RU2000115952A - POLYMERIZED COMPOSITIONS FOR APPLICATION OF ORGANIC COATING ON METAL MATERIALS - Google Patents

POLYMERIZED COMPOSITIONS FOR APPLICATION OF ORGANIC COATING ON METAL MATERIALS

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Publication number
RU2000115952A
RU2000115952A RU2000115952/02A RU2000115952A RU2000115952A RU 2000115952 A RU2000115952 A RU 2000115952A RU 2000115952/02 A RU2000115952/02 A RU 2000115952/02A RU 2000115952 A RU2000115952 A RU 2000115952A RU 2000115952 A RU2000115952 A RU 2000115952A
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RU
Russia
Prior art keywords
acid
composition according
metal
meth
coating
Prior art date
Application number
RU2000115952/02A
Other languages
Russian (ru)
Other versions
RU2216559C2 (en
Inventor
Людвиг ШИФЕРШТАЙН
Манфред ГОРЦИНСКИ
Штефан КЮППЕР
Херберт ФИШЕР
Original Assignee
Хенкель Коммандитгезелльшафт ауф Акциен
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE19751153A external-priority patent/DE19751153A1/en
Application filed by Хенкель Коммандитгезелльшафт ауф Акциен filed Critical Хенкель Коммандитгезелльшафт ауф Акциен
Publication of RU2000115952A publication Critical patent/RU2000115952A/en
Application granted granted Critical
Publication of RU2216559C2 publication Critical patent/RU2216559C2/en

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Claims (8)

1. Полимеризуемая композиция для нанесения органического покрытия на металлические материалы, которая содержит по крайней мере, одну соль титана, марганца или циркония из ненасыщенной олефиновой карбоновой кислоты, способной к полимеризации, в данном случае, другую или другие ненасыщенные олефиновые сомономеры, по крайней мере, один инициатор радикальной полимеризации.1. A polymerizable composition for applying an organic coating to metallic materials, which contains at least one salt of titanium, manganese or zirconium from an unsaturated olefinic carboxylic acid capable of polymerizing, in this case, another or other unsaturated olefin comonomers, at least one initiator of radical polymerization. 2. Композиция по п. 1, отличающаяся тем, что ненасыщенную олефиновую карбоновую кислоту выбирают из акриловой кислоты, метакриловой кислоты, итаконовой кислоты, кротоновой кислоты, малеиновой кислоты, сложного полуэфира малеиновой кислоты, фумаровой кислоты, сложного полуэфира фумаровой кислоты, реактивных макромономеров, содержащих карбоксильные группы или из их смесей. 2. The composition according to p. 1, characterized in that the unsaturated olefinic carboxylic acid is selected from acrylic acid, methacrylic acid, itaconic acid, crotonic acid, maleic acid, half-ester of maleic acid, fumaric acid, half-ester of fumaric acid, reactive macromonomers containing carboxyl groups or from mixtures thereof. 3. Композиция по п. 1, отличающаяся тем, что этот или эти сомономеры выбирают из гидроксиэтил(мет)акрилата, гидроксипропил(мет)акрилата, гидроксибутил(мет)акрилата, С18-алкил(мет)акрилатов и/или ненасыщенных олефиновых карбоновых кислот по п. 2 или из их смесей.3. The composition according to p. 1, characterized in that this or these comonomers are selected from hydroxyethyl (meth) acrylate, hydroxypropyl (meth) acrylate, hydroxybutyl (meth) acrylate, C 1 -C 8 -alkyl (meth) acrylates and / or unsaturated olefinic carboxylic acids according to claim 2 or from mixtures thereof. 4. Композиция по одному из предложенных пунктов, отличающаяся тем, что, по крайней мере, один инициатор радикальной полимеризации активируют путем излучения. 4. The composition according to one of the proposed paragraphs, characterized in that at least one radical polymerization initiator is activated by radiation. 5. Способ для получения композиции по одному из предложенных пунктов, отличающийся тем, что мономеры, в данном случае, дополнительно со стабилизаторами перемешивают до однородного состояния и затем добавляют инициатор(ы). 5. A method for producing a composition according to one of the proposed items, characterized in that the monomers, in this case, are additionally mixed with stabilizers to a homogeneous state and then initiator (s) are added. 6. Способ по п. 5, отличающийся тем, что соль (соли) титана, марганца и/или циркония из ненасыщенной олефиновой карбоновой кислоты получают in situ, причем соответствующие соединения оксидов металлов, гидроксидов металлов, алкоголят металлов, карбонатов металлов и/или β-дикарбонильные соединения металлов растворяют в карбоновой кислоте (кислотах), в данном случае, при нагревании. 6. The method according to p. 5, characterized in that the salt (s) of titanium, manganese and / or zirconium from an unsaturated olefinic carboxylic acid are obtained in situ, the corresponding compounds of metal oxides, metal hydroxides, metal alkoxides, metal carbonates and / or β β-dicarbonyl metal compounds are dissolved in carboxylic acid (s), in this case, by heating. 7. Способ нанесения покрытия на металлические материалы, отличающийся следующими существенными этапами: очистка и обезжиривание стальных полос, промывка поверхности, нанесение на поверхность композиции по, по крайней мере, одному из предложенных пунктов, при толщине слоя 0,1-10 μм, предпочтительно, 0,5-5 μм, наиболее предпочтительно, 1-3 μм, отверждение покрытия через термическую, фото- или электронно-лучевую полимеризацию. 7. The method of coating metal materials, characterized by the following essential steps: cleaning and degreasing steel strips, washing the surface, applying to the surface of the composition according to at least one of the proposed items, with a layer thickness of 0.1-10 μm, preferably 0.5-5 μm, most preferably 1-3 μm, curing of the coating via thermal, photo or electron beam polymerization. 8. Способ нанесения покрытия на стальную полосу, оцинкованную при помощи электрополировки или погружением в расплав, отличающийся следующими существенными этапами: очистка и обезжиривание стальных полос, промывка поверхности, нанесение на поверхность композиции по, по крайней мере, одному из предложенных пунктов, при толщине слоя 0,1-10 μм, предпочтительно, 0,5-5 μм, наиболее предпочтительно, 1-3 μм, отверждение покрытия через термическую, фото- или электронно-лучевую полимеризацию. 8. The method of coating a steel strip, galvanized by electropolishing or by immersion in a melt, characterized by the following essential steps: cleaning and degreasing steel strips, washing the surface, applying to the surface of the composition according to at least one of the proposed items, with a layer thickness 0.1-10 μm, preferably 0.5-5 μm, most preferably 1-3 μm, curing of the coating via thermal, photo or electron beam polymerization.
RU2000115952/02A 1997-11-19 1998-11-10 Polymerizable compositions for application of organic coating on metallic materials RU2216559C2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19751153A DE19751153A1 (en) 1997-11-19 1997-11-19 Chromium-free coil coating composition
DE19751153.8 1997-11-19

Publications (2)

Publication Number Publication Date
RU2000115952A true RU2000115952A (en) 2002-06-10
RU2216559C2 RU2216559C2 (en) 2003-11-20

Family

ID=7849136

Family Applications (1)

Application Number Title Priority Date Filing Date
RU2000115952/02A RU2216559C2 (en) 1997-11-19 1998-11-10 Polymerizable compositions for application of organic coating on metallic materials

Country Status (25)

Country Link
US (1) US6365234B1 (en)
EP (1) EP1038050B1 (en)
JP (1) JP2001523769A (en)
KR (1) KR20010086214A (en)
CN (1) CN1279730A (en)
AT (1) ATE286992T1 (en)
AU (1) AU743054B2 (en)
BG (1) BG104464A (en)
CA (1) CA2310453C (en)
DE (2) DE19751153A1 (en)
ES (1) ES2236970T3 (en)
HU (1) HUP0100182A3 (en)
ID (1) ID24696A (en)
IS (1) IS5483A (en)
LT (1) LT2000047A (en)
LV (1) LV12541B (en)
MD (1) MD20000101A (en)
NO (1) NO20002551L (en)
PL (1) PL341157A1 (en)
RU (1) RU2216559C2 (en)
SK (1) SK7292000A3 (en)
TR (1) TR200001225T2 (en)
WO (1) WO1999025897A1 (en)
YU (1) YU30000A (en)
ZA (1) ZA9810553B (en)

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DE19923118A1 (en) * 1999-05-19 2000-11-23 Henkel Kgaa Polymerizable composition for the anticorrosion coating of metallic substrates contains an organic titanium, silicon or zirconium compound
DE10022352A1 (en) * 2000-05-08 2001-11-22 Georg Gros Coating sheet metal used in the automobile, aviation and naval industries comprises using a chromate-free, water-dilutable anti corrosive binder coating and curing using UV
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AU2002360953B2 (en) * 2001-12-05 2006-07-20 Chemetall Gmbh Polymeric coating mixture, method for applying this coating mixture to a metallic base for protecting an edge or a part, protective layer, a base coated in this manner and the use thereof
DE10258291A1 (en) * 2002-12-13 2004-07-08 Henkel Kgaa Process for coating metal substrates with a free-radically polymerizable coating agent and coated substrates
JP4970773B2 (en) * 2005-11-18 2012-07-11 日本パーカライジング株式会社 Metal surface treatment agent, metal material surface treatment method and surface treatment metal material
DE102007015161A1 (en) * 2007-03-27 2008-10-02 Henkel Ag & Co. Kgaa Polymerizable composition for coating metals
DE102007021364A1 (en) * 2007-05-04 2008-11-06 Henkel Ag & Co. Kgaa Metallizing pretreatment of zinc surfaces
WO2009143144A1 (en) * 2008-05-19 2009-11-26 Henkel Ag & Co. Kgaa Midly alkaline thin inorganic corrosion protective coating for metal substrates
RU2533388C2 (en) * 2009-05-19 2014-11-20 Хенкель Аг Унд Ко. Кгаа Moderately alkaline, thin, inorganic, anti-corrosion coating for metal substrates
EP2489683A4 (en) 2009-10-15 2015-03-18 Toray Industries Process for production of core-shell particles, core-shell particles, and paste composition and sheet composition which contain same
CN102615031B (en) * 2011-01-30 2015-01-21 宝山钢铁股份有限公司 Production method of environmental-friendly extremely-thick coating electric steel product
EP2773795B1 (en) * 2011-11-03 2015-10-14 Basf Se Preparation for passivating metal surfaces, containing polymers having acid groups and containing ti or zr compounds
RU2659547C1 (en) * 2017-07-06 2018-07-02 Общество с ограниченной ответственностью "ТЕТЭЛ" Method for producing anti-corrosive coating on a metallic product (embodiments)
CN108977047A (en) * 2018-05-23 2018-12-11 无锡万博涂料化工有限公司 One kind being based on the cured coil coating of EB

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