PL69B1 - management for the squeezing and condensation of ammonia from ammoniacal vapors containing water vapor. - Google Patents

management for the squeezing and condensation of ammonia from ammoniacal vapors containing water vapor. Download PDF

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Publication number
PL69B1
PL69B1 PL69A PL6919A PL69B1 PL 69 B1 PL69 B1 PL 69B1 PL 69 A PL69 A PL 69A PL 6919 A PL6919 A PL 6919A PL 69 B1 PL69 B1 PL 69B1
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PL
Poland
Prior art keywords
column
ammonia
water vapor
vapors
under
Prior art date
Application number
PL69A
Other languages
Polish (pl)
Filing date
Publication date
Application filed filed Critical
Publication of PL69B1 publication Critical patent/PL69B1/en

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Description

Nowa metoda odnosi sie do koncen¬ trowania i równoczesnego skraplania amo¬ njaku z par amonjakalnych, zawierajacych pare wodna. Zasada tej metody polega na tem, ze gorace pary amonjakalne za¬ wierajace pare wodna, znajdujace sie pod cisnieniem wyzszem niz atmosferyczne, wprowadza sie od dolu do prostopadle stojacej kolumny, napelnionej materja- lem drobnoziarnistym o duzej powierz¬ chni, przyczem spadek temperatury po¬ trzebny do deflegmacji uzyskuje sie przez wprowadzanie odpowiedniej ilosci zimnej wody, splywajacej w kolumnie z góry na dól. Bogate w amonjak pary, zbierajace sie w górnej czesci kolumny, odprowadza sie wentylem stozkowym do chlodnicy równiez pod cisnieniem pozostajacej, chlo¬ dzonej zimna woda, przyczem amonjak ulega skropleniu.Azeby kondensat wodny zbierajacy sie u dolu kolumny, który skutkiem stykania sie z parami amonjaku zawiera jeszcze nieco amonjaku, w zupelnosci od niego uwolnic, prowadzi sie tenze kondensat do drugiej kolumny z drobnoziarnistem wy- pelnieniem,ustawionej najlepiej pod pierw¬ sza, przyczem wedlug zasady przeciwpra- du dopuszcza sie do kolumny pod cisnie¬ niem czysta pare wodna.Skutkiem takiego postepowania naste¬ puje latwe i tanie a zarazem zupelne od¬ dzielenie i równoczesne skroplenie amo¬ niaku ze stojacych pod cisnieniem par amonjakalnych, obficie zmieszanych z pa¬ ra wodna, pochodzacych z urzadzen otrzy¬ mywania amonjaku.Do wykonywania tej metody sluzy apa¬ rat, przedstawiony na zalaczonym sche-matycznym rysunku w jednej z mozliwych form wykonania.Obie kolumny, potrzebne do wykona¬ nia opisanej metody, sa polaczone w je¬ dna kolumne podwójna i, podzielona po¬ srodku przy pomocy dna rusztowego £,' podtrzymujacego wypelnienie górnej ko¬ lumny. Wypelnienie dolnej czesci kolumny spoczywa równiez na dnie w ksztalcie rusztu 3. Wilgotne pary amonjaku wpro¬ wadza sie wentylem A pod srodkowe dno rusztowe £, czysta zas pare wodna wpro¬ wadza sie pod dolne dno rusztowe 3 wen¬ tylem o.Zimna woda doplywa do górnej czesci górnej kolumny przy pomocy pierscienia rozdzielczego 6. Pary amonjakalne odpro¬ wadza sie wentylem stozkowym 7 do chlo¬ dnicy wodnej 8, gdzie amonjak ulega skro¬ pleniu i w stanie cieklym odplywa do dol¬ nego zbiornika 9.Kolumne podwójna 1 laczy sie z ma¬ nometrem 10} chlodnice zas 8 z manome¬ trem 11. Nieskroplone gazy, jak powietrze i t. p., mozna odpuscic wentylem 12, Amo¬ njak skroplony odpuszcza sie rura zgie¬ ta ku dolowi zbiornika 9, opatrzona wen¬ tylem 13. Wode zbierajaca sie na dnie zbiornika 9 mozna usuwac wentylem 14, Kondensat wodny pozbawiony amonjaku odprowadza sie wentylem automatycznym 15. Temperature par amoniakalnych, prze¬ dostajacych sie z kolumny podwójnej do chlodnicy,mozna mierzyc termometrem 16. PL PLThe new method relates to the concentration and the simultaneous condensation of ammonia from ammoniacal vapors containing water vapor. The principle of this method is that hot ammoniacal vapors, containing water vapor, under pressure above atmospheric, are introduced from the bottom into a perpendicular column filled with a large-surface fine-grained material, with a temperature drop after needed for dephlegmation is obtained by introducing an appropriate amount of cold water, flowing down the column from the top. The ammonium-rich vapors that accumulate at the top of the column are discharged through a conical valve to the cooler also under the pressure of the remaining, chilled cold water, and the ammonium condensate condenses through the ammonia. it still contains some ammonia, completely free of it, the condensate is led to the second column with a fine-grained filling, preferably placed under the first, where, according to the principle of countercurrent, pure water vapor is allowed to enter the column under pressure. This procedure is easy and cheap and at the same time complete separation and simultaneous condensation of ammonia from pressurized ammoniacal vapors, abundantly mixed with water vapor, coming from the ammonia preparation equipment. rat, presented in the attached schematic drawing in one of the possible forms of execution. According to the method described, they are combined into one double column and, in the middle, divided by means of a grate bottom supporting the filling of the upper column. The filling of the lower part of the column also rests at the bottom in the shape of the grate 3. The moist ammonia vapors are led through the valve A under the central grate bottom, while the clean water vapor is led under the bottom grate 3 through the rear vent. Cold water flows into the upper part of the upper column by means of a distribution ring 6. Ammoniacal vapors are discharged through a conical valve 7 to a water cooler 8, where the ammonia condenses and flows in a liquid state into the lower reservoir 9. Double column 1 is combined with With ¬ nometer 10} coolers and 8 with manometer 11. Uncondensed gases, such as air and so on, can be released by valve 12, Amon is released as condensed by a pipe bent towards the bottom of the tank 9, provided with a vent 13. Water collecting at the bottom of the tank 9 can be removed with a valve 14, The water condensate without ammonia is discharged through an automatic valve 15. The temperature of ammonia vapors entering the cooler from the double column can be measured with a thermometer 16 . PL PL

Claims (3)

1. Zastrzezenia patentowe: 1. Metoda zgeszczania i skraplania amonjaku z par amonjakalnych, zawiera¬ jacych pare wodna, tern znamienna, ze pary te wprowadza sie pod cisnieniem wyzszem niz atmosferyczne od dolu do kolumny pionowej, z drobnoziarnistem wypelnieniem, o duzej powierzchni, przy- czem chlodzi sie te kolumne wedlug za¬ sady przeciwpradu, a zbierajace sie w gór¬ nej czesci kolumn}^ pary amonjaku ule¬ gaja skropleniu w chlodnicy, pozostajacej równiez pod cisnieniem wyzszem niz atmo¬ sferyczne. 1. Claims: 1. The method of compressing and condensing ammonia from ammoniacal vapors containing water vapor, characterized by the fact that these vapors are introduced at a pressure above atmospheric from the bottom to the vertical column, with fine-grained filling, with a large surface, with - why the columns are cooled according to the principle of countercurrent, and the ammonia vapors accumulating in the upper part of the columns condense in the cooler, which also remains under a pressure higher than the spherical atmosphere. 2. Metoda wedle zastrzezenia 1, tern znamienna, ze ciecz wodna splywajaca do dolnej czesci kolumny deflegmacyjnej, za¬ wierajaca jeszcze nieco amonjaku, wpro¬ wadza sie do drugiej kolumny, z drobno¬ ziarnistem wypelnieniem, o duzej powierz¬ chni, zasilanej od dolu czysta para wodna, przyczem wyparte pary amonjaku musza wracac do kolumny pierwszej. 2. The method according to claim 1, characterized in that the aqueous liquid flowing to the bottom of the dephlegmation column, still containing some ammonia, is fed to the second column, with a fine-grained filling, with a large surface, fed from the bottom. pure water vapor, while the displaced ammonia vapor must return to the first column. 3. Urzadzenie sluzace do wykonania powyzszej metody wedle zastrzezenia 1 i 2, tern znamienne, ze uzywa sie pionowo stojacej kolumny o drobnoziarnistem wy¬ pelnieniu, podzielonej, na dwie czesci, be¬ dacej pod cisnieniem wyzszem niz atmo¬ sferyczne, przyczem pary amonjakalne zmieszane z para wodna wprowadza sie pod dno rusztowe dolnej czesci kolumny, cala zas kolumne podwójna laczy sie w jej górnej czesci przy pomocy wentyla z chlod¬ nica, pozostajaca równiez pod cisnieniem wyzszem niz atmosferyczne.Do opisu paten¬ towego N° 69. | UJ] Wkl GRAF.KCZIANSKICH W WARSZAW,. PL PL3. A device for the implementation of the above method according to claims 1 and 2, characterized by the use of a vertically standing column with a fine-grained filling, divided into two parts, under a pressure higher than the spherical atmosphere, with mixed ammoniacal vapors. The steam is introduced under the grate bottom of the lower part of the column, while the entire double column is connected in its upper part by a valve to the cooler, which is also under higher than atmospheric pressure. To patent description N ° 69. | UJ] Wkl GRAF.KCZIANSKI IN WARSAW. PL PL
PL69A 1919-10-23 management for the squeezing and condensation of ammonia from ammoniacal vapors containing water vapor. PL69B1 (en)

Publications (1)

Publication Number Publication Date
PL69B1 true PL69B1 (en) 1924-05-26

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