RU2007136798A - CONDUCTIVE INK AND METHOD FOR PRODUCING THERE - Google Patents

Abstract

1. A conductive ink composition comprising a metal complex compound obtained by reacting at least one metal or a metal compound represented by formula 1 below with at least one compound based on ammonium carbamate or ammonium carbonate represented by formulas 2, 3 or 4 below, and the supplement! MnX, (1)! where M is a metal or metal alloy, n is an integer from 1 to 10, and X is absent or is at least one substituent selected from the group consisting of hydrogen, ammonium, oxygen, sulfur, halogen, cyano, cyanate, carbonate, nitrate, nitrite, sulfate, phosphate, thiocyanate, chlorate, perchlorate, tetrafluoroborate, acetylacetonate, mercapto, amide, alkoxide, carboxylate and their derivatives; and! ! ! ! wherein each of R1, R2, R3, R4, R5 and R6 is independently selected from hydrogen, substituted or unsubstituted C1-C30 aliphatic alkyl, cycloaliphatic alkyl, aryl or aralkyl, a polymer compound, a heterocyclic compound, and derivatives thereof, wherein R1 and R2 or R4 and R5 can be joined together to form an alkylene ring with or without a heteroatom. ! 2. The composition for conductive ink according to claim 1, where the metal-complex compound is represented by formula 5 below! MAm (5)! A means a compound represented by any of formulas 2-4, and 0.7 ≤ m 5 5.5. ! 3. The conductive ink composition according to claim 1, where the metal or metal compound represented by formula 1 is at least one component selected from the group consisting of Ag, Au, Cu, Zn, Ni, Co, Pd, Pt, Ti, V, Mn, Fe, Cr, Zr, Nb, Mo, W, Ru, Cd, Ta, Re, Os, Ir, Al, Ga, Ge, In, Sn, Sb, Pb, Bi, Sm, Eu, Ac, Th, copper oxide, zinc oxide, vanadium oxide, nickel sulfide, palladium chloride

Claims (39)

1. A conductive ink composition comprising a metal complex compound obtained by reacting at least one metal or a metal compound represented by formula 1 below with at least one compound based on ammonium carbamate or ammonium carbonate represented by formulas 2, 3 or 4 below, and supplement M _n X (one) where M is a metal or metal alloy, n is an integer from 1 to 10, and X is absent or is at least one substituent selected from the group consisting of hydrogen, ammonium, oxygen, sulfur, halogen, cyano, cyanate, carbonate, nitrate, nitrite, sulfate, phosphate, thiocyanate, chlorate, perchlorate, tetrafluoroborate, acetylacetonate, mercapto, amide, alkoxide, carboxylate and their derivatives; and

wherein each of R ₁ , R ₂ , R ₃ , R ₄ , R ₅ and R _{6 is} independently selected from hydrogen, substituted or unsubstituted C ₁ -C ₃₀ aliphatic alkyl, cycloaliphatic alkyl, aryl or aralkyl, a polymer compound, a heterocyclic compound, and derivatives thereof, wherein R ₁ and R ₂ or R ₄ and R ₅ can be joined together to form an alkylene ring with or without a heteroatom. 2. The composition for conductive ink according to claim 1, where the metal complex compound is represented by formula 5 below MA _m (5) A means a compound represented by any of formulas 2-4, and 0.7 ≤ m 5 5.5. 3. The conductive ink composition according to claim 1, where the metal or metal compound represented by formula 1 is at least one component selected from the group consisting of Ag, Au, Cu, Zn, Ni, Co, Pd, Pt, Ti, V, Mn, Fe, Cr, Zr, Nb, Mo, W, Ru, Cd, Ta, Re, Os, Ir, Al, Ga, Ge, In, Sn, Sb, Pb, Bi, Sm, Eu, Ac, Th, copper oxide, zinc oxide, vanadium oxide, nickel sulfide, palladium chloride, copper carbonate, iron chloride, gold chloride, nickel chloride, cobalt chloride, bismuth nitrate, vanadium acetylacetonate, cobalt acetate, tin lactate, manganese oxalate, acetate gold, palladium oxalate, 2- tilgeksanoata copper, iron stearate, nickel formate, ammonium molybdate, zinc citrate, bismuth acetate, copper cyanide, cobalt carbonate, platinum chloride, hydrogen chloroaurate, tetrabutoxytitanium, dimetoksitsirkoniydihlorida, aluminum isopropoxide, tin tetrafluoroborate, tantalum methoxide, dodetsilmerkaptoaurata and indium acetylacetonate. 4. The conductive ink composition according to claim 3, where the metal or metal compound represented by formula 1 is silver (Ag) or a silver compound, n is an integer from 1 to 4, and X means at least one component selected from a group consisting of oxygen, sulfur, halogen, cyano, cyanate, carbonate, nitrate, nitrite, sulfate, phosphate, thiocyanate, chlorate, perchlorate, tetrafluoroborate, acetylacetonate, carboxylate and their derivatives. 5. The conductive ink composition of claim 4, wherein the silver compound is at least one compound selected from the group consisting of silver oxide, silver thiocyanate, silver cyanide, silver cyanate, silver carbonate, silver nitrate, silver nitrite, silver sulfate silver phosphate, silver perchlorate, silver tetrafluoroborate, silver acetylacetonate, silver acetate, silver lactate, silver oxalate and their derivatives, and the silver alloy is an alloy containing at least one metal component selected from a group consisting of Au, Cu, Ni, Co, Pd, Pt, Ti, V, Mn, Fe, Cr, Zr, Nb, Mo, W, Ru, Cd, Ta, Re, Os, Ir, Al, Ga, Ge, In, Sn, Sb, Pb, Bi, Si, As, Hg, Sm, Eu, Th, Mg, Ca, Sr and Ba. 6. The composition for the conductive ink according to claim 1, where each of the substituents R ₁ , R ₂ , R ₃ , R ₄ , R ₅ and R ₆ independently selected from the group consisting of hydrogen, methyl, ethyl, propyl, isopropyl, butyl , isobutyl, amyl, hexyl, ethylhexyl, heptyl, octyl, isooctyl, nonyl, decyl, dodecyl, hexadecyl, octadecyl, docodecyl, cyclopropyl, cyclopentyl, cyclohexyl, allyl, hydroxy, methoxy, methoxyethyl, methoxyethyl, methoxyethyl, butoxypropyl, , methoxyethoxyethyl, methoxyethoxyethoxyethyl, hexamethyleneimine, morpholine, piperidine, pipe Razin, ethylenediamine, propylenediamine, hexamethylenediamine, triethylenediamine, pyrrole, imidazole, pyridine, carboxymethyl, trimethoxysilylpropyl, triethoxysilylpropyl, phenyl, methoxyphenyl, cyanophenyl, phenoxy, tolyl amine, polyethylene. 7. The conductive ink composition of claim 1, wherein the ammonium carbamate-based compound is at least one compound selected from the group consisting of ammonium carbamate, ethylammonium ethyl carbamate, isopropylammonium isopropyl carbamate, n-butyl ammonium n-butyl carbamate, isobutyl ammonium isobutyl carbamate tert-butylammonium β-butyl carbamate, 2-ethylhexylammonium 2-ethylhexylcarbamate, octadecylammonium octadecyl carbamate, 2-methoxyethylammonium 2-methoxyethylammonium, 2-cyanoethylammonium 2-cyanoethylamocarbamate ibutylammonium, dioctadecylammonium dioctadecylcarbamate, methyldecylammonium methyldecyl carbamate, hexamethyleneimine carbamate hexamethyleneiminium morpholinium morpholinium ethyl hexylcarbylamino triamyl benzam triethylamino triamyl triamyl triamyl triamyl triamobiamide and the ammonium carbonate-based compound is at least one compound selected from the group consisting of ammonium carbonate, ethylammonium ethyl carbonate, isopropylammonium isopropyl carbonate, n-butyl ammonium n-butyl carbonate, isobutyl ammonium isobutyl carbonate, tert-butyl ammonium tert-butyl 2-butylcarbonate 2-butyl 2-butylcarbonate tert-butyl 2-butylcarbonate tert-butyl 2-butylcarbonate 2-butylammonate ethylhexylammonium, 2-methoxyethyl carbonate 2-methoxyethylammonium, 2-cyanoethyl carbonate 2-cyanoethylammonium, octadecyl carbonate octadecylammonium, dibutylammonium dibutyl carbonate, dioctadecyl carbonate dioct decylammonium, metildetsilkarbonata metildetsilammoniya, geksametileniminkarbonata hexamethyleneimino morfolinkarbonata morpholine benzilkarbonata benzylammonium, trietoksisililpropilkarbonata trietoksisililpropilammoniya, isopropylammonium triethylenediaminium bicarbonate, ammonium bicarbonate, isopropylammonium bicarbonate, t-butylammonium bicarbonate, 2-ethylhexylcarbamate, sodium 2-metoksietilammoniya bicarbonate 2-tsianoetilammoniya bicarbonate dioktadetsilammoniya bicarbonate pyridinium, triethylenediaminium bicarbonate and and Derivatives. 8. The conductive ink composition according to claim 1, where the additive is at least one additive selected from the group consisting of a conductor, a metal precursor, an oxidizing agent, a stabilizer, a solvent, a dispersant, a binder resin, a reducing agent, a surfactant, a wetting agent , thixotropic additives and leveling agents. 9. The conductive ink composition of claim 8, where the conductor is at least one component selected from the group consisting of at least one metal selected from the group consisting of Ag, Au, Cu, Zn, Ni, Co, Pd, Pt, Ti, V, Mn, Fe, Cr, Zr, Nb, Mo, W, Ru, Cd, Ta, Re, Os, Ir, Al, Ga, Ge, In, Sn, Sb, Pb, Bi, Sm, Eu, Ac and Th, their alloy or their oxide alloy, carbon black, graphite, carbon nanotubes and a conductive polymer. 10. The conductive ink composition of claim 8, where the conductor is at least one metal compound represented by formula 1 below M _n X (one) where M means at least one metal selected from the group consisting of Ag, Au, Cu, Zn, Ni, Co, Pd, Pt, Ti, V, Mn, Fe, Cr, Zr, Nb, Mo, W, Ru , Cd, Ta, Re, Os, Ir, Al, Ga, Ge, In, Sn, Sb, Pb, Bi, Sm, Eu, Ac and Th or an alloy thereof, n is an integer from 1 to 10, and X means at least one substituent selected from the group consisting of hydrogen, ammonium, oxygen, sulfur, halogen, cyano, cyanate, carbonate, nitrate, nitrite, sulfate, phosphate, thiocyanate, chlorate, perchlorate, tetrafluoroborate, acetylacetonate, mercapto, amide, alkoxide, carboxylate and their derivatives. 11. The conductive ink composition of claim 10, wherein the metal precursor is at least one component selected from the group consisting of gold acetate, silver acetate, palladium oxalate, silver 2-ethylhexanoate, copper 2-ethylhexanoate, iron stearate, formate nickel, zinc citrate, silver nitrate, copper cyanide, cobalt carbonate, platinum chloride, hydrogen tetrachloroaurate, tetrabutoxy titanium, dimethoxy zirconium dichloride, aluminum isopropoxide, tin tetrafluoroborate, vanadium oxide, indium tin oxide, tantalum methoxide, and bismuth cetate, dodecyl mercaptoauaurate and indium acetylacetonate. 12. The composition for conductive ink of claim 8, where the conductor, the metal precursor or a mixture thereof is contained in an amount of 1-90 per 100 wt.% Ink composition. 13. The conductive ink composition of claim 8, wherein the metal conductor or precursor is in a form selected from the group consisting of particles, powder, flakes, colloid, hybrid, paste, sol, solution, and combinations thereof. 14. The composition for the conductive ink of claim 8, where the conductor or metal precursor has a spherical, linear or flat shape, or a combination thereof. 15. The conductive ink composition of claim 8, wherein the oxidizing agent is at least one oxidizing agent selected from the group consisting of oxidizing gas, peroxide, peroxyacid, oxidative inorganic acid, oxidative metal compound and oxidative non-metallic compound. 16. The conductive ink composition of claim 15, wherein the oxidizing agent is at least one oxidizing agent selected from the group consisting of air, oxygen, ozone, hydrogen peroxide (H ₂ O ₂ ), Na ₂ O ₂ , KO ₂ , NaBO ₃ , K ₂ S ₂ O ₈ , (NH ₄ ) ₂ S ₂ O ₈ , Na ₂ S ₂ O ₈ , H ₂ SO ₅ , KHSO ₅ , (CH ₃ ) ₃ CO ₂ H, (C ₆ H ₅ CO ₂ ) ₂ , HCO ₃ H, CH ₃ CO ₃ H, CF ₃ CO ₃ H, C ₆ H ₅ CO ₃ H, m-ClC ₆ H ₅ CO ₃ H, nitric acid, sulfuric acid, I ₂ , FeCl ₃ , Fe (NO ₃ ) ₃ , Fe ₂ (SO ₄ ) ₃ , K ₃ Fe (CN) ₆ , (NH ₄ ) ₂ Fe (SO ₄ ) ₂ , Ce (NH ₄ ) ₄ (SO ₄ ) ₄ , NaIO ₄ , KMnO ₄ and K ₂ CrO ₄ . 17. The conductive ink composition of claim 8, wherein the stabilizer is at least one component selected from an amine compound, an ammonium compound, a phosphorus compound, a sulfur compound, and a mixture thereof. 18. The conductive ink composition of claim 17, wherein the amine compound is at least one compound selected from the group consisting of a primary amine, a secondary amine, and a tertiary amine. 19. The conductive ink composition of claim 18, wherein the amine compound is at least one compound selected from the group consisting of methylamine, ethylamine, n-propylamine, isopropylamine, n-butylamine, isobutylamine, isoamylamine, n-hexylamine, 2 -ethylhexylamine, n-heptylamine, n-octylamine, isooctylamine, nonylamine, decylamine, dodecylamine, hexadecylamine, octadecylamine, docodecylamine, cyclopropylamine, cyclopentylamine, cyclohexylamine, allylamine, hydroxyamine, methoxyamine, methoxide ethylamine, 2-hydroxypropylamine, methoxypropylamine, cyanoethylamine, ethoxyamine, n-butoxyamine, 2-hexyloxyamine, methoxyethoxyethylamine, methoxyethoxyethoxyethylamine, diethylamine, dipropylamine, diethanolamine, ethylenediamine diene diamine diene diamine diene diamine diamine (ethylenedioxy) bisethylamine, triethylamine, triethanolamine, pyrrole, imidazole, pyridine, dimethyl acetal aminoacetaldehyde, 3-aminopropyltrimethoxysilane, 3-aminopropyltriethoxysilane, aniline, anisidine, aminobenzonitrile, benzylamine, polyallylamine, polyethyleneimine and their derivatives. 20. The conductive ink composition of claim 17, wherein the phosphorus compound is at least one compound selected from the group consisting of phosphine and phosphite. 21. The conductive ink composition of claim 8, wherein the binder is at least one binder selected from the group consisting of acrylic resin, cellulosic resin, polyester resin, polyamide resin, ether based resin, vinyl resin, polyurethane resin, polyurea, alkyd resin, silicone resin, fluorine resin, olefin resin, coumaronindene resin, rosin, epoxy resin, unsaturated polyester resin, vinyl ester resin, diallyl phthalate resin, phenolic resin, oxetane resin, oxazine moles, bismaleimide resins, modified silicone resins, melamine resins, acrylic resins, rubber, natural resin, resins reinforced with glass fibers, and glass-ceramic solder. 22. The conductive ink composition of claim 8, wherein the reducing agent is at least one reducing agent selected from the group consisting of a reducing amine compound, a metal salt, and an organic compound. 23. The conductive ink composition of claim 22, wherein the reducing amine compound is at least one compound selected from the group consisting of hydrazine, acetic hydrazide, sodium or potassium borohydride, trisodium citrate, methyldiethanolamine, and dimethylaminoborane, and the organic compound is as at least one compound selected from the group consisting of hydrogen, hydrogen iodide, carbon monoxide, aldehyde such as formaldehyde or acetaldehyde, glucose, ascorbic acid, salicylic acid, tannic acid, pyrogallol and hydroquinone. 24. The conductive ink composition of claim 8, wherein the solvent is at least one solvent selected from the group consisting of water, alcohol, glycol, acetate, ether, ketone, aromatic solvent, and halogenated hydrocarbon. 25. The conductive ink composition of claim 24, wherein the solvent is at least one solvent selected from the group consisting of water, methanol, ethanol, isopropanol, 1-methoxypropanol, butanol, ethylhexyl alcohol, terpineol, ethylene glycol, glycerol, ethyl acetate , butyl acetate, methoxypropyl acetate, carbitol acetate, ethyl carbitol acetate, methyl cellosolve, butyl cellosolve, diethyl ether, tetrahydrofuran, dioxane, methyl ethyl ketone, acetone, dimethylformamide, 1-methyl-2-pyrrolidone, hexane, heptane, para oil, white spirit, benzene, toluene, xylene, chloroform, methylene chloride, carbon tetrachloride, acetonitrile and dimethyl sulfoxide. 26. The conductive ink composition according to claim 1, which is obtained by at least one method selected from the group consisting of heating, cooling, electrolysis, sonication, ultra-short wave processing, high-frequency processing, plasma treatment, infrared processing and ultraviolet treatment radiation. 27. The conductive ink composition according to any one of claims 1 to 26, which is obtained by adding at least one component selected from the group consisting of nitrogen dioxide, sulfur dioxide, carbon dioxide, boric acid and boronic acid, together with carbon dioxide to amine compound to obtain at least one compound represented by formula 2, 3 or 4. 28. A method of producing a metal-containing film, comprising the steps of applying the composition for the conductive ink according to any one of claims 1 to 27 and processing it by oxidation, reduction, heat treatment, infrared processing, UV processing, electron beam processing, or laser processing. 29. The method for producing a metal-containing film according to claim 28, wherein the film is formed by coating a substrate. 30. The method of producing a metal-containing film according to clause 29, where the substrate is at least one component selected from the group consisting of metal, glass, silicon wafer, ceramic, polyester, polyimide, oilcloth, fiber, wood and paper. 31. The method of producing a metal-containing film according to clause 29, where the substrate is subjected to pre-treatment before use. 32. The method of obtaining a metal-containing film according to p, where the pre-treatment is carried out by at least one method selected from the group consisting of plasma treatment, treatment with ion beams, treatment by corona discharge, oxidation or reduction, heating, etching, UV treatment and primers. 33. The method of obtaining a metal-containing film according to p. 28 or 32, where the heat treatment is carried out in air, nitrogen, argon, carbon monoxide, hydrogen or a mixture of these gases. 34. The method of producing a metal-containing film according to claim 28, where the heat treatment is carried out in a temperature range from 80 to 300 ° C. 35. The method of producing a metal-containing film according to claim 28, wherein the heat treatment is carried out at 80-150 ° C for 1-30 minutes and then at 150-300 ° C for 1-30 minutes. 36. The method of producing a metal-containing film according to claim 28, wherein the coating is carried out by centrifugation, coating by rollers, spraying, dipping, watering or coating using a knife device. 37. The method of producing a metal-containing film according to claim 28, wherein the coating is carried out by irrigation with dosing, inkjet printing, offset printing, screen printing, pad printing, gravure printing, flexography, rotary printing, embossing, xerography or lithography. 38. The method of producing a metal-containing film according to claim 28, wherein the coating is carried out by dissolving the conductive ink composition in at least one solvent selected from the group consisting of water, alcohol, glycol, acetate, ether, ketone, aliphatic hydrocarbon, aromatic hydrocarbon and halogenated hydrocarbon. 39. The method of obtaining a metal-containing film according to § 38, where the solvent is at least one solvent selected from the group consisting of water, methanol, ethanol, isopropanol, 1-methoxypropanol, butanol, ethylhexyl alcohol, terpineol, ethylene glycol, glycerol, ethyl acetate , butyl acetate, methoxypropyl acetate, carbitol acetate, ethyl carbitol acetate, methyl cellosolve, butyl cellosolve, diethyl ether, tetrahydrofuran, dioxane, methyl ethyl ketone, acetone, dimethylformamide, 1-methyl-2-pyrrolidone, hexane, heptane, d a, paraffin oil, white spirit, benzene, toluene, xylene, chloroform, methylene chloride, carbon tetrachloride, acetonitrile and dimethyl sulfoxide.