PL80880B1 - - Google Patents

Info

Publication number

PL80880B1

PL80880B1 PL13127469A PL13127469A PL80880B1 PL 80880 B1 PL80880 B1 PL 80880B1 PL 13127469 A PL13127469 A PL 13127469A PL 13127469 A PL13127469 A PL 13127469A PL 80880 B1 PL80880 B1 PL 80880B1

Authority

PL

Poland

Prior art keywords

manganese

aluminum

chloride

aluminum trichloride

temperature

Prior art date

1969-01-20

Links

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• VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 claims description 78
• 238000000034 method Methods 0.000 claims description 56
• PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 55
• 229910052748 manganese Inorganic materials 0.000 claims description 55
• 239000011572 manganese Substances 0.000 claims description 55
• 229910052782 aluminium Inorganic materials 0.000 claims description 52
• XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 52
• GLFNIEUTAYBVOC-UHFFFAOYSA-L Manganese chloride Chemical compound Cl[Mn]Cl GLFNIEUTAYBVOC-UHFFFAOYSA-L 0.000 claims description 51
• 239000011565 manganese chloride Substances 0.000 claims description 51
• 229910021380 Manganese Chloride Inorganic materials 0.000 claims description 50
• 235000002867 manganese chloride Nutrition 0.000 claims description 50
• 238000006243 chemical reaction Methods 0.000 claims description 35
• 229940099607 manganese chloride Drugs 0.000 claims description 34
• 239000007788 liquid Substances 0.000 claims description 33
• 230000008569 process Effects 0.000 claims description 30
• 239000000571 coke Substances 0.000 claims description 18
• 230000009467 reduction Effects 0.000 claims description 11
• PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 7
• 238000009835 boiling Methods 0.000 claims description 7
• 238000002844 melting Methods 0.000 claims description 7
• 230000008018 melting Effects 0.000 claims description 7
• WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 5
• 239000003610 charcoal Substances 0.000 claims description 2
• 238000006722 reduction reaction Methods 0.000 claims 7
• 239000007795 chemical reaction product Substances 0.000 claims 1
• 239000012530 fluid Substances 0.000 claims 1
• 229910021385 hard carbon Inorganic materials 0.000 claims 1
• TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims 1
• 239000000047 product Substances 0.000 claims 1
• 239000004927 clay Substances 0.000 description 31
• 239000007789 gas Substances 0.000 description 22
• 239000000463 material Substances 0.000 description 12
• 239000000203 mixture Substances 0.000 description 12
• UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 9
• HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
• QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 9
• 229910052799 carbon Inorganic materials 0.000 description 9
• 239000001301 oxygen Substances 0.000 description 9
• 229910052760 oxygen Inorganic materials 0.000 description 9
• XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
• 238000004519 manufacturing process Methods 0.000 description 7
• 239000002994 raw material Substances 0.000 description 7
• OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
• UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 6
• 229910002091 carbon monoxide Inorganic materials 0.000 description 6
• 239000001257 hydrogen Substances 0.000 description 6
• 229910052739 hydrogen Inorganic materials 0.000 description 6
• KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 5
• 239000007787 solid Substances 0.000 description 5
• XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 4
• 229910001570 bauxite Inorganic materials 0.000 description 4
• 238000005660 chlorination reaction Methods 0.000 description 4
• 229910052710 silicon Inorganic materials 0.000 description 4
• 239000010703 silicon Substances 0.000 description 4
• VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 3
• XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 3
• 239000002585 base Substances 0.000 description 3
• 230000008901 benefit Effects 0.000 description 3
• 239000000460 chlorine Substances 0.000 description 3
• 229910052801 chlorine Inorganic materials 0.000 description 3
• 238000013461 design Methods 0.000 description 3
• 239000003546 flue gas Substances 0.000 description 3
• NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Inorganic materials O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 3
• IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
• CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
• VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
• VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
• 229910000831 Steel Inorganic materials 0.000 description 2
• WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 2
• 229940024548 aluminum oxide Drugs 0.000 description 2
• 229910002092 carbon dioxide Inorganic materials 0.000 description 2
• 239000003575 carbonaceous material Substances 0.000 description 2
• IZMHKHHRLNWLMK-UHFFFAOYSA-M chloridoaluminium Chemical compound Cl[Al] IZMHKHHRLNWLMK-UHFFFAOYSA-M 0.000 description 2
• 239000003245 coal Substances 0.000 description 2
• 150000001875 compounds Chemical class 0.000 description 2
• 238000011109 contamination Methods 0.000 description 2
• 238000010586 diagram Methods 0.000 description 2
• 239000004615 ingredient Substances 0.000 description 2
• 229910052742 iron Inorganic materials 0.000 description 2
• 238000002156 mixing Methods 0.000 description 2
• 239000010959 steel Substances 0.000 description 2
• 239000000126 substance Substances 0.000 description 2
• 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
• BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
• 229910000503 Na-aluminosilicate Inorganic materials 0.000 description 1
• 229910052770 Uranium Inorganic materials 0.000 description 1
• 229910000323 aluminium silicate Inorganic materials 0.000 description 1
• 238000003339 best practice Methods 0.000 description 1
• 239000001569 carbon dioxide Substances 0.000 description 1
• 230000008859 change Effects 0.000 description 1
• 239000003638 chemical reducing agent Substances 0.000 description 1
• 239000003795 chemical substances by application Substances 0.000 description 1
• 150000001805 chlorine compounds Chemical class 0.000 description 1
• 229910052570 clay Inorganic materials 0.000 description 1
• 229910052681 coesite Inorganic materials 0.000 description 1
• 238000007906 compression Methods 0.000 description 1
• 230000006835 compression Effects 0.000 description 1
• 238000009833 condensation Methods 0.000 description 1
• 230000005494 condensation Effects 0.000 description 1
• 238000010411 cooking Methods 0.000 description 1
• 238000001816 cooling Methods 0.000 description 1
• 229910052906 cristobalite Inorganic materials 0.000 description 1
• 229910001610 cryolite Inorganic materials 0.000 description 1
• 239000013078 crystal Substances 0.000 description 1
• 125000004122 cyclic group Chemical group 0.000 description 1
• 230000003247 decreasing effect Effects 0.000 description 1
• 238000011161 development Methods 0.000 description 1
• 238000010494 dissociation reaction Methods 0.000 description 1
• 230000005593 dissociations Effects 0.000 description 1
• 238000001035 drying Methods 0.000 description 1
• 230000000694 effects Effects 0.000 description 1
• 238000001704 evaporation Methods 0.000 description 1
• 230000008020 evaporation Effects 0.000 description 1
• 238000000605 extraction Methods 0.000 description 1
• -1 for example Substances 0.000 description 1
• 229910052809 inorganic oxide Inorganic materials 0.000 description 1
• JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
• 230000007774 longterm Effects 0.000 description 1
• 150000002697 manganese compounds Chemical class 0.000 description 1
• VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
• 238000012986 modification Methods 0.000 description 1
• 230000004048 modification Effects 0.000 description 1
• 229910052757 nitrogen Inorganic materials 0.000 description 1
• QVGXLLKOCUKJST-NJFSPNSNSA-N oxygen-18 atom Chemical compound [18O] QVGXLLKOCUKJST-NJFSPNSNSA-N 0.000 description 1
• 238000012545 processing Methods 0.000 description 1
• 238000000746 purification Methods 0.000 description 1
• 239000011819 refractory material Substances 0.000 description 1
• 238000011160 research Methods 0.000 description 1
• 238000010079 rubber tapping Methods 0.000 description 1
• 239000013049 sediment Substances 0.000 description 1
• 239000000377 silicon dioxide Substances 0.000 description 1
• 235000012239 silicon dioxide Nutrition 0.000 description 1
• 239000002893 slag Substances 0.000 description 1
• 239000010454 slate Substances 0.000 description 1
• 239000000429 sodium aluminium silicate Substances 0.000 description 1
• 235000012217 sodium aluminium silicate Nutrition 0.000 description 1
• URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
• 239000007921 spray Substances 0.000 description 1
• 239000007858 starting material Substances 0.000 description 1
• 238000003756 stirring Methods 0.000 description 1
• 229910052682 stishovite Inorganic materials 0.000 description 1
• 229910052719 titanium Inorganic materials 0.000 description 1
• 229910052905 tridymite Inorganic materials 0.000 description 1
• 229910052720 vanadium Inorganic materials 0.000 description 1