RU2001124017A - Method for measuring methane concentration by thermochemical (thermocatalytic) sensor - Google Patents

Method for measuring methane concentration by thermochemical (thermocatalytic) sensor

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Publication number
RU2001124017A
RU2001124017A RU2001124017/28A RU2001124017A RU2001124017A RU 2001124017 A RU2001124017 A RU 2001124017A RU 2001124017/28 A RU2001124017/28 A RU 2001124017/28A RU 2001124017 A RU2001124017 A RU 2001124017A RU 2001124017 A RU2001124017 A RU 2001124017A
Authority
RU
Russia
Prior art keywords
value
signal
sensor
methane concentration
measurement
Prior art date
Application number
RU2001124017/28A
Other languages
Russian (ru)
Other versions
RU2210762C2 (en
Inventor
Евгений Федорович Карпов
Евгений Сергеевич Харламочкин
Евгений Евгеньевич Карпов
Алексей Анатольевич Сучков
Original Assignee
ООО "Научно-технический центр измерительных газочувствительных датчиков"
Filing date
Publication date
Application filed by ООО "Научно-технический центр измерительных газочувствительных датчиков" filed Critical ООО "Научно-технический центр измерительных газочувствительных датчиков"
Priority to RU2001124017A priority Critical patent/RU2210762C2/en
Priority claimed from RU2001124017A external-priority patent/RU2210762C2/en
Publication of RU2001124017A publication Critical patent/RU2001124017A/en
Application granted granted Critical
Publication of RU2210762C2 publication Critical patent/RU2210762C2/en

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Claims (1)

Способ измерения концентрации метана термокаталитическим датчиком, включающий циклическое измерение сигнала на каталитически активном чувствительном элементе, установленном в реакционной камере с ограниченным диффузионным доступом анализируемой метано-воздушной смеси и определевием величины концентрации метана по значению разности сигналов, снимаемых в фиксированных по времени точках газообменного (диффузионного) периода релаксации переходного процесса, отличающийся тем, что, с целью повышения точности измерения и исключения погрешности показаний, превышающей нормируемое значение, в каждом цикле совмещают процесс измерения с оценкой погрешности для чего при первоначальной градуировке датчика за исходную градуировочную характеристику принимают отрезок времени ΔT, определяемый в период газообменной релаксации как разницу между первой строго фиксированной по времени точкой T1 на кривой переходного процесса S=f(t) и второй точкой Т2 в момент когда величина сигнала S1 (при T1) снизится до нормируемого значения S2, составляющего n% (95÷55%) от S1 (например, 90% S1), затем во всех последующих рабочих циклах измерения определяют разницу сигналов ΔS’ между сигналом S’1 при T1 и S’2 при Т’2 - времени при котором величина выходного сигнала снизится на n% (например, 90% S’1) и сравнивают ΔT с ΔT’ и если ΔT’ отличается от градуировочной характеристики ΔT на величину, превышающую нормируемое значение, осуществляют корректировку показаний в соответствии с зависимостью ΔSскорр=ΔS’(ΔT’/ΔT).A method for measuring methane concentration with a thermocatalytic sensor, including cyclically measuring a signal on a catalytically active sensing element installed in a reaction chamber with limited diffusion access of the analyzed methane-air mixture and determining the methane concentration from the value of the difference of signals recorded at gas exchange (diffusion) fixed points period of relaxation of the transition process, characterized in that, in order to improve the accuracy of measurement and exclusion error of readings in excess of the normalized value in each cycle combines the measurement process with an error estimate for which, during the initial calibration of the sensor, the time interval ΔT, determined during the gas exchange relaxation as the difference between the first strictly fixed in time point T 1 on the transition curve, is taken as the initial calibration characteristic process S = f (t) and the second point T 2 at the moment when the value of the signal S 1 (at T 1 ) decreases to the normalized value of S 2 , which is n% (95 ÷ 55%) of S 1 (for example, 90% S 1 ), then in Cex subsequent working cycles of measurement is determined difference signal ΔS 'between the signal S' 1 when T 1 and S '2 at T 2 - time at which the output value will decrease by n% (e.g., 90% S' 1), and comparing ΔT with ΔT 'and if ΔT' differs from the calibration characteristic ΔT by an amount exceeding the normalized value, the readings are adjusted in accordance with the dependence ΔS scorr = ΔS '(ΔT' / ΔT).
RU2001124017A 2001-09-04 2001-09-04 Procedure measuring concentration of methane by means of thermochemical ( thermocatalytic ) sensor RU2210762C2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
RU2001124017A RU2210762C2 (en) 2001-09-04 2001-09-04 Procedure measuring concentration of methane by means of thermochemical ( thermocatalytic ) sensor

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
RU2001124017A RU2210762C2 (en) 2001-09-04 2001-09-04 Procedure measuring concentration of methane by means of thermochemical ( thermocatalytic ) sensor

Publications (2)

Publication Number Publication Date
RU2001124017A true RU2001124017A (en) 2003-08-10
RU2210762C2 RU2210762C2 (en) 2003-08-20

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RU2001124017A RU2210762C2 (en) 2001-09-04 2001-09-04 Procedure measuring concentration of methane by means of thermochemical ( thermocatalytic ) sensor

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Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2447426C2 (en) * 2010-07-14 2012-04-10 Евгений Евгеньевич Карпов Method and apparatus for detecting pre-explosion concentration of methane in air
RU2483297C1 (en) * 2011-12-12 2013-05-27 Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Омский государственный университет им. Ф.М. Достоевского" Thermochemical sensor
RU2526033C1 (en) * 2013-03-29 2014-08-20 Евгений Федорович Карпов Aerogas control (agc) over coal mine atmosphere
RU2544358C2 (en) * 2013-07-04 2015-03-20 Елена Евгеньевна Карпова Method to measure pre-explosive concentrations of flammable gases in air

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