RO86550B - Procedeu de hidrogenoliza a dietilenglicolului - Google Patents

Procedeu de hidrogenoliza a dietilenglicolului

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Publication number
RO86550B
RO86550B RO108714A RO10871482A RO86550B RO 86550 B RO86550 B RO 86550B RO 108714 A RO108714 A RO 108714A RO 10871482 A RO10871482 A RO 10871482A RO 86550 B RO86550 B RO 86550B
Authority
RO
Romania
Prior art keywords
carbon
diethyleneglycol
covalent bond
catalyst
degrees
Prior art date
Application number
RO108714A
Other languages
English (en)
Other versions
RO86550A (ro
Inventor
William Bartley
Joseph P. Henry
Original Assignee
Union Carbide Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Union Carbide Corp filed Critical Union Carbide Corp
Publication of RO86550A publication Critical patent/RO86550A/ro
Publication of RO86550B publication Critical patent/RO86550B/ro

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  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Prezenta inventie se refera la un procedeu de hidrogenoliza a dietilenglicolului, discontinuu sau continuu, prin clivajul selectiv al dietilenglicolului la legatura covalenta carbon-oxigen si independent la legatura covalenta carbon-oxigen si independent la legatura covalenta carbon-carbon, la temperatura de reactie cuprinsa între circa 125 degree C si 250 degree C si presiunea cuprinsa între circa 18 kg/cm2 si 140 kg/cm2, prin care, în scopul obtinerii a cel putin unuia dintre monoetilenglicolmonometileter,monoetilenglicol si etanol cu un debit de minimum 10 mol/kg catalizator si ora sau cu selectivitatea de circa 95 % molar pentru monoetilenglicolmonometileter, se utilizeaza în proportie de 0,01...50% raportata la greutatea totala a amestecului de reactie, o compozitie de catalizator aleasa dintre 0,5...5% ruteniu si 10...65% nichel cu sau fara promotor pentru cresterea activitatii catalitice în prezenta sau absenta unui suport de catalizator.
RO108714A 1981-09-30 1982-09-29 Procedeu de hidrogenoliza a dietilenglicolului RO86550B (ro)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US30722581A 1981-09-30 1981-09-30
US30722681A 1981-09-30 1981-09-30

Publications (2)

Publication Number Publication Date
RO86550A RO86550A (ro) 1985-04-17
RO86550B true RO86550B (ro) 1985-05-05

Family

ID=26975604

Family Applications (1)

Application Number Title Priority Date Filing Date
RO108714A RO86550B (ro) 1981-09-30 1982-09-29 Procedeu de hidrogenoliza a dietilenglicolului

Country Status (1)

Country Link
RO (1) RO86550B (ro)

Also Published As

Publication number Publication date
RO86550A (ro) 1985-04-17

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