RU2014125552A - Тройные сополимеры на основе пропилена для труб - Google Patents

Тройные сополимеры на основе пропилена для труб Download PDF

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RU2014125552A
RU2014125552A RU2014125552A RU2014125552A RU2014125552A RU 2014125552 A RU2014125552 A RU 2014125552A RU 2014125552 A RU2014125552 A RU 2014125552A RU 2014125552 A RU2014125552 A RU 2014125552A RU 2014125552 A RU2014125552 A RU 2014125552A
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hexene
ethylene
derivative units
triple copolymer
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RU2599251C2 (ru
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Клаудио КАВАЛЬЕРИ
Моника ГАЛЬВАН
Тициана КАПУТО
Херберт ТЕРВИЕН
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Базелль Полиолефин Италия С.Р.Л.
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/14—Monomers containing five or more carbon atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B1/00—Layered products having a non-planar shape
    • B32B1/08—Tubular products
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/304—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/14—Monomers containing five or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L9/00—Rigid pipes
    • F16L9/12—Rigid pipes of plastics with or without reinforcement
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L9/00—Rigid pipes
    • F16L9/12—Rigid pipes of plastics with or without reinforcement
    • F16L9/127—Rigid pipes of plastics with or without reinforcement the walls consisting of a single layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00—Layers arrangement
    • B32B2250/24—All layers being polymeric
    • B32B2250/242—All polymers belonging to those covered by group B32B27/32
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00—Layers arrangement
    • B32B2250/24—All layers being polymeric
    • B32B2250/246—All polymers belonging to those covered by groups B32B27/32 and B32B27/30
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/54—Yield strength; Tensile strength
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/546—Flexural strength; Flexion stiffness
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/558—Impact strength, toughness
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2597/00—Tubular articles, e.g. hoses, pipes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/04—Homopolymers or copolymers of ethene
    • C08J2323/08—Copolymers of ethene

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

1. Тройной сополимер, содержащий пропилен, этилен и 1-гексен, в котором:(i) содержание производных единиц 1-гексена колеблется от 1 до 3,2%;(ii) содержание производных единиц этилена выше 1,4 вес.% и соответствует следующему соотношению (1):где С2 - это содержание производных единиц этилена, вес.%,C6 - это содержание производных единиц 1-гексена, вес. %;(iii) скорость течения расплава (MFR) (ISO 1133 230°C, 5 кг) составляет от 0,1 до 3,9 г/10 мин;(iv) температура плавления колеблется от 130 до 138°C; предпочтительно от 132 до 136°C.2. Тройной сополимер по п. 1, в котором содержание производных единиц 1-гексена колеблется от 1,5 до 3,0%, и содержание производных единиц этилена выше 1,5 вес. %.3. Тройной сополимер по любому одному из пп. 1 или 2, в котором соотношение (1) равно C2<C6-0,3.4. Тройной сополимер по любому одному из пп. 1 или 2, у которого скорость течения расплава (MFR) (ISO 1133 230°C, 2,16 кг) составляет от 0,5 до 1,9 г/10 мин.5. Тройной сополимер по п. 3, у которого скорость течения расплава (MFR) (ISO 1133 230°C, 2,16 кг) составляет от 0,5 до 1,9 г/10 мин.6. Трубопроводные системы и листы, состоящие из полиолефиновой композиции в соответствии с пп. 1-5.7. Однослойные или многослойные трубы и листы, в которых по меньшей мере один слой состоит из полиолефиновой композиции по п. 1.

Claims (7)

1. Тройной сополимер, содержащий пропилен, этилен и 1-гексен, в котором:
(i) содержание производных единиц 1-гексена колеблется от 1 до 3,2%;
(ii) содержание производных единиц этилена выше 1,4 вес.% и соответствует следующему соотношению (1):
Figure 00000001
где С2 - это содержание производных единиц этилена, вес.%,
C6 - это содержание производных единиц 1-гексена, вес. %;
(iii) скорость течения расплава (MFR) (ISO 1133 230°C, 5 кг) составляет от 0,1 до 3,9 г/10 мин;
(iv) температура плавления колеблется от 130 до 138°C; предпочтительно от 132 до 136°C.
2. Тройной сополимер по п. 1, в котором содержание производных единиц 1-гексена колеблется от 1,5 до 3,0%, и содержание производных единиц этилена выше 1,5 вес. %.
3. Тройной сополимер по любому одному из пп. 1 или 2, в котором соотношение (1) равно C2<C6-0,3.
4. Тройной сополимер по любому одному из пп. 1 или 2, у которого скорость течения расплава (MFR) (ISO 1133 230°C, 2,16 кг) составляет от 0,5 до 1,9 г/10 мин.
5. Тройной сополимер по п. 3, у которого скорость течения расплава (MFR) (ISO 1133 230°C, 2,16 кг) составляет от 0,5 до 1,9 г/10 мин.
6. Трубопроводные системы и листы, состоящие из полиолефиновой композиции в соответствии с пп. 1-5.
7. Однослойные или многослойные трубы и листы, в которых по меньшей мере один слой состоит из полиолефиновой композиции по п. 1.
RU2014125552/04A 2011-12-05 2012-12-05 Тройные сополимеры на основе пропилена для труб RU2599251C2 (ru)

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EP11191865.2 2011-12-05
EP11191865.2A EP2602102A1 (en) 2011-12-05 2011-12-05 Propylene-based terpolymers for pipes
PCT/EP2012/074390 WO2013083575A1 (en) 2011-12-05 2012-12-05 Propylene-based terpolymers for pipes

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2727959A1 (en) * 2012-11-01 2014-05-07 Basell Poliolefine Italia S.r.l. Propylene-based terpolymers composition for pipes
EP3227192B1 (en) * 2014-12-03 2018-10-17 Basell Poliolefine Italia S.r.l. Propylene based terpolymer for containers
CN111263698A (zh) * 2017-11-09 2020-06-09 巴塞尔聚烯烃意大利有限公司 热收缩标签
US20210292449A1 (en) * 2018-07-27 2021-09-23 Sabic Global Technologies B.V. Process for making propylene-based terpolymer
WO2020020811A1 (en) 2018-07-27 2020-01-30 Sabic Global Technologies B.V. Propylene-based terpolymer composition for pipes
EP3830143B1 (en) 2018-07-27 2022-11-16 SABIC Global Technologies B.V. Propylene-based terpolymer composition for pipes
US11988319B2 (en) 2020-01-27 2024-05-21 Sabic Global Technologies B.V. Propylene-based terpolymer composition for pipes
WO2024013128A1 (en) 2022-07-11 2024-01-18 Borealis Ag A propylene-ethylene random copolymer for pipe applications
WO2024013126A1 (en) 2022-07-11 2024-01-18 Borealis Ag A process for preparing propylene-ethylene random copolymers for pipe applications

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1098272B (it) 1978-08-22 1985-09-07 Montedison Spa Componenti,di catalizzatori e catalizzatori per la polimerizzazione delle alfa-olefine
IT1209255B (it) 1980-08-13 1989-07-16 Montedison Spa Catalizzatori per la polimerizzazione di olefine.
IT1190681B (it) 1982-02-12 1988-02-24 Montedison Spa Componenti e catalizzatori per la polimerizzazione di olefine
IT1227260B (it) 1988-09-30 1991-03-28 Himont Inc Dieteri utilizzabili nella preparazione di catalizzatori ziegler-natta
AT404252B (de) * 1994-05-13 1998-10-27 Danubia Petrochem Polymere Verfahren zur erhöhung des anteiles der beta-modifikation in polypropylen
IL117114A (en) 1995-02-21 2000-02-17 Montell North America Inc Components and catalysts for the polymerization ofolefins
CA2301517A1 (en) 1998-07-08 2000-01-20 Montell Technology Company B.V. Process and apparatus for the gas-phase polymerisation
US7595103B2 (en) * 2001-10-30 2009-09-29 Basell Poliolefine Italia S.P.A. Pipe systems of polypropylene compositions
US7652092B2 (en) * 2002-08-12 2010-01-26 Exxonmobil Chemical Patents Inc. Articles from plasticized thermoplastic polyolefin compositions
EP1759139B1 (en) * 2004-06-25 2008-05-07 Basell Poliolefine Italia S.r.l. PIPE SYSTEMS MADE FROM RANDOM COPOLYMERS OF PROPYLENE AND alpha-OLEFINS
ATE526350T1 (de) * 2008-05-28 2011-10-15 Borealis Ag In gegenwart eines ziegler-natta-katalysators hergestelltes statistisches propylen-hexen- copolymer
ES2359761T3 (es) * 2008-11-18 2011-05-26 Borealis Ag Copolímero aleatorio de propileno-hexeno producido en presencia de un catalizador metalocénico.
US8785584B2 (en) * 2010-04-14 2014-07-22 Basell Poliolefine Italia S.R.L. Propylene-based terpolymers for films

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EP2602102A1 (en) 2013-06-12
RU2599251C2 (ru) 2016-10-10
BR112014012516A2 (pt) 2017-06-06
BR112014012516B1 (pt) 2020-10-13
CN104271342B (zh) 2018-04-10
EP2788181B1 (en) 2018-07-04
CN104271342A (zh) 2015-01-07
WO2013083575A1 (en) 2013-06-13
EP2788181A1 (en) 2014-10-15
US20140332109A1 (en) 2014-11-13

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