RU2000107440A - METHOD FOR CONTINUOUS SOLUTION COPOLIMERIZATION AND POLYMERIZER FOR ITS IMPLEMENTATION - Google Patents

METHOD FOR CONTINUOUS SOLUTION COPOLIMERIZATION AND POLYMERIZER FOR ITS IMPLEMENTATION

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Publication number
RU2000107440A
RU2000107440A RU2000107440/04A RU2000107440A RU2000107440A RU 2000107440 A RU2000107440 A RU 2000107440A RU 2000107440/04 A RU2000107440/04 A RU 2000107440/04A RU 2000107440 A RU2000107440 A RU 2000107440A RU 2000107440 A RU2000107440 A RU 2000107440A
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RU
Russia
Prior art keywords
cocatalysts
cocatalyst
catalyst
solutions
solvent
Prior art date
Application number
RU2000107440/04A
Other languages
Russian (ru)
Other versions
RU2177957C2 (en
Inventor
Игорь Дмитриевич Афанасьев
Ольга Игоревна Афанасьева
Зуфар Асрарович Абзалин
Леонид Михайлович Курочкин
Рустам Якубович Дебердеев
Карл Самойлович Минскер
Герман Сергеевич Дьяконов
Рустам Гумерович Тахавутдинов
Александр Иорданович Сятковский
Харис Вагизович Мустафин
Юрий Иванович Рязанов
Виктория Афанасьевна Михеева
Табриз Гильмутдинович Бурганов
Геннадий Васильевич Баев
Валерий Николаевич Силантьев
Алексей Яковлевич Баширов
Шамиль Шайхиевич Галявиев
Original Assignee
Открытое акционерное общество "Нижнекамскнефтехим"
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Application filed by Открытое акционерное общество "Нижнекамскнефтехим" filed Critical Открытое акционерное общество "Нижнекамскнефтехим"
Priority to RU2000107440/04A priority Critical patent/RU2177957C2/en
Priority claimed from RU2000107440/04A external-priority patent/RU2177957C2/en
Publication of RU2000107440A publication Critical patent/RU2000107440A/en
Application granted granted Critical
Publication of RU2177957C2 publication Critical patent/RU2177957C2/en

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Claims (2)

1. Способ непрерывной растворной сополимеризации, включающий растворение в углеводородном растворителе мономеров, водорода и компонентов каталитического комплекса: сокатализатора или сокатализаторов и катализатора, подачу газожидкостной смеси в нижнюю часть полимеризатора, снабженного мешалкой, и растворов сокатализатора или сокатализаторов и катализатора и сополимеризацию при перемешивании реакционной массы при повышенном давлении и температуре, отличающийся тем, что подачу растворов сокатализатора или сокатализаторов и катализатора осуществляют над поверхностью реакционной массы в коаксиальном или параллельном или скрещенном потоках, причем сокатализатор или сокатализаторы разбавляют растворителем, в который предварительно вводят полимеризат в соотношении 1:(0,001-0,1), а смешение растворителя и сокатализатора или сокатализаторов осуществляют последовательно в трубчатой насадке штуцера ввода компонентов каталитического комплекса в турбулентном режиме.1. The method of continuous solution copolymerization, including dissolving in a hydrocarbon solvent monomers, hydrogen and components of the catalytic complex: cocatalyst or cocatalysts and catalyst, supplying a gas-liquid mixture to the lower part of the polymerizer equipped with a stirrer, and solutions of cocatalyst or cocatalysts and catalyst and copolymerization with stirring of the reaction mass at elevated pressure and temperature, characterized in that the supply of solutions of cocatalyst or cocatalysts and rolled an atom is carried out over the surface of the reaction mass in coaxial or parallel or crossed flows, moreover, the cocatalyst or cocatalysts are diluted with a solvent into which the polymerizate is preliminarily introduced in a ratio of 1: (0.001-0.1), and the solvent and cocatalyst or cocatalysts are mixed sequentially in a tubular nozzle the nozzle of the input components of the catalytic complex in a turbulent mode. 2. Полимеризатор для непрерывной растворной сополимеризации, содержащий корпус с крышкой и теплообменной рубашкой, перемешивающее устройство с приводом и технологические штуцеры для ввода газожидкостной смеси, растворов сокатализатора или сокатализаторов и катализатора, отвода рециркуляционного газа и полимеризата, отличающийся тем, что штуцер для ввода растворов сокатализатора или сокатализаторов и катализатора снабжен коаксиальными трубчатыми насадками, каждая из которых имеет ступени турбулизации по числу компонентов, вводимых в растворитель, а ступени турбулизации имеют не менее одной конфузор-диффузорной секции. 2. The polymerizer for continuous solution copolymerization, comprising a housing with a lid and a heat exchange jacket, a mixing device with a drive and technological fittings for introducing a gas-liquid mixture, solutions of cocatalyst or cocatalysts and catalyst, removal of recirculation gas and polymerisation, characterized in that the fitting for introducing solutions of cocatalyst or cocatalysts and the catalyst is equipped with coaxial tubular nozzles, each of which has turbulization stages according to the number of components introduced into the solvent, and the turbulization stages have at least one confuser-diffuser section.
RU2000107440/04A 2000-03-27 2000-03-27 Continuous solution copolymerization process and polymerizer for implementation thereof RU2177957C2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
RU2000107440/04A RU2177957C2 (en) 2000-03-27 2000-03-27 Continuous solution copolymerization process and polymerizer for implementation thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
RU2000107440/04A RU2177957C2 (en) 2000-03-27 2000-03-27 Continuous solution copolymerization process and polymerizer for implementation thereof

Publications (2)

Publication Number Publication Date
RU2000107440A true RU2000107440A (en) 2001-12-20
RU2177957C2 RU2177957C2 (en) 2002-01-10

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RU2000107440/04A RU2177957C2 (en) 2000-03-27 2000-03-27 Continuous solution copolymerization process and polymerizer for implementation thereof

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20220411545A1 (en) * 2021-06-25 2022-12-29 Braskem S.A. Propylene preliminary polymerization

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