RO94454B - Process for preparing morphinan derivatives - Google Patents
Process for preparing morphinan derivativesInfo
- Publication number
- RO94454B RO94454B RO123181A RO12318186A RO94454B RO 94454 B RO94454 B RO 94454B RO 123181 A RO123181 A RO 123181A RO 12318186 A RO12318186 A RO 12318186A RO 94454 B RO94454 B RO 94454B
- Authority
- RO
- Romania
- Prior art keywords
- methyl
- hydrogen
- formula
- hydroxy
- general formula
- Prior art date
Links
Landscapes
- Other In-Based Heterocyclic Compounds (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Abstract
Inventia se refera la un procedeu pentru prepararea unor derivati de morfinan cu formula generala I (vezi formula în pag.1 a descrierii) în care Z reprezinta o grupa -CH2-CH2- sau -CH-CH-, R1 reprezinta metil sau 2-propenil, R2 reprezinta hidrogen sau hidroxi, R3 reprezinta hidrogen sau metil, Y reprezinta -NH2, -NH-CONH2, -NH-CSNH2, -NHC6H5, -NH-C6H3(NO2)2, linia fragmentata reprezinta o legatura facultativa, cu conditia ca atunci cînd Z este -CH2-CH2-, R2 este hidroxi si R3 este hidrogen, Y sa nu fie -NH2; cînd Z este -CH2-CH2-, R1 este metil, R2 este hidrogen si R3 este metil, Y sa nu fie -NH2, -NHC6H5, -NH-C6H3(NO2)2 si -NH-CONH2; cînd Z este -CH-CH, R1 este metil, R2 este hidrogen, R3 este metil, Y sa nu fie -NH2; cînd R1 este metil, R2 si R3 sînt hidrogen, în pozitia 4 este o grupa hidroxil, Y sa nu fie -NH-CSNH2, prin tratarea unui derivat cetonic de morfinan cu formula generala similara, dar în care, în locul grupei =N-Y, este un atom de oxigen, cu o amina cu formula NH2Y.The invention relates to a process for the preparation of morphinane derivatives of general formula I (see formula on page 1 of the description) wherein Z represents a group -CH2-CH2- or -CH-CH-, R1 represents methyl or 2- propynyl, R2 represents hydrogen or hydroxy, R3 represents hydrogen or methyl, Y represents -NH2, -NH-CONH2, -NH-CSNH2, -NHC6H5, -NH-C6H3 (NO2) 2, the broken line represents a optional link, as when Z is -CH 2 -CH 2 -, R 2 is hydroxy and R 3 is hydrogen, Y is not -NH 2; when Z is -CH 2 -CH 2 -, R 1 is methyl, R 2 is hydrogen and R 3 is methyl, Y is not -NH 2, -NHC 6 H 5, -NH-C 6 H 3 (NO 2) 2 and -NH-CONH 2; when Z is -CH-CH, R1 is methyl, R2 is hydrogen, R3 is methyl, Y is not -NH2; when R 1 is methyl, R 2 and R 3 are hydrogen, in the 4-position it is a hydroxyl group, Y is not -NH-CSNH 2, by treatment of a morphine ketone derivative of the same general formula, but wherein instead of = NY, is an oxygen atom with an amine of formula NH2 Y.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| RO123181A RO94454B (en) | 1986-04-28 | 1986-04-28 | Process for preparing morphinan derivatives |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| RO123181A RO94454B (en) | 1986-04-28 | 1986-04-28 | Process for preparing morphinan derivatives |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RO94454A RO94454A (en) | 1988-06-30 |
| RO94454B true RO94454B (en) | 1988-07-01 |
Family
ID=20119338
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RO123181A RO94454B (en) | 1986-04-28 | 1986-04-28 | Process for preparing morphinan derivatives |
Country Status (1)
| Country | Link |
|---|---|
| RO (1) | RO94454B (en) |
-
1986
- 1986-04-28 RO RO123181A patent/RO94454B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| RO94454A (en) | 1988-06-30 |
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