RO85565B1 - 1,1'-oxy-bis-[4n-benzamido]-benzene derivatives and process for preparing the same - Google Patents
1,1'-oxy-bis-[4n-benzamido]-benzene derivatives and process for preparing the sameInfo
- Publication number
- RO85565B1 RO85565B1 RO109755A RO10975583A RO85565B1 RO 85565 B1 RO85565 B1 RO 85565B1 RO 109755 A RO109755 A RO 109755A RO 10975583 A RO10975583 A RO 10975583A RO 85565 B1 RO85565 B1 RO 85565B1
- Authority
- RO
- Romania
- Prior art keywords
- benzene derivatives
- benzamido
- oxy
- bis
- preparing
- Prior art date
Links
- 238000004519 manufacturing process Methods 0.000 title 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 4
- MBIZFBDREVRUHY-UHFFFAOYSA-N 2,6-Dimethoxybenzoic acid Chemical compound COC1=CC=CC(OC)=C1C(O)=O MBIZFBDREVRUHY-UHFFFAOYSA-N 0.000 abstract 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 abstract 2
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 abstract 2
- 239000013078 crystal Substances 0.000 abstract 1
- 238000002844 melting Methods 0.000 abstract 1
- 230000008018 melting Effects 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- FAIAAWCVCHQXDN-UHFFFAOYSA-N phosphorus trichloride Chemical compound ClP(Cl)Cl FAIAAWCVCHQXDN-UHFFFAOYSA-N 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
- 238000010992 reflux Methods 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Inventia se refera la derivati de 1,1'-oxibis-(4N-benzanzamido)-benzen, care au structura corespunzatoare formulei generale I: (VEZI FORMULA îN DESC.) în care R este H; 4-Cl; 4-CH3; 2-CH2, produse albe cristaline putin solubile în benten, etanol usor solubile în acetona si cloroform, insolubil în apa, cu puncte de topire în intervalul 162....192 degree C. Procedeul de preparare a derivatiilor consta în aceea ca un aminodifenileter cu formula generala II . (vezi form. în desc) în care R are semnificatiile de mai sus, se trateaza cu acidul 2,6-dimetoxibenzoic, în mediu de clorbenzen, la temperatura de reflux, în prezenta triclorurii de fosfor, în conditii anhidre.The invention relates to 1,1'-oxybis (4N-benzanzamido) -benzene derivatives having the structure corresponding to general formula I wherein R is H; 4-Cl; 4-CH3; 2-CH2, poorly soluble white crystalline white crystals in ethanol, water soluble insoluble ethanol and chloroform, with melting points in the range 162-192 ° C. The process for the preparation of derivatives consists in that an aminodifenileter with the general formula II. (where R is as defined above), treat with 2,6-dimethoxybenzoic acid in chlorobenzene at reflux temperature in the presence of phosphorus trichloride under anhydrous conditions.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| RO109755A RO85565B1 (en) | 1983-01-18 | 1983-01-18 | 1,1'-oxy-bis-[4n-benzamido]-benzene derivatives and process for preparing the same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| RO109755A RO85565B1 (en) | 1983-01-18 | 1983-01-18 | 1,1'-oxy-bis-[4n-benzamido]-benzene derivatives and process for preparing the same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RO85565A2 RO85565A2 (en) | 1985-02-25 |
| RO85565B1 true RO85565B1 (en) | 1985-02-28 |
Family
ID=20112570
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RO109755A RO85565B1 (en) | 1983-01-18 | 1983-01-18 | 1,1'-oxy-bis-[4n-benzamido]-benzene derivatives and process for preparing the same |
Country Status (1)
| Country | Link |
|---|---|
| RO (1) | RO85565B1 (en) |
-
1983
- 1983-01-18 RO RO109755A patent/RO85565B1/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| RO85565A2 (en) | 1985-02-25 |
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