PL93206B2 - - Google Patents

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Publication number
PL93206B2
PL93206B2 PL181358A PL18135875A PL93206B2 PL 93206 B2 PL93206 B2 PL 93206B2 PL 181358 A PL181358 A PL 181358A PL 18135875 A PL18135875 A PL 18135875A PL 93206 B2 PL93206 B2 PL 93206B2
Authority
PL
Poland
Prior art keywords
reaction
butyl
water
temperature
octyltin
Prior art date
Application number
PL181358A
Other languages
Polish (pl)
Other versions
PL93206B1 (en
Inventor
Boboli Edyta
Longin Malasnicki Wladyslaw
Lato Czeslaw
Original Assignee
Instytut Przemyslu Organicznego
Filing date
Publication date
Application filed by Instytut Przemyslu Organicznego filed Critical Instytut Przemyslu Organicznego
Priority to PL181358A priority Critical patent/PL93206B2/pl
Publication of PL93206B1 publication Critical patent/PL93206B1/xx
Publication of PL93206B2 publication Critical patent/PL93206B2/pl

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Claims (2)

1. Zastrzezenia patentowe 1. Sposób wytwarzania karboksylanów dwualkilocynowych o ogólnym wzorze przedstawionym na rysunku, w którym Ra stanowi n-butyl lub n-oktyl, a R1 jest rodnikiem alkilowym o Cg-C^, w bezposredniej reakcji stechiometrycznych ilosci tlenków dwu-n-butylo- lub dwu-n-oktylocynowych I jednokarboksylowych kwasów o C6—C2Qt znamienny tym, ze proces prowadzi sie w srodowisku wody zawierajacej ewentualnie srodek wysalajacy, taki Jak siarczan czy chlorek sodowy, w temperaturze ponizej 100°C, najkorzystniej w temperaturze 70—80°C, po czym po zakonczonej reakcji otrzymany produkt oddziela sie od wody przez rozwarstwienie i saczy sie.1. Claims 1. A process for the preparation of dialkyltin carboxylates of the general formula in which Ra is n-butyl or n-octyl and R1 is a C8-C6 alkyl radical by direct reaction of stoichiometric amounts of di-n-oxides butyl- or di-n-octyltin and monocarboxylic acids of C6-C2Qt, characterized in that the process is carried out in a water environment that may contain a salting-out agent, such as sulfate or sodium chloride, at a temperature below 100 ° C, most preferably at a temperature of 70-80 ° C, then, after the reaction is completed, the product obtained is separated from water by slicing and filtered. 2. Sposób wytwarzania karboksylanów dwualkilocynowych o ogólnym wzorze przedstawionym na rysunku, w którym Ra stanowi n-butyl lub n-oktyl, a R1 jest rodnikiem alkilowym o C5-Clf, w bezposredniej reakcji stechiometrycznych ilosci tlenków dwu-n-butylo- lub dwu-n-oktylocynowych i jednokarboksylowych kwasów oCd-Cao., znamienny tym, ze proces prowadzi sie wylacznie w obecnosci tworzacej sie w reakcji wody, w temperaturze ponizej 100°C, najkorzystniej w temperaturze 70-80°C, po czym po zakonczonej reakcji otrzymany produkt oddziela sie od wody przez rozwarstwienie i saczy sie. USnlOÓCFl PL PL2. A process for the preparation of dialkyltin carboxylates of the general formula shown in the figure, in which Ra is n-butyl or n-octyl and R1 is an alkyl radical of C5-Clf, by direct reaction of stoichiometric amounts of di-n-butyl or di-oxides oCd-Cao n-octyltin and monocarboxylic acids, characterized in that the process is carried out only in the presence of water formed in the reaction, at a temperature below 100 ° C, most preferably at a temperature of 70-80 ° C, and after the reaction is completed, the product obtained separates from water by stratification and seeps. USnlOÓCFl PL PL
PL181358A 1975-06-18 PL93206B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PL181358A PL93206B2 (en) 1975-06-18

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PL181358A PL93206B2 (en) 1975-06-18

Publications (2)

Publication Number Publication Date
PL93206B1 PL93206B1 (en) 1977-05-30
PL93206B2 true PL93206B2 (en) 1977-05-31

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