RU2015110362A - The method of obtaining powdered water-soluble coordination compounds of iron (III) and manganese (II) with hydroxyethylidene diphosphonic acid - Google Patents

The method of obtaining powdered water-soluble coordination compounds of iron (III) and manganese (II) with hydroxyethylidene diphosphonic acid Download PDF

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RU2015110362A
RU2015110362A RU2015110362A RU2015110362A RU2015110362A RU 2015110362 A RU2015110362 A RU 2015110362A RU 2015110362 A RU2015110362 A RU 2015110362A RU 2015110362 A RU2015110362 A RU 2015110362A RU 2015110362 A RU2015110362 A RU 2015110362A
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manganese
iii
tris
iron
diphosphonate
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RU2015110362A
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RU2609787C2 (en
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Владимир Викторович Семенов
Наталья Вадимовна Золотарева
Борис Иванович Петров
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Владимир Викторович Семенов
Наталья Вадимовна Золотарева
Борис Иванович Петров
Федеральное государственное бюджетное учреждение науки Институт металлоорганической химии им. Г.А. Разуваева Российской академии наук
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/02—Iron compounds
    • C07F15/025—Iron compounds without a metal-carbon linkage
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F13/00—Compounds containing elements of Groups 7 or 17 of the Periodic Table
    • C07F13/005—Compounds without a metal-carbon linkage

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Способ получения порошкообразных водорастворимых трис(оксиэтилидендифосфоната) дижелеза(III) Fe(HL)·mAm·nHO, трис(оксиэтилидендифосфоната) железа(III) Fe(HL)·kAm·nHO, оксиэтилидендифосфоната марганца(II) MnHL·qAm·nHO, бис(оксиэтилидендифосфоната) марганца(II) Mn(HL)·pAm·nHO, включающий нагрев реакционной смеси, содержащей промотор растворимости (Am), перемешивание, фильтрование охлажденного раствора, упаривание, высушивание при атмосферном давлении на воздухе при температуре 95-110°C и измельчение полученной сухой массы, отличающийся тем, что в качестве промотора растворимости используют органический амин в количестве k, m, p, q - эквивалентов, выбранный из ряда: моноэтаноламин m=5-7, k=6-9, q=2, p=4-6; диэтаноламин m=5-6, k=8-9, q=2, p=5-6; трис(гидроксиметиламинометан) m=6, k=9, q=2, p=6; 2,2′-(этилидендиокси)бис(этиламин) m=3, k=5, q=1, p=3.Method for the production of powdered water-soluble tris (hydroxyethylidene diphosphonate) dyleza (III) Fe (HL) · mAm · nHO, tris (hydroxyethylidene diphosphonate) iron (III) Fe (HL) · kAm · nHO, manganese (II) oxyethylidene diphosphonate, MnHL qA bis (manganese (oxyethylidene diphosphonate) manganese (II) Mn (HL) grinding the resulting dry mass, characterized in that as a promoter astvorimosti an organic amine in an amount of k, m, p, q - equivalents selected from the group of monoethanolamine m = 5-7, k = 6-9, q = 2, p = 4-6; diethanolamine m = 5-6, k = 8-9, q = 2, p = 5-6; tris (hydroxymethylaminomethane) m = 6, k = 9, q = 2, p = 6; 2,2 ′ - (ethylidenedioxy) bis (ethylamine) m = 3, k = 5, q = 1, p = 3.

Claims (1)

Способ получения порошкообразных водорастворимых трис(оксиэтилидендифосфоната) дижелеза(III) Fe2(H2L)3·mAm·nH2O, трис(оксиэтилидендифосфоната) железа(III) Fe(H3L)3·kAm·nH2O, оксиэтилидендифосфоната марганца(II) MnH2L·qAm·nH2O, бис(оксиэтилидендифосфоната) марганца(II) Mn(H3L)2·pAm·nH2O, включающий нагрев реакционной смеси, содержащей промотор растворимости (Am), перемешивание, фильтрование охлажденного раствора, упаривание, высушивание при атмосферном давлении на воздухе при температуре 95-110°C и измельчение полученной сухой массы, отличающийся тем, что в качестве промотора растворимости используют органический амин в количестве k, m, p, q - эквивалентов, выбранный из ряда: моноэтаноламин m=5-7, k=6-9, q=2, p=4-6; диэтаноламин m=5-6, k=8-9, q=2, p=5-6; трис(гидроксиметиламинометан) m=6, k=9, q=2, p=6; 2,2′-(этилидендиокси)бис(этиламин) m=3, k=5, q=1, p=3. The method of obtaining powdered water-soluble tris (hydroxyethylidene diphosphonate) dyleza (III) Fe 2 (H 2 L) 3 · mAm · nH 2 O, tris (hydroxyethylidene diphosphonate) iron (III) Fe (H 3 L) 3 · kAm · nH 2 O, hydroxyethylidene diphosphonate manganese (II) MnH 2 L · qAm · nH 2 O, bis (hydroxyethylidene diphosphonate) manganese (II) Mn (H 3 L) 2 · pAm · nH 2 O, including heating the reaction mixture containing the solubility promoter (Am), stirring, filtering the cooled solution, evaporation, drying at atmospheric pressure in air at a temperature of 95-110 ° C and grinding the resulting dry mass, characterized in that achestve solubility promoter, an organic amine in an amount of k, m, p, q - equivalents selected from the group of monoethanolamine m = 5-7, k = 6-9, q = 2, p = 4-6; diethanolamine m = 5-6, k = 8-9, q = 2, p = 5-6; tris (hydroxymethylaminomethane) m = 6, k = 9, q = 2, p = 6; 2,2 ′ - (ethylidenedioxy) bis (ethylamine) m = 3, k = 5, q = 1, p = 3.
RU2015110362A 2015-03-23 2015-03-23 Method of producing powdered water-soluble coordination compounds of iron(iii) and manganese(ii) with oxyethylidenediphosphonic acid RU2609787C2 (en)

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