RU2014123615A - THICKENER CONTAINING AT LEAST ONE POLYMER BASED ON ASSOCIATIVE MONOMERS - Google Patents

THICKENER CONTAINING AT LEAST ONE POLYMER BASED ON ASSOCIATIVE MONOMERS Download PDF

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RU2014123615A
RU2014123615A RU2014123615/04A RU2014123615A RU2014123615A RU 2014123615 A RU2014123615 A RU 2014123615A RU 2014123615/04 A RU2014123615/04 A RU 2014123615/04A RU 2014123615 A RU2014123615 A RU 2014123615A RU 2014123615 A RU2014123615 A RU 2014123615A
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polymer
thickener according
monomer
thickener
activator
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RU2014123615/04A
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Райнхольд Дж. ЛАЙРЕР
Кристофер АРИЗАНДИ
Уидад БЕНЛАМАР
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Басф Се
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/43—Thickening agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/04—Acids; Metal salts or ammonium salts thereof
    • C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8105—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • A61K8/8111—Homopolymers or copolymers of aliphatic olefines, e.g. polyethylene, polyisobutene; Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
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    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
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    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
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    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
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    • A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
    • A61K8/8182—Copolymers of vinyl-pyrrolidones. Compositions of derivatives of such polymers
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    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
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    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/02—Preparations for cleaning the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/12—Preparations containing hair conditioners
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    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
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    • C08F2/16—Aqueous medium
    • C08F2/22—Emulsion polymerisation
    • C—CHEMISTRY; METALLURGY
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    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F226/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F6/00—Post-polymerisation treatments
    • C08F6/14—Treatment of polymer emulsions
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/143—Sulfonic acid esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/146—Sulfuric acid esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
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    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
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    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/662—Carbohydrates or derivatives
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
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    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
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    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
    • C11D17/003—Colloidal solutions, e.g. gels; Thixotropic solutions or pastes
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    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
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Abstract

1. Загуститель, содержащийi) по меньшей мере один полимер, получаемый полимеризациейa) по меньшей мере одного водорастворимого, этиленового ненасыщенного мономера, включающего в себя по меньшей мере один анионный мономер и/или по меньшей мере один неионогенный мономер,b) по меньшей мере одного этиленового ненасыщенного ассоциативного мономера, отличающегося тем, что этот этиленовый ненасыщенный ассоциативный мономер выбирается из соединений, соответствующих формуле (II),причем R равно алкилу с 6-50 атомами углерода,R′ равно H или алкилу с 1-4 атомами углерода,R′′ равно H или представляет собой метил,n является целым числом предпочтительно от 3 до 50,c) при необходимости по меньшей мере одного сшивающего агента,d) при необходимости по меньшей мере одного агента переноса цепи,ii) по меньшей мере один активатор, причем этот активатор представляет собой поверхностно-активное вещество,причем соотношение активатора и полимера составляет от >10,5 до 50 к 100 [мас.%/мас.%].2. Загуститель по п. 1, отличающийся тем, что в формуле (II) R равно алкилу с 8-30 атомами углерода или R′ равно H или n равно 25.3. Загуститель по п. 1, отличающийся тем, что компонент а) в полимере включает в себя по меньшей мере один анионный мономер, причем этот анионный мономер выбирается из акриловой кислоты, метакриловой кислоты, итаконовой кислоты, малеиновой кислоты или их соли, в частности, этот анионный мономер представляет собой акрилат натрия.4. Загуститель по п. 3, отличающийся тем, что анионный мономер представляет собой акрилат натрия.5. Загуститель по п. 1 или 2, отличающийся тем, что растворимая в воде доля полимера составляет более чем 25 мас.% (в пересчете на общую мас�1. A thickener containing i) at least one polymer obtained by polymerization a) at least one water-soluble, ethylene unsaturated monomer comprising at least one anionic monomer and / or at least one nonionic monomer, b) at least one an ethylene unsaturated associative monomer, characterized in that this ethylene unsaturated associative monomer is selected from compounds corresponding to the formula (II), wherein R is alkyl with 6-50 carbon atoms, R ′ is H or alkyl with 1-4 a by carbon ohms, R ″ is H or represents methyl, n is an integer, preferably from 3 to 50, c) optionally at least one crosslinking agent, d) optionally at least one chain transfer agent, ii) at least at least one activator, the activator being a surfactant, the ratio of activator to polymer being from> 10.5 to 50 to 100 [wt.% / wt.%]. 2. The thickener according to claim 1, characterized in that in formula (II) R is equal to alkyl with 8-30 carbon atoms or R ′ is H or n is 25.3. The thickener according to claim 1, characterized in that component a) in the polymer includes at least one anionic monomer, wherein this anionic monomer is selected from acrylic acid, methacrylic acid, itaconic acid, maleic acid or a salt thereof, in particular this the anionic monomer is sodium acrylate. 4. The thickener according to claim 3, characterized in that the anionic monomer is sodium acrylate. A thickener according to claim 1 or 2, characterized in that the water-soluble fraction of the polymer is more than 25 wt.% (In terms of total weight

Claims (27)

1. Загуститель, содержащий1. A thickener containing i) по меньшей мере один полимер, получаемый полимеризациейi) at least one polymer obtained by polymerization a) по меньшей мере одного водорастворимого, этиленового ненасыщенного мономера, включающего в себя по меньшей мере один анионный мономер и/или по меньшей мере один неионогенный мономер,a) at least one water-soluble, ethylene unsaturated monomer, including at least one anionic monomer and / or at least one nonionic monomer, b) по меньшей мере одного этиленового ненасыщенного ассоциативного мономера, отличающегося тем, что этот этиленовый ненасыщенный ассоциативный мономер выбирается из соединений, соответствующих формуле (II),b) at least one ethylene unsaturated associative monomer, characterized in that the ethylene unsaturated associative monomer is selected from compounds corresponding to formula (II),
Figure 00000001
Figure 00000001
 причем R равно алкилу с 6-50 атомами углерода,where R is equal to alkyl with 6-50 carbon atoms, R′ равно H или алкилу с 1-4 атомами углерода,R ′ is equal to H or alkyl with 1-4 carbon atoms, R′′ равно H или представляет собой метил,R ″ is equal to H or represents methyl, n является целым числом предпочтительно от 3 до 50,n is an integer, preferably from 3 to 50, c) при необходимости по меньшей мере одного сшивающего агента,c) optionally at least one crosslinking agent, d) при необходимости по меньшей мере одного агента переноса цепи,d) optionally at least one chain transfer agent, ii) по меньшей мере один активатор, причем этот активатор представляет собой поверхностно-активное вещество,ii) at least one activator, the activator being a surfactant, причем соотношение активатора и полимера составляет от >10,5 до 50 к 100 [мас.%/мас.%].moreover, the ratio of activator and polymer is from> 10.5 to 50 to 100 [wt.% / wt.%]. 2. Загуститель по п. 1, отличающийся тем, что в формуле (II) R равно алкилу с 8-30 атомами углерода или R′ равно H или n равно 25.2. The thickener according to claim 1, characterized in that in formula (II) R is equal to alkyl with 8-30 carbon atoms or R ′ is H or n is 25. 3. Загуститель по п. 1, отличающийся тем, что компонент а) в полимере включает в себя по меньшей мере один анионный мономер, причем этот анионный мономер выбирается из акриловой кислоты, метакриловой кислоты, итаконовой кислоты, малеиновой кислоты или их соли, в частности, этот анионный мономер представляет собой акрилат натрия.3. The thickener according to claim 1, characterized in that component a) in the polymer includes at least one anionic monomer, this anionic monomer selected from acrylic acid, methacrylic acid, itaconic acid, maleic acid or their salt, in particular , this anionic monomer is sodium acrylate. 4. Загуститель по п. 3, отличающийся тем, что анионный мономер представляет собой акрилат натрия.4. The thickener according to claim 3, characterized in that the anionic monomer is sodium acrylate. 5. Загуститель по п. 1 или 2, отличающийся тем, что растворимая в воде доля полимера составляет более чем 25 мас.% (в пересчете на общую массу полимера).5. A thickener according to claim 1 or 2, characterized in that the water-soluble fraction of the polymer is more than 25 wt.% (In terms of the total polymer weight). 6. Загуститель по п. 1 или 2, отличающийся тем, что компонент а) в полимере включает в себя по меньшей мере один неионогенный мономер, причем этот неионогенный мономер выбирается из N-винилпирролидона, N-винилимидазола или соединения, соответствующего формуле (I),6. The thickener according to claim 1 or 2, characterized in that component a) in the polymer includes at least one nonionic monomer, this nonionic monomer selected from N-vinylpyrrolidone, N-vinylimidazole or a compound corresponding to formula (I) ,
Figure 00000002
Figure 00000002
 причем R7 равно H или является алкилом с 1-4 атомами углерода,wherein R 7 is H or is alkyl with 1-4 carbon atoms, R8 равно H или является метилом, иR 8 is H or is methyl, and R9 и R10 независимо друг от друга представляют собой H или алкил с 1-30 атомами углерода.R 9 and R 10 independently from each other represent H or alkyl with 1-30 carbon atoms. 7. Загуститель по п. 1 или 2, отличающийся тем, что в полимере сшивающий агент (компонент с) выбирается из дивинилбензола, тетрааллиламмонийхлорида, аллилакрилатов, аллилметакрилатов, диакрилатов и диметакрилатов гликолей или полигликолей, бутадиена, 1,7-октадиена, аллилакриламидов или аллилметакриламидов, бисакриламидоуксусной кислоты, Ν,Ν′-метиленбисакриламида или простых полиолполиаллиловых эфиров, таких как полиаллилсахароза или простой пентаэритритолтриаллиловый эфир.7. The thickener according to claim 1 or 2, characterized in that in the polymer the crosslinking agent (component c) is selected from divinylbenzene, tetraallylammonium chloride, allyl acrylates, allyl methacrylates, diacrylates and dimethacrylates of glycols or polyglycols, butadiene, 1,7-alkyldimethylamides , bisacrylamidoacetic acid, Ν, Ν′-methylenebisacrylamide or polyolpolyallyl ethers such as polyallyl saccharose or pentaerythritol triallyl ether. 8. Загуститель по п. 1 или 2, отличающийся тем, что в полимере агент переноса цепи (компонент d) выбирается из меркаптанов, молочной кислоты, муравьиной кислоты, изопропанола или гипофосфитов.8. The thickener according to claim 1 or 2, characterized in that in the polymer the chain transfer agent (component d) is selected from mercaptans, lactic acid, formic acid, isopropanol or hypophosphites. 9. Загуститель по п. 1 или 2, отличающийся тем, что активатор выбирается из алкоксилатов жирных спиртов, алкилгликозидов, алкилкарбоксилатов, алкилбензолсульфонатов, вторичных алкансульфонатов и сульфатов жирных спиртов.9. The thickener according to claim 1 or 2, characterized in that the activator is selected from alkoxylates of fatty alcohols, alkyl glycosides, alkyl carboxylates, alkylbenzenesulfonates, secondary alkanesulfonates and sulfates of fatty alcohols. 10. Загуститель по п. 9, отличающийся тем, что активатор выбирается из алкоксилатов жирных спиртов.10. The thickener according to claim 9, characterized in that the activator is selected from alkoxylates of fatty alcohols. 11. Загуститель по п. 1 или 2, отличающийся тем, что используется смесь по меньшей мере 2 активаторов, причем по меньшей мере один активатор имеет величину ГЛБ (гидрофильно-липофильного баланса), от >12 до 20, а по меньшей мере один активатор величину ГЛБ от 1 до 12.11. A thickener according to claim 1 or 2, characterized in that a mixture of at least 2 activators is used, wherein at least one activator has an HLB (hydrophilic-lipophilic balance) value of> 12 to 20, and at least one activator HLB value from 1 to 12. 12. Загуститель по п.п. 1 или 2, отличающийся тем, что полимер присутствует диспергированным в масляной фазе.12. The thickener according to claims 1 or 2, characterized in that the polymer is present dispersed in the oil phase. 13. Загуститель по п. 12, отличающийся тем, что полимер присутствует диспергированным в масляной фазе в виде инверсной дисперсии, дисперсии «вода-в-масле» или в виде диспергированного в масле безводного полимера.13. The thickener according to claim 12, wherein the polymer is present dispersed in the oil phase as an inverse dispersion, a water-in-oil dispersion, or as an anhydrous polymer dispersed in oil. 14. Способ получения загустителя по одному из пп. 1-13, отличающийся тем, что полимер получается при помощи эмульсионной полимеризации, при помощи инверсионной эмульсионной полимеризации.14. A method of obtaining a thickener according to one of paragraphs. 1-13, characterized in that the polymer is obtained using emulsion polymerization, using inverse emulsion polymerization. 15. Способ по п. 14, отличающийся тем, что полимер получается при помощи инверсионной эмульсионной полимеризации.15. The method according to p. 14, characterized in that the polymer is obtained using inverse emulsion polymerization. 16. Способ по п. 14, отличающийся тем, что после инверсионной эмульсионной полимеризации и перед добавлением активатора отгоняется по меньшей мере частичное количество воды и по меньшей мере частичное количество низкокипящих компонентов масляной фазы.16. The method according to p. 14, characterized in that after the inverse emulsion polymerization and before the addition of the activator, at least a partial amount of water and at least a partial amount of low-boiling components of the oil phase are distilled off. 17. Способ по п. 16, который проводится при помощи технологии LDP (технологии жидких дисперсионных полимеров).17. The method according to p. 16, which is carried out using technology LDP (technology of liquid dispersion polymers). 18. Способ по п. 14, отличающийся тем, что при инверсионной эмульсионной полимеризации компонент b) добавляется в масляную фазу.18. The method according to p. 14, characterized in that in the case of inverse emulsion polymerization, component b) is added to the oil phase. 19. Способ по п. 14, отличающийся тем, что температура в процессе инверсионной эмульсионной полимеризации поддерживается постоянной или повышается.19. The method according to p. 14, characterized in that the temperature in the process of inverse emulsion polymerization is maintained constant or increases. 20. Способ по п. 14, отличающийся тем, что температура в процессе инверсионной эмульсионной полимеризации поддерживается постоянной и составляет по меньшей мере 40°С.20. The method according to p. 14, characterized in that the temperature in the process of inverse emulsion polymerization is maintained constant and is at least 40 ° C. 21. Способ по п. 20, отличающийся тем, что температура составляет от 50 до 90°С.21. The method according to p. 20, characterized in that the temperature is from 50 to 90 ° C. 22. Содержащая поверхностно-активные вещества кислотная композиция, включающая в себя по меньшей мере один загуститель по одному из пп. 1-13, причем величина pH этой композиции составляет от 1 до <7.22. Containing surfactants acid composition comprising at least one thickener according to one of paragraphs. 1-13, and the pH of this composition is from 1 to <7. 23. Применение содержащей поверхностно-активные вещества кислотной композиции по п. 22 в косметике для волос, при укладке волос, в качестве шампуня, в качестве ополаскивателя, в качестве ухаживающего средства, в качестве кондиционера, в качестве крема для кожи, в качестве геля для душа, в качестве кондиционера для стирки белья или в качестве кислотного чистящего средства.23. The use of the surfactant-containing acid composition of claim 22 in hair cosmetics, hair styling, as a shampoo, as a rinse, as a care agent, as a conditioner, as a skin cream, as a gel for shower, as a fabric softener or as an acidic cleaner. 24. Применение содержащей поверхностно-активные вещества кислотной композиции по п. 23 в качестве кислотного чистящего средства для туалета или ванны.24. The use of a surfactant-containing acid composition according to claim 23 as an acidic cleaning agent for a toilet or bath. 25. Содержащая поверхностно-активные вещества щелочная композиция, включающая в себя по меньшей мере один загуститель по одному из пп. 1-13, причем величина pH этой композиции составляет от 7 до 13.25. Containing surfactants, an alkaline composition comprising at least one thickener according to one of claims. 1-13, and the pH of this composition is from 7 to 13. 26. Применение содержащей поверхностно-активные вещества щелочной композиции по п. 25 в качестве ухаживающего средства, в качестве жидкого моющего средства или в качестве средства для мытья посуды для машинной или ручной мойки.26. The use of a surfactant-containing alkaline composition according to claim 25 as a caring agent, as a liquid detergent, or as a dishwashing detergent for machine or manual washing. 27. Применение загустителя по одному из пп. 1-13 в качестве средства, изменяющего вязкость, для оптимизации разжижения при сдвиговой нагрузке, в качестве загущающего средства, для стабилизирования, находящихся во взвешенном состоянии, ингредиентов с размером частиц в области от нанометров до миллиметров и/или в содержащих поверхностно-активные вещества кислотных или щелочных композициях. 27. The use of a thickener according to one of paragraphs. 1-13 as a viscosity-modifying agent to optimize shear thinning, as a thickening agent, to stabilize suspended particles of particles with particle sizes ranging from nanometers to millimeters and / or in acid-containing surfactants or alkaline compositions.
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