PL8970B1 - The method of producing or processing oils. - Google Patents
The method of producing or processing oils. Download PDFInfo
- Publication number
- PL8970B1 PL8970B1 PL8970A PL897027A PL8970B1 PL 8970 B1 PL8970 B1 PL 8970B1 PL 8970 A PL8970 A PL 8970A PL 897027 A PL897027 A PL 897027A PL 8970 B1 PL8970 B1 PL 8970B1
- Authority
- PL
- Poland
- Prior art keywords
- subjected
- fact
- liquid
- vapors
- high voltage
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 18
- 239000003921 oil Substances 0.000 title claims description 4
- 239000007788 liquid Substances 0.000 claims description 9
- 239000000463 material Substances 0.000 claims description 9
- 239000007858 starting material Substances 0.000 claims description 9
- 239000003054 catalyst Substances 0.000 claims description 8
- 239000000126 substance Substances 0.000 claims description 8
- 239000007789 gas Substances 0.000 claims description 6
- 238000006243 chemical reaction Methods 0.000 claims description 5
- 239000007787 solid Substances 0.000 claims description 4
- 239000000446 fuel Substances 0.000 claims description 3
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 2
- 238000000576 coating method Methods 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 239000003595 mist Substances 0.000 claims description 2
- 239000007921 spray Substances 0.000 claims description 2
- 239000000428 dust Substances 0.000 claims 3
- 230000008020 evaporation Effects 0.000 claims 1
- 238000001704 evaporation Methods 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- 238000009835 boiling Methods 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 239000003077 lignite Substances 0.000 description 2
- 239000013543 active substance Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000004449 solid propellant Substances 0.000 description 1
Description
Okazalo sie, ze przy przepuszczaniu substancji przez pole o Wysokiem napie¬ ciu pradu elektrycznego daja sie osiagnac zarówno procesy syntetyczne, jak i rozkla¬ dowe czasteczki.Wynalazek niniejszy polega na wyzy¬ skaniu tego sposobu do wytwarzania wzglednie przetwarzania olejów. Mozna przytem jako materjal wyjsciowy stosowac ciala stale, plynne albo gazowe, jak pali¬ wo, smole albo produkty smolowcowe, gaz czadnicowy i osiagnac zarówno rozczepie- nie czasteczek, jak i ich uwodornienie.Dla osiagniecia dobrej wydajnosci prze¬ rabia sie materjaly wejsciowe w stanie drobno rozdzielonym i miesza z innemi sproszkowanemi, plynnemi albo gazowemi substancjami. Mozna równiez stosowac i katalizatory. Do przyspieszenia reakcji mozna podwyzszyc zarówno cisnienie, jak i temperature.Przy uzyciu jako materjalu wyjsciowe¬ go stalego paliwa, miele sie je mialko i samo albo zmieszane z odpowiedniemi ga¬ zami wzglednie z parami poddaje dziala¬ niu pradu o wysokiem napieciu wzgled¬ nie dzialaniu katalizatorów.Aparatura o wysokiem napieciu dla plynnych albo gazowych materjalów wyj¬ sciowych jest ta sama, jak dla stalych materjalów wyjsciowych. Drobny podzial osiaga sie zapomoca odpowiednich rozpy¬ laczy.Katalizatory mozna dodac w postaciplynu, mgly albo gazu; stosowane elek¬ trody moga calkowicie albo czesciowo sklalacHie z katalitycznie dzialajacych substancyj. Równiez mozna stosowac dzia¬ laj aca katalitycznie powloke na elektro¬ dach albo na scianach przestrzeni reakcyj¬ nej. Wskazane jest uzycie jako kataliza¬ tora cyny, jednak moga byc stosowane i inne katalizatory o podobnych wlasno¬ sciach.Czesto korzystne jest aparature wyso¬ kiego napiecia poddac cisnieniu i, w da¬ nym razie, mozna pracowac pod bardzo wysokiem cisnieniem, W pewnych wypadkach wskazane jest ogrzanie przerabianej substancji przed jej wprowadzeniem do przestrzeni reakcyjnej albo ogrzanie aparatury wysokiego napie¬ cia. Jezeli wyjsciowym materjalem jest paliwo, to czesto wskazane jest, dla osia¬ gniecia mozliwie drobnego podzialu tego materjalu, poddanie go parowaniu.Jako przyklad wykonania sposobu we¬ dlug wynalazku jest dalej opisane otrzy¬ mywanie oleju z plynnego materjalu wyj¬ sciowego, a mianowicie smoly albo pro¬ duktów smolowcowych.Smola albo produkty smolowcowe, wy¬ twarzajace sie przy destylacji wegla bru¬ natnego, prowadzi sie rura metalowa, po¬ laczona z biegunem maszyny pradu zmien¬ nego i w której znajduje sie polaczona z drugim biegunem elektroda druciana. Ma¬ terjal wyjsciowy zdolu rozpyla sie naprze¬ ciw elektrody drucianej. Produkty konco¬ we splywaja przez przylaczona u dolu rure.Wskazane jest takie urzadzenie, zeby przerabiane substancje kilkakrotnie byly przeprowadzone w procesie kolowym przez aparature, która w calosci jest otoczona o- slona i moze byc opalona.Doswiadczenia pokazaly, ze 100 kg smoly z destylacji wegla brunatnego, za¬ wierajacego przed traktowaniem tylko 4% skladników, wrzacych ponizej 200°, zawie¬ raly po przeróbce okolo 40 kg skladni¬ ków, wrzacych ponizej 200°.Przy wykonaniu procesu w atmosferze wodoru wzrasta zawartosc skladników, wrzacych ponizej 200° z 4% do okolo 50%—60%.Przez przeróbke przeto w atmosferze wodorowej zawartosc lzej wrzacych w niej skladników wzrasta jeszcze bardziej.Dalsze powiekszenie takich skladników mozna osiagnac przez stosowanie kataliza¬ torów. PL PLIt has turned out that by passing a substance through a field with a high voltage of electric current, both synthetic processes and decomposition of molecules can be achieved. The present invention consists in using this method for the production or processing of oils. It is also possible to use solids, liquid or gaseous bodies, such as fuel, tar or tar products, and carbon dioxide as a starting material, and achieve both particle separation and hydrogenation. To achieve good efficiency, the input materials are transformed in the state of finely divided and mixed with other powdered, liquid or gaseous substances. You can also use and catalysts. To accelerate the reaction, both the pressure and the temperature can be raised. When using solid fuel as a starting material, the ground is ground and either alone or mixed with suitable gases or with vapors subjected to a high voltage current or to the action of Catalysts. The high voltage apparatus for liquid or gaseous starting materials is the same as for the solid starting materials. A fine division is achieved with the aid of suitable sprays. The catalysts can be added in the form of a liquid, a mist or a gas; the electrodes used may completely or partially be composed of catalytically active substances. It is also possible to use a catalytically acting coating on the electrodes or on the walls of the reaction space. The use of tin as the catalyst is desirable, but other catalysts with similar properties may be used. Often it is preferred to pressurize the high voltage apparatus and, in any case, to operate at very high pressures. it is advisable to heat the material to be processed before its introduction into the reaction space or to heat the high voltage apparatus. If the starting material is a fuel, it is often desirable to evaporate the material in order to achieve a finely divided material. As an example of an embodiment of the method according to the invention, the preparation of oil from the liquid starting material, namely tar or tar products. The tar or tar products produced by brown coal distillation are led through a metal tube connected to the pole of an AC machine and in which there is a wire electrode connected to the other pole. The starting material is sprayed against the wire electrode. The final products flow down through the pipe attached at the bottom. It is advisable to arrange the substances to be processed several times in a circular process through an apparatus which is completely surrounded by salt and can be tanned. Experience has shown that 100 kg of tar from distillation Brown coal, which before treatment contained only 4% of the ingredients boiling below 200 ° C, contained after processing about 40 kg of ingredients, boiling below 200 °. When the process was carried out in a hydrogen atmosphere, the content of ingredients boiling below 200 ° was increased. 4% to about 50% -60%. By treatment, therefore, in a hydrogen atmosphere, the content of the lighter boiling components therein increases even more. A further increase in such components can be achieved by the use of catalysts. PL PL
Claims (11)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| PL8970B1 true PL8970B1 (en) | 1928-06-30 |
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