RU2010126538A - OIL OF LOW VISCOSITY FROM OLIGOMERS, METHOD FOR ITS PREPARATION AND CONTAINING ITS COMPOSITION - Google Patents

OIL OF LOW VISCOSITY FROM OLIGOMERS, METHOD FOR ITS PREPARATION AND CONTAINING ITS COMPOSITION Download PDF

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RU2010126538A
RU2010126538A RU2010126538/04A RU2010126538A RU2010126538A RU 2010126538 A RU2010126538 A RU 2010126538A RU 2010126538/04 A RU2010126538/04 A RU 2010126538/04A RU 2010126538 A RU2010126538 A RU 2010126538A RU 2010126538 A RU2010126538 A RU 2010126538A
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catalyst
promoter
olefin
vinylidene
combinations
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Вахид БАГХЕРИ (US)
Вахид БАГХЕРИ
Лайонел Д. МУР (US)
Лайонел Д. МУР
Петер М. ДИДЖАЧАНТО (US)
Петер М. ДИДЖАЧАНТО
Мишель САНЧЕЗРИВАС (BE)
Мишель САНЧЕЗРИВАС
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ИНЕОС ЮЭсЭй ЭлЭлСи (US)
ИНЕОС ЮЭсЭй ЭлЭлСи
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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)
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  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

1. Способ изготовления смазки, включающий: ! (a) реакцию первого альфа-олефина в присутствии первого катализатора с образованием винилиденового олефина; ! (b) взаимодействие винилиденового олефина со вторым альфа-олефином в присутствии катализатора ВF3 и системы промотора, включающей по меньшей мере один апротонный промотор; ! (c) удаление остаточных непрореагировавших мономеров; ! (d) гидрирование кубового продукта с образованием композиции смазочного масла. ! 2. Способ по п.1, в котором первый альфа-олефин, используемый для получения винилиденового олефина, выбран из группы, состоящей из линейных олефинов C4-20 и их комбинаций. ! 3. Способ по п.2, в котором содержание винилиденового олефина превышает 70%. ! 4. Способ по п.1, в котором первый катализатор включает алкилалюминиевый катализатор, металлоценовый олефин, катализатор на основе переходного металла конца периода с объемными лигандами и их комбинаций. ! 5. Способ по п.1, в котором первый катализатор представляет собой триалкилалюминиевый катализатор. ! 6. Способ по п.1, в котором первый катализатор представляет собой металлоценовый катализатор, выбранный из металлов IVB группы Периодической системы. ! 7. Способ по п.1, в котором второй альфа-олефин выбран из группы, состоящей из линейных олефинов C4-20 и их комбинаций. ! 8. Способ по п.1, в котором система промотора включает по меньшей мере один апротонный промотор в сочетании по меньшей мере с одним протонным промотором. ! 9. Способ по п.8, в котором протонный промотор выбирают из спиртов C1-20. !10. Способ по п.9, в котором спирт выбирают из 1-пропанола или 1-бутанола. ! 11. Способ по п.1, в котором система промотора включает по меньшей ме� 1. A method of manufacturing a lubricant, including:! (a) reacting a first alpha olefin in the presence of a first catalyst to form a vinylidene olefin; ! (b) reacting a vinylidene olefin with a second alpha olefin in the presence of a BF3 catalyst and a promoter system comprising at least one aprotic promoter; ! (c) removal of residual unreacted monomers; ! (d) hydrogenating the bottom product to form a lubricating oil composition. ! 2. The method according to claim 1, wherein the first alpha olefin used to produce the vinylidene olefin is selected from the group consisting of linear C4-20 olefins and combinations thereof. ! 3. The method according to claim 2, in which the content of vinylidene olefin exceeds 70%. ! 4. The method according to claim 1, in which the first catalyst includes an aluminum alkyl catalyst, a metallocene olefin, an end-period transition metal catalyst with bulky ligands, and combinations thereof. ! 5. The method according to claim 1, in which the first catalyst is a trialkyl aluminum catalyst. ! 6. The method according to claim 1, in which the first catalyst is a metallocene catalyst selected from metals of the IVB group of the Periodic system. ! 7. The method according to claim 1, in which the second alpha olefin is selected from the group consisting of linear C4-20 olefins and combinations thereof. ! 8. The method according to claim 1, wherein the promoter system comprises at least one aprotic promoter in combination with at least one proton promoter. ! 9. The method of claim 8, wherein the proton promoter is selected from C1-20 alcohols. !10. The method of claim 9, wherein the alcohol is selected from 1-propanol or 1-butanol. ! 11. The method according to claim 1, in which the promoter system includes at least

Claims (25)

1. Способ изготовления смазки, включающий:1. A method of manufacturing a lubricant, including: (a) реакцию первого альфа-олефина в присутствии первого катализатора с образованием винилиденового олефина;(a) reacting a first alpha olefin in the presence of a first catalyst to form a vinylidene olefin; (b) взаимодействие винилиденового олефина со вторым альфа-олефином в присутствии катализатора ВF3 и системы промотора, включающей по меньшей мере один апротонный промотор;(b) reacting a vinylidene olefin with a second alpha olefin in the presence of a BF 3 catalyst and a promoter system comprising at least one aprotic promoter; (c) удаление остаточных непрореагировавших мономеров;(c) removal of residual unreacted monomers; (d) гидрирование кубового продукта с образованием композиции смазочного масла.(d) hydrogenating the bottom product to form a lubricating oil composition. 2. Способ по п.1, в котором первый альфа-олефин, используемый для получения винилиденового олефина, выбран из группы, состоящей из линейных олефинов C4-20 и их комбинаций.2. The method according to claim 1, wherein the first alpha olefin used to produce the vinylidene olefin is selected from the group consisting of linear C 4-20 olefins and combinations thereof. 3. Способ по п.2, в котором содержание винилиденового олефина превышает 70%.3. The method according to claim 2, in which the content of vinylidene olefin exceeds 70%. 4. Способ по п.1, в котором первый катализатор включает алкилалюминиевый катализатор, металлоценовый олефин, катализатор на основе переходного металла конца периода с объемными лигандами и их комбинаций.4. The method according to claim 1, in which the first catalyst includes an aluminum alkyl catalyst, a metallocene olefin, an end-period transition metal catalyst with bulky ligands, and combinations thereof. 5. Способ по п.1, в котором первый катализатор представляет собой триалкилалюминиевый катализатор.5. The method according to claim 1, in which the first catalyst is a trialkyl aluminum catalyst. 6. Способ по п.1, в котором первый катализатор представляет собой металлоценовый катализатор, выбранный из металлов IVB группы Периодической системы.6. The method according to claim 1, in which the first catalyst is a metallocene catalyst selected from metals of the IVB group of the Periodic system. 7. Способ по п.1, в котором второй альфа-олефин выбран из группы, состоящей из линейных олефинов C4-20 и их комбинаций.7. The method according to claim 1, in which the second alpha olefin is selected from the group consisting of linear C 4-20 olefins and combinations thereof. 8. Способ по п.1, в котором система промотора включает по меньшей мере один апротонный промотор в сочетании по меньшей мере с одним протонным промотором.8. The method according to claim 1, in which the promoter system includes at least one aprotic promoter in combination with at least one proton promoter. 9. Способ по п.8, в котором протонный промотор выбирают из спиртов C1-20.9. The method of claim 8, in which the proton promoter is selected from alcohols C 1-20 . 10. Способ по п.9, в котором спирт выбирают из 1-пропанола или 1-бутанола.10. The method according to claim 9, in which the alcohol is selected from 1-propanol or 1-butanol. 11. Способ по п.1, в котором система промотора включает по меньшей мере один апротонный промотор без протонного промотора.11. The method according to claim 1, in which the promoter system includes at least one aprotic promoter without a proton promoter. 12. Способ по п.11, в котором апротонный промотор выбирают из группы, состоящей из альдегидов, ангидридов, кетонов, органических сложных эфиров, простых эфиров и их комбинаций.12. The method according to claim 11, in which the aprotic promoter is selected from the group consisting of aldehydes, anhydrides, ketones, organic esters, ethers, and combinations thereof. 13. Способ по п.11, в котором апротонный промотор представляет собой органический сложный эфир, выбранный из группы, состоящей из алкилацетатов C1-С10 и их комбинаций.13. The method according to claim 11, in which the aprotic promoter is an organic ester selected from the group consisting of C 1 -C 10 alkyl acetates and combinations thereof. 14. Способ по п.11, в котором апротонный промотор представляет собой алкилацетат.14. The method according to claim 11, in which the aprotic promoter is an alkyl acetate. 15. Способ по п.14, в котором алкилацетат представляет собой н-бутилацетат.15. The method according to 14, in which the alkyl acetate is n-butyl acetate. 16. Способ по п.1, в котором остаточные непрореагировавшие мономеры удаляют перегонкой.16. The method according to claim 1, in which the residual unreacted monomers are removed by distillation. 17. Способ по п.1, в котором винилиденовый олефин имеет чистоту по меньшей мере 80% и является продуктом димеризации 1-октена с образованием винилидена С16.17. The method according to claim 1, in which the vinylidene olefin has a purity of at least 80% and is a product of dimerization of 1-octene with the formation of vinylidene C16. 18. Способ по п.17, в котором винилиденовый олефин С16 вступает в реакцию с 1-тетрадеценом (С14).18. The method according to 17, in which the C16 vinylidene olefin reacts with 1-tetradecene (C14). 19. Способ по п.18, в котором 1-тетрадецен (С14) содержит по меньшей мере 70% линейных терминальных групп.19. The method according to p, in which 1-tetradecene (C14) contains at least 70% of linear terminal groups. 20. Способ по п.1, в котором композиция смазочного масла имеет вязкость примерно 4 сСт при 100°C, летучесть по Noack в виде потери массы менее 15%, индекс вязкости более 120, температуру застывания ниже -50°С и вязкость при -40°С менее 3000 сСт.20. The method according to claim 1, in which the lubricating oil composition has a viscosity of about 4 cSt at 100 ° C, Noack volatility in the form of a mass loss of less than 15%, a viscosity index of more than 120, a pour point below -50 ° C and a viscosity at - 40 ° C less than 3000 cSt. 21. Способ по п.20, в котором получают композицию смазочного масла без более тяжелых дополнительных продуктов.21. The method according to claim 20, in which the composition of the lubricating oil without heavier additional products. 22. Способ по п.20, в котором композиция смазочного масла характеризуется мольным соотношением винилидена С16 и 1-тетрадецена, равным примерно 1-2.22. The method according to claim 20, in which the lubricating oil composition is characterized by a molar ratio of vinylidene C16 and 1-tetradecene equal to about 1-2. 23. Способ по п.20, в котором композиция смазочного масла характеризуется мольным соотношением винилидена С16 и 1-тетрадецена, равным примерно 1,5.23. The method according to claim 20, in which the lubricating oil composition is characterized by a molar ratio of C16 vinylidene to 1-tetradecene equal to about 1.5. 24. Способ по п.1, в котором смазку смешивают с жидкостью, которую выбирают из группы, состоящей из синтетической жидкости, минерального масла, дисперганта, антиоксиданта, противоизносного реагента, противопенного реагента, ингибитора коррозии, моющего средства, набухающего герметика, присадки для вязкости и их комбинаций.24. The method according to claim 1, in which the lubricant is mixed with a liquid that is selected from the group consisting of synthetic liquid, mineral oil, dispersant, antioxidant, antiwear agent, antifoam agent, corrosion inhibitor, detergent, swelling sealant, viscosity additives and their combinations. 25. Способ получения смазки, включающий:25. A method of obtaining a lubricant, including: (a) реакцию первого альфа-олефина в присутствии первого катализатора с образованием винилиденового олефина;(a) reacting a first alpha olefin in the presence of a first catalyst to form a vinylidene olefin; (b) взаимодействие винилиденового олефина со вторым альфа-олефином в присутствии катализатора ВF3 и системы промотора, включающей по меньшей мере один апротонный промотор;(b) reacting a vinylidene olefin with a second alpha olefin in the presence of a BF 3 catalyst and a promoter system comprising at least one aprotic promoter; (c) удаление остаточных непрореагировавших мономеров;(c) removal of residual unreacted monomers; (d) гидрирование по меньшей мере части кубового продукта; и(d) hydrogenation of at least a portion of the bottoms product; and (е) выделение гидрированной жидкости. (e) the release of hydrogenated liquid.
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Families Citing this family (38)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8748361B2 (en) 2005-07-19 2014-06-10 Exxonmobil Chemical Patents Inc. Polyalpha-olefin compositions and processes to produce the same
US8168838B2 (en) 2009-01-21 2012-05-01 Shell Oil Company Hydrocarbon compositions useful as lubricants
JP6151914B2 (en) * 2010-04-02 2017-06-21 出光興産株式会社 Lubricating oil composition for internal combustion engines
US20130023456A1 (en) * 2010-04-02 2013-01-24 Idemitsu Kosan Co., Ltd. Lubricant composition for an internal combustion engine
JP5671419B2 (en) * 2011-07-15 2015-02-18 出光興産株式会社 Immersion oil for microscope
SG11201401128UA (en) * 2011-10-10 2014-04-28 Exxonmobil Res & Eng Co High efficiency engine oil compositions
CN102937581A (en) * 2012-11-08 2013-02-20 中国人民解放军空军勤务学院 Method for rapid assessing high-temperature oxidation resistance of lubricating grease
US9266793B2 (en) 2012-12-26 2016-02-23 Chevron Phillips Chemical Company Lp Acid-catalyzed olefin oligomerizations
US20140275664A1 (en) 2013-03-13 2014-09-18 Chevron Phillips Chemical Company Lp Processes for Preparing Low Viscosity Lubricants
US10227544B2 (en) * 2013-08-15 2019-03-12 Infineum International Limited Automotive transmission fluid compositions for improved energy efficiency
US11078436B2 (en) 2014-04-11 2021-08-03 Valvoline Licensing And Intellectual Property Llc Lubricant for preventing and removing carbon deposits in internal combustion engines
US10689593B2 (en) * 2014-08-15 2020-06-23 Exxonmobil Research And Engineering Company Low viscosity lubricating oil compositions for turbomachines
KR102329122B1 (en) * 2014-10-23 2021-11-19 에스케이이노베이션 주식회사 upgrading method of hydrocarbon using C4, C5, C6 stream
EP3256552B1 (en) * 2015-02-11 2019-07-31 Shell International Research Maatschappij B.V. Grease composition
US9890093B2 (en) * 2015-12-22 2018-02-13 Chevron Phillips Chemical Company Lp Olefin oligomerizations using chemically-treated solid oxides
CN107304237B (en) * 2016-04-20 2020-10-13 中国石油天然气股份有限公司 Process for synthesis of poly-alpha-olefins
US10647626B2 (en) 2016-07-12 2020-05-12 Chevron Phillips Chemical Company Lp Decene oligomers
CA3043359A1 (en) 2016-11-09 2018-05-17 Novvi Llc Synthetic oligomer compositions and methods of manufacture
US10240102B2 (en) * 2017-03-16 2019-03-26 Chevron Phillips Chemical Company, Lp Lubricant compositions containing hexene-based oligomers
WO2019014533A1 (en) 2017-07-14 2019-01-17 Novvi Llc Base oils and methods of making the same
WO2019031404A1 (en) * 2017-08-10 2019-02-14 出光興産株式会社 Lubricating oil composition, internal combustion engine, and lubrication method for internal combustion engine
US11021553B2 (en) 2018-02-12 2021-06-01 Exxonmobil Chemical Patents Inc. Metallocene dimer selective catalysts and processes to produce poly alpha-olefin dimers
US11078308B2 (en) 2018-02-12 2021-08-03 Exxonmobil Chemical Patents Inc. Processes to produce poly alpha-olefin trimers
US11084894B2 (en) 2018-02-12 2021-08-10 Exxonmobil Chemical Patents Inc. Catalyst systems and processes for poly alpha-olefin having high vinylidene content
JP7150455B2 (en) * 2018-03-30 2022-10-11 出光興産株式会社 Dispersant for lubricating oil, method for producing the same, and lubricating oil composition
ES2949020T3 (en) * 2018-04-25 2023-09-25 Ineos Oligomers Usa Llc Synthetic fluids with improved biodegradability
WO2020060692A2 (en) * 2018-09-17 2020-03-26 Exxonmobil Chemical Patents Inc. Processes to produce poly alpha-olefin trimer and apparatus therefor
US11597890B2 (en) * 2018-09-27 2023-03-07 Exxonmobil Chemical Patents Inc. Base stocks and oil compositions containing the same
KR102115676B1 (en) 2018-12-28 2020-05-27 대림산업 주식회사 Alphaolefin oligomer having a uniform structure and preparation method thereof
KR102275019B1 (en) 2019-06-27 2021-07-08 디엘케미칼 주식회사 Alphaolefin oligomer having low short chain branching and preparation method thereof
US11661465B2 (en) * 2019-10-28 2023-05-30 Exxonmobil Chemical Patents Inc. Dimer selective metallocene catalysts, non-aromatic hydrocarbon soluble activators, and processes to produce poly alpha-olefin oligmers therewith
KR102398899B1 (en) 2019-11-29 2022-05-17 디엘케미칼 주식회사 Low viscosity alpha-olefin oligomer and preparation method thereof
CA3176627A1 (en) 2020-04-29 2021-11-04 Mark H. Li Poly alpha-olefin compositions and processes to produce poly alpha-olefins
KR102368349B1 (en) * 2020-05-04 2022-02-25 디엘케미칼 주식회사 Alphaolefin oligomer having low short chain branching and method for preparating thereof
CN116023562A (en) * 2021-10-25 2023-04-28 中国石油化工股份有限公司 Production process of poly alpha-olefin
US11820740B1 (en) 2022-08-22 2023-11-21 Chevron Phillips Chemical Company Lp Olefin metathesis by reactive distillation
WO2024129687A1 (en) 2022-12-15 2024-06-20 Chevron Phillips Chemical Company Lp Solid oxide and chemically-treated solid oxide catalysts for the production of polyalphaolefins
WO2024162399A1 (en) * 2023-02-01 2024-08-08 Ｅｎｅｏｓ株式会社 Base oil for refrigerating machine oil, refrigerating machine oil, and working fluid composition

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4172855A (en) * 1978-04-10 1979-10-30 Ethyl Corporation Lubricant
US5012020A (en) * 1989-05-01 1991-04-30 Mobil Oil Corporation Novel VI enhancing compositions and Newtonian lube blends
US4973788A (en) * 1989-05-05 1990-11-27 Ethyl Corporation Vinylidene dimer process
US5087788A (en) * 1991-03-04 1992-02-11 Ethyl Corporation Preparation of high purity vinylindene olefin
US5498815A (en) * 1991-12-13 1996-03-12 Albemarle Corporation Preparation of synthetic oils from vinylidene olefins and alpha-olefins
US6824671B2 (en) * 2001-05-17 2004-11-30 Exxonmobil Chemical Patents Inc. Low noack volatility poly α-olefins
US6646174B2 (en) * 2002-03-04 2003-11-11 Bp Corporation North America Inc. Co-oligomerization of 1-dodecene and 1-decene
KR20030073807A (en) * 2002-03-13 2003-09-19 주식회사 안랩유비웨어 An authentication and authorization system for home network
WO2004031330A2 (en) * 2002-09-30 2004-04-15 Shell Internationale Research Maatschappij B.V. Continuously variable transmission fluid and method of making same
RU2287552C2 (en) * 2004-12-22 2006-11-20 Институт Проблем Химической Физики Российской Академии Наук (Ипхф Ран) Method of production of the polyolefin bases of the synthetic oils
US8299002B2 (en) * 2005-10-18 2012-10-30 Afton Chemical Corporation Additive composition

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