that the emulsifier is a colloidal agent, which is polyvinyl acetate with a degree of hydrolysis in excess of 80%, and a viscosity determined for an aqueous solution with a concentration of 4 wt.% at 20 ° C, less than or equal to 5 MPa · s, and the viscosity is determined Brookfield RVT viscometer, spindle No. 3, 20 rpm, according to ISO 2555. 2. Композиция по п. 1, отличающаяся тем, что вязкость частично гидролизованного поливинилацетата, определенная для водного раствора с концентрацией 4 мас.% при 20˚C, меньше или равна 3 мПа·с.2. The composition according to p. 1, characterized in that the viscosity of the partially hydrolyzed polyvinyl acetate, determined for an aqueous solution with a concentration of 4 wt.% At 20 ° C, is less than or equal to 3 MPa · s. 3. Композиция по п. 1 или 2, отличающаяся тем, что частично гидролизованный поливинилацетат модифицирован по ацетатным группам солями металлов, предпочтительно выбранными из карбоксилатов натрия и сульфонатов.3. The composition according to p. 1 or 2, characterized in that the partially hydrolyzed polyvinyl acetate is modified by the acetate groups with metal salts, preferably selected from sodium carboxylates and sulfonates. 4. Композиция по п. 1 или 2, отличающаяся тем, что она содержит второй эмульгатор, представляющий собой неионогенное поверхностно-активное вещество типа этоксилированной жирной кислоты, такой как этоксилированные моно-, ди- или триглицериды жирных кислот, этоксилированных растительных масел, этоксилированного жирного спирта, блок-сополимера, содержащего по меньшей мере один алкиленоксидный блок.4. The composition according to p. 1 or 2, characterized in that it contains a second emulsifier, which is a nonionic surfactant such as ethoxylated fatty acids, such as ethoxylated mono-, di- or triglycerides of fatty acids, ethoxylated vegetable oils, ethoxylated fatty acids alcohol, a block copolymer containing at least one alkylene oxide block. 5. Композиция по п. 4, отличающаяся тем, что второй эмульгатор представляет собой этоксилированное касторовое масло.5. The composition according to p. 4, characterized in that the second emulsifier is ethoxylated castor oil. 6. Композиция по п. 1 или 2, отличающаяся тем, что степень гидролиза поливинилацетата составляет больше 85% и более предпочтительно находится в интервале от 86 до 89%.6. The composition according to p. 1 or 2, characterized in that the degree of hydrolysis of polyvinyl acetate is more than 85% and more preferably is in the range from 86 to 89%. 7. Композиция по п. 1 или 2, отличающаяся тем, что один или несколько органических пероксидов выбраны из сложных пероксиэфиров, пероксидикарбонатов и/или диацилпероксидов.7. The composition according to p. 1 or 2, characterized in that one or more organic peroxides are selected from peroxyesters, peroxydicarbonates and / or diacyl peroxides. 8. Композиция по п. 1 или 2, отличающаяся тем, что она имеет вязкость, определенную по времени истечения, меньше 200 с и предпочтительно меньшее 100 с, причем время истечения определяют при температуре 5˚C по стандарту DIN 53211.8. The composition according to claim 1 or 2, characterized in that it has a viscosity determined by the expiration time, less than 200 s and preferably less than 100 s, and the expiration time is determined at a temperature of 5 ° C according to DIN 53211. 9. Композиция по п. 1 или 2, отличающаяся тем, что она содержит множество капель, образованных пероксидом, так что средний размер (d50) капель меньше 10 мкм (микрометров) и предпочтительно меньше 5 мкм, а максимальный размер (d100) капель меньше 20 мкм.9. The composition according to p. 1 or 2, characterized in that it contains many drops formed by peroxide, so that the average size (d 50 ) of the drops is less than 10 microns (micrometers) and preferably less than 5 microns, and the maximum size (d 100 ) drops less than 20 microns. 10. Композиция по п. 1 или 2, отличающаяся тем, что она содержит больше 30 мас.% и предпочтительно больше 45 мас.% одного или нескольких органических пероксидов.10. The composition according to p. 1 or 2, characterized in that it contains more than 30 wt.% And preferably more than 45 wt.% Of one or more organic peroxides. 11. Композиция по п. 1 или 2, отличающаяся тем, что поливинилацетат содержится в интервале от 1 до 5 мас.% и предпочтительно в интервале от 0,5 до 3%.11. The composition according to p. 1 or 2, characterized in that the polyvinyl acetate is contained in the range from 1 to 5 wt.% And preferably in the range from 0.5 to 3%. 12. Способ получения композиции по любому из предыдущих пунктов, отличающийся тем, что он включает в себя следующие стадии, на которых:12. A method of obtaining a composition according to any one of the preceding paragraphs, characterized in that it includes the following stages, in which: - в воде диспергируют агент против гелеобразования, при необходимости по меньшей мере одну указанную ранее добавку, а также коллоидный агент для получения однородной водной фракции;- an anti-gelling agent is dispersed in water, if necessary, at least one of the additives mentioned above, as well as a colloidal agent to obtain a homogeneous aqueous fraction; - к водной фракции прибавляют пероксид;- peroxide is added to the aqueous fraction; - полученную таким образом смесь эмульгируют на стадии эмульгирования при температуре ниже 5˚C и предпочтительно ниже -5˚C.- the mixture thus obtained is emulsified at the stage of emulsification at a temperature below 5 ° C and preferably below -5 ° C. 13. Применение композиции по любому из п.п. 1-11 для полимеризации или сополимеризации ненасыщенных мономеров этиленового ряда.13. The use of a composition according to any one of paragraphs. 1-11 for the polymerization or copolymerization of unsaturated ethylene monomers. 14. Применение композиции по п. 13, отличающееся тем, что ненасыщенные мономеры этиленового ряда содержат винилхлорид. 14. The use of the composition according to p. 13, characterized in that the unsaturated ethylene monomers contain vinyl chloride.
RU2015114701A 2012-09-21 2013-09-06 Composition of aqueous emulsion of organic peroxide RU2674151C2 (en)

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FR1258874 2012-09-21
FR1258874A FR2995906B1 (en) 2012-09-21 2012-09-21 AQUEOUS EMULSION COMPOSITION OF ORGANIC PEROXIDE
PCT/FR2013/052060 WO2014044949A1 (en) 2012-09-21 2013-09-06 Aqueous emulsion composition of organic peroxide

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FR2995906B1 (en) 2015-02-20
KR101869142B1 (en) 2018-06-19
KR20170110177A (en) 2017-10-10
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US9410002B2 (en) 2016-08-09
CN104781287A (en) 2015-07-15
BR112015006369B1 (en) 2021-08-10
HUE031531T2 (en) 2017-07-28
ES2611761T3 (en) 2017-05-10
US20150218293A1 (en) 2015-08-06
FR2995906A1 (en) 2014-03-28
MX349776B (en) 2017-08-10
KR20150058289A (en) 2015-05-28
MX2015003610A (en) 2015-08-20
RU2674151C2 (en) 2018-12-05
EP2897984B1 (en) 2016-10-26
PL2897984T3 (en) 2017-06-30

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