RU2006106728A - COMPOSITION FOR FLUORESCENT WHITENING OF PAPER - Google Patents

COMPOSITION FOR FLUORESCENT WHITENING OF PAPER Download PDF

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Publication number
RU2006106728A
RU2006106728A RU2006106728/12A RU2006106728A RU2006106728A RU 2006106728 A RU2006106728 A RU 2006106728A RU 2006106728/12 A RU2006106728/12 A RU 2006106728/12A RU 2006106728 A RU2006106728 A RU 2006106728A RU 2006106728 A RU2006106728 A RU 2006106728A
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RU
Russia
Prior art keywords
alkyl
paper
composition according
nhch
fluorescent
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RU2006106728/12A
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Russian (ru)
Inventor
Петер РОРИНГЕР (CH)
Петер РОРИНГЕР
Роберт ХОХБЕРГ (DE)
Роберт ХОХБЕРГ
Оливер БЕХЕРЕР (DE)
Оливер БЕХЕРЕР
Ханс КРАМЕР (CH)
Ханс Крамер
Гетц ШЕФЛЕР (DE)
Гетц ШЕФЛЕР
Original Assignee
Циба Спешиалти Кемикэлз Холдинг Инк. (Ch)
Циба Спешиалти Кемикэлз Холдинг Инк.
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Application filed by Циба Спешиалти Кемикэлз Холдинг Инк. (Ch), Циба Спешиалти Кемикэлз Холдинг Инк. filed Critical Циба Спешиалти Кемикэлз Холдинг Инк. (Ch)
Publication of RU2006106728A publication Critical patent/RU2006106728A/en

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Classifications

    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/32—Bleaching agents
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/30—Luminescent or fluorescent substances, e.g. for optical bleaching

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  • Paper (AREA)
  • Detergent Compositions (AREA)
  • Luminescent Compositions (AREA)

Claims (10)

1. Композиция для флуоресцентного отбеливания бумаги, включающая1. Composition for fluorescent paper whitening, including а) флуоресцентный оптический отбеливатель (ФОО), дериватизированный из 4,4'-бис[(1,3,5-триазин-2-ил)амино]стильбен-2,2'-дисульфоновой кислоты и характеризующийся одним или обоими триазиновыми кольцами, несущими заместитель -NH2;a) a fluorescent optical brightener (FOO), derivatized from 4,4'-bis [(1,3,5-triazin-2-yl) amino] stilbene-2,2'-disulfonic acid and characterized by one or both triazine rings, bearing a substituent —NH 2 ; б) воду иb) water and в) необязательно дополнительные вспомогательные вещества.c) optionally additional excipients. 2. Композиция по п.1,2. The composition according to claim 1, включающая от 5 до 50 мас.% ФОО компонента а),comprising from 5 to 50 wt.% FOO component a), от 50 до 95 мас.% воды иfrom 50 to 95 wt.% water and от 0 до 40 мас.% компонента в), количество каждого указано в пересчете на общую массу композиции, где суммарное количество компонентов сfrom 0 to 40 wt.% component c), the amount of each is indicated in terms of the total weight of the composition, where the total number of components with а) по в) составляет 100%.a) by c) is 100%. 3. Композиция по п.1 или 2, в которой флуоресцентный оптический отбеливатель представляет собой соединение формулы (I)3. The composition according to claim 1 or 2, in which the fluorescent optical brightener is a compound of formula (I)
Figure 00000001
Figure 00000001
 в которой X1, Х2 и Х3 каждый независимо друг от друга обозначает -NR1R2 или -OR3, где R1 и R2 каждый независимо друг от друга обозначает водородный атом;in which X 1 , X 2 and X 3 each independently from each other means -NR 1 R 2 or -OR 3 , where R 1 and R 2 each independently from each other represents a hydrogen atom; С1-С4алкильную группу, которая не замещена или замещена одним или двумя следующими остатками, выбранными из группы, включающей С1-С4алкокси, гидроксил, карбокси, циано, карбонамидо, тиол, гуанидин, замещенный или незамещенный фенил, незамещенный или С1-С4алкилзамещенный С5-С8циклоалкил, атом галогена, гетероцикл и остаток сульфоновой кислоты, и где углеродная цепь алкильной группы, содержащей два, три или четыре углеродных атома, может прерываться атомом кислорода,C 1 -C 4 alkyl group which is unsubstituted or substituted by one or two of the following residues selected from the group consisting of C 1 -C 4 alkoxy, hydroxyl, carboxy, cyano, carbonamido, thiol, guanidine, substituted or unsubstituted phenyl, unsubstituted or C 1 -C 4 alkyl substituted C 5 -C 8 cycloalkyl, a halogen atom, a heterocycle and a sulfonic acid residue, and where the carbon chain of an alkyl group containing two, three or four carbon atoms may be interrupted by an oxygen atom, или, по другому варианту,or, in another embodiment, R1 и R2 совместно с соединяющим их атомом азота образуют 5- или 6-членное гетероциклическое кольцо;R 1 and R 2 together with the nitrogen atom connecting them form a 5- or 6-membered heterocyclic ring; R3 обозначает С1-С4алкил, аR 3 is C 1 -C 4 alkyl, and М обозначает Н, Na, Li, К, Са, Mg, аммоний или аммоний, который моно-, ди-, три- или тетразамещен С1-С4алкилом и/или С2-С4гидроксиалкилом.M is H, Na, Li, K, Ca, Mg, ammonium or ammonium which is mono-, di-, tri- or tetrasubstituted with C 1 -C 4 alkyl and / or C 2 -C 4 hydroxyalkyl. 4. Композиция по п.3, в которой у соединения формулы (1) X1 и Х2 каждый независимо обозначает X1 и Х2 каждый независимо обозначает -NH2, -NHC1-С4алкил, -N(С1-С4алкил)2, -NHC2-С4гидроксиалкил, -N(С2-С4гидроксиалкил)2, -N(С1-С4алкил)-(С2-С4гидроксиалкил), -NH(C2-C4алкилен-С1-С4алкокси), -N(С2-С4алкилен-С1-С4алкокси)2, -NHC1-С4алкилфенил, тетрагидрофурфуриламино-, морфолино, пиперидино, пирролидино- или циклогексиламиногруппу, или остаток аминокислоты или амида аминокислоты, из аминогруппы которой удален водородный атом, а4. The composition according to claim 3, in which the compounds of formula (1) X 1 and X 2 each independently represents X 1 and X 2 each independently represents -NH 2 , -NHC 1 -C 4 alkyl, -N (C 1 - C 4 alkyl) 2 , -NHC 2 -C 4 hydroxyalkyl, -N (C 2 -C 4 hydroxyalkyl) 2 , -N (C 1 -C 4 alkyl) - (C 2 -C 4 hydroxyalkyl), -NH (C 2 -C 4 alkylene-C 1 -C 4 alkoxy), -N (C 2 -C 4 alkylene-C 1 -C 4 alkoxy) 2 , -NHC 1 -C 4 alkylphenyl, tetrahydrofurfurylamino, morpholino, piperidino, pyrrolidino- or a cyclohexylamino group, or a residue of an amino acid or amide of an amino acid from the amino group of which a hydrogen atom has been removed, and Х3 обозначает -NH2,X 3 is —NH 2 , 5. Композиция по п.4, в которой у соединения формулы (1) X1 и Х2 оба обозначают -NH2, -NHC1-C2алкил, -N(С1-С2алкил)2, -NHCH2CH2OH, -N(CH2CH2OH)2, -N(С1-С2алкил)(СН2СН2OH), -NHCH2СН2OCH3, -N(CH2CH2OCH3)2,-NHCH2CH2-O-CH2CH2-OH, -N(CH2CH2-O-CH2CH2-OH)2, -NHCH2CO2M", -N(СН3)СН2CO2М", -NHCH2CH2CO2M", -NHCH(CO2М")СН2СН2СН2NHC(=NH)NH2, тетрагидрофурфуриламино-, бензиламино-, циклогексиламино-, пирролидиновую или морфолиногруппу, а М" обозначает Н, К, Na, аммоний или аммоний, который моно-, ди-, три- или тетразамещен С1-С4алкилом и/или С2-С4гидроксиалкилом.5. The composition according to claim 4, in which the compounds of formula (1) X 1 and X 2 both represent -NH 2 , -NHC 1 -C 2 alkyl, -N (C 1 -C 2 alkyl) 2 , -NHCH 2 CH 2 OH, -N (CH 2 CH 2 OH) 2 , -N (C 1 -C 2 alkyl) (CH 2 CH 2 OH), -NHCH 2 CH 2 OCH 3 , -N (CH 2 CH 2 OCH 3 ) 2 , -NHCH 2 CH 2 -O-CH 2 CH 2 -OH, -N (CH 2 CH 2 -O-CH 2 CH 2 -OH) 2 , -NHCH 2 CO 2 M ", -N (CH 3 ) CH 2 CO 2 M ", -NHCH 2 CH 2 CO 2 M", -NHCH (CO 2 M ") CH 2 CH 2 CH 2 NHC (= NH) NH 2 , tetrahydrofurfurylamino, benzylamino, cyclohexylamino, pyrrolidine or a morpholino group, and M ″ is H, K, Na, ammonium or ammonium which is mono-, di-, tri- or tetrazubstituted with C 1 -C 4 alkyl and / or C 2 -C 4 hydroxyalkyl. 6. Применение композиции по одному из пп.1-5 для флуоресцентного отбеливания бумаги в волокнистой массе, при нанесении покрытия или в дозировочном клеильном прессе или пленочном прессе.6. The use of the composition according to one of claims 1 to 5 for fluorescent bleaching of paper in the pulp, during coating or in a metering size press or film press. 7. Применение по п.6, для флуоресцентного отбеливания бумаги при нанесении покрытия или в дозировочном клеильном прессе или пленочном прессе.7. The use according to claim 6, for fluorescent whitening of paper during coating or in a metering size press or film press. 8. Применение по п.6 или 7 для флуоресцентного отбеливания бумаги в дозировочном клеильном прессе или пленочном прессе.8. The use according to claim 6 or 7 for fluorescent whitening of paper in a metering size press or film press. 9. Способ флуоресцентного отбеливания бумаги, включающий обработку бумаги композицией по одному из пп.1-5.9. A method of fluorescent paper bleaching, including processing the paper with a composition according to one of claims 1 to 5. 10. Бумага, которая оптически отбелена композицией по одному из пп.1-5.10. Paper that is optically bleached by the composition according to one of claims 1 to 5.
RU2006106728/12A 2003-08-06 2004-07-28 COMPOSITION FOR FLUORESCENT WHITENING OF PAPER RU2006106728A (en)

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EP03102449 2003-08-06
EP03102449.0 2003-08-06

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US (1) US20060185805A1 (en)
EP (1) EP1651816A1 (en)
JP (1) JP2007501336A (en)
KR (1) KR20060073588A (en)
CN (1) CN1833072A (en)
AR (1) AR045215A1 (en)
AU (1) AU2004263674A1 (en)
BR (1) BRPI0413352A (en)
CA (1) CA2533364A1 (en)
IL (1) IL173135A0 (en)
MX (1) MXPA06001366A (en)
RU (1) RU2006106728A (en)
TW (1) TW200516193A (en)
WO (1) WO2005014932A1 (en)
ZA (1) ZA200600465B (en)

Cited By (1)

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Publication number Priority date Publication date Assignee Title
RU2495972C2 (en) * 2008-03-26 2013-10-20 Клариант Финанс (Бви) Лимитед Improved optical bleaching compositions

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DE602007009522D1 (en) 2006-05-23 2010-11-11 Basf Se DETERGENT FOR TEXTILE FIBROUS
US8227808B2 (en) * 2007-12-06 2012-07-24 Chimei Innolux Corporation Method for manufacturing thin film transistor (TFT) and OLED display having TFTS manufactured by the same
FI20085345L (en) * 2008-04-22 2009-10-23 Kemira Oyj Method for reducing light-induced yellowing in lignin-containing material
US20120118522A1 (en) * 2009-07-24 2012-05-17 Clariant Finance (Bvi) Limited Aqueous Solutions Of Acid Dyes For Shading In Size Press Applications

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GB2277749B (en) * 1993-05-08 1996-12-04 Ciba Geigy Ag Fluorescent whitening of paper
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ITMI20010884A1 (en) * 2001-04-27 2002-10-27 3V Sigma Spa DETERGENT COMPOSITIONS

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2495972C2 (en) * 2008-03-26 2013-10-20 Клариант Финанс (Бви) Лимитед Improved optical bleaching compositions
RU2495973C2 (en) * 2008-03-26 2013-10-20 Клариант Финанс (Бви) Лимитед Improved optical bleaching compositions

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ZA200600465B (en) 2007-03-28
AR045215A1 (en) 2005-10-19
IL173135A0 (en) 2006-06-11
MXPA06001366A (en) 2006-05-15
JP2007501336A (en) 2007-01-25
US20060185805A1 (en) 2006-08-24
TW200516193A (en) 2005-05-16
WO2005014932A1 (en) 2005-02-17
EP1651816A1 (en) 2006-05-03
BRPI0413352A (en) 2006-10-10
KR20060073588A (en) 2006-06-28
CA2533364A1 (en) 2005-02-17
CN1833072A (en) 2006-09-13
AU2004263674A1 (en) 2005-02-17

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