RU2002116991A - A method of producing carbonyl compounds from di- and polyene cyclic hydrocarbons and their derivatives - Google Patents

A method of producing carbonyl compounds from di- and polyene cyclic hydrocarbons and their derivatives

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Publication number
RU2002116991A
RU2002116991A RU2002116991/04A RU2002116991A RU2002116991A RU 2002116991 A RU2002116991 A RU 2002116991A RU 2002116991/04 A RU2002116991/04 A RU 2002116991/04A RU 2002116991 A RU2002116991 A RU 2002116991A RU 2002116991 A RU2002116991 A RU 2002116991A
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RU
Russia
Prior art keywords
reaction
carried out
nitrous oxide
values
polyene
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RU2002116991/04A
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Russian (ru)
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RU2219160C1 (en
Inventor
Геннадий Иванович Панов
Константин Александрович Дубков
Евгений Владимирович Староконь
Original Assignee
Институт катализа имени Г.К. Борескова СО РАН
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Priority to RU2002116991A priority Critical patent/RU2219160C1/en
Priority to PCT/RU2003/000063 priority patent/WO2004000777A1/en
Priority to AU2003235532A priority patent/AU2003235532A1/en
Application granted granted Critical
Publication of RU2219160C1 publication Critical patent/RU2219160C1/en
Publication of RU2002116991A publication Critical patent/RU2002116991A/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/28—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of CHx-moieties

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Claims (14)

1. Способ получения карбонильных соединений, осуществляемый путем контакта ди- и полиеновых циклических углеводородов и их производных с закисью азота в жидкой фазе при температуре от 20 до 300°С и давлении закиси азота от 0,01 до 200 атм.1. A method of producing carbonyl compounds, carried out by contact of di- and polyene cyclic hydrocarbons and their derivatives with nitrous oxide in the liquid phase at a temperature of from 20 to 300 ° C and a pressure of nitrous oxide from 0.01 to 200 ATM. 2. Способ по п.1, в котором ди- и полиеновые циклические углеводороды и их производные содержат в циклах 5-20 атомов углерода и по крайней мере две С=С связи и имеют химический состав, соответствующий формуле2. The method according to claim 1, in which the di- and polyene cyclic hydrocarbons and their derivatives contain in cycles 5-20 carbon atoms and at least two C = C bonds and have a chemical composition corresponding to the formula
Figure 00000001
Figure 00000001
 где n имеет значения от 5 до 20, s имеет значения от 1 до 4, m имеет значения от 1 до 10, n имеет значения от 4 до 20, Ri - одинаковые или разные заместители в цикле, которые могут быть представлены атомами галогена, алкильными, алкенильными, арильными или любыми другими неорганическими, органическими или металлорганическими радикалами, в том числе содержащими различные функциональные группы, причем при s=l по крайней мере один из заместителей Ri представляет собой радикал, который включает в свой состав неароматические карбоциклы, имеющие двойные связи С=С.where n has values from 5 to 20, s has values from 1 to 4, m has values from 1 to 10, n has values from 4 to 20, R i are the same or different substituents in the cycle that can be represented by halogen atoms, alkyl, alkenyl, aryl or any other inorganic, organic or organometallic radicals, including those containing various functional groups, moreover, at s = l, at least one of the substituents R i is a radical that includes non-aromatic carbocycles having double connection C = C. 3. Способ по любому из пп.1 и 2, по которому в реакционную смесь вводят инертный газ-разбавитель.3. The method according to any one of claims 1 and 2, wherein an inert diluent gas is introduced into the reaction mixture. 4. Способ по любому из пп.1-3, в котором концентрация инертного газа в реакционной смеси не превышает 99%.4. The method according to any one of claims 1 to 3, in which the concentration of inert gas in the reaction mixture does not exceed 99%. 5. Способ но любому из пп.1-4, в котором концентрацию инертного газа подбирают таким образом, чтобы исключить возможность образования взрывоопасных композиций на каждой стадии процесса.5. The method but to any one of claims 1 to 4, in which the concentration of inert gas is selected so as to exclude the possibility of the formation of explosive compositions at each stage of the process. 6. Способ по любому из пп.1-5, в котором концентрацию инертного газа подбирают таким образом, чтобы исключить возможность образования взрывоопасных композиций на всех стадиях процесса.6. The method according to any one of claims 1 to 5, in which the concentration of inert gas is selected so as to exclude the possibility of the formation of explosive compositions at all stages of the process. 7. Способ по любому из пп.1-6, в котором реакцию проводят при температуре 20-199°С и давлении закиси азота 0,01-200 атм.7. The method according to any one of claims 1 to 6, in which the reaction is carried out at a temperature of 20-199 ° C and a nitrous oxide pressure of 0.01-200 atm. 8. Способ по любому из пп.1-7, в котором реакцию проводят при температуре 20-300°С и давлении закиси азота 0,01-20 атм.8. The method according to any one of claims 1 to 7, in which the reaction is carried out at a temperature of 20-300 ° C and a nitrous oxide pressure of 0.01-20 atm. 9. Способ по любому из пп.1-8, в котором реакцию проводят в присутствии катализатора.9. The method according to any one of claims 1 to 8, in which the reaction is carried out in the presence of a catalyst. 10. Способ по любому из пп.1-9, в котором реакцию проводят в присутствии растворителя.10. The method according to any one of claims 1 to 9, in which the reaction is carried out in the presence of a solvent. 11. Способ по любому из пп.1-10, в котором реакцию проводят в присутствии ингибиторов полимеризации.11. The method according to any one of claims 1 to 10, in which the reaction is carried out in the presence of polymerization inhibitors. 12. Способ по любому из пп.1-11, в котором закись азота содержит примеси других газов, не ухудшающих показатели процесса.12. The method according to any one of claims 1 to 11, in which nitrous oxide contains impurities of other gases that do not impair the performance of the process. 13. Способ по любому из пп.1-12, в котором реакцию проводят в статическом или проточном варианте.13. The method according to any one of claims 1 to 12, in which the reaction is carried out in a static or flowing version. 14. Способ по любому из пп.1-13, в котором для проведения реакции используют рециркулирующие газы.14. The method according to any one of claims 1 to 13, in which recirculating gases are used for the reaction.
RU2002116991A 2002-06-25 2002-06-25 Method for production of carbonyl compounds from di- and polyene cyclic hydrocarbons and derivatives thereof RU2219160C1 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
RU2002116991A RU2219160C1 (en) 2002-06-25 2002-06-25 Method for production of carbonyl compounds from di- and polyene cyclic hydrocarbons and derivatives thereof
PCT/RU2003/000063 WO2004000777A1 (en) 2002-06-25 2003-02-26 Method for producing carbonyl compounds from di- and polyene cyclic hydrocarbons and the derivatives thereof
AU2003235532A AU2003235532A1 (en) 2002-06-25 2003-02-26 Method for producing carbonyl compounds from di- and polyene cyclic hydrocarbons and the derivatives thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
RU2002116991A RU2219160C1 (en) 2002-06-25 2002-06-25 Method for production of carbonyl compounds from di- and polyene cyclic hydrocarbons and derivatives thereof

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RU2002116991A true RU2002116991A (en) 2004-01-10

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AU (1) AU2003235532A1 (en)
RU (1) RU2219160C1 (en)
WO (1) WO2004000777A1 (en)

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Publication number Priority date Publication date Assignee Title
DE102004046167A1 (en) 2004-09-23 2006-04-06 Basf Ag Process for purifying and concentrating nitrous oxide
DE102004046171A1 (en) 2004-09-23 2006-04-13 Basf Ag Process for the preparation of cyclopentanone
GB0504260D0 (en) * 2005-03-02 2005-04-06 Warner Noel A Process and plant for gas-based direct steelmaking
DE102005055588A1 (en) 2005-11-22 2007-05-24 Basf Ag Purification of gas mixture comprising dinitrogen monoxide, useful as oxidizing agent for olefins, comprises absorption of the gas mixture in solvent, desorption from the solvent, absorption in water and desorption from the water
JP5108880B2 (en) 2006-06-29 2012-12-26 ビーエーエスエフ ソシエタス・ヨーロピア Method for producing cyclic ketone
KR101390580B1 (en) 2006-06-29 2014-04-30 바스프 에스이 Method for the production of cyclic ketones
CN101558009B (en) 2006-12-11 2012-03-28 巴斯夫欧洲公司 Method for isolating N2O
CA2720403C (en) 2008-04-02 2016-02-23 Basf Se Process for isolating n2o
WO2009121707A1 (en) 2008-04-02 2009-10-08 Basf Se Process for purifying dinitrogen monoxide
CN104761438A (en) 2008-08-29 2015-07-08 巴斯夫欧洲公司 Process for preparing cyclic ketones
EP2384317B1 (en) 2008-12-30 2014-04-23 Basf Se Method for producing ketones by converting 1.1-disubstituted olefines by means of n2o
GB201019701D0 (en) 2010-11-19 2011-01-05 Invista Tech Sarl Reaction process
JP6026428B2 (en) 2010-12-15 2016-11-16 サウジ アラビアン オイル カンパニーＳａｕｄｉ Ａｒａｂｉａｎ Ｏｉｌ Ｃｏｍｐａｎｙ Process for desulfurization of hydrocarbon feedstocks using gaseous oxidants

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GB790607A (en) * 1955-10-11 1958-02-12 Hoffmann La Roche A process for the manufacture of a cyclic ketone and the conversion thereof into its monoketals and into a keto-alcohol and esters of same
CH559156A5 (en) * 1972-11-16 1975-02-28 Firmenich & Cie
RU2058286C1 (en) * 1994-04-12 1996-04-20 Институт катализа им.Г.К.Борескова СО РАН Method for production of phenol or its derivatives
RU2074164C1 (en) * 1994-04-12 1997-02-27 Институт катализа им.Г.К.Борескова СО РАН Method of producing phenol and derivatives thereof

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AU2003235532A1 (en) 2004-01-06
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