PL8901B1 - Washing method at low temperatures. - Google Patents

Washing method at low temperatures. Download PDF

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Publication number
PL8901B1
PL8901B1 PL8901A PL890127A PL8901B1 PL 8901 B1 PL8901 B1 PL 8901B1 PL 8901 A PL8901 A PL 8901A PL 890127 A PL890127 A PL 890127A PL 8901 B1 PL8901 B1 PL 8901B1
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PL
Poland
Prior art keywords
urea
low temperatures
washing
washing method
urease
Prior art date
Application number
PL8901A
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Polish (pl)
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Publication date
Application filed filed Critical
Publication of PL8901B1 publication Critical patent/PL8901B1/en

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Description

Zasadnicza czesc procesu prania sta¬ nowi dotychczas przewaznie mechaniczna obróbka materjalów przeznaczonych do o- czyszczenia, polegajaca na tarciu recznem, tluczeniu, tloczeniu lub poruszaniu w ma¬ szynach do prania. Od pewnego czasu przekonano sie, ze przy uzyciu tak zwa¬ nych „samoczynnych srodków pioracych" zbyteczna staje sie obróbka mechaniczna, oczywiscie bardzo szkodliwa dla wlókien tkanin. Wyzej wymieniona zaleta odzna¬ czaja sie srodki zawierajace nadboran, jak np, persil.Samoczynne dzialanie tych srodków roz¬ poczyna sie dopiero powyzej 70°C, a osia¬ ga najwieksza skutecznosc dopiero w tem¬ peraturze wrzenia. Poniewaz jednak wiele materjalów, jak welna, jedwab i jedwab sztuczny nie znosza bez uszkodzen tempe¬ ratur ponad 70°C, to dla tych materjalów pozostaje jedynie obróbka mechaniczna Doswiadczenia wykazaly, ze samoczyn¬ ne dzialanie piorace mozna osiagnac rów¬ niez i ponizej 70°C, jezeli w cieczy do pra¬ nia wywolac enzymatyczny rozklad mocz¬ nika. Rozklad ten zachodzi juz w tempera¬ turze pokojowej, jednakze przebiega lepiej miedzy 30°C a 70° C i polega na tern, ze mocznik rozklada sie na amonjak i kwas weglowy.Rozklad ten mozna poznac po wydzie¬ laniu sie pecherzyków gazu porywajacych czesciowo brud, oraz po wydzielajacym sie zapachu amonjaku. Samoczynne dzialanie piorace odbywa sie, jak przy zastosowaniu znanych srodków.Dalsza zaleta;wynalazku jest znane la<- godne dzialanie piorace skutkiem obecno¬ sci amonjaku. : ¦¦.* 4 Wybalazek mozna wykonac np. w ten sposób, ze do srodka pior^ego skladajace¬ go sie z mydla, slabej zasady i temu podob¬ nych odczynników, dodaje sie w stanie su¬ chym mocznika w celu wywolania sarnom czynnego dzialania, oraz ureazy jako srod¬ ka rozkladajacego mocznik. Dzialanie roz¬ poczyna sie dopiero po f wprowadzeniu te^ go srodka do wody tek; iz w zaleznosci od skladu srodka, od temperatury i stezenia w ciagu godziny rozklada sie mniejsza lub wieksza ilosc mocznika.Wiadomo, ze optimum temperaturydla enzymatycznego rozkladu mocznika lezy miedzy 40* a 60°C, jednakze rozklad ten zachodzi równiez w wyzszych i nizszych temperaturach,- choc nieco slabiej. Wiado¬ mo równiez, ze istnieje tu takze pewne op¬ timum stezenia jonów wodorowych, lecz mozna go nie zachowywac.Preparat ureazowy mozna otrzymac np. sposobem Slyke & Cullen opisanym w „Deutsche medizinische Wochenschrift" 40, 1914 r. s,tr. 1219 do 1221.W praktyce obok mocznika i ureazy za¬ leca sie stosowanie mydla, lagodnych al- kaljów albo innych srodków zwilzajacych lub rozpuszczajacych brud, poniewaz ani mocznik, ani ureaza, ani tez reakcja roz¬ padu mie nadaja srodkowi pioracemu wla¬ sciwosci zwilzajacych ani emulgujacych.Przyklad- wykonania wynalazku* 10 czesci mydla jedrnego 1,2 cz. fosforanu dwusodowego (Na2HPOJA 2 cz. moczni¬ ka, 0,5 preparatu ureazy. PL PLUntil now, the essential part of the washing process has been largely the mechanical treatment of the materials to be cleaned, by rubbing by hand, rubbing, pressing or moving in washing machines. It has been known for some time that when using so-called "self-cleaning detergents", mechanical treatment becomes unnecessary, of course very harmful to the fibers of fabrics. The above-mentioned advantage is characteristic of perborate-containing agents, such as persil. The agents do not start until above 70 ° C, and they achieve their greatest effectiveness only at the boiling point, but since many materials, such as wool, silk and rayon, cannot withstand temperatures above 70 ° C without damage, of these materials, only mechanical processing remains. Experience has shown that automatic washing action can be achieved even below 70 ° C, if enzymatic decomposition of urea is induced in the washing liquid. This decomposition already takes place at room temperature, however, it is better between 30 ° C and 70 ° C and consists in the fact that urea is broken down into ammonia and carbonic acid. This distribution can be seen from the release of gas bubbles by entraining h partly dirt, and after the smell of ammonia. The self-washing action is carried out as with known means. A further advantage of the invention is that it is effective in washing due to the presence of ammonia. : ¦¦. * 4 The invention can be made, for example, by adding urea to a detergent consisting of soap, a weak base and the like, in the dry state to induce active deer. action, and urease as a urea decomposing agent. The action does not start until the agent has been introduced into the water; that depending on the composition of the agent, the temperature and concentration, within an hour, a smaller or larger amount of urea is distributed. It is known that the optimum temperature for the enzymatic decomposition of urea lies between 40 * and 60 ° C, but this decomposition also takes place at higher and lower temperatures, - though a bit weaker. It is also known that there is also a certain optimum of hydrogen ion concentration here, but it may not be maintained. The urease preparation can be obtained e.g. by the method of Slyke & Cullen described in "Deutsche medizinische Wochenschrift" 40, 1914 pp, tr. 1219 to 1221. In practice, apart from urea and urease, it is recommended to use soaps, mild alkalis or other wetting or dissolving agents, because neither urea, nor urease, nor the decomposition reaction give the detergent wetting or wetting properties. Exemplary embodiment of the invention * 10 parts of soap, 1.2 parts of disodium phosphate (Na2HPOJA, 2 parts of urea, 0.5 parts of urease. PL EN

Claims (3)

1. Zastrzezenia patentowe. 1. Sposób prania w niskich tempera¬ turach, znamienny tern, ze w srodku pio¬ racym wywoluje sie enzymatyczny rozklad mocznika np. pod wplywem ureazy.1. Patent claims. A method of washing at low temperatures, characterized by the fact that enzymatic decomposition of urea is induced in the washing agent, for example under the influence of urease. 2. Sposób wedlug zastrz. 1, znamienr- ry tern, ze materjaly powodujace rozklad mocznika dodaje sie w mieszaninie z jed¬ nym lub kilkoma materjalami, sluzacemi do otrzymywania srodków pioracych.2. The method according to claim A method according to claim 1, characterized in that urea decomposing materials are added in a mixture with one or more materials for the preparation of detergents. 3. Srodek pioracy, sluzacy do wyko¬ nania sposobu wedlug zastrz, 1 i 2, zna¬ mienny tern, ze zawiera mocznik oraz sro¬ dek powodujacy jego enzymatyczny roz¬ klad, Henkel & Cie. G. m. b. H. Zastepca: I. Myszczynski, rzecznik patentowy. Druk L. Boguslawskiego, Warszawa. PL PL3. Detergent for carrying out the process according to claims 1 and 2, characterized by the fact that it contains urea and an enzymatic degradation agent, Henkel & Cie. G. m. B. H. Zastepca: I. Myszczynski, patent attorney. Printed by L. Boguslawski, Warsaw. PL PL
PL8901A 1927-08-09 Washing method at low temperatures. PL8901B1 (en)

Publications (1)

Publication Number Publication Date
PL8901B1 true PL8901B1 (en) 1928-06-30

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