RU2014143582A - METHOD FOR ACTIVATING ALUMINUM FOR PRODUCING HYDROGEN - Google Patents

METHOD FOR ACTIVATING ALUMINUM FOR PRODUCING HYDROGEN Download PDF

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Publication number
RU2014143582A
RU2014143582A RU2014143582A RU2014143582A RU2014143582A RU 2014143582 A RU2014143582 A RU 2014143582A RU 2014143582 A RU2014143582 A RU 2014143582A RU 2014143582 A RU2014143582 A RU 2014143582A RU 2014143582 A RU2014143582 A RU 2014143582A
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Russia
Prior art keywords
mixture
aluminum
inert atmosphere
activating
indium
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RU2014143582A
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Russian (ru)
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RU2606449C2 (en
Inventor
Евгений Иосифович Школьников
Ирина Николаевна Атманюк
Александр Владимирович Долженко
Игорь Витальевич Янилкин
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Общество с ограниченной ответственностью "ХэндиПауэр"
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Priority to RU2014143582A priority Critical patent/RU2606449C2/en
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/36Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Manufacture Of Metal Powder And Suspensions Thereof (AREA)

Abstract

Способ активации алюминия для получения водорода, включающий получение активирующего сплава на основе галлия и индия, его смешивание в инертной атмосфере с алюминием и механохимическую обработку указанной смеси в шаровой мельнице, отличающийся тем, что приготавливают смесь компонентов индия, олова и галлия, предпочтительно, в соотношении 20:20:60 мас.%, нагревают смесь до получения эвтектического сплава, который затем смешивают при нормальных условиях в инертной атмосфере с порошкообразными алюминием и абразивным веществом дисперсностью 0,5-1,5 мм, преимущественно, из группы хлорид натрия или оксид алюминия при следующем соотношении компонентов, мас.%:после чего смесь подвергают механохимической обработке в инертной атмосфере при температуре 20-80°C в течение 5-20 мин.A method of activating aluminum to produce hydrogen, including obtaining an activating alloy based on gallium and indium, mixing it in an inert atmosphere with aluminum and mechanochemical processing of the mixture in a ball mill, characterized in that a mixture of indium, tin and gallium components is prepared, preferably in the ratio 20:20:60 wt.%, The mixture is heated to obtain a eutectic alloy, which is then mixed under normal conditions in an inert atmosphere with powdered aluminum and an abrasive dispersion 0.5-1.5 mm, mainly from the group of sodium chloride or alumina in the following ratio of components, wt.%: After which the mixture is subjected to mechanochemical treatment in an inert atmosphere at a temperature of 20-80 ° C for 5-20 minutes

Claims (1)

Способ активации алюминия для получения водорода, включающий получение активирующего сплава на основе галлия и индия, его смешивание в инертной атмосфере с алюминием и механохимическую обработку указанной смеси в шаровой мельнице, отличающийся тем, что приготавливают смесь компонентов индия, олова и галлия, предпочтительно, в соотношении 20:20:60 мас.%, нагревают смесь до получения эвтектического сплава, который затем смешивают при нормальных условиях в инертной атмосфере с порошкообразными алюминием и абразивным веществом дисперсностью 0,5-1,5 мм, преимущественно, из группы хлорид натрия или оксид алюминия при следующем соотношении компонентов, мас.%:A method of activating aluminum to produce hydrogen, including obtaining an activating alloy based on gallium and indium, mixing it in an inert atmosphere with aluminum and mechanochemical processing of the mixture in a ball mill, characterized in that a mixture of indium, tin and gallium components is prepared, preferably in the ratio 20:20:60 wt.%, The mixture is heated to obtain a eutectic alloy, which is then mixed under normal conditions in an inert atmosphere with powdered aluminum and an abrasive dispersion 0.5-1.5 mm, mainly from the group of sodium chloride or aluminum oxide in the following ratio of components, wt.%: эвтектический сплавeutectic alloy 1-3,51-3,5 абразивное веществоabrasive substance 2-52-5 алюминийaluminum остальное,rest,
после чего смесь подвергают механохимической обработке в инертной атмосфере при температуре 20-80°C в течение 5-20 мин. after which the mixture is subjected to mechanochemical treatment in an inert atmosphere at a temperature of 20-80 ° C for 5-20 minutes.
RU2014143582A 2014-10-29 2014-10-29 Method of activating aluminium for producing hydrogen RU2606449C2 (en)

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RU2014143582A RU2606449C2 (en) 2014-10-29 2014-10-29 Method of activating aluminium for producing hydrogen

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RU2014143582A true RU2014143582A (en) 2016-05-20
RU2606449C2 RU2606449C2 (en) 2017-01-10

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110155943A (en) * 2019-05-13 2019-08-23 湖北工业大学 Super-active hydrolytic hydrogen production aluminum matrix composite and preparation method thereof
CN114506814A (en) * 2022-01-20 2022-05-17 清华大学 Aluminum activation hydrogen production method, hydrogen production device and power generation equipment

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2344989C2 (en) * 2006-06-21 2009-01-27 Открытое акционерное общество "Государственный научно-исследовательский институт машиностроения имени В.В.Бахирева" (ОАО "ГосНИИмаш") Aluminium powdered material and method of obtaining thereof
US8418435B2 (en) * 2008-06-13 2013-04-16 Nagi Hatoum Method for production of power from aluminum
RU2397141C2 (en) * 2008-10-07 2010-08-20 Институт химии твердого тела УрО РАН Method of producing hydrogen and chemical reactor for realising said method
RU2394753C1 (en) * 2009-04-01 2010-07-20 Учреждение Российской Академии Наук Объединенный Институт Высоких Температур Ран (Оивт Ран) Hydroreactive composition for producing hydrogen and method of preparing said composition
RU2414424C2 (en) * 2009-05-04 2011-03-20 Учреждение Российской академии наук Институт катализа им. Г.К. Борескова Сибирского отделения РАН Method of activating aluminium and apparatus for realising said method

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110155943A (en) * 2019-05-13 2019-08-23 湖北工业大学 Super-active hydrolytic hydrogen production aluminum matrix composite and preparation method thereof
CN114506814A (en) * 2022-01-20 2022-05-17 清华大学 Aluminum activation hydrogen production method, hydrogen production device and power generation equipment
CN114506814B (en) * 2022-01-20 2023-03-24 清华大学 Aluminum activation hydrogen production method, hydrogen production device and power generation equipment

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Effective date: 20171030