PL95460B1 - INSOCICTIC AGENT WITH PROLONGED ACTIVITY WITH ONCOBIC - Google Patents
INSOCICTIC AGENT WITH PROLONGED ACTIVITY WITH ONCOBIC Download PDFInfo
- Publication number
- PL95460B1 PL95460B1 PL17723175A PL17723175A PL95460B1 PL 95460 B1 PL95460 B1 PL 95460B1 PL 17723175 A PL17723175 A PL 17723175A PL 17723175 A PL17723175 A PL 17723175A PL 95460 B1 PL95460 B1 PL 95460B1
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- Poland
- Prior art keywords
- lindane
- carbaryl
- mixture
- chlorfenvinphos
- preparation
- Prior art date
Links
- 230000000694 effects Effects 0.000 title claims description 11
- 230000002035 prolonged effect Effects 0.000 title claims description 6
- 239000000203 mixture Substances 0.000 claims description 28
- 229960005286 carbaryl Drugs 0.000 claims description 25
- CVXBEEMKQHEXEN-UHFFFAOYSA-N carbaryl Chemical compound C1=CC=C2C(OC(=O)NC)=CC=CC2=C1 CVXBEEMKQHEXEN-UHFFFAOYSA-N 0.000 claims description 25
- JLYXXMFPNIAWKQ-GNIYUCBRSA-N gamma-hexachlorocyclohexane Chemical compound Cl[C@H]1[C@H](Cl)[C@@H](Cl)[C@@H](Cl)[C@H](Cl)[C@H]1Cl JLYXXMFPNIAWKQ-GNIYUCBRSA-N 0.000 claims description 24
- 229960002809 lindane Drugs 0.000 claims description 23
- JLYXXMFPNIAWKQ-UHFFFAOYSA-N gamma-hexachlorocyclohexane Natural products ClC1C(Cl)C(Cl)C(Cl)C(Cl)C1Cl JLYXXMFPNIAWKQ-UHFFFAOYSA-N 0.000 claims description 22
- FSAVDKDHPDSCTO-WQLSENKSSA-N [(z)-2-chloro-1-(2,4-dichlorophenyl)ethenyl] diethyl phosphate Chemical compound CCOP(=O)(OCC)O\C(=C/Cl)C1=CC=C(Cl)C=C1Cl FSAVDKDHPDSCTO-WQLSENKSSA-N 0.000 claims description 20
- 239000002917 insecticide Substances 0.000 claims description 10
- 238000002360 preparation method Methods 0.000 claims description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- 239000013543 active substance Substances 0.000 claims description 4
- 239000003995 emulsifying agent Substances 0.000 claims description 4
- 125000001637 1-naphthyl group Chemical group [H]C1=C([H])C([H])=C2C(*)=C([H])C([H])=C([H])C2=C1[H] 0.000 claims description 3
- 239000000377 silicon dioxide Substances 0.000 claims description 3
- -1 (2,4-dichlorophenyl) -2-chlorovinyl Chemical group 0.000 claims 1
- 239000000843 powder Substances 0.000 claims 1
- 239000007787 solid Substances 0.000 claims 1
- 239000000126 substance Substances 0.000 description 13
- 241000258916 Leptinotarsa decemlineata Species 0.000 description 10
- 239000003795 chemical substances by application Substances 0.000 description 8
- 241000238631 Hexapoda Species 0.000 description 4
- 229910019142 PO4 Inorganic materials 0.000 description 4
- 239000010452 phosphate Substances 0.000 description 4
- 239000002253 acid Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- IAKOZHOLGAGEJT-UHFFFAOYSA-N 1,1,1-trichloro-2,2-bis(p-methoxyphenyl)-Ethane Chemical compound C1=CC(OC)=CC=C1C(C(Cl)(Cl)Cl)C1=CC=C(OC)C=C1 IAKOZHOLGAGEJT-UHFFFAOYSA-N 0.000 description 2
- 239000004480 active ingredient Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 230000031018 biological processes and functions Effects 0.000 description 2
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 230000000749 insecticidal effect Effects 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 238000011282 treatment Methods 0.000 description 2
- 125000004201 2,4-dichlorophenyl group Chemical group [H]C1=C([H])C(*)=C(Cl)C([H])=C1Cl 0.000 description 1
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 1
- 240000003291 Armoracia rusticana Species 0.000 description 1
- 235000011330 Armoracia rusticana Nutrition 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 244000061456 Solanum tuberosum Species 0.000 description 1
- 235000002595 Solanum tuberosum Nutrition 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000004599 antimicrobial Substances 0.000 description 1
- 239000003124 biologic agent Substances 0.000 description 1
- 230000004071 biological effect Effects 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- CRPOUZQWHJYTMS-UHFFFAOYSA-N dialuminum;magnesium;disilicate Chemical compound [Mg+2].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] CRPOUZQWHJYTMS-UHFFFAOYSA-N 0.000 description 1
- 230000008034 disappearance Effects 0.000 description 1
- 235000013601 eggs Nutrition 0.000 description 1
- DNJIEGIFACGWOD-UHFFFAOYSA-N ethanethiol Chemical compound CCS DNJIEGIFACGWOD-UHFFFAOYSA-N 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- DSNYFFJTZPIKFZ-UHFFFAOYSA-N propoxybenzene Chemical group CCCOC1=CC=CC=C1 DSNYFFJTZPIKFZ-UHFFFAOYSA-N 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 230000009897 systematic effect Effects 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Description
Przedmiotem wynalazku jest srodek owadobójczy o przedluzonym dzialaniu zwlaszcza stonkobójczym, fetory jako substancje czynna zawiera mieszanine N-metylokarbaminiahu_ 1-naftylu z fosforanem 0,0- -dwumetylo-0-1 / 2,4-dwuchlorofenylo / -2-chlorowi- nylowego i gamma izomerem szesciochlorocyklohe¬ ksanu oraz obojetny nosnik.The present invention relates to an insecticide with a prolonged action, especially with a stonicidal effect, stench contains a mixture as an active ingredient N-methylcarbaminiahu_ 1-naphthyl with 0.0- phosphate -dimethyl-0-1 / 2,4-dichlorophenyl / -2-chloro- nylon and gamma isomer hexachlorocyclohe xan and an inert carrier.
Sposród substancji owadobójczych stosowanych do chemicznego zwalczania stonki ziemniaczanej glówna role spelniaja pochodne kwasu N-metylo- karbaminoiwego w szczególnosci N-metylokarbami- nian 1-naftylu ((karbaryl), N-metylokarbaminian 2- -dzopropoksyfenylu (propoksuir), pochodne kwasu fosforowego a w szczególnosci fosforan 0,0-dwue- tylo-0-1 / 2,4Hdiwuchlorofenylo / -2-chlorowimyk>wy / /chlorfenwamfos/, fosforan 0,0-diwumetylo-O-1-/2,4- dwoK:hJoiTofeTiylo/-2-(bxomow!iinylowy /bromfenwin- fos/, fosforan 0,0-dwiuetylo-0-l-/2,4-dwuchlorofenylo/ /-2-bromowinyiowy oraz chlorowane weglowodory takie jak l,l,l-tLrójchlow-2,2,-dwiu/[parametoksyfe^ lo/ etan /metoksychlor/ i gamma izomer szesciochlo- rocyiklohekson /lindan/.Among the insecticides used for chemical control of the Colorado potato beetle the main role is played by derivatives of N-methyl carbaminoids, in particular N-methylcarbates- 1-naphthyl nanate ((carbaryl), 2- N-methylcarbamate -dzopropoxyphenyl (propoxyphenyl), acid derivatives phosphorus and in particular 0,0-dimethylene phosphate tylo-0-1 / 2,4H-di-chlorophenyl / -2-haloimide / (chlorfenwampphos), 0,0-divumethyl-O-1- / 2,4- phosphate dK: hJoiTofeTiylo / -2- (bxomov! iinyl / bromfenvin- phosphor /, 0,0-diuethyl-O-1- (2,4-dichlorophenyl) phosphate / -2-bromovinium and chlorinated hydrocarbons such as l, l, l-tri-trichloro-2,2, -div / [parametroxy lo / ethane / methoxychlor / and gamma hexochlo- rocyiklohekson / lindane /.
Substancje owadobójcze wystepuja w preparatach handlowych samodzielnie lub w mieszaninach. Pre- pairaity zawierajace pojedyncza substancje owado¬ bójcza stosowane byly przez dlugie lata i uzyski¬ wane efekty stonkobójcze byly dobre. Z czasem jednak, przy systematycznym aplikowaniu tych srodków w wielu odmianach szkodników a takze i u stonki nastepowalo powolne uodpornianie sie na te srodki i w konsekwencji skutecznosc zabiegów ochronnych takimi preparatami byla coraz mniej¬ sza. Prowadzone badania nad uodporniona stonka ziemniaczana wykazaly, ze odpowiednio dobrane mieszaniny substancji owadobójczych wykazuja wzmozone dzialanie biologiczne i dzieki temu, przy niewielkim zuzyciu tych substancji, uzyskuje sie znacznie wyzszy efekt stonkobójczy anizeli wynika on z addytywmego dzialania tych substancji. Posiada to równiez wielkie znaczenie z punktu widzenia ochrony srodowiska naturalnego, poniewaz zapobie¬ ga nadmiernej chemizacji gleby.Insecticides are present in preparations commercial alone or in mixtures. Pre- pairaites containing a single insect substance killer have been used for many years and yields important tonicidal effects were good. With time however, with the systematic application of these agents in many varieties of pests as well as i the Colorado beetle slowly develops its resistance to these measures and, consequently, the effectiveness of the treatments There was less and less protective with such preparations Hush. Research on an immunized Colorado beetle potato showed that properly selected mixtures of insecticides show increased biological effect and thus, at little consumption of these substances is achieved much higher stonicidal effect than it results he from the additive action of these substances. It has it is also of great importance from the point of view protect the environment as it prevent over chemical treatment of the soil.
Obecnie, do zwalczania stonki ziemniaczanej, sto¬ suje sie coraz czesciej mieszaniny substancji owa- • dobójczych dwu a nawet trójskladnikowe. Znane sa z opisu patentowego nr 67319 srodki owadobójcze zawierajace mieszanine pochodnych kwasu N-me- tylokarbaminowego z lindanem lufo z innego paten¬ tu srodki bedace mieszanina pochodnych kwasu N- -metylokairbaminowego z metoksychlorem lub pro- ipoksurem. Dzialanie tych srodków jest jednak nie¬ dostatecznie dlugotrwale.Currently, for the control of the Colorado potato beetle, one hundred more and more often mixtures of substances are oval two and even three-component antimicrobials. They are known from Patent Specification No. 67319 insecticides containing a mixture of N-me- acid derivatives tylcarbamate with lindane or other patent here means that are a mixture of N- acid derivatives -methylcarbamin with methoxychlor or pro and an oxur The effect of these measures, however, is not long-term enough.
Równiez preparat zawierajacy karbaryl z chlor- •fenwinfosem wykazuje duza aktywnosc stornkobój- cza i to zarówno w stosunku do larw jak i chrza¬ szczy. Dzialanie tej mieszaniny jest jednak równiez krótkotrwale i po niedlugim czasie nastepuje od¬ budowa populacji owada. Obecnie trwaja poszuki- 95460 A95460 3 wania srodków wykazujacych przedluzone dzialanie na zwalczane owady, co pozwoli wyeliminowac ko¬ niecznosc przeprowadzenia kilku zabiegów ochron¬ nych w jednym sezonie.Also a preparation containing carbaryl with chlorine • fenvinfosem shows high reacticidal activity cza, both against larvae and horseradish peak. However, the effect of this mixture is also briefly and after a short time there is an interruption construction of the insect population. A search is currently underway 95460 A95460 3 the use of measures showing a prolonged effect to fight insects, which will eliminate the horse the necessity to carry out several protective measures in one season.
Przedmiotem wynalazku jest srodek owadobójczy o przedluzonym dzialaniu, zwlaszcza stonkobójczym, który jako substancje czynna zawiera mieszanine N-metyloikanbaminianu 1-naftylu (karbaryl) w ilos¬ ci 80 do 98%, fosforanu 0,0-dwuetylo-0-l-/2,4-diwu- chlorofenylo/-2-chlorowinylowego (chlorfeaiwinfios) w ilosci 1 do 10°/o i gamma izomeru szesciochloro- cykloheksanu (lindan) w ilosci 1 do 10°/o oraz obo¬ jetny nosnik.The present invention relates to an insecticide with a prolonged action, especially with a stonicidal action, which contains a mixture as active substances 1-naphthyl N-methylicanbamate (carbaryl) in an amount ci 80 to 98%, 0,0-diethyl-0-1- / 2,4-divu- phosphate chlorophenyl / -2-chlorovinyl (chlorfeaiwinfios) in the amount of 1 to 10% and gamma of the hexachloro- isomer of cyclohexane (lindane) in an amount of 1 to 10% and ob jetny medium.
Srodek owadobójczy wynalazku otrzymuje sie przez wymieszanie substancji czynnej srodka z obo¬ jetnym nosnikiem i ewentualnie emulgatorem. Ja¬ ko obojetne nosniki stosuje sie gliny atapulgitowe i montmorilonitowe oraz oczyszczone krzemiany.The insecticide of the invention is obtained by mixing the active ingredient with the mixture with a suitable carrier and possibly an emulsifier. Ja¬ attapulgite clays are used as inert media and montmorillonite and purified silicates.
Wynalazek opiera sie na stwierdzeniu, ze dodatek 4 malej ilosci chlorowanych weglowodorów np. lin¬ danu do mieszaniny karbarylu z chlorfeniwamfoseim przedluza znacznie okres aktywnosci stonkobójczej mieszaniny. Srodek wedlug wynalazku, stosowany nawet w malych dawkach, wykazuje duza inicjal¬ na aktywnosc stonkobójcza oraz znaczne dzialanie przedluzone. Dziala on bardzo skutecznie na larwy jak i na chrzaszcze stonki ziemniaczanej. Ze wzgle¬ du na powyzsze wlasnosci okres ochronny ziemnia- ika tym preparatem przed zerowaniem stonki jest dlugi i nie zachodzi potrzeba powtarzania zabiegu.The invention is based on the finding that the additive 4 a small amount of chlorinated hydrocarbons, eg lin danu to a mixture of carbaryl with chlorphenyvamphoseime significantly prolongs the period of stonicidal activity mixture. The agent according to the invention is used even in small doses, it has a high initial on stonicidal activity and significant action extended. It is very effective on the larvae as well as for the Colorado potato beetle. Due to due to the above-mentioned properties, the ika with this preparation before resetting the Colorado beetle long and there is no need to repeat the procedure.
Przyklady owadobójczego dzialania srodka wg wynalazku w porównaniu do znanych zwiazków o dzialaniu owadobójczym i ich mieszanin ilustruja tablice nr I i II.Examples of insecticidal action of the agent according to the invention compared to the known compounds of Fr. the insecticidal activity and their mixtures illustrate tables I and II.
Skutecznosc preparatów wyrazona jest wartoscia LT60 i LT95, to jest czasem, w jakim nastapila smiertelnosc owadów w 50 i 95°/o, po ich ekspozycji na opryskanych powierzchniach.The effectiveness of the preparations is expressed in value LT60 and LT95, this is the time it occurred Mortality of insects at 50 and 95% after exposure on sprayed surfaces.
Tabela I Skutecznosc biologiczna srodka wg. wynalazku badana laboratoryjnie na musze domowej L.p. 1 . 2 3 4 1 6 - Zwiazek lub mieszanina karbaryl chlorfenwinfos » lindan »» karbaryl + chlorfenwinfos karbaryl + lindan karbaryl + chlorfenwinfos + lindan karbaryl + chlorfenwinfos + lindan Substancja czynna w W/o 100 100 100 100 100 95 96 4 91 4 91 4 Substancja czynna w kg na ha 1,0 0,5 0,3 0,5 0,2 1,0 1,0 1,0 0,5 LT50 (min.) 105 180 150 400 240 300 103 150 Wskaznik LT60 LT95 (min.) brak dzialania 3,8 2,2 2,6 1,0 1,6 1,3 3,8 2,6 160 200 200 500 408 250 150 200 Wskaznik LTgs — 3,1 2,5 2,5 1,0 1,2 ¦ 2,0 3,3 2,6 Tabela II Skutecznosc biologiczna srodka wg. wynalazku badana laboratoryjnie na chrzaszczach stonki ziemniaczanej L.p. 1 1 1 2 3 3 4 6 7 1 Zwiazek lub mieszanina Karbaryl chlorfenwinfos lindan karbaryl + chlorfenwinfos karbaryl + lindan karbaryl + chlorfenwinfos + lindan karbaryl + chlorfenwinfos + lindan Substancja czynna iw W/o 100 100 100 100 100 95 96 4 92 3 92 3 Substancja czynna w kg na ha 1,0 0,5 ' 0,3 0,5 0,2 ' 1,0 1,0 1,0 0,5 LT50 (min.) 250 158 200 180 250 226 230 150 200 Wskaznik LT50 1,0 1,7 1,2 1,4 1,0 1,1 1,1 1,6 1,3 LT95 (min.) 800 350 420 450 500 800 800 380 400 Wskaznik LT95 1,0 2,3 1,9 1,8 1,6 1,0 1,0 2,1 2,095460 W badaniach laboratoryjnych na musze domowej i stonce ziemniaczanej stwierdzono, ze skutecznosc biologiczna srodka wg. wynalazku, wyrazona wska¬ znikiem LT50 i LT95 jest najwyzsza, dorównuje mu jedynie chlorfenwinfos i lindan. Stosowanie jednak parat o skladzie, w którym na kazde 100% mie¬ szaniny karbaryl stanowi 84%, chlorfenwinfos 8%, lindan 8% wagowych.Table I. The biological effectiveness of the agent according to the invention tested in a laboratory on a home must L.p. 1. 2 3 4 1 6 - Compound or mixture carbaryl chlorfenvinphos » lindane »» carbaryl + chlorfenvinphos carbaryl + lindane carbaryl + chlorfenvinphos + lindane carbaryl + chlorfenvinphos + lindane Substance open in W / o 100 100 100 100 100 95 96 4 91 4 91 4 Substance open in kg per ha 1.0 0.5 0.3 0.5 0.2 1.0 1.0 1.0 0.5 LT50 (min.) 105 180 150 400 240 300 103 150 Indicator LT60 LT95 (min.) no effect 3.8 2.2 2.6 1.0 1.6 1.3 3.8 2.6 160 200 200 500 408 250 150 200 Indicator LTgs - 3.1 2.5 2.5 1.0 1.2 ¦ 2.0 3.3 2.6 Table II The biological effectiveness of the agent according to The invention was tested in a laboratory on the Colorado potato beetle L.p. 1 1 1 2 3 3 4 6 7 1 Compound or mixture Carbaryl chlorfenvinphos lindane carbaryl + chlorfenvinphos carbaryl + lindane carbaryl + chlorfenvinphos + lindane carbaryl + chlorfenvinphos + lindane Substance open and in W / o 100 100 100 100 100 95 96 4 92 3 92 3 Substance open in kg per ha 1.0 0.5 '0.3 0.5 0.2 ' 1.0 1.0 1.0 0.5 LT50 (min.) 250 158 200 180 250 226 230 150 200 Indicator LT50 1.0 1.7 1.2 1.4 1.0 1.1 1.1 1.6 1.3 LT95 (min.) 800 350 420 450 500 800 800 380 400 Indicator LT95 1.0 2.3 1.9 1.8 1.6 1.0 1.0 2.1 2.095460 In the laboratory research on a home must and the Colorado potato beetle was found to be effective biological agent according to of the invention, expressed by the index the disappearance of the LT50 and LT95 is the highest and is equal to it only chlorfenvinphos and lindane. Application however parat with a composition in which for every 100% of the mixture carbaryl is 84%, chlorfenvinphos 8%, lindane 8 wt.%.
Przyklad II. Do mieszalnika szybkoobroto¬ wego laduje sie 30 kg nosnika (krzemionki), 60 kg I T a b e 1 a III Dlugotrwalosc dzialania biologicznego srodka wg wynalazku badana w polu na larwach i chrzaszczach stonki ziemniaczanej L.p. « 1 2 3 4 Zwiazek lub mieszanina Karbaoryl chlorfenwinfos karbaryl + chlorfenwinfos karbaryl + lindan karbaryl + chlorfenwinfos + lindan karbaryl + • chlorfenwinfos + lindan Substancja czynna w%% 100 100 95 96 4 92 "3 92 3 Substancja czynna w kg na ha 1,0 0,5 1,0 1,0 1,0 0,5 Skutecznosc biologiczna po dniach w %% 1 85 90 92 85 98 92 7 75 80 82 70 94 90 14 50 60 50 88 74 21 40 0 70 60 ? Odbudowa populacji po dniach w %% 7 . 20 18 6 ^ 14 80 40 75 50 12 24 tych substancji samodzielnie, w dawkach skutecz¬ nych jest niewskazane ze wzgledu na ochrone sro¬ dowiska naturalnego.Example II. High speed mixer 30 kg of carrier (silica), 60 kg are loaded I T a b e 1 a III The longevity of the biological action of the agent according to the invention tested in the field on larvae and beetles Colorado potato beetle L.p. « 1 2 3 4 Compound or mixture Carbaoryl chlorfenvinphos carbaryl + chlorfenvinphos carbaryl + lindane carbaryl + chlorfenvinphos + lindane carbaryl + • chlorfenvinphos + lindane Substance open in%% 100 100 95 96 4 92 "3 92 3 Substance open in kg per ha 1.0 0.5 1.0 1.0 1.0 0.5 Biological effectiveness after days in %% 1 85 90 92 85 98 92 7 75 80 82 70 94 90 14 50 60 50 88 74 21 40 0 70 60 ? Rebuilding the population after days in %% 7 . twenty 18 6 ^ 14 80 40 75 50 12 24 of these substances alone, in doses effective it is inadvisable due to the protection of sro natural habitat.
Przedluzone dzialanie biologiczne srodka wg wy¬ nalazku obrazuje tablica nr III.Prolonged biological action of the agent according to The invention is presented in the table No. III.
Srodek wg. wynalazku dziala znacznie dluzej ani¬ zeli substancje owadobójcze zastosowane indywidu¬ alnie lub w mieszaninach dwuskladnikowych. Od¬ budowa populacji stonki ziemniaczanej z jaj po 7 i 14 dniach jest znacznie nizsza anizeli przy zasto¬ sowaniu zarówno pojedynczych skladników stano¬ wiacych substancje czynna srodka wg.Measure according to the invention lasts much longer the insecticides used individually alternatively or in two-component mixtures. Od construction of the Colorado potato beetle population from eggs after 7 and 14 days is significantly lower than for the standstill the use of both the individual components was binding active substances of the agent acc.
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL17723175A PL95460B1 (en) | 1975-01-08 | 1975-01-08 | INSOCICTIC AGENT WITH PROLONGED ACTIVITY WITH ONCOBIC |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL17723175A PL95460B1 (en) | 1975-01-08 | 1975-01-08 | INSOCICTIC AGENT WITH PROLONGED ACTIVITY WITH ONCOBIC |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| PL95460B1 true PL95460B1 (en) | 1977-10-31 |
Family
ID=19970540
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL17723175A PL95460B1 (en) | 1975-01-08 | 1975-01-08 | INSOCICTIC AGENT WITH PROLONGED ACTIVITY WITH ONCOBIC |
Country Status (1)
| Country | Link |
|---|---|
| PL (1) | PL95460B1 (en) |
-
1975
- 1975-01-08 PL PL17723175A patent/PL95460B1/en unknown
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