RU2005101765A - NEW COMPOSITE ETHERS OF PHOSPHONIC CARBONIC ACID - Google Patents

NEW COMPOSITE ETHERS OF PHOSPHONIC CARBONIC ACID Download PDF

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Publication number
RU2005101765A
RU2005101765A RU2005101765/04A RU2005101765A RU2005101765A RU 2005101765 A RU2005101765 A RU 2005101765A RU 2005101765/04 A RU2005101765/04 A RU 2005101765/04A RU 2005101765 A RU2005101765 A RU 2005101765A RU 2005101765 A RU2005101765 A RU 2005101765A
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RU
Russia
Prior art keywords
acid
ester
ester according
group
oil
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RU2005101765/04A
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Russian (ru)
Inventor
Гари ВУДВАРД (GB)
Гари ВУДВАРД
Кристофер Рэймонд ДЖОУНС (GB)
Кристофер Рэймонд Джоунс
Кейт Филип ДЭВИС (GB)
Кейт Филип ДЭВИС
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Родиа Конзьюмер Спешиалтиз Лимитед (Gb)
Родиа Конзьюмер Спешиалтиз Лимитед
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Publication of RU2005101765A publication Critical patent/RU2005101765A/en

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    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
    • C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
    • C23F11/08—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
    • C23F11/10—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids using organic inhibitors
    • C23F11/167—Phosphorus-containing compounds
    • C23F11/1676—Phosphonic acids
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F5/00—Softening water; Preventing scale; Adding scale preventatives or scale removers to water, e.g. adding sequestering agents
    • C02F5/08—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents
    • C02F5/10—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances
    • C02F5/14—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances containing phosphorus
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids RP(=O)(OH)2; Thiophosphonic acids, i.e. RP(=X)(XH)2 (X = S, Se)
    • C07F9/3804—Phosphonic acids RP(=O)(OH)2; Thiophosphonic acids, i.e. RP(=X)(XH)2 (X = S, Se) not used, see subgroups
    • C07F9/3808—Acyclic saturated acids which can have further substituents on alkyl
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids RP(=O)(OH)2; Thiophosphonic acids, i.e. RP(=X)(XH)2 (X = S, Se)
    • C07F9/3804—Phosphonic acids RP(=O)(OH)2; Thiophosphonic acids, i.e. RP(=X)(XH)2 (X = S, Se) not used, see subgroups
    • C07F9/3839—Polyphosphonic acids
    • C07F9/3869—Polyphosphonic acids containing carboxylic acid or carboxylic acid derivative substituents
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
    • C09K8/52—Compositions for preventing, limiting or eliminating depositions, e.g. for cleaning
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
    • C09K8/52—Compositions for preventing, limiting or eliminating depositions, e.g. for cleaning
    • C09K8/524—Compositions for preventing, limiting or eliminating depositions, e.g. for cleaning organic depositions, e.g. paraffins or asphaltenes
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/36—Organic compounds containing phosphorus
    • C11D3/365—Organic compounds containing phosphorus containing carboxyl groups
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
    • C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
    • C23F11/08—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
    • C23F11/10—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids using organic inhibitors
    • C23F11/167—Phosphorus-containing compounds

Claims (24)

1. Сложный эфир фосфонозамещенной или фосфинозамещенной моно- или поликарбоновой кислоты, в котором, по меньшей мере, одна карбоксильная группа указанной кислоты этерифицирована С6-С25 алкильной, алкарильной или алкенильной группой.1. An ester of a phosphonosubstituted or phosphino-substituted mono- or polycarboxylic acid in which at least one carboxyl group of said acid is esterified with a C 6 -C 25 alkyl, alkaryl or alkenyl group. 2. Сложный эфир по п.1, в котором карбоновой кислотой является фосфоноуксусная кислота.2. The ester according to claim 1, wherein the carboxylic acid is phosphonoacetic acid. 3. Сложный эфир по п.1, в котором карбоновой кислотой является фосфоноянтарная кислота.3. The ester according to claim 1, wherein the carboxylic acid is phosphonosuccinic acid. 4. Сложный эфир по п.1, в котором карбоновой кислотой является 1-фосфоно-2,3,4-трикарбоксибутан.4. The ester according to claim 1, wherein the carboxylic acid is 1-phosphono-2,3,4-tricarboxybutane. 5. Сложный эфир по п.1, в котором фосфонокарбоновой кислотой является теломер, полученный путем взаимодействия водорастворимой соли ненасыщенной карбоновой кислоты с фосфитом при рН выше 5 в присутствии свободных радикалов.5. The ester according to claim 1, wherein the phosphonocarboxylic acid is a telomere obtained by reacting a water-soluble salt of an unsaturated carboxylic acid with phosphite at a pH above 5 in the presence of free radicals. 6. Сложный эфир по п.5, в котором ненасыщенной карбоновой кислотой является малеиновая, акриловая, метакриловая, фумаровая, кротоновая, изокротоновая, цитраконовая, мезаконовая, аконитовая, итаконовая, ангеликовая, тиглиновая, коричная, аллокоричная, олеиновая или элаидиновая кислота.6. The ester according to claim 5, in which the unsaturated carboxylic acid is maleic, acrylic, methacrylic, fumaric, crotonic, isocrotonic, citraconic, mesaconic, aconitic, itaconic, angelic, tiglinic, cinnamon, allocoric, oleic or elaidin. 7. Сложный эфир по п.1, в котором эфир представлен формулой:7. The ester according to claim 1, in which the ether is represented by the formula: H(CHCO2M)nPO3M1,H (CHCO 2 M) n PO 3 M 1 , где М представляет С6-С25 алкильную, алкарильную или алкенильную группу, М1 представляет Н или щелочной металл, аммоний или щелочноземельный металл, и n означает число от 1 до 20.where M represents a C 6 -C 25 alkyl, alkaryl or alkenyl group, M 1 represents H or an alkali metal, ammonium or alkaline earth metal, and n means a number from 1 to 20. 8. Сложный эфир по п.7, в котором n означает целое число от 2 до 10.8. The ester according to claim 7, in which n means an integer from 2 to 10. 9. Сложный эфир по п.5, в котором теломер представлен формулой:9. The ester according to claim 5, in which the telomere is represented by the formula: X2O3PCHYCZ2PO2X2,X 2 O 3 PCHYCZ 2 PO 2 X 2 , где Х представляет водород, щелочной металл, аммоний или щелочноземельный металл, и Y и Z, каждый, представляет водород, группу РО3Х2, SO3X или CO2X, или алкильную или арильную группу.where X represents hydrogen, an alkali metal, ammonium or alkaline earth metal, and Y and Z, each represents hydrogen, a group PO 3 X 2 , SO 3 X or CO 2 X, or an alkyl or aryl group. 10. Сложный эфир по любому одному из предшествующих пунктов, в котором алкильная группа включает от 10 до 25 атомов углерода.10. The ester according to any one of the preceding paragraphs, in which the alkyl group contains from 10 to 25 carbon atoms. 11. Способ получения сложного эфира по любому одному из предшествующих пунктов, включающий стадии дефлегмации соответствующей фосфоно- или фосфинокарбоновой кислоты с от 1 до n молями С6-С20 спирта в растворителе, имеющем температуру кипения выше температуры кипения воды, где n представляет число карбоксильных групп в указанной кислоте, с последующим удалением воды из системы дефлегмации.11. A method of producing an ester according to any one of the preceding paragraphs, comprising the stage of refluxing the corresponding phosphono- or phosphinocarboxylic acid with from 1 to n moles of C 6 -C 20 alcohol in a solvent having a boiling point higher than the boiling point of water, where n represents the number of carboxyl groups in the specified acid, followed by removal of water from the reflux system. 12. Способ по п.11, в котором n равно 2.12. The method according to claim 11, in which n is 2. 13. Способ по п.11, в котором n равно 100.13. The method according to claim 11, in which n is 100. 14. Сложный эфир по п.1, в котором фосфоно- или фосфиногруппа кислоты этерифицирована С6-С20 алкильной группой.14. The ester according to claim 1, wherein the phosphono or phosphino group of the acid is esterified with a C 6 -C 20 alkyl group. 15. Способ получения сложного эфира по п.14, включающий этерификацию фосфоно- или фосфинокислоты более чем n молями спирта при высоких температурах и, необязательно, в присутствии одного или нескольких дегидратирующих агентов, где n представляет число карбоксильных групп в кислоте.15. The method of producing an ester according to 14, comprising the esterification of phosphonic or phosphonic acid with more than n moles of alcohol at high temperatures and, optionally, in the presence of one or more dehydrating agents, where n represents the number of carboxyl groups in the acid. 16. Сложный эфир, полученный способом по любому одному из пп.11-13 и 15.16. The ester obtained by the method according to any one of paragraphs.11-13 and 15. 17. Композиция, включающая сложный эфир по любому одному из пп.1-10 и 16.17. A composition comprising an ester according to any one of claims 1 to 10 and 16. 18. Композиция, включающая смесь сложных эфиров по любому одному из пп.1-10 и 16.18. A composition comprising a mixture of esters according to any one of claims 1 to 10 and 16. 19. Композиция по п.17, в которой сложный эфир растворен в масле.19. The composition according to 17, in which the ester is dissolved in oil. 20. Композиция по п.19, в которой масло является ароматическим маслом.20. The composition according to claim 19, in which the oil is an aromatic oil. 21. Композиция по п.20, в которой ароматическим маслом является ксилол.21. The composition according to claim 20, in which the aromatic oil is xylene. 22. Композиция по п.19, в которой масло является минеральным маслом.22. The composition according to claim 19, in which the oil is a mineral oil. 23. Применение сложного эфира по любому одному из пп.1-10 и 16 в качестве ингибитора отложений, ингибитора коррозии, диспергатора асфальтена, диспергатора парафина или ингибитора газовых гидратов.23. The use of the ester according to any one of claims 1 to 10 and 16 as a scale inhibitor, corrosion inhibitor, asphaltene dispersant, paraffin dispersant or gas hydrate inhibitor. 24. Применение композиции по любому одному из пп.17-22 в качестве ингибитора газовых гидратов, ингибитора отложений, ингибитора коррозии, диспергатора асфальтена или диспергатора парафина.24. The use of the composition according to any one of paragraphs.17-22 as a gas hydrate inhibitor, scale inhibitor, corrosion inhibitor, asphaltene dispersant or paraffin dispersant.
RU2005101765/04A 2002-06-26 2003-06-25 NEW COMPOSITE ETHERS OF PHOSPHONIC CARBONIC ACID RU2005101765A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB0214711.4 2002-06-26
GB0214711A GB0214711D0 (en) 2002-06-26 2002-06-26 Novel phosphonocarboxylic acid esters

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EP (1) EP1527078A2 (en)
AU (1) AU2003240137A1 (en)
CA (1) CA2490931A1 (en)
GB (1) GB0214711D0 (en)
NO (1) NO20050394L (en)
RU (1) RU2005101765A (en)
WO (1) WO2004002994A2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2679399C2 (en) * 2013-09-20 2019-02-08 Бейкер Хьюз Инкорпорейтед Method of inhibiting fouling on metallic surfaces using surface modifying treatment agent

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Publication number Priority date Publication date Assignee Title
US7235161B2 (en) 2003-11-19 2007-06-26 Alcoa Inc. Stable anodes including iron oxide and use of such anodes in metal production cells

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US3300337A (en) * 1960-10-06 1967-01-24 Stauffer Chemical Co Anti-static coated textile fiber
LU68583A1 (en) * 1973-10-09 1975-06-16
US4052439A (en) * 1976-04-30 1977-10-04 Abbott Laboratories Carboxylic esters of phosphonoacetic acid
JPS5929697A (en) * 1982-08-12 1984-02-16 Sakai Chem Ind Co Ltd Phosphonic ester, its preparation, and metal extraction agent containing it
DE3605800A1 (en) * 1986-02-22 1987-08-27 Bayer Ag 2-PHOSPHONOBUTAN-1,2,4-TRICARBONIC ACID DERIVATIVES AS EMULSIFIERS
CA2057822C (en) * 1990-12-18 1998-04-21 Keith Philip Davis Water treatment agent
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GB9703951D0 (en) * 1997-02-26 1997-04-16 Albright & Wilson Uk Ltd Novel phosphino derivatives
FR2789999B1 (en) * 1999-02-18 2004-05-28 Arc Chimie PROCESS FOR TREATING HYDROCARBON MIXTURES CONTAINING ASPHALTENES

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2679399C2 (en) * 2013-09-20 2019-02-08 Бейкер Хьюз Инкорпорейтед Method of inhibiting fouling on metallic surfaces using surface modifying treatment agent

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WO2004002994A2 (en) 2004-01-08
EP1527078A2 (en) 2005-05-04
WO2004002994A3 (en) 2004-04-08
NO20050394L (en) 2005-01-25
GB0214711D0 (en) 2002-08-07
AU2003240137A8 (en) 2004-01-19
CA2490931A1 (en) 2004-01-08
AU2003240137A1 (en) 2004-01-19

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