RU2010153151A - CORROSION INHIBITORS BASED ON TUNGSTEN - Google Patents
CORROSION INHIBITORS BASED ON TUNGSTEN Download PDFInfo
- Publication number
- RU2010153151A RU2010153151A RU2010153151/02A RU2010153151A RU2010153151A RU 2010153151 A RU2010153151 A RU 2010153151A RU 2010153151/02 A RU2010153151/02 A RU 2010153151/02A RU 2010153151 A RU2010153151 A RU 2010153151A RU 2010153151 A RU2010153151 A RU 2010153151A
- Authority
- RU
- Russia
- Prior art keywords
- tungstate
- acrylamide
- alkali metal
- solution
- acrylic acid
- Prior art date
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
- C23F11/08—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
- C23F11/18—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids using inorganic inhibitors
- C23F11/187—Mixtures of inorganic inhibitors
- C23F11/188—Mixtures of inorganic inhibitors containing phosphates
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05C—NITROGENOUS FERTILISERS
- C05C1/00—Ammonium nitrate fertilisers
- C05C1/02—Granulation; Pelletisation; Stabilisation; Colouring
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/20—Liquid fertilisers
- C05G5/23—Solutions
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
- C23F11/08—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
- C23F11/18—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids using inorganic inhibitors
- C23F11/185—Refractory metal-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F14/00—Inhibiting incrustation in apparatus for heating liquids for physical or chemical purposes
- C23F14/02—Inhibiting incrustation in apparatus for heating liquids for physical or chemical purposes by chemical means
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
- Fertilizers (AREA)
Abstract
1. Способ ингибирования коррозии поверхности черного металла, подвергаемой воздействию раствора азотных удобрений, включающий: добавление к раствору азотных удобрений от примерно 1 млн-1 до примерно 5 млн-1 вольфрамата щелочного металла, эффективного количества ортофосфата, фосфоната и/или фосфонита и при необходимости эффективного количества стабилизатора железа. ! 2. Способ по п.1, в котором указанный раствор азотных удобрений представляет собой раствор мочевины и нитрата аммония. ! 3. Способ по п.1, в котором вольфрамат щелочного металла выбирают из группы, состоящей из вольфрамата натрия, вольфрамата калия, вольфрамата лития и их сочетаний. ! 4. Способ по п.1, в котором стабилизатор железа представляет собой полимерный диспергирующий агент. ! 5. Способ по п.4, в котором полимерный диспергирующий агент представляет собой гомополимер акриловой кислоты и/или тройной сополимер акриловой кислоты, акриламида и акриламидометансульфоновой кислоты. ! 6. Способ по п.4, в котором полимерный диспергирующий агент включает один или более мономеров, выбранных из группы, состоящей из акриловой кислоты, акриламида, третбутилакриламида, метакриловой кислоты, итаконовой кислоты, малеинового ангидрида, 2-акриламид-2-метилпропансульфоновой кислоты, стиролсульфоната, винилсульфоната, аллилглицидилового простого эфира, аллил-гидроксипропил-сульфонатного простого эфира, простого аллилового эфира полиэтиленгликоля, аллилсульфоната и их сочетаний. ! 7. Способ по п.4, в котором полимерный диспергирующий агент представляет собой сополимер акриламида и акриловой кислоты при соотношении 3:1. ! 8. Способ по п.1, в котором вольфрамат щелочно 1. A method of inhibiting corrosion of the surface of a ferrous metal exposed to a solution of nitrogen fertilizers, comprising: adding to the solution of nitrogen fertilizers from about 1 ppm to about 5 ppm of alkali metal tungstate, an effective amount of orthophosphate, phosphonate and / or phosphonite and, if necessary effective amount of iron stabilizer. ! 2. The method according to claim 1, in which the specified solution of nitrogen fertilizers is a solution of urea and ammonium nitrate. ! 3. The method according to claim 1, wherein the alkali metal tungstate is selected from the group consisting of sodium tungstate, potassium tungstate, lithium tungstate, and combinations thereof. ! 4. The method according to claim 1, in which the iron stabilizer is a polymeric dispersing agent. ! 5. The method according to claim 4, in which the polymer dispersing agent is a homopolymer of acrylic acid and / or a triple copolymer of acrylic acid, acrylamide and acrylamide methanesulfonic acid. ! 6. The method according to claim 4, in which the polymer dispersing agent comprises one or more monomers selected from the group consisting of acrylic acid, acrylamide, tert-butyl acrylamide, methacrylic acid, itaconic acid, maleic anhydride, 2-acrylamide-2-methylpropanesulfonic acid, styrene sulfonate, vinyl sulfonate, allyl glycidyl ether, allyl hydroxypropyl sulfonate ether, polyethylene glycol allyl ether, allyl sulfonate, and combinations thereof. ! 7. The method according to claim 4, in which the polymer dispersing agent is a copolymer of acrylamide and acrylic acid in a ratio of 3: 1. ! 8. The method according to claim 1, in which tungstate is alkaline
Claims (14)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US12/141,512 US7968007B2 (en) | 2005-04-25 | 2008-06-18 | Tungstate based corrosion inhibitors |
US12/141,512 | 2008-06-18 | ||
PCT/US2009/047493 WO2009155282A1 (en) | 2008-06-18 | 2009-06-16 | Tungstate based corrosion inhibitors |
Publications (2)
Publication Number | Publication Date |
---|---|
RU2010153151A true RU2010153151A (en) | 2012-07-27 |
RU2509178C2 RU2509178C2 (en) | 2014-03-10 |
Family
ID=41064647
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
RU2010153151/02A RU2509178C2 (en) | 2008-06-18 | 2009-06-16 | Tungstate-based corrosion inhibitors |
Country Status (7)
Country | Link |
---|---|
US (1) | US7968007B2 (en) |
AR (1) | AR072190A1 (en) |
BR (1) | BRPI0909918B1 (en) |
CA (1) | CA2727033C (en) |
RU (1) | RU2509178C2 (en) |
TW (1) | TWI526577B (en) |
WO (1) | WO2009155282A1 (en) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2431346A1 (en) * | 2010-09-15 | 2012-03-21 | Uhde Fertilizer Technology B.V. | Method for producing urea fertilizer with low moisture absorption tendencies |
US9175405B2 (en) | 2013-03-15 | 2015-11-03 | Ecolab Usa Inc. | Corrosion control compositions and methods of mitigating corrosion |
US9222019B2 (en) | 2013-10-29 | 2015-12-29 | Ecolab Usa Inc. | Use of niobate containing compounds as corrosion inhibitors |
CN109776722A (en) * | 2019-02-11 | 2019-05-21 | 山东理工大学 | Ternary graft copolymer and its preparation method and application |
RU2732844C1 (en) * | 2020-03-26 | 2020-09-23 | Алексей Станиславович Владыкин | Corrosion and scaling inhibitor |
US11746294B2 (en) * | 2021-05-28 | 2023-09-05 | Chemtreat, Inc. | Corrosion control using organic filmers and passivators in systems for processing nitrogen-containing solutions |
Family Cites Families (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3790610A (en) * | 1971-09-07 | 1974-02-05 | Colloids Inc | Organic polymer chelants for iron and manganese ions |
US4289634A (en) * | 1979-07-25 | 1981-09-15 | Chevron Research Company | Deposit control additives and fuel and lube oil compositions containing them |
US4409121A (en) * | 1980-07-21 | 1983-10-11 | Uop Inc. | Corrosion inhibitors |
US4659481A (en) * | 1983-10-26 | 1987-04-21 | Betz Laboratories Inc. | Water treatment polymers and methods of use thereof |
US5047078A (en) * | 1985-05-02 | 1991-09-10 | Calgon Corporation | Method and compositions for increasing plant growth |
RU2048461C1 (en) | 1991-07-22 | 1995-11-20 | Сократ Павлович Голенецкий | Complex microfertilizer |
US5288410A (en) * | 1991-11-07 | 1994-02-22 | W. R. Grace & Co.-Conn. | Scale control in aqueous systems |
US5376159A (en) * | 1993-09-10 | 1994-12-27 | Nalco Chemical Company | Corrosion inhibitor for nitrogen fertilizer solutions |
US6007772A (en) * | 1994-10-06 | 1999-12-28 | Green; Bruce Philip | Cold sterilant solution |
WO1999028238A1 (en) * | 1997-12-04 | 1999-06-10 | Steris Corporation | Chemical modification of electrochemically activated water |
US6537678B1 (en) | 2000-09-20 | 2003-03-25 | United Technologies Corporation | Non-carcinogenic corrosion inhibiting additive |
SE523240C2 (en) * | 2001-12-12 | 2004-04-06 | Akzo Nobel Nv | Use of hydroxyethyl substituted amine as corrosion inhibitor in saline environment in oilfield applications |
US6953537B2 (en) * | 2002-05-24 | 2005-10-11 | Scott David Trahan | Corrosion inhibitor |
US7402263B2 (en) * | 2005-04-25 | 2008-07-22 | Nalco Company | Tungstate based corrosion inhibitors |
ES2426173T3 (en) | 2006-07-26 | 2013-10-21 | Nalco Company | Tungstate-based corrosion inhibitors |
-
2008
- 2008-06-18 US US12/141,512 patent/US7968007B2/en active Active
-
2009
- 2009-04-24 TW TW098113610A patent/TWI526577B/en active
- 2009-06-16 CA CA2727033A patent/CA2727033C/en active Active
- 2009-06-16 BR BRPI0909918 patent/BRPI0909918B1/en active IP Right Grant
- 2009-06-16 WO PCT/US2009/047493 patent/WO2009155282A1/en active Application Filing
- 2009-06-16 RU RU2010153151/02A patent/RU2509178C2/en active
- 2009-06-18 AR ARP090102226A patent/AR072190A1/en active IP Right Grant
Also Published As
Publication number | Publication date |
---|---|
US20080289384A1 (en) | 2008-11-27 |
CA2727033A1 (en) | 2009-12-23 |
RU2509178C2 (en) | 2014-03-10 |
WO2009155282A1 (en) | 2009-12-23 |
US7968007B2 (en) | 2011-06-28 |
CA2727033C (en) | 2015-03-31 |
TW201000675A (en) | 2010-01-01 |
AR072190A1 (en) | 2010-08-11 |
BRPI0909918A2 (en) | 2015-10-20 |
BRPI0909918B1 (en) | 2019-12-03 |
TWI526577B (en) | 2016-03-21 |
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